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Results for “Hydrolytic depolymerization”

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Strength and fracture of glass in the lunar environment

Due to the lack of water on the moon, the effects of hydrolytic depolymerization - stress corrosion cracking - will be nonexistent in glasses produced and used on the moon. This would seem to make lunar glass very attractive for use in a wide variety of space engineering applications. We have applied the equation that describes stress corrosion cracking to lunar glass to show that, indeed, decreasing water vapor pressure results in an increase in strength. Experimental results on simulated lunar glass confirm this. The stress corrosion equation predicts an extremely high strength for glasses produced on the moon. This equation, however, cannot be applied to glasses under anhydrous conditions. In an environment completely devoid of water, the strength of glass will be determined by the fracture of the glass at the tip of a flaw, without the corrosive effects of water. Under this condition, in accordance with fracture theory, the strength of the glass will primarily be a function of the flaw size. Our experimental results show that the presence of surface flaws is more detrimental to the strength of simulated lunar glass than the effect of hydrolytic depolymerization.

Allen, Daniel D.

Aqueous ionic liquid–mediated depolymerization of textile waste

Textile waste, dominated by polyester-cotton blends, largely evades recycling and ends up in landfills or incinerators. Here, we demonstrate an aqueous ionic liquid–mediated route for selective depolymerization of textile waste, including polyester and polycotton (polyester/cotton blend). Using aqueous cholinium lysinate ([Ch][Lys]), we depolymerized poly(ethylene terephthalate) (PET) textiles with over 95 % terephthalic acid (TPA) yields, comparable to virgin PET resin. Notably, colored fabrics showed no inhibitory effect from dyes. While protic ionic liquids such as ethanolammonium acetate showed limited efficiency, their precursor amine enabled near-complete PET conversion—ethanolamine promoted aminolysis with byproduct formation whereas butylamine achieved higher TPA recovery through combined hydrolysis and aminolysis. Importantly, polycotton blends achieved complete PET depolymerization with TPA yield above 85 % and preserved cotton. These results establish aqueous ionic liquids as efficient, selective agents for deconstructing polyester in blended textiles, offering flexible product and ionic liquid management pathways toward scalable and facile textile recycling.

Amines