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At least 415 records · Page 23

The impact of increasing stratospheric radiative damping on the quasi-biennial oscillation period

Stratospheric radiative damping increases as atmospheric carbon dioxide concentration rises. We use the one-dimensional mechanistic models of the quasi-biennial oscillation (QBO) to conduct sensitivity experiments and find that the simulated QBO period shortens due to the enhancing of radiative damping in the stratosphere. This result suggests that increasing stratospheric radiative damping due to rising CO2 may play a role in determining the QBO period in a warming climate along with wave momentum flux entering the stratosphere and tropical vertical residual velocity, both of which also respond to increasing CO2.

Stratospheric Radiative Damping↗

Volcanic Stratospheric Injections up to 160 Tg(S) Yield a Eurasian Winter Warming Indistinguishable from Internal Variability

Early observational and modeling work suggested that low-latitude volcanic eruptions, comparable to the one of Pinatubo in 1991 or Krakatau in 1883, cause substantial surface warming over the northern continents at mid-latitudes in winter. The proposed mechanism consists of the formation of an anomalously strong Equator-to-pole temperature gradient in the stratosphere due to the presence of volcanic aerosols in the tropics, which are accompanied by an acceleration of the stratospheric polar vortex, which then shifts the Northern Annular Mode into a positive phase, resulting in warming surface temperatures over Eurasia. However, a large body of research in the past decade has shown that, for eruptions such as Pinatubo or Krakatau, no such warming is seen in simulations with more recent climate models which, in general, have much finer vertical and horizontal resolution than the early ones, and which have separated the forced response from the internal variability by using large ensembles of integrations. Since the proposed physical mechanism is sound, it is then possible that eruptions comparable to those of Pinatubo or Krakatau are simply too weak, but even larger ones might indeed be capable of causing Eurasian surface warming in winter. In this study, we explore this possibility using a state-of-the-art, stratosphere-resolving climate model, forced with prescribed aerosols from the Easy Volcanic Aerosol protocol. We consider eruptions with stratospheric sulfur injections of 5, 10, 20, 40, 80, and 160 Tg(S). With 20-member ensembles, we find that with injections of 20 Tg(S) or more – roughly twice the amplitude of the Pinatubo and Krakatau eruptions – our model simulates a winter surface warming over Eurasia, which is statistically significant with a t test given our 20-member ensembles. However, the forced volcanic signal on Eurasian winter surface temperatures is very small, barely exceeding the 1σ range of internal variability for the 160 Tg(S) injection case, and much smaller for smaller eruptions. Most importantly, the number of eruptions needed to establish statistical significance is considerably larger than the number of eruptions known to have occurred in the past 2000 years.

Volcanic eruptions↗

Impact of Biomass Burning and Stratospheric Intrusions in the Remote South Pacific Ocean Troposphere

The ozone mixing ratio spatiotemporal variability in the pristine South Pacific Ocean is studied, for the first time, using 21-year-long ozone (O3) records from the entire southern tropical and subtropical Pacific between 1994 and 2014. The analysis considered regional O3 vertical observations from ozonesondes, surface carbon monoxide (CO) observations from flasks, and three-dimensional chemistry-transport model simulations of the global troposphere. Two 21-year-long numerical simulations, with and without biomass burning emissions, were performed to disentangle the importance of biomass burning relative to stratospheric intrusions for ambient ozone levels in the region. Tagged tracers of O3 from the stratosphere and CO from various biomass burning regions have been used to track the impact of these different regions on the southern tropical Pacific O3 and CO levels. Patterns have been analyzed based on atmospheric dynamics variability. Considering the interannual variability in the observations, the model can capture the observed ozone gradients in the troposphere with a positive bias of 7.5 % in the upper troposphere/lower stratosphere (UTLS) as well as near the surface. Remarkably, even the most pristine region of the global ocean is affected by distant biomass burning emissions by convective outflow through the mid and high troposphere and subsequent subsidence over the pristine oceanic region. Therefore, the biomass burning contribution to tropospheric CO levels maximizes in the UTLS. The Southeast Asian open fires have been identified as the major contributing source to CO from biomass burning in the tropical South Pacific, contributing on average for the study period about 8.5 and 13 ppbv of CO at Rapa Nui and Samoa, respectively, at an altitude of around 12 km during the burning season in the spring of the Southern Hemisphere. South America is the second-most important biomass burning source region that influences the study area. Its impact maximizes in the lower troposphere (6.5 ppbv for Rapa Nui and 3.8 ppbv for Samoa). All biomass burning sources contribute about 15–23 ppbv of CO at Rapa Nui and Samoa and account for about 25 % of the total CO in the entire troposphere of the tropical and subtropical South Pacific. This impact is also seen on tropospheric O3, to which biomass burning O3 precursor emissions contribute only a few ppbv during the burning period, while the stratosphere–troposphere exchange is the most important source of O3 for the mid troposphere of the South Pacific Ocean, contributing about 15–20 ppbv in the subtropics.

Tropospheric ozone↗

Projecting the Lasting Fate of the Hunga Tonga-Hunga Ha’apai Eruption on the Stratosphere through Connecting Measurements to Models

On 15th Jan. 2022 the submarine volcano Hunga Tonga-Hunga Ha’apai (HTHH) injected approximately 0.5 Tg of sulfur dioxide into the stratosphere, but more significantly added 150-170 Tg of water vapor to the stratospheric background (over a 10% perturbation) in a matter of several hours. The sulfur dioxide rapidly converted to sulfate aerosol and along with water vapor, was transported around the Southern Hemisphere sub-tropics into midlatitudes with some transport into the Northern Hemisphere. With a much longer lifetime than sulfate aerosol, measurable water vapor anomalies are likely to persist for the remainder of the decade. Satellite measurements from limb and nadir viewing observing instruments provide the information needed to reasonably initialize the HTHH eruption in the Goddard Earth Observing System (GEOS) model using the “replay” framework coupled to the Global Modeling Initiative (GMI) stratosphere-troposphere chemical mechanism for the recent past and continue the simulations into the future with the free running chemistry climate model (CCM). Using a number of model ensemble members together with the satellite observations, we are beginning to quantify how the HTHH eruption is perturbing stratospheric composition and climate and projecting the influences to come as the enhanced water vapor continues to spread globally with only very slow removal mechanisms. We will also discuss some of the future measurement needs to understand how the atmosphere is responding to events like the HTHH eruption, large wildfires, and a changing climate.

volcano↗

Unexpected Repartitioning of Stratospheric Inorganic Chlorine after the 2020 Australian Wildfires

The inorganic chlorine (Cl y ) and odd nitrogen (NO y ) chemical families influence stratospheric O 3 . In January 2020 Australian wildfires injected record-breaking amounts of smoke into the southern stratosphere. Within 1-2 months ground-based and satellite observations showed Cl y and NO y were repartitioned. Compared to decadal means, lower stratospheric (LS) HCl columns declined by ~30% between March and May while ClONO 2 columns increased by 40-50%. The Cl y perturbations recovered from June to October. The LS NO 2 decreased from February to April, consistent with sulfate aerosol reactions, but returned to typical values by June - months earlier than the Cl y recovery. Transport tracers show an air mass change explains the observed O 3 decrease after April. Simulations assuming wildfire smoke behaves identically to sulfate aerosols couldn’t reproduce observed Cl y changes, suggesting that their composition and chemistry differs from sulfate aerosols. This undermines our ability to predict ozone in a changing climate.

middle atmosphere chemistry and composition↗

The Lack of Evidence on the Madden–Julian Oscillation to Drive Its Relationship With the Quasi–Biennial Oscillation Through Modulation of Stratospheric Wave Activity

Previous studies have found that Madden-Julian Oscillation (MJO) amplitude depends on the Quasi-Biennial Oscillation (QBO) during boreal winter. This MJO-QBO relationship is important to realizing subseasonal-to-seasonal prediction skills, but the underlying mechanism remains unclear. It is often thought that this relationship arises through the modulation of the upper-troposphere and lower-stratosphere lapse rate by the QBO, but this mechanism assumes the one-way impact of the QBO onto the MJO. Alternatively, the MJO can be hypothesized to influence the QBO by modulating stratospheric wave activity that is known to be critical to QBO dynamics. Therefore, using satellite and reanalysis data, this study examines whether MJO monthly activity can impact stratospheric wave activity and QBO downward propagation speed. The results depicted a lack of such impacts, suggesting this observed MJO-QBO relationship cannot be driven by the MJO modulation of stratospheric wave forcing.

54 ENVIRONMENTAL SCIENCES↗

Stratospheric Climate Anomalies and Ozone Loss Caused by the Hunga Tonga-Hunga Ha'apai Volcanic Eruption

We report the Hunga Tonga-Hunga Ha'apai (HTHH) volcanic eruption in January 2022 injected unprecedented amounts of water vapor (H 2 O) and a moderate amount of the aerosol precursor sulfur dioxide (SO 2 ) into the Southern Hemisphere (SH) tropical stratosphere. The H 2 O and aerosol perturbations have persisted during 2022 and early 2023 and dispersed throughout the atmosphere. Observations show large-scale SH stratospheric cooling, equatorward shift of the Antarctic polar vortex and slowing of the Brewer-Dobson circulation. Satellite observations show substantial ozone reductions over SH winter midlatitudes that coincide with the largest circulation anomalies. Chemistry-climate model simulations forced by realistic HTHH inputs of H 2 O and SO 2 qualitatively reproduce the observed evolution of the H 2 O and aerosol plumes over the first year, and the model exhibits stratospheric cooling, circulation changes and ozone effects similar to observed behavior. The agreement demonstrates that the observed stratospheric changes are caused by the HTHH volcanic influences.

58 GEOSCIENCES↗

Limited surface impacts of the January 2021 sudden stratospheric warming

Subseasonal weather prediction can reduce economic disruption and loss of life, especially during “windows of opportunity” when noteworthy events in the Earth system are followed by characteristic weather patterns. Sudden stratospheric warmings (SSWs), breakdowns of the winter stratospheric polar vortex, are one such event. They often precede warm temperatures in Northern Canada and cold, stormy weather throughout Europe and the United States - including the most recent SSW on January 5th, 2021. Here we assess the drivers of surface weather in the weeks following the SSW through initial condition “scrambling” experiments using the real-time CESM2(WACCM6) Earth system prediction framework. We find that the SSW itself had a limited impact, and that stratospheric polar vortex stretching and wave reflection had no discernible contribution to the record cold in North America in February. Instead, the tropospheric circulation and bidirectional coupling between the troposphere and stratosphere were dominant contributors to variability.

54 ENVIRONMENTAL SCIENCES↗

Stratospheric aerosol injection can weaken the carbon dioxide greenhouse effect

Abstract Stratospheric aerosol injection is a proposed method for offsetting greenhouse gas-induced warming by introducing scattering aerosols into the lower stratosphere to reflect sunlight. Here we explore a potentially more efficient alternative: weakening the Earth’s greenhouse effect by deploying absorptive aerosols in the upper stratosphere (~10 hPa). These aerosols warm the carbon dioxide emission level—where outgoing longwave radiation is most sensitive to temperature—thereby enhancing top-of-atmosphere infrared emission without altering atmospheric carbon dioxide concentrations. Idealized climate model simulations indicate that this approach can reduce global temperatures an order of magnitude more efficiently per unit aerosol mass than conventional scattering-based interventions. Although based on simplified model experiments lacking interactive aerosol processes and operational constraints, our results identify a distinct physical mechanism for climate intervention, arguing for further research into the impacts—especially potential unintended side effects—of injecting absorptive aerosols into the upper stratosphere as an alternative solar radiation management strategy.

Environmental Sciences & Ecology↗

Harnessing stratospheric diffusion barriers for enhanced climate geoengineering

Stratospheric sulfate aerosol geoengineering is a proposed method to temporarily intervene in the climate system to increase the reflectance of shortwave radiation and reduce mean global temperature. In previous climate modeling studies, choosing injection locations for geoengineering aerosols has, thus far, only utilized the average dynamics of stratospheric wind fields instead of accounting for the essential role of time-varying material transport barriers in turbulent atmospheric flows. Here we conduct the first analysis of sulfate aerosol dispersion in the stratosphere, comparing what is now a standard fixed-injection scheme with time-varying injection locations that harness short-term stratospheric diffusion barriers. We show how diffusive transport barriers can quickly be identified, and we provide an automated injection location selection algorithm using short forecast and reanalysis data. Within the first 7 d days of transport, the dynamics-based approach is able to produce particle distributions with greater global coverage than fixed-site methods with fewer injections. Additionally, this enhanced dispersion slows aerosol microphysical growth and can reduce the effective radii of aerosols up to 200–300 d after injection. While the long-term dynamics of aerosol dispersion are accurately predicted with transport barriers calculated from short forecasts, the long-term influence on radiative forcing is more difficult to predict and warrants deeper investigation. Statistically significant changes in radiative forcing at timescales beyond the forecasting window showed mixed results, potentially increasing or decreasing forcing after 1 year when compared to fixed injections. We conclude that future feasibility studies of geoengineering should consider the cooling benefits possible by strategically injecting sulfate aerosols at optimized time-varying locations. Our method of utilizing time-varying attracting and repelling structures shows great promise for identifying optimal dispersion locations, and radiative forcing impacts can be improved by considering additional meteorological variables.

54 ENVIRONMENTAL SCIENCES↗

Long-range prediction and the stratosphere

Abstract. Over recent years there have been concomitant advances in the development of stratosphere-resolving numerical models, our understanding of stratosphere–troposphere interaction, and the extension of long-range forecasts to explicitly include the stratosphere. These advances are now allowing for new and improved capability in long-range prediction. We present an overview of this development and show how the inclusion of the stratosphere in forecast systems aids monthly, seasonal, and annual-to-decadal climate predictions and multidecadal projections. We end with an outlook towards the future and identify areas of improvement that could further benefit these rapidly evolving predictions.

54 ENVIRONMENTAL SCIENCES↗

Stratospheric ozone

The photochemical and transport processes in the earth stratosphere are discussed. The effects of certain trace constituents such as water vapor and oxides of nitrogen on the stratospheric ozone distribution are analyzed. The changes in the surface ultraviolet radiation levels which result from changes in the chemical composition in the stratosphere are examined. The influences of absorption and scattering of ultraviolet radiation on the thermal structure of the stratosphere are explained.

Stewart, R. W.↗

A study of the energetics of an upper stratospheric warming /1969-1970/.

Results of stratospheric hemispheric synoptic analyses at the 10-, 5-, and 2-mb levels for seven days during an intense warming. Employing these analyses along with the daily objective analyses from 1000-30 mb, some of the major energy transformations for the troposphere and lower and middle stratosphere were computed. It was found that the middle stratospheric warming event was of a direct baroclinic type, forced from below. It was noted that if the warming is to propagate into the lower stratosphere, it is necessary to reverse the normal eddy kinetic to eddy potential energy transfer in that region so that it operates in a direct baroclinic sense.

Miller, A. J.↗

Physical properties of the stratospheric aerosols

A comparison of the equilibrium vapor pressure over nitric acid solutions with observed water and nitric acid partial pressures in the stratosphere implies that nitric acid cannot be present as an aerosol particle in the lower stratosphere. A similar comparison for sulfuric acid solutions indicates that sulfuric acid aerosol particles are 75% H2SO4 by weight in water, in good agreement with direct observations. The freezing curve of H2SO4 solutions requires that the H2SO4 aerosol particles be solid or supercooled. The equilibrium vapor pressure of H2SO4 in the stratosphere is of the order of 20 picotorr. At stratospheric temperatures, ammonium sulfate is in a ferroelectric phase. As a result, polar molecules may form a surface coating on these aerosols, which may be a fertile ground for further chemical reaction.

Toon, O. B.↗

A study of the effect of stratospheric aerosols produced by SST emissions on the albedo and climate of the earth

Hypothesized fleets of supersonic aircraft, flying at stratospheric altitude, may lead to a significant increase in the aerosol population of the stratosphere. Exact multiple scattering calculations have been carried out to determine the response of the earth's albedo to an increase of the stratospheric aerosol optical depth. It is found that a tripling of the aerosol population in the stratosphere, which represents an extreme upper limit to the effects of SST's, results in a 0.6% increase of the earth's reflectivity and a decrease of the mean surface temperature on the order of 0.3 K. Such changes could be marginally significant.

Pollack, J. B.↗

An analysis of the strong zonal circulation within the stratosphere of Venus

A dynamic model is presented for the strong zonal circulation within the stratosphere of Venus which was observed by Mariner 10 and Venera. Rotational effects are neglected, a compressible and radiating atmosphere is considered, and diurnal radiative heating is shown to be negligible in the lower stratosphere (below 85 km). Analysis of the model indicates that propagating internal gravity waves generated by solar heating of the upper stratosphere may induce mean zonal velocities within the upper and lower stratosphere which would have a retrograde direction. The nonlinear equations of motion and energy are solved by an approximate analytical method to determine the magnitude of the zonal velocity, which is found to increase from zero at the tropopause to about 200 m/sec at the 85-km level. The calculated velocity near the UV cloud level compares favorably with the observed value of 100 m/sec.

Ramanathan, V.↗

Minor constituents in the stratosphere and mesosphere

This paper is a brief survey of a portion of the research on trace constituents in the stratosphere and mesosphere between 1971 and 1974. A primary motivation for much of the stratospheric research came from the realization that man's activities may influence global climate and the atmospheric ozone content, our shield against certain UV wavelengths. A great deal of progress has been reported in understanding both the present background stratosphere and the responses to be expected from additions of nitrogen oxides, water, and chlorine oxides, especially with respect to ozone. Trace constituents in the mesosphere have been modeled and measured to increase our understanding of the physics and chemistry of the mesosphere but also to relate mesospheric composition and transport to ionospheric processes at higher altitudes, to D region ion chemistry, and to upper stratospheric composition.

Cicerone, R. J.↗

Study of the lower stratospheric thermal structure and total ozone from Nimbus-4 IRIS

The global distribution of temperature in the stratosphere from 100 to 10 mbar and the total ozone in the atmosphere are remotely sensed from the Nimbus-4 IRIS measurements for a period of about one year. The temperature and ozone data are presented in the form of monthly mean global maps. The standard deviations of temperature and ozone with respect to zonal averages are calculated. The mean and the variable state of the stratosphere are discussed with the help of these observations. The lower stratosphere in the tropical regions reveals a significant wave number one pattern in the circulation. The Arctic and Antarctic stratospheric winter circulation regimes display a different behavior apparently due to the ocean and orographic differences.

Prabhakara, C.↗