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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 19 records

Safety Standard for Hydrogen and Hydrogen Systems: Guidelines for Hydrogen System Design, Materials Selection, Operations, Storage and Transportation

The NASA Safety Standard, which establishes a uniform process for hydrogen system design, materials selection, operation, storage, and transportation, is presented. The guidelines include suggestions for safely storing, handling, and using hydrogen in gaseous (GH2), liquid (LH2), or slush (SLH2) form whether used as a propellant or non-propellant. The handbook contains 9 chapters detailing properties and hazards, facility design, design of components, materials compatibility, detection, and transportation. Chapter 10 serves as a reference and the appendices contained therein include: assessment examples; scaling laws, explosions, blast effects, and fragmentation; codes, standards, and NASA directives; and relief devices along with a list of tables and figures, abbreviations, a glossary and an index for ease of use. The intent of the handbook is to provide enough information that it can be used alone, but at the same time, reference data sources that can provide much more detail if required.

Source record

The columbium-hydrogen system and hydrogen embrittlement of columbium

Columbium specimens are charged uniformly with hydrogen allowing accurate measurement of the hydrogen content by a procedure involving the removal of hydrogen from flowing argon at 2000 degrees F. Hydrogen content effects on the ductile-to-transition temperature are determined for temperatures between 200 and 600 degrees F.

Walter, R. J.

Study of cryogenic propellant systems for loading the space shuttle. Part 2: Hydrogen systems

Computer simulation studies of liquid hydrogen fill and vent systems for the space shuttle are studied. The computer programs calculate maximum and minimum permissible flow rates during cooldown as limited by thermal stress considerations, fill line cooldown time, pressure drop, flow rates, vapor content, vent line pressure drop and vent line discharge temperature. The input data for these programs are selected through graphic displays which schematically depict the part of the system being analyzed. The computed output is also displayed in the form of printed messages and graphs. Digital readouts of graph coordinates may also be obtained. Procedures are given for operation of the graphic display unit and the associated minicomputer and timesharing computer.

Steward, W. G.

Lessons Learned in Hydrogen System Operation

NASA has learned extensive lessons on the operations of hydrogen systems during the developments and operations of space hardware. A subset of these lessons that are useful for aircraft and terrestrial applications using liquid hydrogen are presented to help disseminate the information learned. Discussion includes test data, analysis, and observations on cryogenic insulation systems, stratification and temperature gradients within tank systems, fittings to reduce leakage, and integration of refrigeration systems within a cryogenic fluids system.

Liquid Hydrogen

Hybrid Theory of Electron-Hydrogenic Systems Elastic Scattering

Accurate electron-hydrogen and electron-hydrogenic cross sections are required to interpret fusion experiments, laboratory plasma physics and properties of the solar and astrophysical plasmas. We have developed a method in which the short-range and long-range correlations can be included at the same time in the scattering equations. The phase shifts have rigorous lower bounds and the scattering lengths have rigorous upper bounds. The phase shifts in the resonance region can be used to calculate very accurately the resonance parameters.

Bhatia, A. K.

Safe Use of Hydrogen and Hydrogen Systems

This is a viewgraph presentation that is a course for teaching the safe use of hydrogen. The objectives of the course are 1. To familiarize the student with H2 safety properties 2. To enable the identification, evaluations and addressing of H2 system hazards 3. To teach: a. Safe practices for, b. Design, c. Materials selection, d. H2 system operation, e. Physical principles and empirical observations on which these safe practices are based, f. How to respond to emergency situations involving H2, g How to visualize safety concepts through in-class exercises, h. Identify numerous parameters important to H2 safety.

Maes, Miguel

Gas-Phase Reaction Pathways and Rate Coefficients for the Dichlorosilane-Hydrogen and Trichlorosilane-Hydrogen Systems

As part of NASA Ames Research Center's Integrated Process Team on Device/Process Modeling and Nanotechnology our goal is to create/contribute to a gas-phase chemical database for use in modeling microelectronics devices. In particular, we use ab initio methods to determine chemical reaction pathways and to evaluate reaction rate coefficients. Our initial studies concern reactions involved in the dichlorosilane-hydrogen (SiCl2H2--H2) and trichlorosilane-hydrogen (SiCl2H-H2) systems. Reactant, saddle point (transition state), and product geometries and their vibrational harmonic frequencies are determined using the complete-active-space self-consistent-field (CASSCF) electronic structure method with the correlation consistent polarized valence double-zeta basis set (cc-pVDZ). Reaction pathways are constructed by following the imaginary frequency mode of the saddle point to both the reactant and product. Accurate energetics are determined using the singles and doubles coupled-cluster method that includes a perturbational estimate of the effects of connected triple excitations (CCSD(T)) extrapolated to the complete basis set limit. Using the data from the electronic structure calculations, reaction rate coefficients are obtained using conventional and variational transition state and RRKM theories.

Dateo, Christopher E.

Milestone report TCTP application to the SSME hydrogen system analysis

The Transient Cryogen Transfer Computer Program (TCTP) developed and verified for LOX systems by analyses of Skylab S-1B stage loading data from John F. Kennedy Space Center launches was extended to include hydrogen as the working fluid. The feasibility of incorporating TCTP into the space shuttle main engine dynamic model was studied. The program applications are documented.

Richards, J. S.

Superconductivity in the palladium-hydrogen system

Band theory and phonon measurements are used to calculate the electron-phonon coupling constant wavelength for Pd and PdD. The results indicate that superconductivity is absent in Pd metal because of the large value of the Coulomb pseudopotential, and that superconductivity occurs in PdD primarily because of coupling with the optic phonons. These results are consistent with superconducting transition-temperature measurements for these systems.

Papaconstantopoulos, D. A.

Damping of thermal acoustic oscillations in hydrogen systems

Acoustic waves initiated by a large temperature gradient along a tube are defined as thermal acoustic oscillations (TAOs). These oscillations have been damped by introducing such sound absorbing techniques as acoustic filters, resonators, etc.. These devices serve as an acoustic sink that is used to absorb or dissipate the acoustic energy thereby eliminating or damping such oscillations. Several empirical damping techniques, such as attaching a resonator as a side branch or inserting a wire in the tube, have been developed in the past and have provided reasonable success. However, the effect of connecting tube radius, length, and resonator volume on the damping of thermal acoustic oscillations has not been evaluated quantitatively. Further, these methods have not been effective when the oscillating tube radius was relatively large. Detailed theoretical analyses of these techniques including a newly developed method for damping oscillations in a tube of relatively large radius are provided in this presentation.

Gu, Youfan

Thermodynamics of Volatile Species in the Silicon-Oxygen-Hydrogen System Studied

The volatilization of silica (SiO2) to silicon hydroxides and oxyhydroxides because of reaction with water vapor is important in a variety of high-temperature corrosion processes. For example, the lifetimes of silicon carbide (SiC) and silicon nitride (Si3N4) - based components in combustion environments are limited by silica volatility. To understand and model this process, it is essential to have accurate thermodynamic data for the formation of volatile silicon hydroxides and oxyhydroxides.

Jacobson, Nathan S.

Nondestructive Evaluation of the Gimbal Joint Flowliner Slots in the Space Shuttle Main Propulsion System Hydrogen Feedline

Fatigue cracks were discovered in the STS-112 Liquid Hydrogen Feedline flowliners in 2002. This led to a development program aimed at providing nondestructive evaluation methods and techniques to verify the existence of these types of cracks in oval shaped slots cut into the ends of the feedlines above the bellows joints. These slots were used to improve flow dynamics and to facilitate cleaning in the bellow joint region. These types of fatigue cracks posed a possible metal debris ingestion threat for the Space Shuttle Main Engines, which attached to these particular joints. Results of this program produced three reliable inspection techniques utilizing the imaging of replisets with a Scanning Electron microscope, eddy current, and ultrasound. The program developed unique probes and fixtures and in the case of eddy current and ultrasound, provided qualification and certification of the particular techniques by various Design of Experiments and Probability of Detection studies utilizing multiple inspectors.

Suits, Michael W.

Scattering of Low Energy Electrons and Positrons from Hydrogenic Systems and Applications

While the electron scatters from the target, the target no longer stays in its original form. One of the first methods to take into account the distortion of the target at low incident energies is the method of polarized orbitals. In this method the wave function for the process is written using the first-order perturbation theory and the equation for the scattering function is derived from the Schradinger equation. This method has been very successful in calculating the phase shifts and therefore the cross sections at various energies. The total wave function can be used to calculate photoionization cross sections. The disadvantage of this approach is that the method is not variational and therefore does not provide bounds on the phase shifts. These difficulties can be overcome by using the Feshbach projection operator formalism. This approach has been employed for the scattering of electrons and positrons from targets. Results of various calculations will be discussed.

Bhatia, Anand K.