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At least 19 records

Integral Experiment Execution of Thermal or Epithermal eXperiments using Plutonium with Polyethylene and Iron, IER 519, TEX-Hanford (-Iron), CED-3b

This report documents the execution of experiments and measurements for IER 519, Thermal/Epithermal eXperiments (TEX) for Hanford applications, using plutonium Zero Power Physics Reactor (ZPPR) plates moderated by interstitial polyethylene and iron (Fe) absorber plates. Initial hand stack, mass, and dimensional measurements were performed in July 2025. The experiments were completed over three weeks from December 2025 to January 2026 at the National Criticality Experiments Research Center (NCERC) at the Nevada National Security Sites (NNSS). All photos and critical data were provided by NCERC and experimenters in LANL’s NEN-2.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS

IER 519 Experiment Execution Report: TEX Hanford

The TEX-Hanford experiments were performed at the National Criticality Experiments Research Center (NCERC) at the Device Assembly Facility (DAF) at the Nevada Nuclear Security Site (NNSS). Three configurations were measured, with the measurements occurring in December 2025 and January 2026. The Fe-14 configuration was executed in December 2025; the Fe-11 configuration began its handstack on the Planet critical assembly machine in December 2025, but was taken critical in January 2026; the Fe-16 configuration was executed entirely in January 2026. The TEX-Hanford experiments were performed on the Planet critical assembly machine utilizing using PANN (Plutonium Aluminum No Nickel) ZPPR (Zero Power Physics Reactor) plutonium plates as fuel. The configurations were moderated with varying thicknesses of HDPE and iron absorber. This document details the configurations that were measured, preliminary reactivity measurements of the measured configurations, data files from the neutron detection systems, and results from the coordinate-measuring machine (CMM) measurements of the final stack height measurements each configuration.

22 GENERAL STUDIES OF NUCLEAR REACTORS

Fully Recyclable CFRP Particles (CRADA 519)

The proposed resin-enhanced materials, which utilize fully recycled CFRP (carbon-fiber-reinforced polymer) particles, are enabled by PARC's proprietary Chemically Linked Particles Networks (13 granted patents and patent applications). PNNL and PARC have collaborated to develop manufacturing methods, such as vacuum-assisted wet compression molding and filament winding, for fabricating fiber-reinforced composites with the PARC matrix. PNNL has conducted various mechanical, physical, and thermal characterizations to compare their differences between the composites with baseline and PARC matrices. Those characterizations include density, void volume fraction, optical micrography, uniaxial tension, four-point bending/flexure, interlaminar shear, coefficient of thermal expansion, glass transition temperature, and curing kinetics.

36 MATERIALS SCIENCE

Evaluation of coal-associated sediments, wastes, and AMD sludge in the Southern Appalachian Basin as feedstock materials for REE and Li recovery

Critical minerals (CM) such as rare earth elements (REE+) and Lithium (Li) are essential to technological innovation, energy transitions, global economic and defense security, necessitating the search for unconventional resources and efficient recovery methods to avert supply chain disruptions. Here, this study evaluates coal-associated sediments (underclay and roof rock) and wastes from the Pennsylvanian Pottsville Formation of the Southern Appalachian Basin (SAB) as potential feedstocks for CM recovery. A total of 34 samples (15 underclays, 12 roof rocks, 5 Acid Mine Drainage (AMD) sludges, and 2 coal mining wastes) were characterized using XRD, XRF, ICP-MS, and μ-XRF analytical methods. The REE+ and Li concentrations of these materials ranged from 46.8 to 334.4 ppm and from 11.1 to 519 ppm, respectively, with one underclay sample (Hendrix 3456) yielding the highest values for both. Bulk mineralogy for all samples was dominated by aluminosilicate clay phases, particularly illite and kaolinite. All samples exhibited REY def, rel% values >26% and C outl indices that ranged from 0.69 to 0.94, classifying their REE ore potential as Category II (Promising) as defined by Seredin and Dai (2012). Extractability tests (EPA method 3051 A) yielded low REE+ and Li recoveries, with maximum values of 3.3% and 3.6%, respectively, suggesting associations with resistant minerals like clay and phosphates. Elemental mapping indicates that REE+ is associated with phosphate, whereas statistical analysis suggests that REE+ are associated with aluminosilicates, suggesting heterogeneous associations or minimal phosphate contribution. Li also correlated positively with Al 2 O 3 , indicating an aluminosilicate host. This study highlights the potential of coal-associated sediments in the SAB.

Clay minerals

Equilibrium Fe isotope fractionation between olivine, pyroxene, spinel and MORB glass: Implications for mantle partial melting to generate MORBs

Primitive mid-ocean ridge basalts (MORBs) exhibit Fe isotopic compositions heavier than the upper mantle by +0.074 ± 0.028 ‰ for δ 56 Fe. The processes responsible for this isotopic difference remain unclear. Modeling of Fe isotope fractionation during mantle partial melting requires reliable equilibrium Fe isotope fractionation factors between minerals and melts, for which consistent data are still lacking. Here, in this study, we used Nuclear Resonant Inelastic X-ray Scattering (NRIXS) technique to measure Fe force constants for a MORB glass (ALV 519-4-1) and natural mantle minerals (olivine, orthopyroxene, clinopyroxene, and spinel) to determine the equilibrium Fe isotope fractionation factors between them. The force constants determined in this study, in increasing order, are 167 ± 26 N/m for spinel, 175 ± 17 N/m for olivine, 176 ± 20 N/m for MORB glass, 205 ± 26 N/m for clinopyroxene, and 219 ± 36 N/m for orthopyroxene. We evaluated the previously proposed mechanisms for the heavy Fe isotopic composition of MORBs, including (i) mantle partial melting, (ii) mantle lithological heterogeneity, with pyroxenite in the source, (iii) mantle metasomatism by low-degree melts, and (iv) fractional crystallization of olivine from melts. For (i), we used the pMELTS program to simulate adiabatic decompression melting of mantle peridotites, and calculated Fe isotope fractionation based on Fe 3+ –Fe 2+ equilibrium-controlled fractionation, where Fe 3+ forms stronger bonds and is more incompatible than Fe 2+ . At 10 wt% peridotite melting, corresponding to MORB generation, only +0.03 ‰ Fe isotope fractionation between the melt and the original bulk composition (Δ 56 Fe = δ 56 Fe melt - δ 56 Fe 0 ) was produced, insufficient to account for the observed MORB-upper mantle difference. For (ii), melting of pyroxenites yields smaller Fe isotope fractionation than melting of peridotites, making it unlikely the cause for the MORB-upper mantle isotopic difference. For (iii), both the Fe 3+ /ΣFe ratio and the δ 56 Fe of melts increase with the degree of partial melting, indicating that low-degree melts are not isotopically heavy enough to significantly alter the isotopic composition of lithospheric mantle through metasomatism. For (iv), equilibrium isotope fractionation between olivine and melt is near zero. These results suggest that equilibrium Fe isotope fractionation alone cannot explain the MORB isotopic signature, highlighting the potential role of kinetic isotope fractionation. Using a diffusion model, we calculated kinetic Fe and Mg isotope fractionations associated with (iv) olivine crystallization from a melt, and found that the predicted Fe and Mg isotope fractionations were inconsistent with observations in MORBs. Qualitatively, two processes could have induced kinetic Fe isotope fractionation during MORB generation: (a) Fe-Mg interdiffusion between melt and solid during melt migration and (b) reactive melt-rock interactions during melt focusing. However, a quantitative understanding of their role in modifying the melt isotopic composition remains limited and requires further investigation.

Fe isotopes

Photophysical properties of three-coordinate heteroleptic Cu( I ) β-diketiminate triarylphosphine complexes

A series of heteroleptic copper(I) β-diketiminate triarylphosphine complexes is reported, having the general formula Cu(R 1 NacNac R2 )(PPh X 3 ), where R 1 NacNac R2 is a substituted β-diketiminate and PPh X 3 is a triphenylphosphine derivative. A total of five different R 1 NacNac R2 ligands and three different triarylphosphines are used to assemble the nine complexes. Here, the syntheses, X-ray crystal structures, cyclic voltammograms, and UV–vis absorption spectra of all compounds are described. Whereas most of the compounds are weakly luminescent or only luminesce at 77 K, the four complexes with the more sterically encumbered β-diketiminate ligands, with methyl or isopropyl substituents at the 2- and 6-positions of the N-phenyl rings, exhibit weak room-temperature photoluminescence with peaks between 519 and 566 nm and long excited-state lifetimes in the range of 15–70 μs. The sterically encumbering substituents in this subset have subtle effects on the UV–vis absorption maximum, which red shifts slightly as the steric bulk increases, as well as significant effects on the photoluminescence lifetime, which is observed to increase as the steric bulk is augmented. Substituents on the triarylphosphine also influence the excited-state dynamics in the bulky complexes, with the more electron-rich tris(4-methoxyphenyl)phosphine (PPh OMe 3 ) giving longer-excited-state lifetimes compared to triphenylphosphine (PPh 3 ) when the same R 1 NacNac R2 ligand is used.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH

Long-Length SiC/SiC Tube Irradiation Experiment at LWR Temperatures Inserted into HFIR

This report describes the pre-irradiation characterization and successful assembly of a High Flux Isotope Reactor (HFIR) irradiation experiment designed to assess radiation-induced lateral bowing of silicon carbide fiber–reinforced, silicon carbide matrix composite (SiC/SiC) components under a radial fast neutron flux gradient at representative light-water reactor (LWR) temperatures of approximately 300 °C. The over-arching goal of this work is to validate thermomechanical models of SiC/SiC composite fuel assembly distortion used to predict the extent of lateral bowing and dose at which bowing reaches a maximum value. Ultimately, these models are used to ensure that fuel assembly distortion does not block coolant channels, interfere with control rod/blade movements, and/or impact local reactivity. The experiment contains six cladding tube specimens that are approximately 558.5 mm long with representative pressurized water reactor (PWR) outer and inner diameters of 9.5 mm and 7.5 mm, respectively. The specimens were thoroughly characterized prior to irradiation using traditional dimensional inspection and surface profilometry so that these measurements can later be compared with similar measurements that will be made post-irradiation to determine radiation-induced deformations. Furthermore, fine engraving markers were inscribed along the outer surfaces of the specimen and mapped using analytic photography and a three-dimensional stage. This technique allowed for accurate measurements of the marker spacings, which can be compared with similar measurements that will be made post-irradiation to provide local radiation-induced strain mapping. A light curtain optical micrometer was also employed to measure the pre-irradiation bowing of each specimen. The experiment was successfully assembled and inserted into position VXF-19 for HFIR cycle 516, which began May 12, 2026. The experiment will be removed after cycle 519, which is currently scheduled to end in December 2026.

22 GENERAL STUDIES OF NUCLEAR REACTORS

Experimental Validation of a Modular All-Electric Power Take-Off Topology for Wave Energy Converter Enabling Marine Renewable Energy Interconnection

Power electronic converters are an enabling technology for the emerging marine energy applications, such as using ocean waves to produce electricity. This paper outlines the power take-off system and its key components used in a wave energy converter offering modularity and scalability to generate power efficiently. The proposed power take-off system was implemented based on a modular multilevel converter and could be deployed to convert any alternating current electrical energy to a different alternating current for interconnection to grid or non-grid applications. Examples of widespread deployment are supplying electricity to coastal communities or producing clean drinking water. The analysis using both the simulation tests and laboratory experiments verified the design objectives and basic functionality of the developed power take-off system. An acceptable response using a field programmable gate array-based controlled laboratory testbench was achieved, complying with guidelines specified in the prevalent industry standards. Seamless operation during steady-state and transients for the studied wave energy converter was achieved as supported by the obtained results. The key findings of this work were experimentally examined under different load conditions, direct current bus voltage fluctuations, and generator speed–torque regulation. The ability of the power take-off system to generate high-power quality of the waveforms, e.g., against adhering to the IEEE 519-2022 standard for total harmonic distortion limits, is also confirmed.

Engineering

Thermionic performance of a cesium diminiode with relatively impure 110-tungsten electrodes

Thermionic performance data from a miniature plane cesium diode (diminiode) with 110-tungsten electrodes are presented. The diminiode has a guard-ringed collector and a spacing of 0.23 mm. The data were obtained by using a computerized acquisition system. The diode was tested at increments between 1700 and 1900 K for the emitter, 694 and 1101 K for the collector, and 519 and 650 K for the reservoir. A maximum power density of 4.5 W/sq cm was obtained at an emitter temperature of 1900 K. This relatively low output probably results from high carbon and sodium impurities in the electrode materials.

Smith, A. L.

ISEE 1 and 2 observations of Birkeland currents in the earth's inner magnetosphere

Signatures of Birkeland currents in the earth's inner magnetosphere observed from the ISEE 1 and 2 spacecraft during November 1977-December 1978 at distances ranging from 2.4-7.0 earth radii are examined. The data reveal that most of the currents were detected during outbound rather than inbound passes. Large-scale current structures were identified as parts of the region 1 and 2 current systems in 27 percent of the spacecraft outbound passes; no distinguishable region 1 or 2 currents were detected in 19 percent of the outbound passes; and in 54 percent of the passes multiple current structures and ambiguous magnetic signatures were observed. The properties of Birkeland current structures observed on January 31, 1978, February 28, 1978, March 15, 1978, June 21, 1978, and June 25, 1978 are described. It is observed that the current sheet thicknesses range from 519-18,279 km; sheet current density ranges from 13-150 mA/m; and the volume current density ranges from 1.7-128 nA/sq m.

Kelly, T. J.

Aeronautical engineering: A continuing bibliography with indexes (supplement 211)

A continuing bibliography (NASA SP-7037) lists 519 reports, journal articles and other documents originally announced in February 1987 in Scientific and Technical Aerospace Reports (STAR) or in the International Aerospace Abstracts (IAA). The coverage includes documents on the engineering and theoretical aspect of design, construction, evaluation, testing, operation, and performance of aircraft (including aircraft engines) and associated components, equipment, and systems. It also includes research and development in aerodynamics, aeronautics, and ground support equipment for aeronautical vehicles. Each entry in the bibliography consists of a standard bibliographic citation accompanied in most cases by an abstract. The listing of the entries is arranged by the first nine STAR specific categories and the remaining STAR major categories. The arrangement offers the user the most advantageous breakdown for individual objectives. The citations include the original accession numbers from the respective announcement journals. The IAA items will precede the STAR items within each category. Seven indexes entitled subject, personal author, corporate source, foreign technology, contract number, report number, and accession number are included.

Source record

The vibrational spectrum of H2O3: An ab initio investigation

Theoretically determined frequencies and absorption intensities are reported for the vibrational spectrum of the covalent HOOOH and hydrogen bonded HO---HOO intermediates that may form in the reaction of the hydroxyl and hydroperoxyl radicals. Basis sets of DZP quality, augmented by diffuse and second sets of polarization functions have been used with CASSCF wave functions. The calculated harmonic vibrational frequencies of HOOOH have been corrected with empirical factors and presented in the form of a 'stick' spectrum. The oxygen backbone vibrations, predicted to occur at 519, 760, and 870 cm(exp -1), are well separated from most interferences, and may be the most useful for the species' identification. In the case of the hydrogen bonded isomer, emphasis has been placed upon prediction of the shifts in the intramolecular vibrational frequencies that take place upon formation of the complex. In particular, the HO stretch and HOO bend of HO2 are predicted to have shifts of -59 and 53 cm(exp -1), respectively, which should facilitate their identification. It is also noted that the antisymmetric stretching frequency of the oxygen backbone in HOOOH exhibits a strong sensitivity to the degree of electron correlation, such as has been previously observed for the same mode in ozone.

Jackels, Charles F.

SO2 in the middle atmosphere of Venus: IR measurements from Venera 15 and comparison to UV

Two sets of measurements of SO2 bands in the Venus spectra are presented and compared: IR spectra obtained on the USSR Venera 15 orbiter and UV spectra from the American Pioneer Venus orbiter and sounding rockets. The 40-mbar level was chosen as a reference level for comparison. The UV data are referred to this level. There are three SO2 bands in the infrared spectrum: at 519, 1150, and 1360 cm(exp -1). The levels of their formation in the atmosphere may differ significantly, by more than 10 km.

Zasova, L. V.

IR observations in gamma-ray blazars

The infrared photometric and spectral observation of five gamma ray blazars in coordination with the energetic gamma ray experiment telescope (EGRET) onboard the Compton Gamma Ray Observatory is reported. The infrared measurements were made with a Cassegrain infrared camera and the mid-infrared large well imager at the Mt. Palomar 5 m telescope. The emphasis is on the three blazars observed simultaneously by EGRET and the ground-based telescope during viewing period 519. In addition to the acquisition of broadband spectral measurements for direct correlation with the 100 MeV EGRET observations, near infrared images were obtained, enabling a search for intra-day variability to be carried out.

Mahoney, W. A.

Dynamic Flow Management Problems in Air Transportation

In 1995, over six hundred thousand licensed pilots flew nearly thirty-five million flights into over eighteen thousand U.S. airports, logging more than 519 billion passenger miles. Since demand for air travel has increased by more than 50% in the last decade while capacity has stagnated, congestion is a problem of undeniable practical significance. In this thesis, we will develop optimization techniques that reduce the impact of congestion on the national airspace. We start by determining the optimal release times for flights into the airspace and the optimal speed adjustment while airborne taking into account the capacitated airspace. This is called the Air Traffic Flow Management Problem (TFMP). We address the complexity, showing that it is NP-hard. We build an integer programming formulation that is quite strong as some of the proposed inequalities are facet defining for the convex hull of solutions. For practical problems, the solutions of the LP relaxation of the TFMP are very often integral. In essence, we reduce the problem to efficiently solving large scale linear programming problems. Thus, the computation times are reasonably small for large scale, practical problems involving thousands of flights. Next, we address the problem of determining how to reroute aircraft in the airspace system when faced with dynamically changing weather conditions. This is called the Air Traffic Flow Management Rerouting Problem (TFMRP) We present an integrated mathematical programming approach for the TFMRP, which utilizes several methodologies, in order to minimize delay costs. In order to address the high dimensionality, we present an aggregate model, in which we formulate the TFMRP as a multicommodity, integer, dynamic network flow problem with certain side constraints. Using Lagrangian relaxation, we generate aggregate flows that are decomposed into a collection of flight paths using a randomized rounding heuristic. This collection of paths is used in a packing integer programming formulation, the solution of which generates feasible and near-optimal routes for individual flights. The algorithm, termed the Lagrangian Generation Algorithm, is used to solve practical problems in the southwestern portion of United States in which the solutions are within 1% of the corresponding lower bounds.

Patterson, Sarah Stock

Global Impacts of Gas-Phase Chemistry-Aerosol Interactions on Direct Radiative Forcing by Anthropogenic Aerosols and Ozone

We present here a first global modeling study on the influence of gas-phase chemistry/aerosol interactions on estimates of anthropogenic forcing by tropospheric O3 and aerosols. Concentrations of gas-phase species and sulfate, nitrate, ammonium, black carbon, primary organic carbon, secondary organic carbon, sea salt, and mineral dust aerosols in the preindustrial, present-day, and year 2100 (IPCC SRES A2) atmospheres are simulated online in the Goddard Institute for Space Studies general circulation model II' (GISS GCM II'). With fully coupled chemistry and aerosols, the preindustrial, presentday, and year 2100 global burdens of tropospheric ozone are predicted to be 190, 319, and 519 Tg, respectively. The burdens of sulfate, nitrate, black carbon, and organic carbon are predicted respectively to be 0.32. 0.18, 0.01, 0.33 Tg in preindustrial time, 1.40, 0.48, 0.23, 1.60 Tg in presentday, and 1.37, 1.97, 0.54, 3.31 Tg in year 2100. Anthropogenic O3 is predicted to have a globally and annually averaged present-day forcing of +0.22 W m(sup -2) and year 2100 forcing of +0.57 W m(sup -2) at the top of the atmosphere (TOA). Net anthropogenic TOA forcing by internally mixed sulfate, nitrate, organic carbon, and black carbon aerosols is estimated to be virtually zero in the present-day and +0.34 W m(sup -2) in year 2100, whereas it is predicted to be -0.39 W m(sup -2) in present-day and -0.61 W m(sup -2) in year 2100 if the aerosols are externally mixed. Heterogeneous reactions are shown to be important in affecting anthropogenic forcing. When reactions of N2O5, NO3, NO2, and HO2 on aerosols are accounted for, TOA anthropogenic O3 forcing is less by 20-45% in present-day and by 20-32% in year 2100 at mid to high latitudes in the Northern Hemisphere, as compared with values predicted in the absence of heterogeneous gas aerosol reactions. Mineral dust uptake of HNO3 and O3 is shown to have practically no influence on anthropogenic O3 forcing. Heterogeneous reactions of N2Os, NO3, NO2, and HO2 are predicted to have noticeable impacts on anthropogenic aerosol forcing over industrialized areas, leading to 0-2 W m(sup -2) more anthropogenic aerosol cooling in present-day and 2-8 W m(sup -2) more cooling in year 2100 in these areas as compared with forcings calculated in the absence of heterogeneous reactions. Sea salt uptake of SO2 reduces the magnitude of TOA aerosol cooling by 0.5-1 W m(sup -2) over the oceans around 60 N in the present-day and year 2100 scenarios. Near dust sources, mineral dust uptake of SO2 and HNO3 leads to less anthropogenic aerosol cooling by 0.5-1 W m(sup -2) in the present day and 1-2 W m(sup -2) in year 2100.

Liao, Hong

Detection of High Velocity Absorption Components in the He I Lines of Eta Carinae near the Time of Periastron

We have obtained a total of 58 high spectral resolution (R90,000) spectra of the massive binary star eta Carinae since 2012 in an effort to continue our orbital and long-term echelle monitoring of this extreme binary (Richardson et al. 2010, AJ, 139, 1534) with the CHIRON spectrograph on the CTIO 1.5 m telescope (Tokovinin et al. 2013, PASP, 125, 1336) in the 45507500A region. We have increased our monitoring efforts and observation frequency as the periastron event of 2014 has approached. We note that there were multiple epochs this year where we observe unusual absorption components in the P Cygni troughs of the He I triplet lines. In particular, we note high velocity absorption components related to the following epochs for the following lines: He I 4713: HJD 2456754- 2456795 (velocity -450 to -560 kms) He I 5876: HJD 2456791- 2456819 (velocity -690 to -800 kms) He I 7065: HJD 2456791- 2456810 (velocity -665 to -730 kms) Figures: Note that red indicates a high-velocity component noted above. He I 4713: http:www.astro.umontreal.carichardson4713.png He I 5876: http:www.astro.umontreal.carichardson5876.png He I 7065: http:www.astro.umontreal.carichardson7065.png These absorptions are likely related to the wind-wind collision region and bow shock, as suggested by the high-velocity absorption observed by Groh et al. (2010, AA, 519, 9) in the He I 10830 Atransition. In these cases, we suspect that we look along an arm of the shock cone and that we will see a fast absorption change from the other collision region shortly after periastron. We suspect that this is related to the multiple-components of the He II 4686 line that was noted by Walter (ATel6334), and is confirmed in our data. Further, high spectral resolution data are highly encouraged,especially for resolving powers greater than 50,000.These observations were obtained with the CTIO 1.5 m telescope, operated by the SMARTS Consortium, and were obtained through both SMARTS and NOAO programs 2012A-0216,2012B-0194, and 2013b-0328). We thank Emily MacPherson (Yale) for her efforts in scheduling the observations that we have and will obtain in the coming weeks.

binary star eta Carinae

Multiple Absorption Components in the Post-Periastron He I P Cygni Absorption Troughs of Eta Carinae

We have obtained more than 100 high spectral resolution (R approx. 90,000) spectra of the massive binary star eta Carinae since 2012 in an effort to continue our orbital and long-term echelle monitoring of this extreme binary (Richardson et al. 2010, AJ, 139, 1534) with the CHIRON spectrograph on the CTIO 1.5 m telescope (Tokovinin et al. 2013, PASP, 125, 1336) in the 4550-7500A region. We increased our monitoring efforts and observation frequency as the periastron event of 2014 has approached, and resumed observations in October. We note that since mid-October, we have observed unusual multiple absorption components in the P Cygni troughs of the He I lines (4714, 5876, 6678, and 7065; 4921 and 5015 are blended with Fe II). In particular, we note that these components extend to -700 km/s, well beyond the terminal wind speed of the primary. These absorptions are likely related to clumps and turbulence in the wind-wind collision region and bow shock, as suggested by the high-velocity absorption observed by Groh et al. (2010, A&A, 519, 9) in the He I 10830A transition and our pre-periastron observations (Richardson et al. 2014, ATel #6336). In these cases, we suspect that we look along an arm of the shock cone and that we see a fast absorption change from the other collision region shortly after periastron. Further, high spectral resolution data are highly encouraged, especially for resolving powers greater than 50,000. These observations were obtained with the CTIO 1.5 m telescope, operated by the SMARTS Consortium, and were obtained through both SMARTS and NOAO programs 2012A-0216, 2012B-0194, and 2013b-0328. We thank Emily MacPherson (Yale) for her efforts in scheduling the observations that we have and will obtain in the coming weeks and months.

multiple absorption components