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At least 19 records

Detecting Contamination With Photoelectron Emission

Photoelectron emission from aluminum or epoxy-painted aluminum can be used to reveal presence and concentration of surface contaminants. Emission can be used to locate those parts of surface that are excessively contaminated and to which coatings cannot be reliably bonded. Cleaning can then be done on areas that most need it. Probe moves at rate of typically 1 ft/s (30 cm/s), speed slow enough to ensure sensitivity but fast enough to keep scanning time within reasonable limit.

Smith, T.↗

A noncontacting scanning photoelectron emission technique for bonding surface cleanliness inspection

Molecular contamination of bonding surfaces can drastically affect the bond strength that can be achieved and therefore the structural integrity and reliability of the bonded part. The presence of thin contaminant films on bonding surfaces can result from inadequate or incomplete cleaning methods, from oxide growth during the time between cleaning (such as grit blasting) and bonding, or from failure to properly protect cleaned surfaces from oils, greases, fingerprints, release agents, or deposition of facility airborne molecules generated by adjacent manufacturing or processing operations. Required cleanliness levels for desired bond performance can be determined by testing to correlate bond strength with contaminant type and quantity, thereby establishing the degree of contamination that can be tolerated based on the strength that is needed. Once the maximum acceptable contaminant level is defined, a method is needed to quantitatively measure the contaminant level on the bonding surface prior to bonding to verify that the surface meets the established cleanliness requirement. A photoelectron emission technique for the nondestructive inspection of various bonding surfaces, both metallic and nonmetallic, to provide quantitative data on residual contaminant levels is described. The technique can be used to scan surfaces at speeds of at least 30 ft/min using a servo system to maintain required sensor to surface spacing. The fundamental operation of the photoelectron emission sensor system is explained and the automated scanning system and computer data acquisition hardware and software are described.

Gause, Raymond L.↗

Scanning Photoelectron-Emission Inspection Equipment

Surfaces to be bonded tested for cleanliness. Equipment includes commercial photoelectron-emission sensor. Inspected surface irradiated with ultraviolet photons from source in sensor head while anode in sensor head collects photoelectrons ejected from surface by absorbed photons. If intensity and spectrum of ultraviolet light and distance between sensor and surface held constant, then photocurrent varies according to amount and type of contamination.

Gause, Raymond L.↗

A model of solar flux attenuation during eclipse passage and its effects on photoelectron emission from satellite surfaces

The basic theory of solar flux attenuation by the earth's atmosphere is reviewed and a model of the time-varying flux observed by a satellite during eclipse passage developed. The general model is applied to the specific problem of variations in photoelectron flux during penumbral passage and the effects of wavelength, solar activity, and atmospheric constituents on photoelectron emission investigated. Predictions of the photoelectron current expected from tungsten and aluminum surfaces are then successfully compared with actual observations from the ATS-5 and Injun 5 satellites confirming the validity of the model.

Garrett, H. B.↗

Photoelectron emission from Io as the cause of enhancements of the Jovian decametric radiation.

A theoretical explanation for the dependence of the Jovian decametric radiation on the position of its satellite Io is advanced in terms of electrostatic instabilities created by injection into the hot natural plasma of cold photoelectrons from Io. This may be tested with appropriately positioned and presently planned deep-space probes that search for variations of the Jovian decametric radiation at times following local sunset and sunrise at Io.

Mozer, F. S.↗

Photoelectron emission analysis of surface elements of the International Sun Earth Explorer

The photoemission was measured of engineering materials (aluminum; copper, plain; copper, abraded; copper-beryllium; magnesium; silver; In2O3 on silica; reflective coating on silica; teflon; kapton; and Pyre ML) associated with the International Sun Earth Explorer (ISEE) Satellite. The procedures used are described, including the experimental equipment; results of the program, the conclusions reached, and areas for further work are presented. Data regarding the measured yield of the 11 materials whose surface emission was determined is included in the form of plots of photoelectric yield versus incident light wavelength.

Spencer, W. T.↗

Solar EUV measurements at Venus based on photoelectron emission from the Pioneer Venus Langmuir probe

Data from the Pioneer Venus Langmuir probe, collected since 1979 (and thus, including the period between solar maximum in 1979-1980 and solar minimum in 1986-1987) are examined. Calculations show that about 51 percent of the solar emission at Venus is due to Lyman alpha (1216 A), 46 percent is produced by wavelengths between 550 and 1100 A, and less than 3 percent is due to wavelengths longer than Lyman alpha. The photocurrents were found to exhibit variations related to the solar cycle and solar rotation, as well as a major 7.2-month periodicity. Three different indices of solar EUV behavior at Venus were derived, which include the photoemission current itself, the total EUV flux, and an F(10.7)-like solar index, and are compared with related measurements made simultaneously at earth.

Brace, L. H.↗

The ultraviolet dayglow at solar maximum. III - Photoelectron-excited emissions of N2 and O

Rocket observations of the far ultraviolet dayglow spectrum near solar cycle maximum are analyzed using laboratory cross sections, atmospheric composition models, and photoelectron production models. Photoelectron-excited emissions of N2 and O are used to derive a self-consistent description of the atmosphere at solar maximum. Spectral synthesis of the N2 Lyman-Birge-Hopfield bands shows a departure of a 1Pi(q) state vibrational populations from the direct excitation theory. Observations of the N2 second positive (0, 0) 3371-A band and O I 1356-A emission indicate an exospheric temperature of 1600 K, 200 K higher than predicted by empirical models. The empirical models are also found to overestimate the O and O2 densities required to fit the data by a factor of 2 and 1.4, respectively. These results are compared to the results of an analysis of similar observations made in 1978 near solar minimum.

Meier, R. R.↗

Residual Silicone Detection

Both photoelectron emission and ellipsometry proved successful in detecting silicone contamination on unpainted and epoxy painted metal surfaces such as those of the external tank and the solid rocket booster. Great success was achieved using photoelectron emission (PEE). Panels were deliberately contaminated to controlled levels and then mapped with PEE to reveal the areas and levels that were contaminated. The panels were then tested with regard to adhesive properties. Tapes were bonded over the contaminated and uncontaminated regions and the peel force was measured, or the contaminated panels were bonded (with CPR 483 foam) to uncontaminated panels and made into lap shear specimens. Other panels were bonded and made into wedge specimens for hydrothermal stress endurance tests. Strong adhesion resulted if the PEE signal fell within an acceptance window, but was poor outside the acceptance window. A prototype instrument is being prepared which can automatically be scanned over the external liquid hydrogen tank and identify those regions that are contaminated and will cause bond degradation.

Smith, T.↗

Conjugate photoelectron excitation of O I 4368 airglow emission.

Conjugate photoelectron fluxes are shown to be mainly responsible for the excitation of O I 4368 radiation observed with a grille spectrometer located at Langmuir Laboratory, New Mexico (L equals 1.7). On the basis of observations of O I 7774 and 4368 tropical emissions at Agulhas, Negras, Brazil (L equals 1.1), the contribution of radiative recombination to the New Mexico intensity is shown to be small. Conjugate photoelectron excitation at the Brazilian site has not been observed.

Christensen, A. B.↗

Conductorlike behavior of a photoemitting dielectric surface

It has been suggested in the past that a uniformly illuminated photoemitting dielectric surface of finite extent acquires in the steady state a surface charge distribution as if the surface were conducting (i.e., the surface becomes equipotential). In this paper an analytical proof of this conductorlike behavior is given. The only restrictions are that the photoelectron emission from the surface has azimuthal symmetry and that the photosheath may be assumed to be collisionless. It is tacitly assumed that a steady state is attainable, which means that the photoelectron spectrum has a high-energy cutoff.

De, B. R.↗

Experiences with thin film filter development for the Extreme Ultraviolet Explorer

The design, development, and optimization of the thin film filters used on the Extreme Ultraviolet Explorer (EUVE) Satellite to define the EUV wavelength bandpasses of the individual instruments was a complicated task. The bandpasses had to be optimized for the astrophysical goals of the EUVE mission and constrained by the strong geocoronal EUV background emission. Materials with optical constants that met these requirements had to be found and tested. In many cases these materials were not compatible or were not strong enough to survive the intense vibrations of a rocket launch. Other effects, such as photoelectron 'halo' produced in the filters, were not discovered until flight qualification. The final set of flight filters included: lexan/boron, aluminum/carbon, titanium/antimony/aluminum, and tin/silicon monoxide. This paper discusses the lessons learned in the development of these filters, including the optimization process, material interactions and problems, calibration techniques, vibration susceptibility, thermal tests, and photoelectron emission. We feel the experiences gained over the last 10 years creating the filter sets for EUVE will be invaluable for future missions that use thin film filters.

Vallerga, J. V.↗

Improvements In Optically Stimulated Electron Emission

Optically stimulated electron emission (OSEE) used in inspection for contamination of critical bonding surfaces in solid rocket motors of Space Shuttle prior to formation of adhesive bonds on surfaces during manufacture and refurbishment. Fundamental OSEE inspection technique described in "Surface-Contamination Inspection Tool for Field Use" (MFS-25581) and "Detecting Contamination With Photoelectron Emission" (MFS-25619). OSEE measurement head easily portable, and measurement operation convenient and rapid, making it useful inspection technique in industrial environment. Reveals contamination in many situations in which other techniques do not work.

Yost, William T.↗

Intense localized photoelectric charging in the lunar sunset terminator region. I - Development of potentials and fields. II - Supercharging at the progression of sunset

Numerical computations show that locally sunlit areas in the dark lunar sunset terminator region can acquire large electric potentials and fields due to the retention of photoelectrons emitted from sunlit areas by surrounding dark areas of the highly resistive lunar surface. It is shown that the potential can increase or decrease depending on the rates of photoelectron emission and areal contraction. It is concluded that in the lunar situation, the likely result is an increase in the potential, or a 'supercharging' of the sunlit area.

Criswell, D. R.↗

Study of changes in properties of solar sail materials from radiation exposure

Techniques for monitoring changes in preparation of solar sail materials resulting from space radiation simulation, stressing (e.g., thermal, mechanical) and exposure to terrestrial environments are developed. The properties of interest are: metallic coating deterioration, polymeric film deterioration, interfacial debonding and possible metallic coating diffusion into the polymeric film. Four accelerated tests were devised to simulate the possible degradation processes mentioned above. These four tests are: a thermal shock test to simulate the wide variation of temperature expected in space (260 C to -100 C), a cyclic temperature test to stimulate the 6 minute temperature cycle anticipated in space, a mechanical vibration test to simulate mechanical bonding, folding and handling, and a humidity test to simulate terrestrial environment effects. The techniques for monitoring property changes are: visual and microscopic examination, ellipsometry, surface potential difference (SPD), photoelectron emission (PEE), and water contact angles.

Smith, T.↗

Configuration effects on satellite charging response

The response of various spacecraft configurations to a charging environment in sunlight was studied using the NASA Charging Analyzer Program code. The configuration features geometry, type of stabilization, and overall size. Results indicate that sunlight charging response is dominated by differential charging effects. Shaded insulation charges negatively result in the formation of potential barriers which suppress photoelectron emission from sunlit surfaces. Sunlight charging occurs relatively slowly: with 30 minutes of charging simulations, in none of the configurations modeled did the most negative surface cell reach half its equilibrium potential in eclipse.

Purvis, C. K.↗