Aqueous ionic liquid–mediated depolymerization of textile waste

Chen, Xueli [Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States)]; Lewis, Tyrell S.A. [Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States); Lawrence Berkeley National Laboratory (LBNL), Emeryville, CA (United States)]; Hitt, Addison J. [Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States); Lawrence Berkeley National Laboratory (LBNL), Emeryville, CA (United States)]; Palasz, Joseph [Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States)]; Krishnamoorthy, Anagha [Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States)]; Dou, Chang [Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States); Lawrence Berkeley National Laboratory (LBNL), Emeryville, CA (United States)]; Choudhary, Hemant [Joint BioEnergy Institute (JBEI), Emeryville, CA (United States); Sandia National Laboratories (SNL-CA), Livermore, CA (United States)] (ORCID:0000000328473080); Sun, Ning [Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States); Lawrence Berkeley National Laboratory (LBNL), Emeryville, CA (United States)]; Simmons, Blake A. [Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States); Joint BioEnergy Institute (JBEI), Emeryville, CA (United States)] (ORCID:0000000213321810)

doi:10.1016/j.jil.2026.100199

DOE OSTI · 3023855

Aqueous ionic liquid–mediated depolymerization of textile waste

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Abstract

Textile waste, dominated by polyester-cotton blends, largely evades recycling and ends up in landfills or incinerators. Here, we demonstrate an aqueous ionic liquid–mediated route for selective depolymerization of textile waste, including polyester and polycotton (polyester/cotton blend). Using aqueous cholinium lysinate ([Ch][Lys]), we depolymerized poly(ethylene terephthalate) (PET) textiles with over 95 % terephthalic acid (TPA) yields, comparable to virgin PET resin. Notably, colored fabrics showed no inhibitory effect from dyes. While protic ionic liquids such as ethanolammonium acetate showed limited efficiency, their precursor amine enabled near-complete PET conversion—ethanolamine promoted aminolysis with byproduct formation whereas butylamine achieved higher TPA recovery through combined hydrolysis and aminolysis. Importantly, polycotton blends achieved complete PET depolymerization with TPA yield above 85 % and preserved cotton. These results establish aqueous ionic liquids as efficient, selective agents for deconstructing polyester in blended textiles, offering flexible product and ionic liquid management pathways toward scalable and facile textile recycling.

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Amines Aminolysis Aqueous ionic liquid Blended textiles Hydrolytic depolymerization

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Chen, Xueli [Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States)], Lewis, Tyrell S.A. [Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States); Lawrence Berkeley National Laboratory (LBNL), Emeryville, CA (United States)], Hitt, Addison J. [Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States); Lawrence Berkeley National Laboratory (LBNL), Emeryville, CA (United States)], Palasz, Joseph [Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States)], Krishnamoorthy, Anagha [Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States)], Dou, Chang [Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States); Lawrence Berkeley National Laboratory (LBNL), Emeryville, CA (United States)], Choudhary, Hemant [Joint BioEnergy Institute (JBEI), Emeryville, CA (United States); Sandia National Laboratories (SNL-CA), Livermore, CA (United States)] (ORCID:0000000328473080), Sun, Ning [Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States); Lawrence Berkeley National Laboratory (LBNL), Emeryville, CA (United States)], Simmons, Blake A. [Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States); Joint BioEnergy Institute (JBEI), Emeryville, CA (United States)] (ORCID:0000000213321810). 2026-03-12. Aqueous ionic liquid–mediated depolymerization of textile waste. https://doi.org/10.1016/j.jil.2026.100199

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