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Demonstrating non-isothermal vacuum membrane air dehumidification for efficient next-generation air conditioning
Vacuum membrane air dehumidification has gained significant interest in recent years as a highly efficient means of air dehumidification. Prior theoretical modeling work by the authors introduced the Active Membrane Energy Exchanger (AMX) concept, which combines active heat exchange and vacuum membrane dehumidification into one non-isothermal system, and found that it could outperform other air conditioning technologies under many conditions. However, no experimental literature exists on combining active heat exchangers and vacuum membrane dehumidification. Here, the goal of the present study is to evaluate the dehumidification (mass transfer) performance of the AMX concept relative to isothermal membrane dehumidification through three main methodologies: (1) membrane material-level characterization, (2) experimental prototype development and testing, and (3) computational fluid dynamics (CFD) simulations. The dense membranes used in this work showed up to a 40% increase in water vapor permeance at cooler temperatures, and the prototype system showed up to a 6% increase in humidity removal when the air was simultaneously cooled. Furthermore, the membrane module-integrated heat exchange tubes provided additional mixing and turbulence, leading to a 4–8% increase in humidity removal. The upper limit coefficient of performance was equal to approximately 2.2, necessitating advanced system designs to improve efficiency. This study is the first to highlight that combining the cooling and vacuum dehumidification processes can improve dehumidification performance.
NOx mediated formation of ε – UO 3 during thermal decomposition of uranyl nitrate hexahydrate under static air conditions
The thermal decomposition of uranyl nitrate hexahydrate in air at temperatures of 650 – 800 °C is expected to yield α – U 3 O 8 through intermediate UO 3 phases. Here, n this study, Raman spectroscopy complimented by powder X-ray diffraction revealed the unexpected formation of ε – UO 3 as an accompanying phase during thermal decomposition of UNH at 700 °C under static air conditions. Experiments demonstrated that ε – UO 3 does not form during the initial ramp up stage nor during the high temperature heating period; but instead forms during the cooling stage between 250 – 400 °C. Additional experiments revealed that UNH initially decomposes through an amorphous UO 3 intermediate prior to α – U 3 O 8 formation. Attempts to bypass the U 3 O 8 precursor in the formation of ε – UO 3 were unsuccessful, supporting the necessity of U 3 O 8 (α – U 3 O 8 in this study) in the formation of ε – UO 3 . The observed phase evolution is proposed to result from the NOx species generated during UNH thermal decomposition, which create localized oxidizing conditions within the furnace under static air conditions. Furthermore, a predominantly phase pure ε – UO 3 was synthesized under static air conditions through the addition of an extra plateau at 250 °C during the cooling step. These findings demonstrate the importance of gas-phase chemistry and cooling conditions in uranium oxide phase evolution and provide additional insight into ε – UO 3 formation pathways.
A high efficiency rooftop air conditioning system using multi-speed compressors
This study delineates a meticulous exploration of technologies to enhance the energy efficiency of rooftop air conditioning units, employing the DOE/ORNL heat pump design model for comprehensive engineering design and optimization. A baseline rooftop air conditioning unit, featuring a 13 ton (45.7 kW) cooling capacity and a 17.9 integrated energy efficiency ratio, served as the point of departure for substantive efficiency enhancements. Key modifications included the consolidation of two refrigerant circuits into one, integrating three parallel 2-stage (dual-speed) compressors, fan replacements with high-efficiency substitutes. Notably, a lower global warming potential refrigerant, R452B, was evaluated as a substitute for R-410A, demonstrating better performance in the lab prototype. Further, the achieved measured integrated energy efficiency ratio of 21.4 in the lab prototype surpassed the baseline integrated energy efficiency ratio. Comparative evaluations between R410A and R452B indicated heightened efficiency with the latter, showcasing a lab-demonstrated integrated energy efficiency ratio of 22.4 at the rated capacity of 13.8 ton (48.5 kW) and 23.9 integrated energy efficiency ratio at the rated capacity of 10 ton (35.2 kW). This research underscores the successful development of a rigorous, energy efficient rooftop air conditioning unit prototype with noteworthy environmental and economic implications.
Sensitivity analysis of an automated fault detection algorithm for residential air-conditioning systems
The state of the art of fault detection and diagnosis (FDD) for residential air-conditioning systems is expensive and not yet amenable to widespread implementation. FDD for homes can significantly reduce utility costs, and increase the lifespan of the equipment. The cost barriers currently, however, make FDD for homes economically unviable for large scale implementation. In prior work, we offered a solution to reduce FDD costs by proposing an automated fault detection algorithm to serve as a screening step before more expensive FDD tests can be conducted. The algorithm uses only the home thermostat and local weather information to identify thermodynamic parameters and detect high-impact air-conditioning faults, including those that occur during equipment installation. We had tested the algorithm on a single EnergyPlus™ model of a home in Orlando, Florida. The thermodynamic parameter identification process is highly nonconvex involving several local optimal solutions. In this paper we propose a novel method to select the best model for fault detection from among the list of local optimal solutions to make the algorithm more robust to homes of different construction, without which the fault detection process would be infeasible. Another unique contribution of the paper is implementing the solution on real-world data. We also bring the algorithm closer to market by testing it on real-world data. We implement the algorithm on data obtained from experiments conducted by the Florida Solar Energy Center (FSEC) on a laboratory home equipped with a heat pump where faults were intentionally added for a period of seven months. The algorithm successfully detected an undercharge fault with 70.6% accuracy, concurrent duct leakage and undercharge faults with 85.2% accuracy, and duct leakage faults with 69.1% accuracy. A sensitivity analysis is also performed on EnergyPlus models of nine types of homes that vary in construction to demonstrate the robustness of the algorithm. Finally, the algorithm achieves an average accuracy of 71% for no-fault condition, 77% for 40% undercharge fault, and 76% for duct-leak fault.
A review of computing-based automated fault detection and diagnosis of heating, ventilation and air conditioning systems
We report faults in Heating, Ventilation, and Air Conditioning (HVAC) systems of buildings result in significant energy waste in building operation. With fast-growing sensing data availability and advancement in computing, computational modeling has demonstrated strong capability to detect and diagnose HVAC system faults, hence, ensuring efficient building operation. This paper comprehensively reviews the state-of-the-art computing-based fault detection and diagnosis (FDD) for HVAC systems. Overall, the reviewed computing-based FDD methods are classified as two major approaches: knowledge-based and data-driven approaches. We then identify multiple important topics, including data availability, training data size, data quality, approach generality, capability, interpretability, and required modeling efforts, along with corresponding metrics to summarize the most updated FDD development. Generally, the knowledge-based approaches are further divided as physics-based modeling, Diagnostic Bayesian Network, and performance indicator-based methods while data-driven approaches include supervised learning, unsupervised learning, and regression and statistics-based methods. State-of-the-art FDD development, remaining challenges, and future research directions are further discussed to push forward FDD in practice. Availability of fault data, capability of existing methods to deal with complex fault situations (such as simultaneous faults), modeling interpretability for data-driven methods, and required engineering efforts for physics-based methods are identified as remaining challenges in FDD development. Improving modeling fidelity and reducing modeling efforts are essential for applying physics-based methods in real buildings. Meanwhile, addressing fault data availability, increasing algorithm adaptability, and handling multiple faults are essential to further enhance the applicability of data-driven FDD approaches.
Humidity’s impact on greenhouse gas emissions from air conditioning
We report that the increasing need to cool the air in our built environment is both a cause and an effect of climate change. Air conditioning accounts for a large portion of global greenhouse gas emissions today, which we estimate at 3.9%; however, the role that humidity plays in these emissions is often overlooked. Here, we show that the emissions associated with reducing air humidity (i.e., removing water vapor from air) are larger than emissions associated with reducing air temperature (i.e., cooling air). We calculate these emissions for today and 2050 and show how dramatically humidity-related emissions will increase with rising cooling demand around the world. We also calculate the minimum separation energy for removing water vapor from air and find that this is at least an order of magnitude less than the processes used today.
Material properties of aqueous potassium acetate solutions for use in liquid desiccant air conditioning
We present thermophysical properties of aqueous potassium acetate solutions relevant to their application as a liquid desiccant in air-conditioning systems. Liquid desiccant air conditioners could provide up to 80% energy savings compared to high-efficiency vapor compression air conditioners. However, the commonly used liquid desiccants, particularly chloride salt solutions, are highly corrosive. This precludes the use of metallic components, necessitating specialized plastics and thereby driving up cost, weight, and limiting operational temperature and pressure ranges. Potassium acetate has been identified as a less corrosive alternative, potentially enabling broader material compatibility in LDAC components. In this study we systematically measured and modelled key thermophysical properties of KAc solutions density, vapor pressure, viscosity, specific heat capacity, phase behavior, and diffusion coefficient across a range of concentrations (10 - 70wt%) and temperatures. For instance, KAc exhibits a vapor pressure of 3.1 kPa at 50wt% and 40degrees C, demonstrating dehumidification capability comparable to chloride salts. By providing an extended dataset and associated models, this work advances the understanding needed to design energy-efficient, corrosion mitigating LDAC system.
Benefits and challenges in deployment of low global warming potential R290 refrigerant for room air conditioning equipment in California
High global warming potential gases (“high GWP”) are the fastest growing sector of greenhouse gas emissions in the world and in California and are primarily used as refrigerant gases in refrigeration and cooling equipment. Hydrofluorocarbons (HFCs) refrigerants are the dominant type of high GWP gases with GWP values thousands of times larger than CO 2 on a 100-year timescale. Refrigerant-grade propane (“R290”) has a very low GWP (GWP = 3.3) with good thermodynamic properties and good cooling equipment performance but the flammability of any leaked refrigerant makes equipment design, handling, and maintenance critical factors to manage. This paper focuses on the potential climate benefits and costs of transitioning to R290 refrigerant in small room air conditioning (AC) units, specifically window AC, packaged terminal AC/heat pumps (PTAC/PTHP), and mini-split heat pumps. Overall climate impact for a transition to all three types of air conditioning units in the 2022–2051 timeframe is found to be from 15 to 64 million metric tons of greenhouse gas (GHG) savings in California with a cost of saved CO 2 eq that ranges from $14.50 per ton of CO 2 eq saved to -$50.30 per ton of CO 2 eq saved (net savings) depending on whether the baseline refrigerant is R32 or R410A and depending on the relative energy efficiency for R290 units compared to baseline units.
Building Technologies Office 03.02.02.38 Milestone Report — Technology Options for Low Environmental Impact Air-Conditioning and Refrigeration Systems
Due to increasing concerns about global warming, various environmental regulations will eventually phase out refrigerants used in air conditioning and refrigeration systems (e.g., R-410A, R-404A). Several refrigerants have been proposed as replacements, offering a variety of global warming potential (GWP), levels of energy efficiency and flammability. Some of these options are synthetic HFC/HFO mixtures such as R-454C and R-455A while other are commonly called naturals such as R-290 (Propane) and R-744 (Carbon Dioxide). This study discusses the merits of the leading options for air Conditioning and refrigeration systems. The fundamental requirements (environmental, performance, safety) are employed to fairly evaluate these options. Performance data and Life Cycle analysis results for these options are presented. Overall, this study provides information needed to judge the prospects of getting adequate replacement for R-410A and R-404A in a long-term sustainable basis.
Geologic Seawater Air Conditioning (GeoSWAC) System: Resource Assessment and Techno-Economic Evaluation in Puerto Rico
Puerto Rico's hot, humid climate drives a high and persistent demand for cooling, straining an aging and fuel-dependent energy grid while increasing peak electricity loads. Much of this challenge stems from inefficient air-conditioning systems operating in buildings without passive cooling design, making cooling both costly and vulnerable to disruption - especially during hurricanes. To address these issues, researchers evaluated a new alternative called Geologic Seawater Air Conditioning (GeoSWAC), which uses inland wells connected to naturally cold, deep seawater. By avoiding long offshore pipelines and energy-intensive refrigeration cycles, GeoSWAC can cut electricity use by 75-90%, reduce environmental impacts, and operate more reliably during power outages. A case study at the University of Puerto Rico's Rio Piedras campus found that GeoSWAC could deliver significantly lower levelized costs of cooling, reduced operational expenses, and improved water conservation compared to the campus's existing chilled-water plant. The system offers key advantages - including access to a constant cold heat sink, low pumping requirements, and enhanced resilience - for coastal regions such as Puerto Rico, the broader Caribbean, and Florida. However, its effectiveness depends heavily on site-specific geological conditions, such as subsurface connectivity and aquifer characteristics, which require detailed investigation. Future research should refine hydrogeological models, conduct performance and economic analyses, and address regulatory and permitting frameworks to support broader adoption of this promising technology.
Numerical Simulation Studies of Ultrasonic De-Icing for Heating, Ventilation, Air Conditioning, and Refrigeration Structures
Ice accumulation on heating, ventilation, air conditioning, and refrigeration (HVACR) structures presents significant operational challenges. These challenges include reduced efficiency, increased energy consumption, and potential damage to equipment. Traditional de-icing methods, such as chemical treatments, mechanical scraping, or heating-based techniques, are often labor-intensive, costly, and environmentally harmful. Here, this study uniquely investigates ultrasonic de-icing as an energy-efficient alternative for HVACR applications, focusing on the specific structural geometries found in these systems. A comprehensive numerical simulation framework was developed using finite element analysis to explore ultrasonic wave propagation across four distinct HVACR structures. Key parameters such as ultrasonic frequency, power levels, and the number and placement of actuators were examined for their impact on ice detachment efficiency. Results from simulations on a plate structure reveal that ultrasonic excitation can propagate effectively across large areas (at least 150 × 150 mm), enhancing the de-icing coverage. Lower frequency (e.g., 30 to 45 kHz) excitation results in greater displacement, improving de-icing performance, while increased actuator numbers with the same total power input also enhance effectiveness. Two actuators seem sufficient for the de-icing of a 300 × 300 mm plate. For tube-and-fin structures, specific high-power ultrasonic frequencies selectively excite the fin plates, demonstrating efficient ice removal when actuated on the tube. However, optimal performance requires careful design of actuator placement and vibration modes to accommodate the irregular shapes of these structures.
Air Conditioning Systems Fault Detection and Diagnosis-Based Sensing and Data-Driven Approaches
The air conditioning (AC) system is the primary building end-use contributor to the peak demand for energy. The energy consumed by this system has grown as fast as it has in the last few decades, not only in the residential section but also in the industry and transport sectors. Therefore, to combat energy crises, urgent actions on energy efficiency should be taken to support energy security. Consequently, the faults in AC system components increase energy consumption due to the degradation of the system’s performance and the losses in the energy conversion procedure. In this work, AC system fault detection and diagnosis (FDD) methods are investigated to propose analytic tools to identify faults and provide solutions to those problems. The analysis of existing work shows that data-driven approaches are more accurate for both soft and hard fault detection and diagnosis in AC systems. Therefore, the proposed methods are not accurate for simultaneous fault detection, while in some works, authors tested the method with several faults separately without investigating scenarios that combine more than one fault. Moreover, this study shows that integrating data-driven approaches requires deploying an optimal sensing and measurement architecture that can detect a maximum number of faults with minimally deployed sensors. The new sensing, information, and communication technologies are discussed for their integration in AC system monitoring in order to optimize system operation and detect faults.
Corrosion of Metal Alloys in Potassium Acetate Solutions for Liquid Desiccant Dehumidification and Air Conditioning
For commercial buildings, liquid desiccant air conditioners (LDACs) could provide up to 80% energy savings compared to high-efficiency vapor compression AC, but commonly utilized liquid desiccants are highly corrosive. This precludes the use of metallic components, necessitating specialized plastics and thereby driving up cost, weight, and limiting operational temperature and pressure ranges. Less corrosive alternatives are sought. Here, potassium acetate solutions are investigated as less-corrosive alternatives to the chloride salt solutions that are typically used in LDAC systems. Corrosion evaluations for a Cu alloy (C12200) and two Al alloys (Al3003 and Al1100) in both potassium acetate and chloride salt solutions are presented. We show that yearly corrosion rates are lower in potassium acetate solutions by up to three orders of magnitude. Active corrosion behavior is largely absent in potassium acetate solutions but is present in chloride salt solutions. Furthermore, solid corrosion products are observed in chloride salt solutions. Thus, we conclude that potassium acetate is a promising candidate as a less corrosive alternative liquid desiccant for LDAC systems with metallic components.
Performance and Characterization of Membrane Liquid Desiccant Air Conditioning Systems
This document is intended to describe the work objectives and tasks for several projects between the National Renewable Energy Laboratory (NREL) and 7AC Technologies, with indirect support from 3M. The projects all revolve around the performance and characterization of membrane liquid desiccant air conditioning systems. Projects are listed in order of preference to 7AC's technical and business goals.
ResStock Measure Documentation: Reference Space Heating and Air Conditioning Upgrade Circa 2025
This report is part of a series describing different ResStock (TM) measures. "Measures" refers to energy efficiency retrofits that can be applied to buildings during modeling. This documentation covers the "Reference Space Heating and Air Conditioning Upgrade Circa 2025" measure upgrade methodology and briefly discusses key results.
Inequality in the availability of residential air conditioning across 115 US metropolitan areas
Continued climate change is increasing the frequency, severity, and duration of populations’ high temperature exposures. Indoor cooling is a key adaptation, especially in urban areas, where heat extremes are intensified—the urban heat island effect (UHI)—making residential air conditioning (AC) availability critical to protecting human health. In the United States, the differences in residential AC prevalence from one metropolitan area to another is well understood, but its intra-urban variation is poorly characterized, obscuring neighborhood-scale variability in populations’ heat vulnerability and adaptive capacity. We address this gap by constructing empirically derived probabilities of residential AC for 45,995 census tracts across 115 metropolitan areas. Within cities, AC is unequally distributed, with census tracts in the urban “core” exhibiting systematically lower prevalence than their suburban counterparts. Moreover, this disparity correlates strongly with multiple indicators of social vulnerability and summer daytime surface UHI intensity, highlighting the challenges that vulnerable urban populations face in adapting to climate-change driven heat stress amplification.
Apparatus and system for controlling power to an air conditioning compressor for a vehicle
A climate control system for vehicles includes an internal combustion engine that may be coupled to selectively power a first motor generator, and an air conditioning compressor that may be selectively powered by one or both of the first motor generator and a second motor generator, or by the internal combustion engine. The system may include a rechargeable battery, and a vehicle controller having a vehicle state circuit structured to determine a vehicle operating condition value and a state-of-charge value of the rechargeable battery, and a coupling determination circuit structured to provide an internal combustion engine-first motor generator coupling command in response to the vehicle operating condition value and the state-of-charge value. In response to the internal combustion engine-first motor generator coupling command being provided as coupled, the internal combustion engine may power the first motor generator.