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Results for “photoelectron emission”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 19 records
All sourcesNASA NTRSDOE OSTI
NASA NTRS1982

Detecting Contamination With Photoelectron Emission

Photoelectron emission from aluminum or epoxy-painted aluminum can be used to reveal presence and concentration of surface contaminants. Emission can be used to locate those parts of surface that are excessively contaminated and to which coatings cannot be reliably bonded. Cleaning can then be done on areas that most need it. Probe moves at rate of typically 1 ft/s (30 cm/s), speed slow enough to ensure sensitivity but fast enough to keep scanning time within reasonable limit.

Smith, T.↗
DOE OSTI2026

Visualization of the surface distribution of photocatalytic activity at the anatase/rutile TiO2 interface using X-ray photoelectron emission microscopy

We applied X-ray photoelectron emission microscopy (XPEEM) to visualize the surface distribution of photocatalytic activity at the anatase/rutile (A/R) interface of titanium dioxide. Acetic acid was adsorbed on the surface, and its decomposition and desorption reactions under ultraviolet light irradiation were monitored by observing C 1s spectra, enabling direct observation of the spatial distribution of photocatalytic activity. Complementary crystal structure information was obtained using spatially resolved low-energy electron diffraction, low-energy electron microscopy, X-ray absorption spectroscopy, and micro-focused Raman spectroscopy. Comparison with these structural data allowed for the evaluation of the photocatalytic activity as a function of the distance from the A/R interface. The activity is enhanced in the vicinity of the interface and gradually decreases toward both the anatase and rutile regions. These results demonstrate that XPEEM is an effective technique for spatially resolved mapping of photocatalytic activity, which has\\r\\npreviously been inaccessible using conventional characterization techniques.

25 ENERGY STORAGE↗
NASA NTRS1989

A noncontacting scanning photoelectron emission technique for bonding surface cleanliness inspection

Molecular contamination of bonding surfaces can drastically affect the bond strength that can be achieved and therefore the structural integrity and reliability of the bonded part. The presence of thin contaminant films on bonding surfaces can result from inadequate or incomplete cleaning methods, from oxide growth during the time between cleaning (such as grit blasting) and bonding, or from failure to properly protect cleaned surfaces from oils, greases, fingerprints, release agents, or deposition of facility airborne molecules generated by adjacent manufacturing or processing operations. Required cleanliness levels for desired bond performance can be determined by testing to correlate bond strength with contaminant type and quantity, thereby establishing the degree of contamination that can be tolerated based on the strength that is needed. Once the maximum acceptable contaminant level is defined, a method is needed to quantitatively measure the contaminant level on the bonding surface prior to bonding to verify that the surface meets the established cleanliness requirement. A photoelectron emission technique for the nondestructive inspection of various bonding surfaces, both metallic and nonmetallic, to provide quantitative data on residual contaminant levels is described. The technique can be used to scan surfaces at speeds of at least 30 ft/min using a servo system to maintain required sensor to surface spacing. The fundamental operation of the photoelectron emission sensor system is explained and the automated scanning system and computer data acquisition hardware and software are described.

Gause, Raymond L.↗
NASA NTRS1989

Scanning Photoelectron-Emission Inspection Equipment

Surfaces to be bonded tested for cleanliness. Equipment includes commercial photoelectron-emission sensor. Inspected surface irradiated with ultraviolet photons from source in sensor head while anode in sensor head collects photoelectrons ejected from surface by absorbed photons. If intensity and spectrum of ultraviolet light and distance between sensor and surface held constant, then photocurrent varies according to amount and type of contamination.

Gause, Raymond L.↗
NASA NTRS1981

A model of solar flux attenuation during eclipse passage and its effects on photoelectron emission from satellite surfaces

The basic theory of solar flux attenuation by the earth's atmosphere is reviewed and a model of the time-varying flux observed by a satellite during eclipse passage developed. The general model is applied to the specific problem of variations in photoelectron flux during penumbral passage and the effects of wavelength, solar activity, and atmospheric constituents on photoelectron emission investigated. Predictions of the photoelectron current expected from tungsten and aluminum surfaces are then successfully compared with actual observations from the ATS-5 and Injun 5 satellites confirming the validity of the model.

Garrett, H. B.↗
DOE OSTI2025

Imaging Photonic Resonances within an All‐Dielectric Metasurface via Photoelectron Emission Microscopy

Dielectric metasurfaces, through volume‐type photonic resonances, enable precise control of light‐matter interactions for applications including imaging, holography, and sensing. The application space of dielectric metasurfaces has extended from infrared to visible wavelengths by incorporating high refractive index materials, such as titanium dioxide (TiO 2 ). Understanding the fundamental and fabrication limits for these applications requires metrology with nanoscale resolution, sensitivity to electromagnetic fields within the meta‐atom volume, and far‐field excitation. In this work, photoelectron emission microscopy (PEEM) is used to image field distributions of photonic resonances in a TiO 2 metasurface excited with far‐field, visible‐wavelength illumination. The local volumetric field variations within the meta‐atoms are analyzed as a function of illumination angle and polarization by comparing photoelectron images to finite‐difference time‐domain simulations. This study determines the inelastic mean free path of very low‐energy (<1 eV) photoelectrons to be 35 ± 10 nm, which is comparable to the meta‐atom height thereby highlighting PEEM sensitivity to resonances within the volume. Additionally, the simulations reveal high sensitivity of PEEM images to an in‐plane component of the illumination k ‐vector. These results demonstrate that photoelectron imaging with subwavelength resolution offers unique advantages for examining light‐matter interactions in volume‐type (as opposed to surface) photonic modes within dielectric nanophotonic structures.

electron inelastic mean free path↗
DOE OSTI2021

Ex Situ Photoelectron Emission Microscopy of Polycrystalline Bismuth and Antimony Telluride Surfaces Exposed to Ambient Oxidation

The surfaces of textured polycrystalline N-type bismuth telluride and P-type antimony telluride materials were investigated using ex situ photoelectron emission microscopy (PEEM). PEEM enabled imaging of the work function for different oxidation times due to exposure to air across sample surfaces. The spatially averaged work function was also tracked as a function of air exposure time. N-type bismuth telluride showed an increase in the work function around grain boundaries relative to grain interiors during the early stages of air exposure-driven oxidation. At longer time exposure to air, the surface became homogenous after a ~5 nm-thick oxide formed. X-ray photoemission spectroscopy was used to correlate changes in PEEM imaging in real space and work function evolution to the progressive growth of an oxide layer. The observed work function contrast is consistent with the pinning of electronic surface states due to the defects at a grain boundary.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2023

Enhanced cutoff energies for direct and rescattered strong-field photoelectron emission of plasmonic nanoparticles

Abstract The efficient generation, accurate detection, and detailed physical tracking of energetic electrons are of applied interest for high harmonics generation, electron-impact spectroscopy, and femtosecond time-resolved scanning tunneling microscopy. We here investigate the generation of photoelectrons (PEs) by exposing plasmonic nanostructures to intense laser pulses in the infrared (IR) spectral regime and analyze the sensitivity of PE spectra to competing elementary interactions for direct and rescattered photoemission pathways. Specifically, we measured and numerically simulated emitted PE momentum distributions from prototypical spherical gold nanoparticles (NPs) with diameters between 5 and 70 nm generated by short laser pulses with peak intensities of 8.0 × 10 12 and 1.2 × 10 13 W/cm 2 , demonstrating the shaping of PE spectra by the Coulomb repulsion between PEs, accumulating residual charges on the NP, and induced plasmonic electric fields. Compared to well-understood rescattering PE cutoff energies for strong-field photoemission from gaseous atomic targets (10× the ponderomotive energy), our measured and simulated PE spectra reveal a dramatic cutoff-energy increase of two orders of magnitude with a significantly higher contribution from direct photoemission. Our findings indicate that direct PEs reach up to 93 % of the rescattered electron cutoff energy, in contrast to 20 % for gaseous atoms, suggesting a novel scheme for the development of compact tunable tabletop electron sources.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗
NASA NTRS1972

Photoelectron emission from Io as the cause of enhancements of the Jovian decametric radiation.

A theoretical explanation for the dependence of the Jovian decametric radiation on the position of its satellite Io is advanced in terms of electrostatic instabilities created by injection into the hot natural plasma of cold photoelectrons from Io. This may be tested with appropriately positioned and presently planned deep-space probes that search for variations of the Jovian decametric radiation at times following local sunset and sunrise at Io.

Mozer, F. S.↗
NASA NTRS1975

Photoelectron emission analysis of surface elements of the International Sun Earth Explorer

The photoemission was measured of engineering materials (aluminum; copper, plain; copper, abraded; copper-beryllium; magnesium; silver; In2O3 on silica; reflective coating on silica; teflon; kapton; and Pyre ML) associated with the International Sun Earth Explorer (ISEE) Satellite. The procedures used are described, including the experimental equipment; results of the program, the conclusions reached, and areas for further work are presented. Data regarding the measured yield of the 11 materials whose surface emission was determined is included in the form of plots of photoelectric yield versus incident light wavelength.

Spencer, W. T.↗
NASA NTRS1988

Solar EUV measurements at Venus based on photoelectron emission from the Pioneer Venus Langmuir probe

Data from the Pioneer Venus Langmuir probe, collected since 1979 (and thus, including the period between solar maximum in 1979-1980 and solar minimum in 1986-1987) are examined. Calculations show that about 51 percent of the solar emission at Venus is due to Lyman alpha (1216 A), 46 percent is produced by wavelengths between 550 and 1100 A, and less than 3 percent is due to wavelengths longer than Lyman alpha. The photocurrents were found to exhibit variations related to the solar cycle and solar rotation, as well as a major 7.2-month periodicity. Three different indices of solar EUV behavior at Venus were derived, which include the photoemission current itself, the total EUV flux, and an F(10.7)-like solar index, and are compared with related measurements made simultaneously at earth.

Brace, L. H.↗
NASA NTRS1985

The ultraviolet dayglow at solar maximum. III - Photoelectron-excited emissions of N2 and O

Rocket observations of the far ultraviolet dayglow spectrum near solar cycle maximum are analyzed using laboratory cross sections, atmospheric composition models, and photoelectron production models. Photoelectron-excited emissions of N2 and O are used to derive a self-consistent description of the atmosphere at solar maximum. Spectral synthesis of the N2 Lyman-Birge-Hopfield bands shows a departure of a 1Pi(q) state vibrational populations from the direct excitation theory. Observations of the N2 second positive (0, 0) 3371-A band and O I 1356-A emission indicate an exospheric temperature of 1600 K, 200 K higher than predicted by empirical models. The empirical models are also found to overestimate the O and O2 densities required to fit the data by a factor of 2 and 1.4, respectively. These results are compared to the results of an analysis of similar observations made in 1978 near solar minimum.

Meier, R. R.↗
NASA NTRS1980

Residual Silicone Detection

Both photoelectron emission and ellipsometry proved successful in detecting silicone contamination on unpainted and epoxy painted metal surfaces such as those of the external tank and the solid rocket booster. Great success was achieved using photoelectron emission (PEE). Panels were deliberately contaminated to controlled levels and then mapped with PEE to reveal the areas and levels that were contaminated. The panels were then tested with regard to adhesive properties. Tapes were bonded over the contaminated and uncontaminated regions and the peel force was measured, or the contaminated panels were bonded (with CPR 483 foam) to uncontaminated panels and made into lap shear specimens. Other panels were bonded and made into wedge specimens for hydrothermal stress endurance tests. Strong adhesion resulted if the PEE signal fell within an acceptance window, but was poor outside the acceptance window. A prototype instrument is being prepared which can automatically be scanned over the external liquid hydrogen tank and identify those regions that are contaminated and will cause bond degradation.

Smith, T.↗