Critical fluid light scattering

Abstract

Thermal fluctuations give rise to a host of thermodynamic anomalies near critical points. The background for these phenomena is presented, and an experimental design on STS flight experiment called Zeno is described. The objective is to measure the decay rates of critical density fluctuations in a simple fluid (xenon) very near its liquid-vapor critical point using laser light scattering and photon correlation spectroscopy. Such experiments have been limited on Earth by the presence of gravity, which causes large density gradients in the sample. Fluctuation decay rates in xenon will be measured at least 100 times closer to the critical point than is possible on Earth. This will require taking data as close as 145 micro K to the critical temperature, after locating it to + or - 10 micro K. The minimum mission time of 100 hours will allow a complete range of temperature points to be covered, limited by the thermal response of the sample. An essential part of the apparatus is the thermostat. Its design principles and key features are given together with some observed performance characteristics of a prototype: + or - 20 micro K stability for 18 hours, and one minute programmed step response for steps less than 10 mK.