NIOBIUM-1% ZIRCONIUM, NATURAL-CIRCULATION, BOILING-POTASSIUM CORROSION LOOP TEST
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BOILING↗
SEARCH · Engineering Papers
Results for “Vacuum Vaporization”
Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.
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Space Suit Material Compatibility with Space Vehicle Coolant PMS-1.5R
During a survey of 82P on February 11, 2023, a shiny substance was detected on the Progress vehicle. The suspected material was PMS-1.5R, a low volatility silicone oil coolant used in the vehicle. Crew exposure to the coolant was a concern as the low volatility would increase residence time, the time a material will stay on a surface after exposure to vacuum. A review of space suit materials revealed several materials with compatibility concerns that could impact Extravehicular Activity (EVA) operations and safety. To understand the risk, space suit materials were exposed to a simulant and tested. This testing provided the basis for rationale generated to continue with EVA operations for US EVA 86 on April 2, 2023. This testing also served as the basis to assess impacts to ISS EMU hardware due to potential contamination brought inside ISS on Russian space suits during RS EVA 61 on October 25, 2023, following an ISS Russian Multipurpose Lab Module (MLM) radiator leak of the same fluid on October 9, 2023. This paper will discuss the testing performed and analyze test results impacts to EVA operations. Additional work was conducted to determine coolant evaporation rates in space vacuum and demonstrate that no significant unreacted coolant from the MLM leak would remain on ISS surfaces long enough to contaminate the EMU or affect the ISS ECLSS water separator.
Space Suit Materials↗
Europa Propulsion Valve Seat Material Testing
The Europa mission and spacecraft design presented unique challenges for selection of valve seat materials that met the fluid compatibility requirements, and combined fluid compatibility and high radiation exposure level requirements. The Europa spacecraft pressurization system valves will be exposed to fully saturated propellant vapor for the duration of the mission. The effects of Nitrogen Tetroxide (NTO) and Monomethylhydrazine (MMH) propellant vapors on heritage valve seat materials, such as Vespel SP-1 and Polychlorotrifluoroethylene (PCTFE), were evaluated to determine if an alternate material is required. In liquid system applications, Teflon is the only available compatible valve seat material. Radiation exposure data for Teflon in an air or vacuum environment has been previously documented. Radiation exposure data for Teflon in an oxidizer environment such as NTO, was not available, and it was unknown whether the effects would be similar to those on air-exposed samples. Material testing was conducted by Marshall Space Flight Center (MSFC) and White Sands Test Facility (WSTF) to determine the effects of propellant vapor on heritage seat materials for pressurization valve applications, and the effects of combined radiation and NTO propellant exposure on Teflon. The results indicated that changes in heritage pressurization valve seat materials' properties rendered them unsuitable for the Europa application. The combined radiation and NTO exposure testing of Teflon produced results equivalent to combined radiation and air exposure results.
Brad M Addona↗
EnergyPlus Building Energy Simulations of High-Performance Vapor-Compression Based Cold Climate Water Heaters
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Zhang, Mingkan [ORNL] (ORCID:000000022224698X)↗
Improving PBL Temperature and Water Vapor Information by Combining Hyperspectral MW and IR Sounders with Active Lidar Measurements
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SiFSAP↗
Vaporization Would Cool Primary Battery
Temperature of discharging high-power-density primary battery maintained below specified level by evaporation of suitable liquid from jacket surrounding battery, according to proposal. Pressure-relief valve regulates pressure and boiling temperature of liquid. Less material needed in cooling by vaporization than in cooling by melting. Technique used to cool batteries in situations in which engineering constraints on volume, mass, and location prevent attachment of cooling fins, heat pipes, or like.
Bhandari, Pradeep↗
The Detection of Water Vapor on Mars
We have found eleven weak lines of water vapor on a high dispersion near-infrared spectrogram of Mars taken at the coudè focus of the Mount Wilson 100-inch reflector on April 12/13,1963. We exposed 43 hours on ammoniated IV-N emulsion with a dispersion of 5.6 A/mm; the plate is well exposed at the poles and somewhat overexposed at the center of the planet’s disk. The Martian H 2 O lines in the X 8200 water-vapor band are displaced 0.42 A longward of their telluric counterparts due to the relative velocities of the earth and Mars: AV = +15 km/sec on that date. The Martian lines are strongest over the poles of the planet-we set the spectrograph slit daost north-south to cover both polar regions. This apparent polar strengthening of the Martian H 2 O lines is at least partially due to the increased air mass through the line of sight to high latitudes.
MARS /PLANET/↗
Validation of Accurate Cryogenic Fluid Vapor-Liquid Boundary Conditions Via Molecular Simulations
Vapor-liquid interfaces drive many important phenomena in cryogenic fluid management, including heat transfer, evaporation, and capillary flow. Design of cryogenic fluid systems, such as propellant storage, requires accurate predictions of fluid behavior, including evaporation rates. Many models have been proposed for heat and mass transfer at vapor liquid interfaces, but the accuracy of these models in the context of cryogenic fluids has not been performed. We use molecular dynamics simulations, which allow for nanometer scale resolution of fluid phenomena, to evaluate the accuracy of a variety of vapor-liquid boundary conditions at evaporating and condensing interfaces. We find that an anisotropic temperature distribution is a critical ingredient for accurate prediction of intensive evaporation and condensation.
Daniel Vigil↗
The Significance of Water Vapor Isotopes in Improving Weather Prediction
Water vapor isotopes carry the integrated history of evaporation, condensation, mixing, and transport. Although previous studies have shown potential to improve forecasts under controlled conditions, real-world applications have been limited by systematic biases in both models and satellite retrievals arising from sparse measurements in the free troposphere. Here we assimilate mid‑tropospheric δD retrievals (peak sensitivity ~4.2 km) from the Infrared Atmospheric Sounding Interferometer into the Isotope‑incorporated Global Spectral Model and evaluate the added value beyond co‑assimilated temperature and specific humidity with identical spatial and temporal coverage. Assimilating δD improves 0–120 h forecasts of wind, temperature, specific humidity, and geopotential height, with the largest gains in the midlatitudes; heavy‑precipitation skill also increases for thresholds >3 mm per 6 h. Demonstrated in a coarse‑resolution configuration with limited observations, the results indicate that isotopic information strengthens transport tracking and hydrological constraints, motivating evaluation in operational high‑resolution forecasting systems.
Hydrology↗
Vapor Transport Crystal Growth of Mercury-Cadmium-Telluride in Microgravity
Two epitaxial growth experiments of Hg 1-x Cd x Te layers on (100) CdTe substrates in closed ampoules using HgI 2 as a transport agent have been performed during the USML-1 mission. The characterization results to date demonstrate a considerable improvement of the space-grown epitaxial layers relative to ground-control specimens in terms of morphology, compositional uniformity, and structural micro homogeneity. These results show the effects of microgravity and fluid dynamic disturbances on-ground on the deposition and growth processes. The continued analysis of this technologically important system is designed to further elucidate the observed crystallographic improvements and their relation to mass flow.
Heribert Wiedemeier↗
Enhancement of Superconductivity in WP via Oxide-Assisted Chemical Vapor Transport
Tungsten monophosphide (WP) has been reported to superconduct below 0.8 K, and theoretical work has predicted an unconventional Cooper pairing mechanism. Here we present data for WP single crystals grown by means of chemical vapor transport (CVT) of WO3, P, and I2. In comparison to synthesis using WP powder as a starting material, this technique results in samples with substantially decreased low-temperature scattering and favors a more three-dimensional morphology. We also find that the resistive superconducting transitions in these samples begin above 1 K. Variation in Tc is often found in strongly correlated superconductors, and its presence in WP could be the result of influence from a competing order and/or a non-s-wave gap.
Chemistry↗
Salt‐Assisted Vapor–Liquid–Solid Growth of 1D van der Waals Materials
The method of salt-assisted vapor–liquid–solid (VLS) growth is introduced to synthesize 1D nanostructures of trichalcogenide van der Waals (vdW) materials, exemplified by niobium trisulfide (NbS 3 ). The method uses a unique catalyst consisting of an alloy of Au and an alkali metal halide (NaCl) to enable rapid and directional growth. High yields of two types of NbS 3 1D nanostructures, nanowires and nanoribbons, each with sub-ten nanometer diameter, tens of micrometers length, and distinct 1D morphology and growth orientation are demonstrated. Strategies to control the location, size, and morphology of growth, and extend the growth method to synthesize other transition metal trichalcogenides, NbSe 3 and TiS 3 , as nanowires are demonstrated. Finally, the role of the Au–NaCl alloy catalyst in guiding VLS synthesis is described and the growth mechanism based on the relationships measured between structure (growth orientation, morphology, and dimensions) and growth conditions (catalyst volume and growth time) is discussed. These results introduce opportunities to expand the library of emerging 1D vdW materials to make use of their unique properties through controlled growth at nanoscale dimensions.
1D van der Waals material↗
Effect of Oxidizing Impurities on the Corrosion Behavior of Structural Alloys Exposed to MgCl 2 Molten Salt Vapor
The corrosion behavior of structural alloys SS304 and IN617 when exposed to vapors of MgCl 2 molten salt at 764 °C for 100 h in an argon atmosphere was investigated as a function of the level of oxidizing impurities (e.g., NaOH) present in the salt. Increasing the concentration of oxidizing impurities in the salt caused an increase in corrosion in both structural alloys, as measured by Cr depletion layers. A poorly adhered oxide scale layer containing Mg, Al, and Cr was observed on the surface of the metals, and local attack was observed as well. The Ni-based IN617 showed lower Cr depletion and less scale formation than the Fe-based SS304. These results demonstrate that oxidizing impurities in the molten salt will impact the vapor phase corrosion for structural members exposed to the molten salt headspace. This finding is highly relevant for understanding the effects of the vapor phase in molten salt applications, including molten salt thermal energy storage, molten salt nuclear reactors, and molten salt electrochemistry.
25 ENERGY STORAGE↗
Reduced Order Models for Liquid Hydrogen Pooling and Vaporization Supported by Experiments
In the event of a leak of liquid hydrogen, a pool can form that vaporizes, disperses, and eventually dilutes to a non-flammable mixture. In this work, we describe fast-running models for the pooling and vaporization of liquid hydrogen in a steady cross-wind. Several pooling models from the literature are compared to solve for the flow and extent of the pool. The size of the pool can serve as the source for a separate dispersion model, which builds upon the existing one-dimensional Gaussian plume model in HyRAM+. Additional terms for the effects of a cross-wind on momentum and entrainment were added so that the model could handle the effects of a cross-wind on a low-speed flow. The models are compared to experimental data on pooling extent and downwind dispersion for steady flow rates of liquid hydrogen in a steady cross-wind. In the two compared experiments, liquid flow rates of 15 and 45 g/s were spilled onto concrete in cross-winds of approximately 1.8 m/s. The rate of growth of the pool and the downwind concentration boundaries are compared to the models, showing good agreement, although additional tuning is needed. These models can contribute to the advancement of codes and standards for liquid hydrogen systems.
dispersion↗
Amphiphilic nanopores that condense undersaturated water vapor and exude water droplets
Condensation of water vapor in confined geometries, known as capillary condensation, is a fundamental phenomenon with far-reaching implications. While hydrophilic pores enable liquid formation from undersaturated vapor without energy input, the condensate typically remains confined, limiting practical utility. Here, we explore the use of amphiphilic nanoporous polymer-infiltrated nanoparticle films that condense and release liquid water under isothermal and undersaturated conditions. By tuning the polymer fraction and nanoparticle size, we optimize condensation and droplet formation. As vapor pressure increases, voids fill with condensate, which subsequently exudes onto the surface as microscopic droplets. This behavior, enabled by a balance of polymer hydrophobicity and capillarity, reveals how amphiphilic nanostructures can drive accessible water collection. Our findings provide design insights for materials supporting energy-efficient water harvesting and heat management without external input.
Science & Technology - Other Topics↗
A Case Study of AI-assisted Creation of a Thermodynamics Model of Precipitation Formation During Rapid Depressurization of a Vented Container
Precipitation may form in humid containers undergoing rapid depressurization. This precipitation may be liquid, i.e. fog, if the dewpoint is crossed above the freezing point of water, or direct snow crystallization if the dewpoint is crossed below the freezing point. Accurate modeling of this effect is potentially important for rapidly ascending vented containers in aircraft, spacecraft, and launch vehicles, as well as rapidly depressurizing vacuum chambers. A transient thermodynamics model of precipitation formation during the rapid depressurization of a container was developed in python. The model is written for a generic container and includes an optional water pool and water vapor source. Details of the model and results from several example cases spanning the full capabilities of the model, including a validation case, will be presented. Although the model is not novel, in contrast to prior works, this one was treated as a case study of the assistance of AI Large Language Models (LLMs) to create physical models. Impressions, performance, time, and cost of using AI for this task will be discussed.
precipitation↗
Recirculating and Sub-Atmospheric Rapid Cycle Amine Swing Bed Testing at Various Metabolic Profiles, Temperatures, and Half-Cycle Times
Sixty years since the first spacewalk, NASA’s Extravehicular Mobility Unit (xEMU) exploration space suit has undergone numerous design improvements and iterations. As commercial manufacturers develop next-generation systems to support increasingly complex missions, including Moon-to-Mars architecture prototyping and the design of the Martian Portable Life Support System (PLSS), material selection and individual subunit testing under realistic metabolic and pressure conditions are paramount. To determine whether a reusable carbon dioxide (CO 2 ) scrubber design and adsorbent can be utilized in new suit configurations, an all-encompassing test rig is required to compare existing and newly developed technologies. The test rig must be capable of sub-atmospheric testing, calibrated humid CO 2 dosing, and facilitation of the evaluation of sorbents across a wide range of operational requirements. Recently, XploSafe has developed an Extravehicular Mobility Unit (xEMU) testing rig specifically designed to explore CO 2 and humidity control materials for spacesuits. This closed-loop recirculating swing bed (Rapid Cycle Amine Test Rig) was utilized to compare adsorbent utility across a wide range of xEMU operating conditions. Following successful testing with Xplo-SA9T over multiple simulated eight-hour Extravehicular Activity (EVA) tests, improvements to the test stand were considered. Regeneration vacuum supply within the test rig was updated to more closely resemble space vacuum, theoretically increasing half-cycle timing. An improved water vapor delivery system was incorporated to dose a wider calibrated range of humidity over both short and long-duration EVAs. A range of metabolic profiles between 800 and 3000 BTU/h were tested, and the corresponding average CO 2 steady-states were compared. The effect of dosing temperature at the adsorbent bed inlet between 10 and 40 ̊C and the corresponding CO 2 removal efficiency was also evaluated.
John R Tidwell↗
Vapor-phase pillarization of MXenes for engineering hierarchical interlayer porosity
MXenes, a family of two-dimensional (2D) multilamellar materials, possess excellent thermal and electronic properties for a range of applications. Their use in heterogeneous catalysis, however, is limited by the low surface area resulting from stacked layers. Pillarization with inorganic oxides can create more open, mesoporous MXene structures, improving accessibility for guest species to diffuse, reside or react in the space between 2D layers. A previous liquid-phase pillarization method, however, involves excessive use of solvent-based precursors and multiple processing steps. Here, we report a vapor-phase pillarization (VPP) strategy to introduce pillars, exemplified by silica pillars, with high pillar precursor usage efficiency and a simplified processing workflow. The resulting silica-pillared mesoporous MXene exhibits significantly increased surface area and porosity. These textural properties can be easily tuned by the VPP synthesis conditions. When applied as a ruthenium (Ru) catalyst support for the hydrogenolysis of low-density polyethylene (LDPE), the silica-pillared MXene enabled high Ru dispersion and catalytic activity. This study highlights the potential of the VPP method for engineering mesoporous, 2D MXene materials and demonstrates the effectiveness of mesoporous MXene as a catalyst support in overcoming mass transport and active-site accessibility challenges in heterogeneous catalysis involving bulky substances, such as plastics upcycling.
Luo, Song [University of Delaware, Newark, DE (Uni↗