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At least 1,765 records · Page 98

Thermal contact resistance in vacuum.

Similar or dissimilar materials thermal contact resistance in vacuum with negligible film effect, obtaining constriction resistance

THERMAL CONDUCTOR↗

Preliminary metallographic studies of ball fatigue under rolling-contact conditions

The metallurgical results produced on balls tested in the rolling-contact fatigue spin rig were studied by metallographic examination. Origin and progression of fatigue failures were observed. These evaluations were made on SAE 52100 and AISI M-1 balls fatigue tested at room temperature (80 F) and 200 to 250 F. Most failures originated subsurface in shear; inclusions, structure changes, and directionalism adversely affected ball fatigue life. Structures in the maximum-shear-stress region of the balls of both materials were stable at room temperature and unstable at 200 to 250 F. Failures were of the same type as those found in full-scale bearings.

SURFACES, CONTACT - ROLLING↗

Stress-life relation of the rolling-contact fatigue spin rig

The rolling-contact fatigue spin rig was used to test groups of SAE 52100 9.16-inch-diameter balls lubricated with a mineral oil at 600,000-, 675,000-, and 750,000-psi maximum Hertz stress. Cylinders of AISI M-1 vacuum and commercial melts and MV-1 (AISI M-50) were used as race specimens. Stress-life exponents produced agree closely with values accepted in industry. The type of failure obtained in the spin rig was similar to the subsurface fatigue spells found in bearings.

SURFACES, CONTACT - ROLLING↗

Effect of Fiber Orientation on Ball Failures Under Rolling-contact Conditions

The rolling-contact fatigue spin rig was used to test bails of a bearing steel at maximum Hertz stresses of 600,000 to 750,000 psi. The effect of fiber orientation was observed with the ball track restricted to passing directly over the poles, coincident with the equator, or randomly around the ball. The polar areas were found to be weaker in fatigue than the nonpolar areas. This resulted in a much greater portion of the failures occurring in the polar areas than would be expected from a homogeneous material. The early failures are discussed.

MATERIALS, PROPERTIES - FATIGUE↗

A Comparison of Two Non-Contact Strain Measurement Techniques with Applications to Scientific Balloons

Strain measurements of scientific balloon films are necessary for evaluating the film’s material properties, validating material models, and structural evaluations of scale model balloons. This paper presents a comparison of the strain measurement techniques used by the Balloon Program Office’s Balloon Research and Development Lab at NASA Wallops Flight Facility. Two non-contact strain measurement techniques are presented for comparison, along with an assessment of measurement accuracy for both methods. The case study of a vertically oriented cylindrical balloon is presented to illustrate both systems’ performance and draw nominal conclusions of strain as a function of pressure and axial load.

Non-Contact↗

A Comparison of Two Non-Contact Strain Measurement Techniques with Applications to Scientific Balloons

Strain measurements of scientific balloon films are necessary for evaluating the film’s material properties, validating material models, and structural evaluations of scale model balloons. This paper presents a comparison of the strain measurement techniques used by the Balloon Program Office’s Balloon Research and Development Lab at NASA Wallops Flight Facility. Two non-contact strain measurement techniques are presented for comparison, along with an assessment of measurement accuracy for both methods. The case study of a vertically oriented cylindrical balloon is presented to illustrate both systems’ performance and draw nominal conclusions of strain as a function of pressure and axial load.

Non-Contact↗

Effect of Deposition Temperature on the Tribology of MOCVD Zinc Oxide Thin Films Tested under Dry Contact

Zinc oxide has justifiably been attracting attention in several fields, and the relatively new field of tribology is not left out. Aside from its already extensively researched and documented applications in materials science, semiconductor and electronics industry, zinc oxide nanoparticles and thin films appear to be gaining fast grounds as tribological materials, thereby justifying a zealous approach in further exploring their inherent properties in this area. In this work, zinc oxide thin films were deposited by MOCVD (metal-organic chemical vapour deposition) on soda lime glass andAISI304L stainless steel plates at temperatures of 300°C, 330°C, 360°C, 390°C and 420°C respectively, using anhydrous zinc acetate as the precursor. The carrier gas was air with a flow rate of 2.5 dm 3 min -1 at atmospheric pressure, and deposition time of 2 hours each. The thickness and tribological properties of the thin films produced were thereafter investigated. The thickness was measured by RBS (Rutherford backscattering spectroscopy) using a 1.7 MeV Tandem Accelerator, and the friction and wear properties were tested with a HFRR (high frequency reciprocating rig) under dry contact conditions, Olympus BH-2 Optical Microscope, and ADE Phase Shift MicroXam Optical Surface Profiler. The thickness was found to decrease with increasing deposition temperature, although for the 300°C deposition temperature there appeared to be a bloated thickness, which is attributable to such factors as incomplete precursor decomposition, turbulence in precursor flow, and energy straggling during RBS measurement. The friction tests highlighted coefficients of friction which were relatively low at the onset of the tests, but thereafter rapidly increased, owing possibly to temperature rise, attendant rapid oxidation and aided abrasion by worn debris. The average coefficient of friction of each test was computed, and the outcome (0.33 – 0.43) for all of them was a material still good enough for use in reducing friction at nanolevel, even with worn out matter and increased working temperature, with no noticeable trend regarding their varied deposition temperatures. Microscope and profilometer profiles vividly showed wear scars with material removal and material transfer. The average wear scar diameters as well as the wear volumes were compiled for both the test balls and the thin films. The result showed a largely correlated trend in the wear scar diameters and the wear volumes, and the thin film deposited at 330°C was the coating with the least wear scars, material removal cum transfer on the test ball and sample. This result is attributed to the enhanced thickness of the sample over the others, apart from sample X1 earlier reported to have a problem in its thickness. As a result, this temperature is therefore recommended as the optimum deposition temperature for the best tribologically applicable zinc oxide thin films, using zinc acetate precursor by MOCVD.

36 MATERIALS SCIENCE↗

Controlled Dielectric Breakdown to Form Pinhole Passivated Contacts

This contribution explores a low-temperature route to forming dielectric pinholes to form poly-Si/dielectric/c-Si passivated contacts. The method utilizes controlled dielectric breakdown to form nanoscale pinholes in a thick (non-tunnelling) dielectric which, when annealed, allows dopant atoms to pass from doped poly-Si through the dielectric and into the c-Si wafer forming conductive pathways. We show that the pinholes can be repassivated with dopants and H diffusion which results in increased PL signals after processing. The method can be expanded to optimized dielectric passivation stacks (not just a single layer) and can be formed in parallel over the faces of the wafer in selected areas (only under the grid).

controlled dielectric breakdown↗

Self-Assembled Monolayer Procedure to Pattern Silicon Passivated Contacts

We utilize hexamethyldisilazane (HMDS)-based self-assembled monolayers to pattern polysilicon (polySi) passivated contacts. We find process conditions that allow for etching frontside n/polySi between fingers, thereby increasing Jsc. Importantly, the Voc does not degrade indicating the additional process steps do not introduce defects or impurities. HMDS layers remain on the surface for metallization without detriment to transport.

hexamethyldisilazane↗

Understanding Hydrogen Passivation Mechanism in Poly-Si Passivating Contacts: Insights from Effusion Studies

Silicon PV is the dominant PV technology, and captures >95% world market share, supporting -100 GW/year. Diffused and passivated pn junctions along with other rear side passivation technologies are the mainstream technologies and will continue to remain so in the coming decades. Passivated contacts, using tunnel oxide passivation stacks at the rear side, will gain market share from about 10% in 2022 up to 58% within the next 10 years. Most mature approaches use passivating layers of hydrogenated Al2O3 and SiNx. LPCVD SiNx provides less hydrogen for passivation compared to PECVD SiNx but can retain the hydrogen up to higher temperatures which is beneficial for firing. Although SiNx provides large amount of hydrogen, this doesn't necessarily translate to good passivation. AlOx:H contributes to retaining H at higher temperatures. Water molecules are also detected during H-effusion and may play a role in passivation of the oxide/wafer interface.

effusion study↗

Defect Characterization of Monocrystalline Silicon Solar Cells with Polysilicon Passivated Contact Using Electrically-Detected Magnetic Resonance (EDMR) Spectroscopy

As the c-Si based solar cell efficiencies are approaching over 26%, it is becoming critical to characterize the low concentrations of the defects – as low as 10^10-10^11 cm-3 (for e.g., iron contamination in high-lifetime Ga-doped wafers3 and n-type wafers), and further reduce them. Also, atomistic level understanding of the mechanisms of the low concentration process-induced-defects and reliability limiting defects (such as light and elevated temperature induced degradation, surface passivation degradation) is needed to design the mitigation strategies. The conventional characterization techniques are limited due to their detection limitations. Some of the techniques based on lifetime spectroscopies can still be used for low concentration characterization however, they are based on estimations and theoretical models and hence, indirect and cannot fully reveal information about the microscopic mechanism of the defects. Thus, we present the application of an ultrasensitive magnetic resonance-based technique for the direct spectroscopic detection of the defects in Si PV - electrically detected magnetic resonance (EDMR). In this work, we aim to focus on establishing a process flow for fabrication of minicells with (miniature replica of the larger-area cells) and setting up the routine for EDMR measurements on them with the EDMR instrumentation capability at NREL. For the EDMR measurements, sample size is limited by the dimensions of sample holder tube (width less than 3.2 mm, active area - 20 mm). Thus, we have designed c-Si based minicells with polysilicon (poly-Si) passivated contacts same as the larger-area cells that we fabricate in our group at NREL. We also modified our minicell process flow for fabricating the textured minicells for preserving the texture during processing and taking care of the laser-ablation edge damage which can significantly affect the performance of such small devices. We have achieved comparable performance on these newly fabricated minicells as that of our 4 cm2 devices with same structure (comparable VOC, JSC, FF). We also conducted EDMR measurements on the minicells and observed a distinct EDMR signal at g-value ~2.005 at temperatures 30K and above, as shown in Fig. 2. We associate this signal to the presence of silicon dangling bonds based on the g-value. We also observed an EDMR signal at g-value ~1.998 at temperature ~5K. The origin of this signal is still being investigated. Thus, we show the proof of concept of minicells and EDMR measurements with which we now aim to study some of the unknown defects in silicon solar cell devices.

EDMR↗

Organic matter maturation in the contact aureole of an igneous sill as a tracer of hydrothermal convection: A TRACER OF HYDROTHERMAL CONVECTION

The intrusion of magmas can start hydrothermal convection which in turn enhances the transport of heat and solutes. We use a heat convection model to interpret the temperature evolution documented by organic matter maturation, as recorded by the vitrinite reflectance Rr, in a contact aureole of a 15 m thick basaltic sill in the Deep Sea Drilling Project (DSDP) 41-368 hole near Cape Verde Rise, eastern Atlantic. Here we report on a pronounced asymmetry of variations of Rr with distance above and below the sill that cannot be explained by heat conduction alone. Neglecting the results of possible two-phase flow and thermal pressurization from the production of fluids, convection begins to enhance the observed asymmetry for permeabilities greater than about 1md, and the observations can be matched with permeabilities of at least several tens of millidarcies.

58 GEOSCIENCES↗

In Situ Back‐Contact Passivation Improves Photovoltage and Fill Factor in Perovskite Solar Cells

Abstract Organic–inorganic hybrid perovskite solar cells (PSCs) have seen a rapid rise in power conversion efficiencies in recent years; however, they still suffer from interfacial recombination and charge extraction losses at interfaces between the perovskite absorber and the charge–transport layers. Here, in situ back‐contact passivation (BCP) that reduces interfacial and extraction losses between the perovskite absorber and the hole transport layer (HTL) is reported. A thin layer of nondoped semiconducting polymer at the perovskite/HTL interface is introduced and it is shown that the use of the semiconductor polymer permits—in contrast with previously studied insulator‐based passivants—the use of a relatively thick passivating layer. It is shown that a flat‐band alignment between the perovskite and polymer passivation layers achieves a high photovoltage and fill factor: the resultant BCP enables a photovoltage of 1.15 V and a fill factor of 83% in 1.53 eV bandgap PSCs, leading to an efficiency of 21.6% in planar solar cells.

Tan, Furui↗