Dynamic Nuclear Polarization Facility at UNH
Dynamic Nuclear Polarization Facility at UNH
Slifer, Karl↗
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New helium recapture and reliquefier system for Dynamic Nuclear Polarization at UNH.
A new helium recapture and reliquefaction system, consisting of a gas bag, recapture manifold, cooling chiller, cryogenic purifier and, a gas storage cylinder banks, has been installed in the dynamic nuclear polarized target lab at the University of New Hampshire. This new system has the capability to improve the efficiency of our capacity to do target polarization runs by recycling our cryogenic helium which would otherwise be lost during polarization operations. Our helium liquefier is rated upto 40 L/Day under normal full-capacity operations, and is rated for a capacity of 500 liquid liters of helium. I explain the initial installation process followed by a discussion of the challenges with installation, including issues of impurities which appeared during the initial operation of the system. Then I discuss how we overcame these difficulties. Finally, I discuss the function of the system during normal operation and the present situation of the helium recapture and reliquefaction processing in the UNH Lab.
Lama, Chhetra [Univ. of New Hampshire, Durham, NH ↗
Data analysis support for UNH gamma ray detector on OSO-7
The data is reviewed from the gamma ray experiment on OSO-7. Analysis of the data, and information on the data processing are described.
Chupp, E. L.↗
A summary of major activities of the UNH and NRL groups
The major activities of the SMM GRS team members at the University of New Hampshire and the Naval Research Laboratory since the last semi-annual report are summarized. An updated list of published papers and invited papers or contributed papers presented at scientific meetings is provided.
Chupp, E. L.↗
In-Situ Blade Strain Measurements and Fatigue Analysis of a Cross-Flow Turbine Operating in a Tidal Flow
Cross-flow turbines (CFTs) are inherently unsteady devices with regards to operating principle and loading. By improving our understanding of the dynamic loading on these turbines, we hope to better inform CFT design, improve survivability, and reduce overall costs. The University of New Hampshire (UNH) and the National Renewable Energy Laboratory (NREL) collaborated on a project to instrument and test a four-bladed New Energy Corp. vertical axis cross-flow turbine in a real tidal flow. One blade from the 3.2 m diameter x 1.7 m height turbine was instrumented with eight full-bridge strain gauges along the span of the blade. The turbine was then deployed at the UNH-Atlantic Marine Energy Center (AMEC) Tidal Energy Test Site in Portsmouth, NH. Time-synchronized measurements of blade strain, inflow, thrust, rotational speed, and electrical output were obtained to characterize blade loading under various conditions. The blade strain was examined to assess the dynamic loading and conduct a fatigue analysis on the device.
blade strain↗
Recovering high-purity uranyl nitrate from simulated used nuclear fuel dissolver solutions by crystallization: rejecting technetium
The separation of U from Tc and other problematic fission product elements like Mo and Ru, along with Sr, Zr, Cs, and Nd, has been achieved via the crystallization of uranyl nitrate hexahydrate (UNH). Rejection of technetium as pertechnetate anion ( 99 TcO 4 – ) is an especially important feature of this system, as it otherwise tends to follow U (VI) in extractive separations. It also raises the salient question regarding why this oxoanion cannot replace nitrate within the crystalline lattice of UNH. Results showed high-yield (>90 %), high-purity (>99 %) recovery of U as UNH from solutions containing 99 TcO 4 – by simple reduction of temperature from 60°C to 20°C. There was no observable interaction of 99 TcO 4 – with UO 2 2+ . The addition of other cations like, Sr 2+ , Zr 4+ , Cs + , and Nd 3+ , also did not form secondary, contaminant solid phases, leaving the > 99 % of the fission product elements in the mother liquor, while the U was recovered at > 90 %. Similarly, Mo and Ru, when added to the mixture, were shown to behave as the other fission-product elements, remaining in the mother liquor during crystallization. As a result, DFT calculations showed that, despite the higher binding strength of TcO 4 – , HMoO 4 – , and BiO 3 – with the UO 2 2+ cation compared to NO 3 – , the hydrogen-bonding network of the two coordinated ions and four waters of hydration in the UNH crystal structure is the driving force for the high specificity of this separation.
11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗
Remote sensing of Pu in uranyl nitrate crystals using reflectance spectroscopy and chemometrics
Remote quantification of Pu(VI) (0–5 mol%) co-crystallized with U in uranyl nitrate hexahydrate (UNH) crystals was achieved in a glove box using reflectance spectroscopy coupled with chemometric modeling. Reflectance spectra were also acquired for Pu(IV) and Np(VI) (0–5 mol%) crystallized with UNH; revealing spectral features consistent with their solution-phase analogs. Principal component analysis revealed Pu(IV/VI) and Np(VI) concentrations as the primary source of variation in the data, informing the development of a supervised partial least squares regression model for Pu(VI). The resulting calibration demonstrated robust performance, with replicate root mean square errors near 10% and quantifiable limits near 0.2 mol% Pu(VI) relative to U. The Pu(VI) remained stable in the crystalline UNH matrix for at least one week with minimal reduction to Pu(IV). Notably, Pu(VI) and Np(VI) incorporation in UNH quenched U(VI) fluorescence while Pu(IV) did not. This study presents a noninvasive, spectroscopic approach for solid-state Pu quantification, with direct implications for material accountability and nuclear nonproliferation monitoring.
Sadergaski, Luke R. [Oak Ridge National Laboratory↗
EGRET High Energy Capability and Multiwavelength Flare Studies and Solar Flare Proton Spectra
UNH was assigned the responsibility to use their accelerator neutron measurements to verify the TASC response function and to modify the TASC fitting program to include a high energy neutron contribution. Direct accelerator-based measurements by UNH of the energy-dependent efficiencies for detecting neutrons with energies from 36 to 720 MeV in NaI were compared with Monte Carlo TASC calculations. The calculated TASC efficiencies are somewhat lower (by about 20%) than the accelerator results in the energy range 70-300 MeV. The measured energy-loss spectrum for 207 MeV neutron interactions in NaI were compared with the Monte Carlo response for 200 MeV neutrons in the TASC indicating good agreement. Based on this agreement, the simulation was considered to be sufficiently accurate to generate a neutron response library to be used by UNH in modifying the TASC fitting program to include a neutron component in the flare spectrum modeling. TASC energy-loss data on the 1991 June 11 flare was transferred to UNH. Also included appendix: Gamma-rays and neutrons as a probe of flare proton spectra: the solar flare of 11 June 1991.
Chupp, Edward L.↗
NOx mediated formation of ε – UO 3 during thermal decomposition of uranyl nitrate hexahydrate under static air conditions
The thermal decomposition of uranyl nitrate hexahydrate in air at temperatures of 650 – 800 °C is expected to yield α – U 3 O 8 through intermediate UO 3 phases. Here, n this study, Raman spectroscopy complimented by powder X-ray diffraction revealed the unexpected formation of ε – UO 3 as an accompanying phase during thermal decomposition of UNH at 700 °C under static air conditions. Experiments demonstrated that ε – UO 3 does not form during the initial ramp up stage nor during the high temperature heating period; but instead forms during the cooling stage between 250 – 400 °C. Additional experiments revealed that UNH initially decomposes through an amorphous UO 3 intermediate prior to α – U 3 O 8 formation. Attempts to bypass the U 3 O 8 precursor in the formation of ε – UO 3 were unsuccessful, supporting the necessity of U 3 O 8 (α – U 3 O 8 in this study) in the formation of ε – UO 3 . The observed phase evolution is proposed to result from the NOx species generated during UNH thermal decomposition, which create localized oxidizing conditions within the furnace under static air conditions. Furthermore, a predominantly phase pure ε – UO 3 was synthesized under static air conditions through the addition of an extra plateau at 250 °C during the cooling step. These findings demonstrate the importance of gas-phase chemistry and cooling conditions in uranium oxide phase evolution and provide additional insight into ε – UO 3 formation pathways.
Epsilon uranium trioxide↗
Study of Ring Current Dynamics During Geomagnetic Storms
This research program considered modeling the dynamical evolution of the ring current during several geomagnetic storms. The first year (6/01/1997-5/31/1998) of this successful collaborative research between the University of New Hampshire (UNH) and the University of California Los Angeles (UCLA) was supported by NASA grant NAG5-4680. The second and third years (6/01/1998-5/31/2000) were funded at UNH under NASA grant NAG5-7368. Research work at UNH concentrated on further development of a kinetic model to treat all of the important physical processes that affect the ring current ion population during storm conditions. This model was applied to simulate ring current development during several International Solar-Terrestrial Physics (ISTP) events, and the results were directly compared to satellite observations. A brief description of our major accomplishments and a list of the publications and presentations resulting from this effort are given.
Jordanova, Vania K.↗
A Co-Investigator Proposal for the Cornell University CAPER Rocket: Cleft Accelerated Plasma Experiment Rocket
The objectives are: 1) To support the Cornell wave instruments in a study of dayside ion outflow. 2) In conjunction with the U. of Alaska ground optical data, a prime objective was to measure the topside Cusp ion spectra responsible for dayside proton aurora. If such a correlative measurement could be made, then monitoring of this cusp precipitation from the ground could be routinely achieved. The nature of Cusp ions has and will continue to provide information about dayside magnetic reconnection. 3) A third objective was to study the dayside microburst electron precipitation from the BPS/CPS population. The Scifer rocket flight showed a bursty electron population at 1000 km altitude correlated closely with pulsation ground aurora on closed field lines. The frequency of this pulsating aurora is about 1 Hz. Ground pulsation measurements have recorded dayside bursts of Pc1 waves which could very well be the source of the electrons responsible for the pulsating aurora. In support of the Caper flight, UNH provided ground induction antennas to measure the equatorial Pc1 waves that might be dumping trapped electrons from the Central Plasma Sheet population. The Caper flight was launched on the last day of the window and all the Cornell and UNH instrumentation worked perfectly. Unfortunately the rocket trajectory flew very far to the west of the ground site at Longyearbyen missing conjugacy by several hundred kilometers. This meant the intended aurora was not crossed and all the ground experiments were far from being near the foot print of the rocket ruling out correlative science. The "miss" was primarily due to a decision during the countdown by the Andoya Rocket Range to move the azimuth of the rocket to the west to avoid Norwegian fishing boats at the splash point of the first two stages, and to make matters worse, the dispersion of the fourth stage of the rocket added entirely in this direction. Although no publications have resulted from the UNH data up to this point, a joint publication with the U. of Alaska group using both the Scifer and Caper data is in preparation. The data will continue to be worked on. There is interest in the Caper data as evidence by two recent papers presented at the "Low Latitude Boundary Layer Chapman Conference" held in New Orleans, Louisiana in April 2001.
Arnoldy, Roger L.↗
TEAMER: Pitching Foil Crossflow Turbine Efficiency Data
This dataset documents the efficiency testing of a pitching foil crossflow turbine, conducted at the University of New Hampshire's (UNH) Chase Ocean Engineering Laboratory tow tank facility. The tests explored various pitch phases and amplitudes, ranging from 0 to 18 degrees, across different flow speeds and turbine RPMs. Specifically, testing was performed at pitch amplitudes of 0,3,6,9,12,15 and 18 degrees. The results indicate that turbine efficiency improves with increased pitch amplitude, reaching optimal performance at 12 degrees. Modifications were made to the test frame by UNH to enhance the stiffness of the support structure. The testing specifically mapped the efficiency of a single quadrant of the Ocean Renewable Power Company (ORPC) Autonomous Turbine Generator Unit (ATGU), covering the full range of allowable pitching amplitudes and phases. The dataset provides both raw and processed data, including drag and torque measurements, and contains Python scripts used for data processing and visualization. This research was supported by funding from TEAMER RFTS 1 (Request for Technical Support).
16 TIDAL AND WAVE POWER↗
Wave-powered water pump for upwelling in aquaculture: Numerical model and ocean test
Wave-powered upwelling can increase the productivity and survivability of several aquaculture species. This enhancement is due to transporting cold, nutrient-rich ocean water, typically found lower in the water column, to the surface. Macroalgaes, like kelp, exhibit increased growth from these altered conditions. The University of New Hampshire’s (UNH) wave-powered water pump (wave pump) is a point absorber wave energy converter (WEC) that uses ocean waves to create relative motion between a spar buoy and a concentric float which drives an internal pump. A numerical model of the wave pump was developed using WEC-Sim to predict device performance in the ocean. Wave pump performance was evaluated during a five day ocean test near Appledore Island in Maine in March 2023, where volumetric flow rate, relative distance between spar and float, and wave conditions were measured. These data were then used for numerical model validation. The ocean deployment recorded the device’s performance in a variety of sea states, with average significant wave heights up to 0.7 m. The ocean test data were compared to the WEC-Sim numerical model of the device with favorable results. Average values of device stroke period, stroke height, and flow rate agreed between the ocean test and model data to within approximately 16 to 22%. Furthermore, the validated numerical model provides a valuable tool for improving the design and developing a commercial-scale, wave-powered water pump for use in aquaculture.
16 TIDAL AND WAVE POWER↗
Development of chemometric models to classify solid-state U materials by micro-Raman spectroscopy
Discerning uranium (U) particles found in environmental sampling is of interest for monitoring the peaceful use of nuclear material. In this study, a soft independent modeling of class analogy (SIMCA) library was successfully developed for the classification of a four-class system consisting of α-U 3 O 8 , UO 2 , UO 2 (NO 3 ) 2 ·6H 2 O (UNH), and UO 2 O 2 ·4H 2 O (studtite) by Raman spectroscopy in the presence of matrix particulates and additional outliers. Spectral variability between numerous particles of each type revealed appreciable differences as a function of particle size with respect to hydration state and potential oxide phase within each class. Interclass variability was accounted for using both unsupervised and supervised chemometric models. The supervised SIMCA model displayed reasonable sensitivity for each U class and a high degree of specificity by returning whether a spectrum belonged to one class or not. This work demonstrates how Raman spectral features and chemometrics can be used to distinguish U materials from one another and from matrix materials such as flint clay. Combining the outlined chemometric approach with Raman mapping sequences could provide a rapid, nondestructive technique to characterize the chemical composition of a diverse collection of U compounds amid background samples for environmental sampling, nuclear forensics, and industrial applications.
Actinide↗
Gamma ray observations during the August 1972 solar activity
During the solar activity period in August 1972, the UNH gamma ray monitor on the OSO-7 satellite measured gamma ray line and continuum fluxes of solar origin on at least two occasions; August 4 and 7. In this discussion, the experiment and the gamma ray line observations are reviewed with a few brief remarks on interpretation. The specific observations discussed are measurements of gamma ray lines at 0.51 and 2.2 MeV during two of the largest optical solar flares. Evidence for lines at other energies is also given.
Chupp, E. L.↗