Engineering Papers⌕ Search

SEARCH · Engineering Papers

Results for “long-duration storage”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 19 records

A Comprehensive Comparison of Methods for Evaluating Dispatch of Long-Duration Energy Storage in Power Systems Models

Long-duration energy storage (LDES) could play a pivotal role in the transformation of electricity grids with high shares of variable renewable energy (VRE) such as solar and wind. However, the weather-dependent nature of VRE introduces challenges for grid balancing and stability, which LDES - along with short-duration energy storage (SDES) - can help address. However, modeling LDES in production cost models (PCMs) is particularly challenging due to the need for high temporal resolution over extended optimization windows while preserving chronology, which ensures the alignment of energy storage operations with VRE generation over multi-day periods. This report compares traditional dispatch methods with advanced LDES dispatch strategies, such as the extended horizon approach, across different PCM platforms and examines tradeoffs and scalability. The comparison reveals that the traditional 1-day optimization horizon within the PCM leads to inefficient utilization of LDES. In contrast, extending the optimization horizon as much as possible significantly reduces curtailment and improves storage dispatch, especially in renewable-dense systems. There is also promise in using state-of-charge or end volume targets set by an external model, however this requires an additional modeling set and generally increases computational burden. This paper presents a comparison of these various methods in a number of power systems, showing algorithms initially in small test systems and scaling up to large, country-wide simulations. Overall, the research presents the trade-offs of various computational methods and illustrates how LDES may play an essential role in power systems of the future.

14 SOLAR ENERGY↗

Electricity Markets and Long-Duration Energy Storage: A Survey of Grid Services and Revenue Streams

Purpose of Review Long Duration Energy Storage (LDES) is increasingly viewed as a potential resource for providing grid services that enhance the stability and flexibility of electricity systems. While some LDES services are integrated into existing market frameworks, traditional mechanisms may not fully account for their operational characteristics, potentially leading to undervaluation. Within this context, this paper reviews the literature and industry practices to assess potential grid services for LDES, evaluates existing compensation mechanisms, and identifies challenges to full market integration. Recent Findings We first review existing literature and identify key grid services unique to LDES, including enhancing grid resilience during extreme weather events, enabling long-term energy shifting, and providing flexible and firm energy in systems with limited dispatchable resources. Here, we also review how LDES services are compensated in current market frameworks and the challenges associated with the full realization of LDES values. Additionally, we summarize market mechanisms for storage technologies across U.S. wholesale markets. We find that some markets are adjusting incentive structures, such as incorporating storage duration in capacity accreditation, to better align with system needs and LDES contributions to the grid. However, further refinements in capacity remuneration and dispatch timeframes may be needed for more effective realization of LDES value. Summary This review evaluates potential grid services for LDES, examines existing compensation mechanisms for LDES technologies, and identifies gaps between these mechanisms and LDES operational characteristics. The review concludes by outlining potential market enhancements for more effective LDES integration and articulating additional research needs to support its efficient participation in future power systems.

Flexible resources↗

Quantifying Energy Storage Density Utilization Trends in Redox Flow Battery Chemistries

The transition to new energy resources is driving the need for efficient energy storage. Redox flow batteries (RFBs) are a promising solution due to their flexible design and safer materials, particularly for long-duration storage applications. Despite these advantages, RFB technologies still have considerable room for growth in terms of utilizing all of their available energy storage density. Herein, we assess RFB energy storage density utilization trends for multiple chemistries by accounting for their unique thermodynamic limits, energy efficiencies, and charge capacity constraints. Of the RFBs chemistries analyzed, most still use less than 60% of their theoretical energy storage capacity. The conventional all-vanadium RFB was the closest to its thermodynamic limit available. Moreover, the volumetric footprint and electrolyte cost analyses demonstrate the real-world implications of these inefficiencies. This analysis further indicates that future studies would benefit from clearer reporting of two key quantities: discharge efficiency, which is more directly tied to practically recoverable energy density than round-trip energy efficiency, and state-of-charge or capacity-utilization limits, which govern access to theoretical storage capacity. More consistent reporting of these factors would improve the accuracy and comparability of energy storage utilization analyses across RFB chemistries.

battery energy storage↗

CSP Plant Optimization Study for the California Power Market (“CalCSP”) (Final Technical Report)

Concentrating Solar Power (CSP) with thermal energy storage offers a unique and strategic opportunity to support California’s clean energy transition. Unlike photovoltaic (PV) systems, CSP with thermal storage can generate electricity after sunset and during periods of high demand, making it a valuable complement to intermittent renewable resources. CSP also provides synchronous, inertia-contributing generation, long-duration storage, and flexible dispatch—capabilities increasingly important as thermal plants retire. This report summarizes the findings of the CSP Plant Optimization Study for the California Power Market or “CalCSP study,” which evaluated the technical, economic, environmental, and policy factors that influence the deployment of CSP technologies in California. The CalCSP study was conducted to assess how CSP can contribute to California’s long-term decarbonization goals while enhancing grid reliability, supporting local economic development, and making efficient use of land and transmission resources. It draws on detailed modeling of CSP performance and costs, site suitability analysis, policy reviews, and stakeholder engagement across utilities, regulators, developers, and community organizations. The analysis focuses on mature molten-salt tower technology and incorporates lessons learned from the global CSP fleet, distinguishing today’s CSP from earlier first-of-a-kind projects in the U.S. The findings support a more prominent role for CSP in California’s evolving clean energy landscape. With strategic planning, targeted policy support, and continued cost improvements, CSP can complement PV and batteries to deliver reliable, around-the-clock clean electricity—especially in areas with high solar resource and constrained grid capacity.

14 SOLAR ENERGY↗

Value of Geothermal Energy Storage for Supply-Side and Demand-Side Applications

This report presents the results of a study examining the value potential for geothermal energy storage (GES), a long-duration energy storage resource that stores thermal and/or geomechanical energy in the subsurface. GES could benefit the overall U.S. power system by temporally shifting electricity generation (supply-side) or meeting building heating and cooling load (demand-side). This report analyzes supply-side and demand-side opportunities independently because of differences in applications and models. Currently there is significant uncertainty about the development costs for GES, with only a limited number of demonstration plants for electric energy storage and building heating and cooling storage developments. In this report, we estimate the value of supply-side and demand-side GES to the bulk power system in the contiguous United States. Because of the significant uncertainty about GES development costs, this analysis does not consider GES deployment costs but instead focuses on the value of GES to the U.S. electricity system. The estimated values of GES provide reference points for economically competitive commercial cost targets. Supply-side GES is modeled as part of an enhanced geothermal system (EGS) generation plant in NREL's Regional Energy Deployment System (ReEDS) capacity expansion model (Ho et al. 2021). In contrast to conventional geothermal plants, which generate constant power, EGS plants have unique features that may allow for in-reservoir energy storage for flexible generation. Demand-side GES for heating and cooling, including seasonal hot and cold storage and short-duration heat pump storage, is incorporated into a price-taker model using Cambium electricity marginal cost projections. To establish an upper bound for the value of GES, analysis focused on favorable scenarios for storage with high generation from zero marginal cost, variable renewable energy resources. High penetrations of variable renewable energy generation can increase hourly electricity price variability, which increases the value of temporal energy arbitrage for storage technologies like GES.

15 GEOTHERMAL ENERGY↗

Pumped Thermal Energy Storage Using Low-Cost Particles and a Fluid Bed Heat Exchanger for Maximum Power Efficiency

Robust, efficient, cost-effective long-duration electricity storage (LDES) solutions can enhance grid resiliency, support existing transmission and distribution infrastructure, and enable a greater share of low-cost, variable alternative energy sources to penetrate the market. To meet this need, the project team at the National Renewable Energy Laboratory developed a transformative LDES system based on pumped thermal energy storage (TES) using low-cost particles and a fluid bed heat exchanger for maximum power efficiency (PUMP). The PUMP system is composed of high-temperature, low-cost particle TES coupled with an advanced pressurized fluid bed heat exchanger (PFB HX) that supports a high-efficiency pumped thermal energy storage (PTES) system integrated with concentrating solar thermal power (CSP). The PUMP project developed and de-risked a PFB HX and particle CSP system intended to be integrated with reversible turbomachinery and a modeling tool to assess PTES cost and performance.

14 SOLAR ENERGY↗

Deployment Pathways for Long Duration Energy Storage

We apply a least-cost generation expansion model of the continental United States to assess how optimal investments in long-duration energy storage (LDES) technologies are impacted by changes in system generation portfolios and technology costs, assessing 369 capacity expansion scenarios in total. The expansion model considers 8,760 h of chronological operations for the entire target year, 2040. We find that low-cost LDES technologies can reduce generation investments and system costs. Specifically, once the costs for 24- and 100-h storage reach $38/kWh and $14/kWh, respectively, substantial deployments are observed. The distribution of storage investments across durations is strongly influenced by the system generation portfolio. We also demonstrate that a high-fidelity temporal representation is required to capture the value of LDES in generation expansion. Finally, we conduct a regression analysis of our capacity expansion results and find that LDES deployments are positively correlated with the combined wind and solar capacity share and negatively correlated with peaking and baseload shares.

Levin, Todd↗

CEC Quest: Long Duration Energy Storage Impact Analysis Tool

SAND2025-14389O CEC Quest is a Python tool with a user interface designed to analyze the greenhouse gas impacts of long-duration energy storage projects in California. The tool automates data collection from public sources and uses an Application Programming Interface (API) to enable users to download photovoltaic resource availability, marginal operating emissions rate, and utility rate data. It guides users in inputting parameters for a battery energy storage model and uploading site electrical load data, while also prompting for relevant analysis parameters like timestep and grid limits. CEC Quest performs monthly optimization of one year of data to assess impacts on the site’s electrical bill and the grid’s greenhouse gas emissions. Finally, it conducts a lifecycle analysis to evaluate changes over a defined quantification period, with results aggregated through automated report generation. Sandia National Laboratories is a multimission laboratory managed and operated by National Technology & Engineering Solutions of Sandia, LLC, a wholly owned subsidiary of Honeywell International Inc., for the U.S. Department of Energy’s National Nuclear Security Administration under contract DE-NA0003525.

Rosewater, David [Sandia National Lab. (SNL-CA), L↗

Enhanced Simulation Tools for Scheduling Solar Plus Storage Power Plants

This is the final technical report for the Department of Energy's Office of Energy Efficiency and Renewable Energy (EERE) under the Solar Energy Technology's Office Balance of Systems program, Award Number 38429. This report summarizes the key outputs and findings of the project, which was focused on long-duration energy storage (LDES) and solar. In particular, one of the most significant challenges of maximizing the value of variable solar energy is the timing of charging and discharging stored energy from LDES devices. Power systems often fail to capture the benefits of LDES and can undervalue the role of storage in providing energy arbitrage, reliability support, and resiliency. This project examined those challenges and proposed alternative methodologies that better capture the value that LDES can provide.

14 SOLAR ENERGY↗

Binder-Stabilized Carbon Fiber Hosts for High-Utilization Sodium–Polysulfide Flow Catholytes

Sodium-sulfur (Na-S) batteries hold promise as high-energy-density batteries for long-duration energy storage due to their high open circuit voltage and Earth-abundant active materials. However, low utilization of the sulfur active material limits the achievable specific capacity, especially when a liquid polysulfide catholyte is utilized. High-surface-area carbon materials demonstrate promise to increase sulfur utilization in a Na-S battery. To make the carbon host material applicable for a flow battery application, a binder is required to bind the carbon materials together and to a porous substrate. Here, we utilize a composite carbon paper electrode coated by polymer,carbon nanofibers (CNFs) and carbon black (CB). By varying the mass ratios of CNF to CB, we found that a 70/20/10 mass ratio of CNF/CB/binder provided the highest capacity (260 mAh g −1 compared to the baseline of 156 mAh g −1 ) and stable battery performance over 100 cycles. Analysis of the composite electrode and full cells reveals that the amount of CB in the composite electrode influences binder distribution, cell resistance, and full cell performance.

Lehmann, Michelle L. [Oak Ridge National Laborator↗

Pilot Development Progress to Demonstrate Electric Thermal Energy Storage (ETES) Using Low-Cost Particles

The rapid growth of future energy demand increases the need to economically store electrical energy over durations up to several days in long-duration energy storage (LDES) applications. LDES can reduce the grid stress for improving the resilience of the grid. The integration of renewable power and storage has several significant and positive impacts including expanding the renewable energy portion of electricity generation, meeting peak-load demand, and coordinating supply and demand. Several energy storage approaches including mechanical, chemical and electrochemical methods are currently deployed or under development. However, LDES requirements pose unique challenges for scalability, energy capacity, and cost. Thermal energy storage (TES) has the ability to store a large capacity of energy with improved site flexibility compared to incumbent LDES technologies (i.e., pumped hydro) and has attracted significant interest. Our development in TES technology using solid particles as the storage medium has shown feasibility and potential in serving LDES purposes. Particle TES has various advantages over commercialized molten nitrate salt TES and has emerged as a promising storage technology originating from Generation 3 concentrating solar power (CSP) development. Stable, inexpensive silica sand produced in the Midwestern U.S. was identified as a suitable storage medium and has been validated through lab heating and cycling tests. We have successfully developed particle TES for bidirectional electric energy storage to broaden the applications for TES beyond CSP technologies and into standalone electric-thermal energy storage (ETES) systems. Key component designs and performance were verified with prototype testing and model simulations. The ETES system uses high-temperature, low-cost particle thermal energy storage coupled with a unique pressurized fluidized bed heat exchanger that supports a high-efficiency, air-Brayton combined power cycle. At times of low energy demand or high renewable production, an electric particle heater heats large quantities of solid particles to high temperatures in excess of 1100 degrees C. The particles are stored in internally insulated silos. At times of high electricity demand, the hot particles are gravity-fed through the heat exchanger where stored thermal energy is transferred to the power cycle working fluid to drive the gas turbine power generation system, thereby converting the thermal energy back into electricity for the grid. The cold particles leaving the heat exchanger are returned to the storage silos by a well-insulated particle conveyor. This ETES technology using particle TES can be sited anywhere and is predicted to be economic and efficient. Moreover, this ETES technology could be co-located with a retired coal or gas plant to leverage existing power generation and grid infrastructure. Our work has focused on the development of each of the key components (e.g., the electric particle heater, particle storage silos, and the particle-to-gas pressurized fluidized bed heat exchanger) through conceptual designs, prototype testing, and computational modeling. These developments demonstrate technological feasibility and are an important step towards the next phase of development of this promising LDES technology. This presentation will show the progress in developing a pilot demonstration of the ETES system on a commercially relevant scale.

25 ENERGY STORAGE↗

Pilot Development Progress to Demonstrate Electric Thermal Energy Storage (ETES) Using Low-Cost Particles

The rapid growth of variable renewable power generation increases the need to economically store electrical energy over durations up to several days in long-duration energy storage (LDES) applications. LDES can bridge the intermittency of increasing variable renewable energy (VRE) and facilitate emission-free dispatchable electricity to improve the resilience of the grid and provide reliable and potentially cost-effective energy. Several energy storage approaches including mechanical, chemical and electrochemical methods are currently deployed or under development. However, LDES requirements pose unique challenges for scalability, energy capacity, and cost. Electro-thermal energy storage (ETES) can store a large capacity of energy with site flexibility and has attracted significant interest for LDES purposes. This paper shows the progress of developing a demonstration test facility for particle ETES technology including pilot-scale component design and fabrication.

25 ENERGY STORAGE↗

Parametric optimization of PCM-enhanced underground thermal energy storage for buildings in moderate cold climates

This study presents a novel underground thermal energy storage (UTES) system designed for space heating in buildings located in moderate cold climates. The proposed UTES features a borehole with a depth of 25 ft. (7.62 m) and a diameter of 3 ft. (0.91 m), containing two helical pipe loops-one for discharge fluid and another for recharge fluid-and a thermally enhanced phase change material (PCM) layer that provides high energy storage capacity. The system requires daily thermal recharging using a low-grade heat source for a few hours and delivers continuous heating at a nearly constant discharge rate without significant performance degradation over a 24-h period. This study demonstrates that the optimized UTES, when recharged with hot fluid at an inlet temperature of 40 degrees C for 6 h daily, can provide a continuous heat discharge rate of approximately 2.9 kW for 24 h or 3.4 kW if operated under a shorter discharge period of 15 h (17:00-08:00). With a round-trip efficiency of 72-97%, the proposed UTES offers an efficient and reliable solution for short- and long-duration thermal energy storage technology, making it a promising technology for cold climates.

15 GEOTHERMAL ENERGY↗

Revealing Progressive Degradation of Cobalt Oxide Nanoparticles During Thermochemical Redox Cycling via Operando STEM-EELS

Metal oxides are promising materials for long-duration thermochemical energy storage. Efforts to characterize their reaction kinetics, conversion rate, and morphological evolution during thermochemical cycling have largely focused on bulk and microscale measurements. However, the design of nanostructured metal oxides could improve the reaction reversibility and kinetics, warranting the development of platforms to investigate how these materials behave at the nanoscale. Here, we demonstrate the use of correlative, time-resolved electron energy loss spectroscopy and imaging in an environmental transmission electron microscope for studying the thermochemical cyclability of cobalt oxide nanoparticles with high spatial and temporal resolution. The spectroscopic data reveal a striking decrease in reaction kinetics after the first cycle, resulting from sintering-driven nanostructural densification. Comparison between cycling in humid and dry air shows that atmospheric conditions can modulate reaction transition temperatures but have limited effects on sintering over multiple cycles, suggesting long-term durability will instead rely on synthetic and/or nanostructural modifications.

25 ENERGY STORAGE↗

Planning for Seattle at the Convergence of Resilience and Energy

Grid reliability metrics obscure important temporal, spatial, and categorical considerations for increasing energy resilience. Systemwide or feeder-level outage metrics do not identify which kinds of services are affected by outages, where, and for how long. These outage metrics indicate the impacts of outages but cannot measure the consequences to customers that could result from those outages. The consequences of power outages for surrounding community members are caused by disruptions to electricity-dependent critical services, rather than to electricity itself. Power outages can decrease a community's access to healthcare, fuel, safe indoor temperatures, and provisions like food and water. This project developed critical service access, a new consequence-focused resilience metric that quantifies the relative access to critical services provided to households by distribution infrastructure during normal conditions and major disruptions. We use a spatially granular grid analysis that facilitates targeted resilience interventions; dividing feeders into isolatable sections and combining those sections with the critical service access metric allows us to identify where energy improvements like solar-plus-storage microgrids could create the most benefits for community members by protecting access to food, fuel, health, shelter, and public safety services. We identify locations in a South Seattle study area that could be high priorities for resilience investment and summarize their potential neighborhood-scale resilience benefits. This analysis was complemented by direct feedback from study area residents collect through a survey and focus groups. Results can help utilities understand how and where long power outages can create real consequences for customers, set strategic targets based on that understanding, and measure the potential benefits of energy resilience upgrades for more informed decisions.

14 SOLAR ENERGY↗

Modeling and Experimental Validation of a Direct-Contact Counter-Flow Fluidized Bed Heat Exchanger for Thermal Energy Storage (TES) Applications

Particle-based thermal energy storage (TES) systems are an emerging energy storage technology. The technological advances have reduced costs, making TES more competitive and reliable in the marketplace but an efficient and reliable operation is heavily dependent on coherent heat transfer between air to particles or vice versa. The particle-based TES technologies provide an intermediate system that can store energy for short (0-10 h), long (10-200 h) and seasonal (> 200 h) timescales. The TES systems store energy by converting electricity to thermal energy; electricity can be directly sourced intermittent generation technologies and/or the grid, helping manage peak loads and other mismatches in supply and demand. The overall efficiency of the TES system depends on the performance of system components (particle storage silos and particle transfer mechanism etc.). The particle heat exchanger is one of the key system components that affects the system efficiency. The pressurized fluidized bed heat exchanger (PFB HX) performance is challenging to predict due to the chaotic behavior of particle and fluid interaction. This research presents a computational study of a novel direct-contact, counter-flow and air-to-particles PFB HX, that contributes in advancing the particle-based long-duration TES technologies. For the current analysis an unsteady Eulerian-Eulerian CFD model was developed and validated against experiments performed at the National Laboratory of the Rockies for two particle sizes (600 ..mu..m and 825 ..mu..m ). Following validation, parametric simulations were conducted to evaluate the effects of interphase drag models (Syamlal-O'Brien and Gidaspow), particle size, bed height and the influence of a frictional-viscosity term on hydrodynamics and heat transfer between the air & particles. The key findings from the analysis are: (1) for the studied operating window Syamlal-O'Brien provides superior agreement with measured gas temperatures (errors generally < 10%) while Gidaspow shows large deviations for the coarse particle case; (2) model predictions are most sensitive in the lower 0.2 m above the air distributor where bubble initiation and local mixing dominate interphase heat transfer; (3) representation of the distributor (number of inlet ports) materially affects predicted local mixing and temperature stratification; and (4) the Eulerian-Eulerian framework reproduces bulk thermal trends but shows regime dependent limitations for coarse particles, motivating mesoscale informed closures for scale-up analysis for future studies. These results provide validated guidance for drag selection and distributor design in particle-based thermal energy storage applications. Collectively, the validated model and parametric results quantify key drivers of PHB-HX performance and provide practical guidance for design and optimization. The results provide confidence in the model predictability and provide a step forward to improve on heat exchange performance. The demonstrated performance and modeling approach support the deployment and further development of this novel PHB-HX concept for robust, particle-based long-duration thermal energy storage systems.

25 ENERGY STORAGE↗

External perturbation-driven Sabatier breakthrough

The Sabatier reaction (CO 2 + 4H 2 → CH 4 + 2H 2 O) is gaining renewed interest due to its potential to reduce energy carrier storage costs, serve as a feedstock for various organic chemicals, and supply in-situ propellant and life-support resources for long-duration Mars missions. This study demonstrates that combining a modest 2 mA electric field with H 2 feed modulation markedly elevates the CO 2 hydrogenation activity of 2 wt% Ru/CeO 2 catalyst. CO 2 conversion reaches 88 % and 93 % with a CH 4 yield of 83 % and 89 % at 350 °C and 450 °C, respectively. A simple lumped kinetic model reveals that the combined external perturbations not only shift the reaction mechanism but also redistribute key surface-adsorbed intermediates such as hydrogen adatoms and hydrogen-activated CO 2 among the Ru clusters, Ru/CeO 2 interface, and ceria surface. The electric field accelerates the conversion of adsorbed CO 2 to the hydrogenated CO 2 species on Ru and boosts CH 4 formation rate constant, while simultaneously suppresses the formation of undesired, non-reactive surface intermediates. Degree-of-rate-control analysis pinpoints proton migration across the metal-support interface as the decisive lever under these coupled perturbations. In conclusion, these findings establish that rational pairing of metal-support design with well-tuned electric fields and feed oscillations can unlock unprecedented Sabatier rates, guiding the development of next-generation reactors for efficient CO 2 to CH 4 conversion.

10 - SYNTHETIC FUELS↗