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Turco, R. P.

Publications and source records attributed to Turco, R. P..

At least 55 records · Page 3

Simulation studies of the physical and chemical processes occurring in the stratospheric clouds of the Mount St. Helens eruptions of May and June 1980

The large and diverse set of observational data collected in the high-altitude clouds of May 18, May 25, and June 13, 1980 was organized and analyzed for trends which reveal the processes at work. The data were used to guide and constrain model simulations of the volcanic eruptions. A comprehensive one-dimensional model of stratospheric sulfate aerosols, sulfur precursor gases, and volcanic ash and dust particles is utilized which accounts for homogeneous and heterogeneous chemistry in the clouds, aerosol nucleation and growth, and cloud expansion. Computational results are given for the time histories of the gaseous species concentrations, sulfate aerosol size dispersions, and ash burdens in the eruption clouds. The long-term buildup of stratospheric aerosols in the Northern Hemisphere and the persistent effects of injected chlorine and water vapor on ozone are discussed. It is concluded that SO2, water vapor, and ash are the most important substances injected by the volcano into the stratosphere, with respect to both the widespread effects on composition and the impact on climate. It is found that the volcano probably had little influence on the climate ( 0.05 K global surface cooling) or on stratospheric ozone ( 0.2 percent maximum hemispherical reduction).

Turco, R. P.

Space Shuttle ice nuclei

Estimates are made showing that, as a consequence of rocket activity in the earth's upper atmosphere in the Shuttle era, average ice nuclei concentrations in the upper atmosphere could increase by a factor of two, and that an aluminum dust layer weighing up to 1000 tons might eventually form in the lower atmosphere. The concentrations of Space Shuttle ice nuclei (SSIN) in the upper troposphere and lower stratosphere were estimated by taking into account the composition of the particles, the extent of surface poisoning, and the size of the particles. Calculated stratospheric size distributions at 20 km with Space Shuttle particulate injection, calculated SSIN concentrations at 10 and 20 km altitude corresponding to different water vapor/ice supersaturations, and predicted SSIN concentrations in the lower stratosphere and upper troposphere are shown.

Turco, R. P.

The ultraviolet absorber on Venus - Amorphous sulfur

It is pointed out that the identity of the chemical species responsible for the yellow coloration of the clouds of Venus and for the dark features which dapple the planet at ultraviolet wavelengths has long been a mystery. Independent pieces of evidence, discovered recently, suggest now that amorphous sulfur is the so-called UV absorber. A review of earlier ideas and controversies is presented, and attention is given to a new physical-chemical model of the Venus clouds which shows that sulfur should form there. A description is provided of physical characteristics of the cloud particles that, in comparison with model predictions, indicate the presence of sulfur. Optical data suggesting that elemental sulfur occurs in the clouds is discussed, and cloud morphological evidence for sulfur is considered.

Toon, O. B.

Stratospheric aerosols - Observation and theory

Important chemical and physical roles of aerosols are discussed, and properties of stratospheric aerosols as revealed by experimental data are described. In situ measurements obtained by mechanical collection and scattered-light detection yield the overall size distribution of the aerosols, and analyses of preserved aerosol precursor gases by wet chemical, cryogenic and spectroscopic techniques indicate the photochemical sources of particle mass. Aerosol chemical reactions including those of gaseous precursors, those in aqueous solution, and those on particle surfaces are discussed, in addition to aerosol microphysical processes such as nucleation, condensation/evaporation, coagulation and sedimentation. Models of aerosols incorporating such chemical and physical processes are presented, and simulations are shown to agree with measurements. Estimates are presented for the potential aerosol changes due to emission of particles and gases by aerospace operations and industrial consumption of fossil fuels, and it is demonstrated that although the climatic effects of existing levels of stratospheric aerosol pollution are negligible, potential increases in those levels might pose a future threat.

Turco, R. P.

An analysis of the physical, chemical, optical, and historical impacts of the 1908 Tunguska meteor fall

An analysis is presented of the physical characteristics and photochemical aftereffects of the 1908 Tunguska explosive cometary meteor, whose physical manifestations are consistent with a five million ton object's entry into the earth's atmosphere at 40 km/sec. Aerodynamic calculations indicate that the shock waves emanating from the falling meteor could have generated up to 30 million tons of nitric oxide in the stratosphere and mesosphere. A fully interactive one-dimensional chemical-kinetics model of atmospheric trace constituents is used to estimate the photochemical consequences of such a large NO injection. The 35-45% hemispherical ozone depletion predicted by the model is in keeping with the 30 + or - 15% ozone variation reported for the first year after the Tunguska fall. Attention is also given to the optical anomalies which followed the event for indications of NO(x)-O(x) chemiluminescent emissions, NO2 solar absorption, and meteoric dust turbidity, along with possible climate changes due to the nearly one million tons of pulverized dust deposited in the mesosphere and stratosphere by the meteor.

Turco, R. P.

The satellite power system - Assessment of the environmental impact on middle atmosphere composition and on climate

Numerical models were developed to calculate the total deposition of watervapor, hydrogen, CO2, CO, SO2, and NO in the middle atmosphere from operation of heavy lift launch vehicles (HLLV) used to build a satellite solar power system (SPS). The effects of the contaminants were examined for their effects on the upper atmosphere. One- and two-dimensional models were formulated for the photochemistry of the upper atmosphere and for rocket plumes and reentry. An SPS scenario of 400 launches per year for 10 yr was considered. The build-up of the contaminants in the atmosphere was projected to have no significant effects, even at the launch latitude. Neither would there by any dangerous ozone depletion. It was found that H, OH, and HO2 species would double in the thermosphere. No measurable changes in climate were foreseen.

Whitten, R. C.

A study of mesospheric rocket contrails and clouds produced by liquid-fueled rockets

Changes in the atmospheric composition, particularly through the condensation of rocket vehicle exhaust, caused by the flights of 400 heavy lift launch vehicles (HLLV) to carry crews and materials into space to build a satellite solar power system (SPS) were examined. Attention was given to the formation of mesospheric contrails and clouds. A one-dimensional model was used to formulate the photochemistry and vertical transport of water vapor, its nucleation into an ice cloud, and the microphysical development of the cloud. Considering one HLLV launch per day for a decade, it is projected that the upper atmosphere water vapor concentration would be increased by 10-20%, thereby augmenting the size and opacity of natural noctilucent clouds by 50%. No climatological consequences are foreseen from the clouds, although spectacular noctiluminescent cloud displays are thought to be possible.

Turco, R. P.

Importance of heterogeneous processes to tropospheric chemistry - Studies with a one-dimensional model

A one-dimensional, time-dependent model of tropospheric air composition is developed which incorporates several heterogeneous physical and chemical processes. The model includes the interaction of gases, aerosols, and hydrometeors through the physical mechanisms of nucleation, condensation, evaporation, coagulation, coalescence, and deliquescence. Precipitation, sedimentation, and dry deposition act to remove material from the atmosphere, while chemical transformations occur both in the vapor and the condensed phases. The model also incorporates the sources and vertical diffusion of gases and particles, as well as changes in the solar intensity caused by light-scattering from aerosols and clouds. Preliminary simulations made using this model indicate that rainout and washout processes strongly influence the distributions of tropospheric gases and aerosols under certain conditions.

Turco, R. P.

Evolution of an impact-generated dust cloud and its effects on the atmosphere

A simulation is carried out of the evolution of an optically thick dust cloud in the earth's atmosphere, and calculations are made of the effects that such a dust cloud would have on the amount of visible light reaching the surface and the temperature at the earth's surface. It is found that large quantities of dust remain in the atmosphere for periods of only three to six months. This duration is fixed by the physical processes of coagulation; these cause the rapid formation of micron-sized particles and sedimentation that quickly removes the particles from the atmosphere. The duration of the event is found to be nearly independent of the initial altitude, initial particle size, initial mass, atmospheric vertical diffusive mixing rate, and rainout rate. It depends to a slight extent on the particle density and the probability that colliding particles stick together to form a larger particle. In addition, the duration is limited by the rate at which the debris spreads from the initial impact site. A doubling code is used to calculate the visible radiative transfer in the dust clouds. It is found that light levels are too low for vision for one to six months and too low for photosynthesis for two months to one year.

Toon, O. B.

Tunguska meteor fall of 1908 - Effects on stratospheric ozone

The Tunguska meteor, whose disintegration over Siberia in 1908 may have generated as much as 30 million metric tons of nitric oxide (NO) in the stratosphere and mesosphere, is discussed. The photochemical aftereffects of the event are simulated using a comprehensive model of atmospheric trace composition. Calculations are made which indicate that up to 45% of the ozone in the Northern Hemisphere may have been depleted by the meteor's nitric oxide cloud early in 1909 and that large ozone reductions may have persisted until 1912. Measurements of atmospheric transparency by the Smithsonian Astrophysical Observatory for the years 1909-1911 reveal evidence of a steady ozone recovery from unusually low levels in early 1909, implying a total ozone deficit of 30 + or - 15%. The coincidence in time between the observed ozone recovery and the Tunguska meteor fall suggests that the event may provide a test of current ozone depletion theories.

Turco, R. P.

Long wavelength carbonyl sulfide photodissociation

The aeronomic implications of a preliminary observation of weak OCS photoabsorption above 270 nm are investigated. It is argued that the measured cross section is consistent with a forbidden transition in this wavelength region. Model calculations are made for the OCS photodissociation rates in daylight, the OCS and SO2 distributions in the upper atmosphere, and the budgets of sulfur in the stratosphere and OCS in the troposphere, assuming various extrapolations of the measured OCS absorption cross sections and quantum yields to longer wavelengths. It is shown that weak OCS absorption above 300 nm can have important consequences for all of these quantities. Laboratory and field experiments are identified which might lead to a better understanding of the atmospheric OCS cycle.

Turco, R. P.

Effects of meteoric debris on stratospheric aerosols and gases

Characterizations of meteoric dust height and size distributions are obtained using Hunten's calculations of meteor ablation and recondensation rates. The contribution of meteor residues to aerosol composition, the role of meteoric dust as condensation nuclei, and the effects of meteor debris on aerosol size distributions are quantified, and particle surface areas are estimated. The potential importance of heterogeneous chemistry for stratospheric trace gases is discussed. The interaction between H2SO4 vapor and meteor metal vapors is investigated. It is concluded that meteoric particles may dominate the natural stratospheric aerosols at small (less than .01 micron radius) and large (greater than 1 micron radius) sizes under normal conditions.

Turco, R. P.

Stratospheric hydroxyl radical concentrations - New limitations suggested by observations of gaseous and particulate sulfur

A one-dimensional aerosol model is employed in investigating the sensitivity of the stratospheric distributions of gaseous sulfur compounds and sulfate aerosol particles to changes in OH and CS2 concentrations, in eddy diffusion coefficients, and in important chemical rate constants. By comparing model predictions with recent observational data for SO2, OCS, and particulates, it is found that, with regard to atmospheric sulfur, CS2 is only a secondary source of sulfur for the stratosphere relative to OCS and that background tropospheric CS2 concentrations by volume are likely to be less than 70 parts per trillion. It is also established that under stratospheric conditions the rate coefficients for the reactions of OH with OCS and CS2 may be substantially smaller than the room temperature laboratory values of Kurylo (1978).

Turco, R. P.

Aircraft NO/x/ emissions and stratospheric ozone reductions - Another look

New estimates for stratospheric ozone perturbations attributable to supersonic transport (SST) emissions are presented. First, a review is given of recent data pointing to lower OH concentrations below 30 km, as compared to the values predicted by photochemical models. The evidence for lower OH comes from a wide range of laboratory and atmospheric studies. The sensitivity of theoretical estimates of ozone change to OH abundances, and the coupling mechanisms between the O(x)-NO(x)-HO(x)-Cl(x) families which are responsible for the sensitivity, are discussed. Updated calculations for SST-induced ozone alterations are compared with older predictions. For example, assuming continuous aircraft injection of NO2 at 20 km at a rate of 1 x 10 to the 9th kg per year (globally), a 4% ozone decrease, is now calculated where earlier a 3% ozone increase was found. This large variance from previous forecasts suggests that new assessments of certain other polluting agents, particularly nitrogen fertilizers, are needed.

Turco, R. P.

Implications of stratospheric aerosol measurements for models of aerosol formation and evolution

Calculations of the distribution of stratospheric sulfur gases and of stratospheric aerosols are compared with measurements obtained in Alaska during July 1979. Generally, the measurements are reasonably consistent with the model results. COS is the major sulfur-bearing gas in the stratosphere while CS2 plays a lesser role in the formation of sulfate aerosols. Ammonia, which earlier measurements suggested was a major aerosol constituent, is found to be a contaminant, so models without ammonia chemistry may be justified. The model and the measurements suggest that stratospheric sulfuric acid aerosols nucleate just above the tropopause, but they are older and have grown to larger sizes at higher altitudes.

Toon, O. B.

Implications of smaller concentrations of stratospheric OH - A two-dimensional model study of ozone perturbations

There is growing observational evidence that stratospheric OH concentrations are smaller than models have been predicting. Using very recent HOx reaction rate coefficient measurements in a two-dimensional photochemical model, results which support these observations are obtained. As a consequence of smaller OH concentrations, we show that perturbations of stratospheric ozone by NOx (SST emissions and nitrogen fertilizers) may be larger than expected, while perturbations due to added water vapor and chlorine (SSTs and chlorofluoromethanes, respectively) may be smaller.

Whitten, R. C.

Ozone photochemistry and OH - A two-dimensional model study

Recent measurements of key HO(x) reaction rates are presented which imply that OH concentrations at altitudes below 30 km are lower than those predicted by current photochemical models. The consequences of the lower OH abundances are examined with respect to calculated perturbations of ozone by added nitrogen oxides, chlorine, and water vapor. Consideration is also given to the perturbation of stratospheric ozone by continuing release of chlorofluoromethanes in light of the new HO(x) reaction rates. The ozone loss is found to be reduced by about 25% compared with earlier estimates, mainly because the reduced OH abundance below 30 km slows the reaction between OH and HCl.

Whitten, R. C.