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At least 1,765 records · Page 98

ASSEMBLY OF MASSIVE GALAXIES IN A HIGH-z PROTOCLUSTER

We present the results of wide-field deep JHK imaging of the SSA22 field using the MOIRCS instrument equipped with the Subaru telescope. The observed field is 112 arcmin{sup 2} in area, which covers the z = 3.1 protocluster characterized by the overdensities of Ly{alpha} emitters (LAEs) and Ly{alpha} blobs (LABs). The 5{sigma} limiting magnitude is K{sub AB} = 24.3. We extract the potential protocluster members from the K-selected sample by using the multi-band photometric-redshift selection as well as the simple color cut for distant red galaxies (DRGs; J - K{sub AB} > 1.4). The surface number density of DRGs in our observed fields shows clear excess compared with those in the blank fields, and the location of the densest area whose projected overdensity is twice the average coincides with the large-scale density peak of LAEs. We also found that K-band counterparts with z{sub phot} {approx_equal} 3.1 are detected for 75% (15/20) of the LABs within their Ly{alpha} halo, and the 40% (8/20) of LABs have multiple components, which gives a direct evidence of the hierarchical multiple merging in galaxy formation. The stellar mass of LABs correlates with their luminosity, isophotal area, and the Ly{alpha} velocity widths, implying that the physical scale and the dynamical motion of Ly{alpha} emission are closely related to their previous star formation activities. Highly dust-obscured galaxies such as hyper extremely red objects (J - K{sub AB} > 2.1) and plausible K-band counterparts of submillimeter sources are also populated in the high-density region.

79 ASTRONOMY AND ASTROPHYSICS↗

RESOLVING THE OPTICAL EMISSION LINES OF Ly{alpha} BLOB ''B1'' AT z = 2.38: ANOTHER HIDDEN QUASAR

We have used the SINFONI near-infrared integral field unit on the Very Large Telescope to resolve the optical emission line structure of one of the brightest (L{sub Ly{alpha}} Almost-Equal-To 10{sup 44} erg s{sup -1}) and nearest (z Almost-Equal-To 2.38) of all Ly{alpha} blobs (LABs). The target, known in the literature as object {sup B}1{sup ,} lies at a redshift where the main optical emission lines are accessible in the observed near-infrared. We detect luminous [O III] {lambda}{lambda}4959, 5007 and H{alpha} emission with a spatial extent of at least 32 Multiplication-Sign 40 kpc (4'' Multiplication-Sign 5''). The dominant optical emission line component shows relatively broad lines (600-800 km s{sup -1}, FWHM) and line ratios consistent with active galactic nucleus (AGN) photoionization. The new evidence for AGN photoionization, combined with previously detected C IV and luminous, warm infrared emission, suggest that B1 is the site of a hidden quasar. This is confirmed by the fact that [O II] is relatively weak compared with [O III] (extinction-corrected [O III]/[O II] of about 3.8), which is indicative of a high, Seyfert-like ionization parameter. From the extinction-corrected [O III] luminosity we infer a bolometric AGN luminosity of {approx}3 Multiplication-Sign 10{sup 46} erg s{sup -1}, and further conclude that the obscured AGN may be Compton-thick given existing X-ray limits. The large line widths observed are consistent with clouds moving within the narrow-line region of a luminous QSO. The AGN scenario is capable of producing sufficient ionizing photons to power the Ly{alpha}, even in the presence of dust. By performing a census of similar objects in the literature, we find that virtually all luminous LABs harbor obscured quasars. Based on simple duty-cycle arguments, we conclude that AGNs are the main drivers of the Ly{alpha} in LABs rather than the gravitational heating and subsequent cooling suggested by cold stream models. We also conclude that the empirical relation between LABs and overdense environments at high redshift must be due to a more fundamental correlation between AGNs (or massive galaxies) and environment.

79 ASTRONOMY AND ASTROPHYSICS↗

A DEEP SEARCH FOR CO J = 2-1 EMISSION FROM A Ly{alpha} BLOB AT z {approx} 6.595

We have used the Green Bank Telescope to carry out a deep search for redshifted CO J = 2-1 line emission from an extended (>17 kpc) Ly{alpha} blob (LAB), 'Himiko', at z {approx} 6.595. Our non-detection of CO J = 2-1 emission places the strong 3{sigma} upper limit of L'{sub CO} < 1.8 Multiplication-Sign 10{sup 10} Multiplication-Sign ({Delta}V/250){sup 1/2} K km s{sup -1} pc{sup 2} on the CO line luminosity. This is comparable to the best current limits on the CO line luminosity in LABs at z {approx} 3 and lower-luminosity Ly{alpha} emitters at z {approx}> 6.5. High-z LABs appear to have lower CO line luminosities than the host galaxies of luminous quasars and submillimeter galaxies at similar redshifts, despite their high stellar mass. Although the CO-to-H{sub 2} conversion factor is uncertain for galaxies in the early universe, we assume X{sub CO} = 0.8 M{sub Sun} (K km s{sup -1} pc{sup 2}){sup -1} to obtain the limit M(H{sub 2}) <1.4 Multiplication-Sign 10{sup 10} M{sub Sun} on Himiko's molecular gas mass; this is a factor of {approx}> 2.5 lower than the stellar mass in the z {approx} 6.595 LAB.

79 ASTRONOMY AND ASTROPHYSICS↗

Nonmonotonic-potential description of polarization effects, fusion, and nuclear rainbows in elastic scattering of 6 Li + 12 C at 4.5–600 MeV

The experimental differential cross-section (CS) and analyzing power (AP) data of the 6 Li + 12 C elastic scattering over a wide laboratory energy scale (4.5MeV≤𝐸 lab ≤600MeV) are analyzed within the framework of the optical model (OPM) using nonmonotonic (NM) nucleus–nucleus potentials. The real part of the NM potentials is derived from the Pauli-embodied energy density-functional (EDF) formalism with the sudden approximation. The real part of the noncentral spin-orbit and tensor terms, as well as the imaginary parts, are treated phenomenologically. The effect of the radius of sensitivity on the CS and AP data is found to be more important at lower energies. The diffractive and refractive scattering with Airy structures in the whole angular region of the elastic scattering across the studied energy range is successfully described within the OPM using the NM 6 Li + 12 C potential. The near- and far-side (N and F) decomposition of the total elastic-scattering amplitudes has also been studied using our NM potentials. The evolution of the Airy minima in the angular distributions, coupled with the fitting of the AP data, provides an accurate description of Airy minima of different orders. The OPM calculations with the NM potentials describe exceptionally well the CS, vector analyzing power (VAP), and tensor analyzing power data at 𝐸 lab =9.0,19.24,20,30, and 50MeV. In agreement with our past successful descriptions of CS and the opposite signs of the VAP data for the 6 Li and 7 Li elastic scattering using NM potentials in OPM, the present results appear to provide a better fit, so far, than those obtained from the coupled-channels method. The fusion cross sections of 6 Li + 12 C have been predicted in the energy range (4.5MeV≤𝐸 lab ≤20MeV), fitting the experimental data well in the range 𝐸 lab =2.97–11.77MeV. The EDF potential without any energy dependence and renormalization is also found to describe satisfactorily the experimental CS and AP data at energies up to several hundreds of MeV.

6 ≤ A ≤ 19↗

Implications of the Formation of Small Polarons in Li2O2 for Li-Air Batteries

Lithium-air batteries (LABs) are an intriguing next-generation technology due to their high theoretical energy density of {approx}11 kWh/kg. However, LABs are hindered by both poor rate capability and significant polarization in cell voltage, primarily due to the formation of Li{sub 2}O{sub 2} in the air cathode. Here, by employing hybrid density functional theory, we show that the formation of small polarons in Li{sub 2}O{sub 2} limits electron transport. Consequently, the low electron mobility {mu} = 10{sup -10}-10{sup -9} cm{sup 2}/V s contributes to both the poor rate capability and the polarization that limit the LAB power and energy densities. The self-trapping of electrons in the small polarons arises from the molecular nature of the conduction band states of Li{sub 2}O{sub 2} and the strong spin polarization of the O 2p state. Our understanding of the polaronic electron transport in Li{sub 2}O{sub 2} suggests that designing alternative carrier conduction paths for the cathode reaction could significantly improve the performance of LABs at high current densities.

25 ENERGY STORAGE↗

Leveraging National Laboratory Assets to Address Stability Challenges due to Declining Grid Inertia Using Geographically Distributed Electrical–Thermal Co-Emulation

Due to increased penetration of low-inertia resources into the electric grid, challenges are increasing for maintaining wide-area system stability. Grid stability assessment requires a faithful representation of the multiple-physics interaction at the system level, and timescales of interaction varying in orders of magnitude, from microseconds to seconds to several minutes. Along with the simulation-based techniques, hardware-in-the-loop (HIL), controller HIL, and power HIL techniques have been developed to better understand the emergent behavior of the system with emerging technologies. US National Laboratories have played a vital role in research and development to understand the behavior of individual technologies and devices integrated to the electric grid. Each national laboratory forwards a technological and strategic initiative tied core and enabling capabilities. Due to strategic, efficiency, and economic reasons, not all the labs have assets to conduct research on all technologies concomitantly, so it becomes crucial to integrate the labs across geographies to understand the interplay of different technologies together at the system level. This approach avoids duplication of the assets at different lab facilities and helps understand the integrated system behavior of various technologies representative of actual grid conditions by connecting multiple national labs. This article talks about techniques of connecting three national laboratories to enable co-emulation of electrical–mechanical–thermal characteristics of devices and systems. Such an approach can be used to understand the dynamic and transient interaction of multi-physics in a system level, at-scale emulation using real-time simulation tools and techniques.

24 POWER TRANSMISSION AND DISTRIBUTION↗

Consistency and reproducibility in atomic layer deposition

Atomic layer deposition (ALD) is a thin film synthesis technique that can provide exquisite accuracy and precision in film thickness and composition even on complex, large area substrates. Based on self-limiting surface chemistry, ALD can be insensitive to process conditions and reactor designs, allowing an ALD process developed in one lab to be easily reproduced in other labs. In practice, however, ALD is sometimes difficult to reproduce or replicate, and the results can vary substantially between ALD reactors and between labs. This is exemplified by large deviations in reports on the growth of, e.g., Al2O3, FeOx, and TiO2 given the same precursors under similar conditions. Furthermore, the problem of irreproducibility seems to be growing as ALD is adopted by more researchers and integrated into new applications. In this article, the authors highlight some of the major sources of variations and errors and common misconceptions related to ALD. In particular, the authors focus on issues related to precursors, substrates, and deposition tools. The authors illustrate these problems through examples from the literature, and they present results from numerical simulations that describe how nonidealities would manifest in thickness profiles in a typical cross-flow reactor. They also describe how reproducibility in ALD is linked to consistent experimental practice and reporting between labs. The authors’ hope is that by educating newcomers to ALD and advocating for consistent reporting of deposition conditions, they can minimize irreproducibility and enable ALD practitioners to realize the full potential afforded by self-limiting surface chemistry.

36 MATERIALS SCIENCE↗

Evidence of scaling advantage for the quantum approximate optimization algorithm on a classically intractable problem

The quantum approximate optimization algorithm (QAOA) is a leading candidate algorithm for solving optimization problems on quantum computers. However, the potential of QAOA to tackle classically intractable problems remains unclear. Here, we perform an extensive numerical investigation of QAOA on the low autocorrelation binary sequences (LABS) problem, which is classically intractable even for moderately sized instances. We perform noiseless simulations with up to 40 qubits and observe that the runtime of QAOA with fixed parameters scales better than branch-and-bound solvers, which are the state-of-the-art exact solvers for LABS. The combination of QAOA with quantum minimum finding gives the best empirical scaling of any algorithm for the LABS problem. We demonstrate experimental progress in executing QAOA for the LABS problem using an algorithm-specific error detection scheme on Quantinuum trapped-ion processors. Our results provide evidence for the utility of QAOA as an algorithmic component that enables quantum speedups.

97 MATHEMATICS AND COMPUTING↗

Precise polarization measurements via detection of compton scattered electrons

The Qweak experiment at Jefferson Lab aims to make a 4% measurement of the parity-violating asymmetry in elastic scattering at very low Q{sup 2} of a longitudinally polarized electron beam off a proton target. One of the dominant experimental systematic uncertainties in Qweak will result from determining the beam polarization. A new Compton polarimeter was installed in the fall of 2010 to provide a non-invasive and continuous monitoring of the electron beam polarization in Hall C at Jefferson Lab. The Compton-scattered electrons are detected in four planes of diamond micro-strip detectors. We have achieved the design goals of <1% statistical uncertainty per hour and expect to achieve <1% systematic uncertainty.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗

Solving challenges in QCD 3D partonic distributions

The superior luminosity and high polarization of CEBAF, combined with the high resolution and excellent particle identification capabilities of its detectors, as well as the ability for multidimensional and multiparticle detection using polarized targets, make Jefferson Lab uniquely positioned to disentangle the genuine intrinsic transverse structure of hadrons encoded in 3D partonic distributions—particularly in the kinematic regime dominated by valence quarks. The inclusion of Jefferson Lab data on semi-inclusive and hard exclusive hadron production has the potential to dramatically advance our understanding of non-perturbative QCD dynamics. Although a wealth of data from various Jefferson Lab experiments is already available, its incorporation into phenomenological studies has been slow, and a significant portion of data from other leptoproduction experiments is still missing from global fits. In this contribution, we discuss the existing challenges and outline a path forward for improving the analysis of low center-of-mass electroproduction experiments in general, and Jefferson Lab data in particular.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗

Production of ${\Sigma (1385)^{\pm }}$ and ${\Xi (1530)^{0}}$ in p–Pb collisions at ${\sqrt{s_{\mathrm{NN}}}= 5.02}$ TeV

The transverse momentum distributions of the strange and double-strange hyperon resonances (Σ(1385) ± , Ξ(1530) 0 ) produced in p–Pb collisions at √ s NN = 5.02 TeV were measured in the rapidity range –0.5 < y CMS < 0 for event classes corresponding to different charged-particle multiplicity densities, < dN ch /dη lab >. The mean transverse momentum values are presented as a function of < dN ch /dη lab >, as well as a function of the particle masses and compared with previous results on hyperon production. The integrated yield ratios of excited to ground-state hyperons are constant as a function of < dN ch /dη lab >. The equivalent ratios to pions exhibit an increase with < dN ch /dη lab >, depending on their strangeness content.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗

Diving into Petascale Production File Systems through Large Scale Profiling and Analysis

As leadership computing facilities grow their storage capacity into the multi- petabyte range, the number of files and directories leap into the scale of billions. A complete profiling of such a parallel file system in a production environment presents a unique challenge. On one hand, the time, resources, and negative performance impact on production users can make regular profiling difficult. On the other hand, the result of such profiling can yield much needed understanding of the file system's general characteristics, as well as provide insight to how users write and access their data on a grand scale. This paper presents a lightweight and scalable profiling solution that can efficiently walk, analyze, and profile multi-petabyte parallel file systems. This tool has been deployed and is in regular use on very large-scale production parallel file systems at both Oak Ridge National Lab's Oak Ridge Leadership Facility (OLCF) and Lawrence Livermore National Lab's Livermore Computing (LC) facilities. We present the results of our initial analysis on the data collected from these two large-scale production systems, organized into three use cases: (1) file system snapshot and composition, (2) striping pattern analysis for Lustre, and (3) simulated storage capacity utilization in preparation for future file systems. Our analysis shows that on the OLCF file system, over 96% of user files exhibit the default stripe width, potentially limiting performance on large files by underutilizing storage servers and disks. Our simulated block analysis quantitatively shows the space overhead when doing a forklift system migration. It also reveals that due to the difference in system compositions (OLCF vs. LC), we can achieve better performance and space trade-offs by employing different native file system block sizes.

Wang, Feiyi↗

Metal-Rich Transition Metal Diborides as Electrocatalysts for Hydrogen Evolution Reactions in a Wide Range of pH

Solid solutions of HfB 2 -ZrB 2 mixtures were prepared by high-energy ball milling of diboride and additive powders followed by spark plasma sintering (SPS). A mixture of stoichiometric 1:1 HfB 2 -ZrB 2 borides was the base composition to which Hf, Zr, Ta, LaB 6 or Gd 2 O 3 was added. Hf, Zr and Ta were added in order to bring the boron-to-metal ratio down to 1.86, rendering the boride as MeB 1.86 . In the case of LaB 6 and Gd 2 O 3 , 1.8 mol% was added. Electroanalytical behavior of hydrogen evolution reactions was evaluated in 1 M H 2 SO 4 and 1 M NaOH solutions. The LaB 6 additive material showed Tafel slopes of 125 and 90 mV/decade in acidic and alkaline solutions respectively. The Hf and Zr rich samples showed Tafel slopes of about 120 mV/decade in both electrolytes. The over potentials of hydrogen evolution reactions (at 10 mA/cm 2 ) in the alkaline solution were about 100 mV lower than those in acidic solution. The metal-rich diborides and addition of LaB 6 showed better hydrogen evolution reaction (HER) activities than the base 1:1 HfB 2 -ZrB 2 stoichiometric diboride solid solution. Furthermore, the higher activity of metal-rich borides could be attributed to the increased electron population at the d-orbitals of the metal shown by band structure modeling calculations using the Density Functional Theory approach.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Data for “Fast-decaying plant litter enhances soil carbon in temperate forests, but not through microbial physiological traits”

This data package contains data and code used in the paper “Fast-decaying plant litter enhances soil carbon in temperate forests, but not through microbial physiological traits”. This paper details results from two studies: 1) a laboratory leaf litter incubation experiment (lab experiment) and 2) a multi-site observational field study (field study). Both studies were designed to test the relationships among litter quality, microbial physiological traits, and mineral-associated soil carbon (C). In the lab experiment, we incubated 16 temperate tree litters of differing chemical quality with isotopically distinct soil, measuring microbial physiological traits and the flow of litter-derived C into the mineral-associated soil C pool. In the field study, we sampled soils (0-5 cm) across six eastern US temperate forests, measuring microbial physiological traits, soil abiotic properties, and leaf litter chemistry. The analysis data are provided in two .csv files corresponding to either the lab experiment or field study. Both files contain data on litter chemistry, microbial physiological traits (growth and turnover rates, and carbon use efficiency [CUE]), and the mineral-associated soil C pool. The lab experiment dataset additionally contains litter-derived versus soil-derived soil C, respiration, and litter decomposition parameters. The field study dataset additionally contains site-level climatic information, ectomycorrhizal dominance of plots, and plot-level soil properties. Also provided is the R code and output reproducing the results in the related publication. Analyses were originally performed using R version 3.6.1 using the package "lavaan" and the packages listed on lines 5-7 in the file "data.R".

54 ENVIRONMENTAL SCIENCES↗

Shape Evolution of C75 Large-Grain Niobium Half-Cells During Cavity Fabrication

The largely anisotropic deformation of large-grain Nb discs during deep drawing into half-cells poses a challenge for achieving a desired shape accuracy. Two 5-cell cavities for the C75 CEBAF cryomodule rework program have been fabricated at Jefferson Lab from large-grain Nb discs directly sliced from an ingot. The shape of the inner surface of eight half-cells has been inspected using a FARO Edge laser scanner during the fabrication process and compared to the reference shape. On average, approximately 63% of the half-cell inner surface was found to be within 0.1 mm of the reference shape and ~90% to be within 0.2 mm, after the final equator machining. Several 5-cell C75 cavities have also been fabricated at Research Instruments, Germany, and measurements of the shape accuracy using a Zeiss 3D coordinate measuring machine gave similar results. One half-cell was measured both at Research Instruments and Jefferson Lab for comparison.

Ciovati, G.↗

RESULTS OF ANALYTICAL SAMPLE CROSSCHECKS FOR NEXT GENERATION SOLVENT EXTRACTION SAMPLES ISOPAR L CONCENTRATION AND PH

As part of the implementation process for the Next Generation Cesium Extraction Solvent (NGCS), SRNL and F/H Lab performed a series of analytical cross-checks to ensure that the components in the NGCS solvent system do not constitute an undue analytical challenge. For measurement of entrained Isopar{reg_sign} L in aqueous solutions, both labs performed similarly with results more reliable at higher concentrations (near 50 mg/L). Low bias occurred in both labs, as seen previously for comparable blind studies for the baseline solvent system. SRNL recommends consideration to use of Teflon{trademark} caps on all sample containers used for this purpose. For pH measurements, the labs showed reasonable agreement but considerable positive bias for dilute boric acid solutions. SRNL recommends consideration of using an alternate analytical method for qualification of boric acid concentrations.

22 GENERAL STUDIES OF NUCLEAR REACTORS↗

Behavior of Mercury During DWPF Chemical Process Cell Processing

The Defense Waste Processing Facility has experienced significant issues with the stripping and recovery of mercury in the Chemical Processing Cell (CPC). The stripping rate has been inconsistent, often resulting in extended processing times to remove mercury to the required endpoint concentration. The recovery of mercury in the Mercury Water Wash Tank has never been high, and has decreased significantly since the Mercury Water Wash Tank was replaced after the seventh batch of Sludge Batch 5. Since this time, essentially no recovery of mercury has been seen. Pertinent literature was reviewed, previous lab-scale data on mercury stripping and recovery was examined, and new lab-scale CPC Sludge Receipt and Adjustment Tank (SRAT) runs were conducted. For previous lab-scale data, many of the runs with sufficient mercury recovery data were examined to determine what factors affect the stripping and recovery of mercury and to improve closure of the mercury material balance. Ten new lab-scale SRAT runs (HG runs) were performed to examine the effects of acid stoichiometry, sludge solids concentration, antifoam concentration, form of mercury added to simulant, presence of a SRAT heel, operation of the SRAT condenser at higher than prototypic temperature, varying noble metals from none to very high concentrations, and higher agitation rate. Data from simulant runs from SB6, SB7a, glycolic/formic, and the HG tests showed that a significant amount of Hg metal was found on the vessel bottom at the end of tests. Material balance closure improved from 12-71% to 48-93% when this segregated Hg was considered. The amount of Hg segregated as elemental Hg on the vessel bottom was 4-77% of the amount added. The highest recovery of mercury in the offgas system generally correlated with the highest retention of Hg in the slurry. Low retention in the slurry (high segregation on the vessel bottom) resulted in low recovery in the offgas system. High agitation rates appear to result in lower retention of mercury in the slurry. Both recovery of mercury in the offgas system and removal (segregation + recovery) from the slurry correlate with slurry consistency. Higher slurry consistency results in better retention of Hg in the slurry (less segregation) and better recovery in the offgas system, but the relationships of recovery and retention with consistency are sludge dependent. Some correlation with slurry yield stress and acid stoichiometry was also found. Better retention of mercury in the slurry results in better recovery in the offgas system because the mercury in the slurry is stripped more easily than the segregated mercury at the bottom of the vessel. Although better retention gives better recovery, the time to reach a particular slurry mercury content (wt%) is longer than if the retention is poorer because the segregation is faster. The segregation of mercury is generally a faster process than stripping. The stripping factor (mass of water evaporated per mass of mercury stripped) of mercury at the start of boiling were found to be less than 1000 compared to the assumed design basis value of 750 (the theoretical factor is 250). However, within two hours, this value increased to at least 2000 lb water per lb Hg. For runs with higher mercury recovery in the offgas system, the stripping factor remained around 2000, but runs with low recovery had stripping factors of 4000 to 40,000. DWPF data shows similar trends with the stripping factor value increasing during boiling. These high values correspond to high segregation and low retention of mercury in the sludge. The stripping factor for a pure Hg metal bead in water was found to be about 10,000 lb/lb. About 10-36% of the total Hg evaporated in a SRAT cycle was refluxed back to the SRAT during formic acid addition and boiling. Mercury is dissolved as a result of nitric acid formation from absorption of NO x . The actual solubility of dissolved mercury in the acidic condensate is about 100 times higher than the actual concentrations measured. Mercury metal present in the MWWT from previous batches could be dissolved by this acidic condensate. The test of the effect of higher SRAT condenser temperature on recovery of mercury in the MWWT and offgas system was inconclusive. The recovery at higher temperature was lower than several low temperature runs, but about the same as other runs. Factors other than temperature appear to affect the mercury recovery. The presence of chloride and iodide in simulants resulted in the formation of mercurous chloride and mercurous iodide, respectively, in the offgas system. Actual waste data shows that the chloride content is much less than the simulant concentrations. Future simulant tests should minimize the addition of chloride. Similarly, iodine addition should be eliminated unless actual waste analyses show it to be present; currently, total iodine is not measured on actual waste samples.

36 MATERIALS SCIENCE↗

Bridging the PSI Knowledge Gap: A Multi-Scale Approach

Plasma-surface interactions (PSI) pose an immense scientific hurdle in magnetic confinement fusion and our present understanding of PSI in confinement environments is highly inadequate; indeed, a recent Fusion Energy Sciences Advisory Committee report found that 4 out of the 5 top five fusion knowledge gaps were related to PSI. The time is appropriate to develop a concentrated and synergistic science effort that would expand, exploit and integrate the wealth of laboratory ion-beam and plasma research, as well as exciting new computational tools, towards the goal of bridging the PSI knowledge gap. This effort would broadly advance plasma and material sciences, while providing critical knowledge towards progress in fusion PSI. This project involves the development of a Science Center focused on a new approach to PSI science; an approach that both exploits access to state-of-the-art PSI experiments and modeling, as well as confinement devices. The organizing principle is to develop synergistic experimental and modeling tools that treat the truly coupled multi-scale aspect of the PSI issues in confinement devices. This is motivated by the simple observation that while typical lab experiments and models allow independent manipulation of controlling variables, the confinement PSI environment is essentially self-determined with few outside controls. This means that processes that may be treated independently in laboratory experiments, because they involve vastly different physical and time scales, will now affect one another in the confinement environment. Also, lab experiments cannot simultaneously match all exposure conditions found in confinement devices typically forcing a linear extrapolation of lab results. At the same time programmatic limitations prevent confinement experiments alone from answering many key PSI questions. The resolution to this problem is to usefully exploit access to PSI science in lab devices, while retooling our thinking from a linear and de-coupled extrapolation to a multi-scale, coupled approach. The PSI Plasma Center consisted of three equal co-centers; one located at the MIT Plasma Science and Fusion Center, one at UC San Diego Center for Energy Research and one at the UC Berkeley Department of Nuclear Engineering, which moved to the University of Tennessee, Knoxville (UTK) with Professor Brian Wirth in July 2010. The Center had three co-directors: Prof. Dennis Whyte led the MIT co-center, the UCSD co-center was led by Dr. Russell Doerner, and Prof. Brian Wirth led the UCB/UTK center. The directors have extensive experience in PSI and material research, and have been internationally recognized in the magnetic fusion, materials and plasma research fields. The co-centers feature keystone PSI experimental and modeling facilities dedicated to PSI science: the DIONISOS/CLASS facility at MIT, the PISCES facility at UCSD, and the state-of-the-art numerical modeling capabilities at UCB/UTK. A collaborative partner in the center is Sandia National Laboratory at Livermore (SNL/CA), which has extensive capabilities with low energy ion beams and surface diagnostics, as well as supporting plasma facilities, including the Tritium Plasma Experiment, all of which significantly augment the Center. Interpretive, continuum material models are available through SNL/CA, UCSD and MIT. The participating institutions of MIT, UCSD, UCB/UTK, SNL/CA and LLNL brought a formidable array of experimental tools and personnel abilities into the PSI Plasma Center. Our work has focused on modeling activities associated with plasma surface interactions that are involved in effects of He and H plasma bombardment on tungsten surfaces. This involved performing computational material modeling of the surface evolution during plasma bombardment using molecular dynamics modeling. The principal outcomes of the research efforts within the combined experimental – modeling PSI center are to provide a knowledgebase of the mechanisms of surface degradation, and the influence of the surface on plasma conditions.

36 MATERIALS SCIENCE↗