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Results for “x-ray absorption spectroscopy”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 19 records
All sourcesNASA NTRSDOE OSTI
NASA NTRS1994

X-Ray Absorption Spectroscopy in High Temperature Oxidation of Metals and Alloys

An experimental technique is described that allows for the joint study of the kinetics and of the oxide structure during the high temperature oxidation of metal surfaces. Oxygen is supplied at the metal through an electrochemical oxygen pump and the oxygen pressure, at the metal surface, is measured during oxidation by a YSZ (yttria stabilized zirconia) oxygen sensor. XAS (x-ray absorption spectroscopy) is performed in fluorescence mode at the cation K edge and after each oxidation step. An appropriate analysis of the XAS spectra could provide information on both the oxidation kinetics and oxide structure. Experimental data on the high temperature oxidation of nickel, cobalt, and Fe(64%)Ni(36%) alloy, at low oxygen pressure, are reported and analyzed according to the proposed data reduction. These results indicate the presented technique to be particularly suitable for studying the hot corrosion of oxide film too thick for common surface spectroscopy (AUGER, ESCA) and too thin for conventional thermogravimetric technique.

Daniele Gozzi↗
NASA NTRS1978

Studies of volatiles in Apollo 17 samples and their implication to vapor transport processes

Flameless atomic absorption (FLAA), X-ray photoemission spectroscopy (XPS) and grain size separation techniques were adopted to analyze Pb, Cd, Zn and S in orange and black droplets from Apollo 17 samples. The FLAA and XPS investigations show volatile trace metal enrichment in smaller grain fractions (broken droplets); thus a part of the volatiles was probably deposited after break-up of the droplets. In addition, redistribution of the volatiles by a cratering event is indicated by continuous decreases in Pb and Cd with core depth. Studies of Zn on individual regolith grains are also reported.

Cirlin, E. H.↗
NASA NTRS1966

New techniques in geochemical analysis

Thin layer and gas chromatography, Mossbauer and atomic absorption spectrometry, fission track analysis, X-ray fluorescence spectroscopy, and other methods employed in geochemistry

X-RAY FLUORESCENCE SPECTROSCOPY↗
NASA NTRS1976

Variations in the spectra and pulse period of GX301-2

Spectra from observations of GX301-2 (3U1223-62) by the Goddard X-ray spectroscopy experiment on OSO-8 show an absorption edge due to cool iron with column densities of a few x 10 to the 19th power/cm squared. A decrease in intensity was associated with increased absorption and a spectrum similar to those of binary X-ray sources in absorption dips. Observed variations of the pulse period are consistent with Doppler shifts for reasonable orbit parameters.

Swank, J. H.↗
NASA NTRS1976

OSO-8 GSFC results on Cen X-3

Spectra of Cen X-3 during eclipse, in transition out of eclipse, and during several later phases of the binary orbit were obtained from quick look data of the July 16-25, 1975 observation by the Goddard X-ray spectroscopy experiment on OSO-8. In the high state there was no absorption turn over. Pulsations were present at least to 23 keV. The spectrum at the pulse minimum was flatter above 7 keV than that of the pulse peak. In transition out of eclipse Cen X-3 emerged above a small low energy flux seen during eclipse. The observations appear to indicate absorption by cold and ionized matter and the presence of iron in the companion's atmosphere. Decreased intensities were observed at late phases of some binary orbits in some cases corresponding to dips. Absorption appears although the low energy component remains. Variable features may be interpretable as absorption and emission by iron and possibly other trace elements.

Swank, J. H.↗
NASA NTRS1974

Solid state polymerization and crystallography of polyimide precursors

Although the production of crystallinity in a polymeric system has historically led to commerically useful properties, the polyimides, prized for their high temperature characteristics, as customarily synthesized by melt or solution casting, are amorphous. It is shown that polymide containing residual crystallinity can be synthesized by isothermal annealing of crystals of the salt of the diisopropyl ester of pyromellitic acid and phenylene diamine. The reaction is topochemical in that the geometry of the polymer product is dependent upon that of the crystalline precursor. Infrared spectroscopy reveals the presence of imide absorption in the polymer, while powder diffractometry suggests residual crystallinity. Single crystal X-ray analysis of the monomer yields a structure of chains of alternating acid and base suggesting that the monomer is amenable to polymerization with a minimum of geometrical disruption.

Wakelyn, N. T.↗
NASA NTRS1971

Stress corrosion in titanium alloys and other metallic materials

Multiple physical and chemical techniques including mass spectroscopy, atomic absorption spectroscopy, gas chromatography, electron microscopy, optical microscopy, electronic spectroscopy for chemical analysis (ESCA), infrared spectroscopy, nuclear magnetic resonance (NMR), X-ray analysis, conductivity, and isotopic labeling were used in investigating the atomic interactions between organic environments and titanium and titanium oxide surfaces. Key anhydrous environments studied included alcohols, which contain hydrogen; carbon tetrachloride, which does not contain hydrogen; and mixtures of alcohols and halocarbons. Effects of dissolved salts in alcohols were also studied. This program emphasized experiments designed to delineate the conditions necessary rather than sufficient for initiation processes and for propagation processes in Ti SCC.

Harkins, C. G.↗
NASA NTRS1976

Spectral variability in the X-ray pulsar GX 1+4

Observations of the galactic center region, hard X-ray source GX 1+4 by the GSFC X-ray spectroscopy experiment on OSO-8 confirm that GX 1+4 is a slow X-ray pulsar. The amount of absorption by cold matter in the spectrum of GX 1+4 varies significantly within a 24 hour period, behavior typical of many X-ray binary systems. The light curve for the pulsations from GX 1+4 appears to be energy dependent.

Becker, R. H.↗
NASA NTRS1976

Spectral variability in the X-ray pulsar GX 1 + 4

Observations of the galactic-center-region hard X-ray source GX 1 + 4 by the GSFC X-ray spectroscopy experiment on OSO-8 confirm that GX 1 + 4 is a slow X-ray pulsar. The amount of absorption by cold matter in the spectrum of GX 1 + 4 varies significantly within a 24-hour period, which is typical of many X-ray binary systems. The light curve for the pulsations from GX 1 + 4 appears to be energy-dependent.

Becker, R. H.↗
NASA NTRS1978

Interaction of hydrogen chloride with alumina

The influence of temperature, pressure, and outgas conditions on the absorption of hydrogen chloride and water vapor on both alpha and gamma alumina was studied. Characterization of the adsorbents was performed using X-ray powder diffraction, scanning electron microscopy (SEM), low temperature nitrogen adsorption desorption measurements, BET nitrogen surface area measurements and electron spectroscopy for chemical analysis (ESCA). Water vapor adsorption isotherms at 30, 40, and 50 C were measured on alpha and gamma alumina after outgassing at 80, 200, and 400 C. Both outgas temperature and adsorption temperature influenced the adsorption of water vapor on the aluminas. The water vapor adsorption was completely reversible. Alpha alumina absorbed more water per unit area than gamma alumina. Differences in the adsorption capacity for water vapor of the two aluminas were explained on the basis of ideal surface models of alpha and gamma alumina. Isosteric heats of adsorption for water vapor on the aluminas were determined over a limited range of surface coverage.

Bailey, R. R.↗
NASA NTRS1975

Soft X-ray spectroscopy of three extragalactic sources

Soft X-ray spectra (0.5 to 5 KeV) acquired with a rocket-borne argon-methane proportional counter are reported for M87, 3C 273, and NGC 4151. The counter sensitivity range allowed derivation of simultaneous information on the magnitude of soft X-ray absorption and the slope of the hard X-ray spectrum. Error estimation techniques for the free parameters of X-ray spectra are analyzed, and the results are applied to the spectra previously reported for these sources. It is shown that the technique used to analyze the previous spectra can drastically underestimate the magnitude of errors, and it is concluded that the proposed division of extragalactic X-ray sources into two groups according to the magnitude of absorption in their spectra is premature.

Margon, B.↗
NASA NTRS1976

Cosmic X-ray observations with OSO-8

The GSFC Cosmic X-ray Spectroscopy experiment aboard OSO-8 has operated successfully since launch providing spectral and temporal data on X-ray sources in tha energy range 2-60 keV. Analysis of quick look data shows a variety of spectral features, some stable, others variable, which will increase understanding of the nature of individual sources. In particular, observed emission and absorption features that can be attributed to iron will result in abundance measures of this important element in sources such as some X-ray binaries, the supernova remnant Cas A, and the nucleus of the galaxy Cen A.

Serlemitsos, P. J.↗
NASA NTRS1978

X ray spectra of X Per

The cosmic X-ray spectroscopy experiment on OSO-8 observed X Per for twenty days during two observations in Feb. 1976 and Feb. 1977. The spectrum of X Per varies in phase with its 13.9 min period, hardening significantly at X-ray minimum. Unlike other X-ray binary pulsar spectra, X Per's spectra do not exhibit iron line emission or strong absorption features. The data show no evidence for a 22 hour periodicity in the X-ray intensity of X Per. These results indicate that the X-ray emission from X Per may be originating from a neutron star in a low density region far from the optically identified Be star.

Becker, R. H.↗
NASA NTRS1976

Stellar crystal X-ray spectroscopy on OSO-8

The large-area graphite crystal X-ray spectrometer on the OSO-8 satellite is described, and its response to stellar line and continuum radiation is discussed. A high resolution X-ray spectrum of Sco X-1 obtained from a preliminary analysis of quick look data shows a strong, smooth continuum with an absence of emission or absorption features over the energy range 2.2 to 8 keV. Upper limits are set on narrow line emission from highly ionized states of S, Ca, and Fe.

Kestenbaum, H. L.↗