Survey of heat transfer to near-critical fluids
Near critical heat transfer in cryogenic fluids, discussing thermodynamic and transport properties
Hendricks, R. C.↗
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A Geophysical Flow Experiment in a Compressible Critical Fluid
The first objective of this experiment is to build an experimental system in which, in analogy to a geophysical system, a compressible fluid in a spherical annulus becomes radially stratified in density through an A.C. electric field. When this density gradient is demonstrated, the system will be augmented so that the fluid can be driven by heating and rotation and tested in preparation for a microgravity experiment. This apparatus consists of a spherical capacitor filled with critical fluid in a temperature controlled environment. To make the fluid critical, the apparatus will be operated near the critical pressure, critical density, and critical temperature of the fluid. This will result in a highly compressible fluid because of the properties of the fluid near its critical point. A high voltage A.C. source applied across the capacitor will create a spherically symmetric central force because of the dielectric properties of the fluid in an electric field gradient. This central force will induce a spherically symmetric density gradient that is analogous to a geophysical fluid system. To generate such a density gradient the system must be small (approx. 1 inch diameter). This small cell will also be capable of driving the critical fluid by heating and rotation. Since a spherically symmetric density gradient can only be made in microgravity, another small cell, of the same geometry, will be built that uses incompressible fluid. The driving of the fluid by rotation and heating in these small cells will be developed. The resulting instabilities from the driving in these two systems will then be studied. The second objective is to study the pattern forming instabilities (bifurcations) resulting from the well controlled experimental conditions in the critical fluid cell. This experiment will come close to producing conditions that are geophysically similar and will be studied as the driving parameters are changed.
Hegseth, John↗
Zeno: Critical Fluid Light Scattering Experiment
The Zeno (Critical Fluid Light Scattering) experiment is the culmination of a long history of critical fluid light scattering in liquid-vapor systems. The major limitation to making accurate measurements closer to the critical point was the density stratification which occurs in these extremely compressible fluids. Zeno was to determine the critical density fluctuation decay rates at a pair of supplementary angles in the temperature range 100 mK to 100 (mu)K from T(sub c) in a sample of xenon accurately loaded to the critical density. This paper gives some highlights from operating the instrument on two flights March, 1994 on STS-62 and February, 1996 on STS-75. More detail of the experiment Science Requirements, the personnel, apparatus, and results are displayed on the Web homepage at http://www.zeno.umd.edu.
Gammon, Robert W.↗
Assessment of critical-fluid extractions in the process industries
The potential for critical-fluid extraction as a separation process for improving the productive use of energy in the process industries is assessed. Critical-fluid extraction involves the use of fluids, normally gaseous at ambient conditions, as extraction solvents at temperatures and pressures around the critical point. Equilibrium and kinetic properties in this regime are very favorable for solvent applications, and generally allow major reductions in the energy requirements for separating and purifying chemical component of a mixture.
Source record↗
Survey of heat transfer to near-critical fluids
Survey of heat transfer to near-critical fluids
Hendricks, R. C.↗
Critical fluid thermal equilibration experiment (19-IML-1)
Gravity sometimes blocks all experimental techniques of making a desired measurement. Any pure fluid possesses a liquid-vapor critical point. It is defined by a temperature, pressure, and density state in thermodynamics. The critical issue that this experiment attempts to understand is the time it takes for a sample to reach temperature and density equilibrium as the critical point is approached; is it infinity due to mass and thermal diffusion, or do pressure waves speed up energy transport while mass is still under diffusion control. The objectives are to observe: (1) large phase domain homogenization without and with stirring; (2) time evolution of heat and mass after temperature step is applied to a one phase equilibrium sample; (3) phase evolution and configuration upon going two phase from a one phase equilibrium state; (4) effects of stirring on a low g two phase configuration; (5) two phase to one phase healing dynamics starting from a two phase low g configuration; and (6) effects of shuttle acceleration events on spatially and temporally varying compressible critical fluid dynamics.
Wilkinson, R. Allen↗
Penetration model explanation for turbulent forced-convection heat transfer observed in near-critical fluids
Penetration model explanation for turbulent forced convection heat transfer in near-critical fluids
Graham, R. W.↗
Critical fluid dynamics in two and three dimensions
We describe a numerical method for simulating stochastic fluid dynamics near a critical point in the Ising universality class. This theory is known as model H, and is expected to govern the nonequilibrium dynamics of quantum chromodynamics (QCD) near a possible critical endpoint of the phase transition between a hadron liquid and the quark-gluon plasma. The numerical algorithm is based on a Metropolis scheme, and automatically ensures that the distribution function of the hydrodynamic variables in equilibrium is independent of the transport coefficients and only governed by the microscopic free energy. We verify dynamic scaling near the critical point of a two and three-dimensional fluid and extract the associated critical exponent z. Here, we find z≃3 in three dimensions, and z≃2 for a two-dimensional fluid. In a finite system, we observe a crossover between the mean field value z=4 and the true critical exponent z≃3 (z≃2 in d=2). This crossover is governed by the values of the correlation length and the renormalized shear viscosity.
73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗
ZENO: A Critical Fluid Light Scattering Experiment
The ZENO experiment flew on the STS-62, it is designed to verify intriguing, but previously untested, theories in fluid physics. These theories attempt to describe dramatic changes in the properties of fluids near the critical temperature at which the vapor and liquid forms co-exist.
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Density Relaxation of Liquid-Vapor Critical Fluids Examined in Earth's Gravity
This work shows quantitatively the pronounced differences between the density equilibration of very compressible dense fluids in Earth's gravity and those in microgravity. The work was performed onsite at the NASA Glenn Research Center at Lewis Field and is complete. Full details are given in references 1 and 2. Liquid-vapor critical fluids (e.g., water) at their critical temperature and pressure, are very compressible. They collapse under their own weight in Earth's gravity, allowing only a thin meniscus-like layer with the critical pressure to survive. This critical layer, however, greatly slows down the equilibration process of the entire sample. A complicating feature is the buoyancy-driven slow flows of layers of heavier and lighter fluid. This work highlights the incomplete understanding of the hydrodynamics involved in these fluids.
Wilkinson, R. Allen↗
Long-Range Dispersion Governs the Behavior of Near-Critical Fluids: Universal Scaling and Implications for Accurate Molecular Simulation
Computer simulations of near-critical and supercritical fluids often deviate from experimental results, a discrepancy commonly attributed to force-field resolutions and inaccuracies. We demonstrate that these errors primarily stem from using finite cutoff schemes for dispersion interactions, which become effectively long-range as the correlation length grows near the critical point. By employing the smooth particle-mesh Ewald method to account for full long-range dispersion, we show that coarse-grained models can also achieve high quantitative accuracy for n-undecane and propylbenzene. This approach enables the precise determination of density fluctuations and correlation lengths, which exhibit universal critical scaling and depend on the molecular size and shape. Our findings resolve a longstanding debate in molecular simulations of near-critical fluids, establishing that capturing long-wavelength fluctuations is essential for bridging the gap between the microscopic behavior and macroscopic critical phenomena.
Chen, Guang↗
Transport processes in boiling and two-phase systems, including near-critical fluids
Aspects of pool boiling are considered, taking into account nucleate boiling, the nucleate boiling mechanism, film boiling, and the transition between nucleate and film boiling. The characteristics of two-phase flow are also investigated, giving attention to two-phase flow parameters and equations, the flow pattern in two-phase flow, the pressure drop in two-phase flow, heat transfer in two-phase flow, two-phase flow dynamics, the boiling crisis in two-phase flow, the critical flow rate, the propagation of the pressure pulse and the sonic velocity in two-phase media, instrumentation for two-phase flow, and geometry and field effects on boiling and two-phase flow. Near-critical fluids are also considered.
Hsu, Y.-Y.↗
Electric field effects on a near-critical fluid in microgravity
The effects of an electric field on a sample of SF6 fluid in the vicinity of the liquid-vapor critical point is studied. The isothermal increase of the density of a near-critical sample as a function of the applied electric field was measured. In agreement with theory, this electrostriction effect diverges near the critical point as the isothermal compressibility diverges. Also as expected, turning on the electric field in the presence of density gradients can induce flow within the fluid, in a way analogous to turning on gravity. These effects were observed in a microgravity environment by using the Critical Point Facility which flew onboard the Space Shuttle Columbia in July 1994 as part of the Second International Microgravity Laboratory Mission. Both visual and interferometric images of two separate sample cells were obtained by means of video downlink. The interferometric images provided quantitative information about the density distribution throughout the sample. The electric field was generated by applying 500 Volts to a fine wire passing through the critical fluid.
Zimmerli, G.↗
Critical fluid light scattering
The objective is to measure the decay rates of critical density fluctuations in a simple fluid (xenon) very near its liquid-vapor critical point using laser light scattering and photon correlation spectroscopy. Such experiments were severely limited on Earth by the presence of gravity which causes large density gradients in the sample when the compressibility diverges approaching the critical point. The goal is to measure fluctuation decay rates at least two decades closer to the critical point than is possible on earth, with a resolution of 3 microK. This will require loading the sample to 0.1 percent of the critical density and taking data as close as 100 microK to the critical temperature. The minimum mission time of 100 hours will allow a complete range of temperature points to be covered, limited by the thermal response of the sample. Other technical problems have to be addressed such as multiple scattering and the effect of wetting layers. The experiment entails measurement of the scattering intensity fluctuation decay rate at two angles for each temperature and simultaneously recording the scattering intensities and sample turbidity (from the transmission). The analyzed intensity and turbidity data gives the correlation length at each temperature and locates the critical temperature. The fluctuation decay rate data from these measurements will provide a severe test of the generalized hydrodynamic theories of transport coefficients in the critical regions. When compared to equivalent data from binary liquid critical mixtures they will test the universality of critical dynamics.
Gammon, Robert W.↗
Stirring Up an Elastic Fluid: Critical Viscosity of Xenon-2 (CVX-2)
Whipped cream stays in place even when turned upside down. Yet it readily flows through the nozzle of a spray can to reach the dessert plate. This demonstrates the phenomenon of shear thinning that is important to many industrial and physical processes. Paints, film emulsions, and other complex solutions that are highly viscous under normal conditions but become thin and flow easily under shear forces. A simple fluid, such as water, does not exhibit shear thinning under normal conditions. Very close to the liquid-vapor critical point, where the distinction between liquid and vapor disappears, the fluid becomes more complex and is predicted to display shear thinning. At the critical point, xenon atoms interact over long distances in a classical model of cooperative phenomena. Physicists rely on this system to learn how long-range order arises. The Critical Viscosity of Xenon Experiment (CVX-2) will measure the viscous behavior of xenon, a heavy inert gas used in flash lamps and ion rocket engines, at its critical point. Although it does not easily combine with other chemicals, its viscosity at the critical point can be used as a model for a range of fluids. Viscosity originates from the interactions of individual molecules. It is so complicated that, except for the simplest gas, it cannot be calculated accurately from theory. Tests with critical fluids can provide key data, but are limited on Earth because critical fluids are highly compressed by gravity. CVX-2 employs a tiny metal screen vibrating between two electrodes in a bath of critical xenon. The vibrations and how they dampen are used to measure viscosity. CVX flew on STS-85 (1997), where it revealed that, close to the critical point, the xenon is partly elastic: it can 'stretch' as well as flow. For STS-107, the hardware has been enhanced to determine if critical xenon is a shear-thinning fluid.
Berg, Robert F.↗
Critical fluid light scattering
Thermal fluctuations give rise to a host of thermodynamic anomalies near critical points. The background for these phenomena is presented, and an experiment design on STS flight experiment called 'Zeno' described. The objective is to measure the decay rates of critical density fluctuations in a simple fluid (xenon) very near its liquid-vapor critical point using laser light-scattering and photon-correlation spectroscopy. Such experiments have been limited on earth by the presence of gravity, which causes large density gradients in the sample. Fluctuation decay rates in xenon will be measured at least 100 times closer to the critical point than is possible on earth. This will require taking data as close as 145 microK to the critical temperature (Tc = 289.72 K), after locating it to + or - 10 microK. The minimum mission time of 100 hours will allow a complete range of temperature points to be covered, limited by the thermal response of the sample. An essential part of the apparatus is the thermostat. Its design principles and key features are given together with some observed performance characteristics of a prototype: + or - 20 microK stability for 18 hours, and one minute programmed step response for steps less than 10 mK.
Gammon, Robert W.↗
Critical fluid light scattering
Thermal fluctuations give rise to a host of thermodynamic anomalies near critical points. The background for these phenomena is presented, and an experimental design on STS flight experiment called Zeno is described. The objective is to measure the decay rates of critical density fluctuations in a simple fluid (xenon) very near its liquid-vapor critical point using laser light scattering and photon correlation spectroscopy. Such experiments have been limited on Earth by the presence of gravity, which causes large density gradients in the sample. Fluctuation decay rates in xenon will be measured at least 100 times closer to the critical point than is possible on Earth. This will require taking data as close as 145 micro K to the critical temperature, after locating it to + or - 10 micro K. The minimum mission time of 100 hours will allow a complete range of temperature points to be covered, limited by the thermal response of the sample. An essential part of the apparatus is the thermostat. Its design principles and key features are given together with some observed performance characteristics of a prototype: + or - 20 micro K stability for 18 hours, and one minute programmed step response for steps less than 10 mK.
Gammon, Robert W.↗
Survey of heat transfer to near critical fluids
Survey topics include - heat transfer boundaries of near critical region, free, natural, and forced convection experiments, oscillations, geometric effects, parameters which appear to be significant to heat transfer in critical region, and theories which have been proposed for region.
Hendricks, R. C.↗