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At least 1,747 records · Page 97

Kinetic aspects of magnetotail dynamics - Observations

The observed kinetic (as opposed to fluid) aspects of particle behavior in the geomagnetic tail are discussed. Such behavior has been observed from thermal plasma energies to energies a few MeV or more. The importance of recognizing and analyzing the kinetic behavior of tail particles is that it provides a powerful diagnostic tool for inferring the state of the local and remote environment and the mechanisms responsible for observed tail dynamics, and a way of determining when fluid analyses (relying upon moments such as bulk velocity and temperature) may be misleading. Thus kinetic analyses provide a valuable complement to fluid-dynamics-based studies of the collective behavior of geomagnetic tail particles. Observed kinetic effects can be analyzed to examine spatial gradients; convection electric fields, distances to source regions, source-region characteristics, magnetic-field topology, heating/acceleration mechanism, boundary characteristics, and remote mechanisms affecting local particle distributions.

Mitchell, D. G.↗

Role of Intra-Domain Heterogeneity on Ion and Polymer Dynamics in Block Polymer Electrolytes: An Approach for Spatially Resolving Dynamics and Ion Transport

The design of safe and high-performance, nanostructured, block polymer (BP) electrolytes for lithium-ion batteries requires a thorough understanding of the key parameters that govern local structure and dynamics. Yet, the interfaces between microphase separated domains can introduce complexities in this local behavior that can be challenging to quantify. Herein, the local polymer, cation (Li + ), and anion dynamics were described in salt-doped polystyrene block poly(oligo-oxyethylene methyl ether methacrylate) (PS-b-POEM) through a quantitative framework that considered the effects of polymer architecture, segmental mixing, chain stretching, and confinement on polymer mobility and ion transport. This framework was validated through nuclear magnetic resonance (NMR) spectroscopy measurements on solid (dry) polymer electrolyte samples. Notably, a mobility transition temperature (T mobility ) was identified through NMR spectroscopy that captured the local dynamics more accurately than the thermal glass transition temperature. Additionally, the approach quantitatively described the mobility gradient across a domain when segmental mixing effects were combined with chain stretching and confinement information, especially at higher segregation strengths – facilitating the assessment of local ion diffusion and conductivity. As a result, spatially averaged local ion diffusion predictions quantitatively matched NMR-measured ion diffusivities in the BP samples, while spatially summed ionic conductivity predictions across a domain qualitatively captured trends in the measured ionic conductivities.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Continuous wave dye-laser technique for simultaneous, spatially resolved measurements of temperature, pressure, and velocity of NO in an underexpanded free jet

Gas dynamic quantities within an underexpanded nitrogen free jet, seeded with 0.5 percent NO, were measured nonintrusively by using an intracavity-doubled, rapid-tuning, CW ring dye laser. The UV beam passed obliquely through the jet axis, and its frequency repetitively scanned across adjacent rotational lines in the NO gamma band near 225 nm at a rate of 4 kHz. Spatially resolved excitation scans were obtained by monitoring the induced broadband fluoresence. Modeling the Doppler-shifted excitation scans with Voigt profiles permitted simultaneous determinations of NO velocity, rotational temperature, and pressure. Zero Doppler shift was referenced to an absorption trace obtained across a static cell and recorded concurrently with the excitation scan. Typically, the measured and predicted axial distributions agreed within 10 percent. At high Mach numbers there was evidence of rotational freezing of NO.

Di Rosa, Michael D.↗

Leptogenesis with dynamical couplings

We propose a novel leptogenesis mechanism with a temperature-dependent coupling between the right-handed neutrino and Standard Model particles. This coupling experiences suppression at high temperatures and becomes sizable when the lepton asymmetry washout processes are Boltzmann-suppressed. Such a feature ensures that the washout rates remain consistently below the Hubble expansion rate, preserving all lepton asymmetry generated in the decay of right-handed neutrinos. We illustrate the feasibility of this mechanism with two example models and show that the observed baryon asymmetry of the Universe can be successfully obtained for right-handed neutrino masses larger than 10 9 GeV as well as for smaller violation of charge-parity symmetry. Published by the American Physical Society 2024

Huang, Peisi (ORCID:0000000333602641)↗

Dynamic crystallization of silicate melts

Two types of furnaces with differing temperature range capabilities were used to provide variations in melt temperatures and cooling rates in a study of the effects of heterogeneous nucleation on crystallization. Materials of chondrule composition were used to further understanding of how the disequilibrium features displayed by minerals in rocks are formed. Results show that the textures of natural chondrules were duplicated. It is concluded that the melt history is dominant over cooling rate and composition in controlling texture. The importance of nuclei, which are most readily derived from preexisting crystalline material, support an origin for natural chondrules based on remelting of crystalline material. This would be compatible with a simple, uniform chondrule forming process having only slight variations in thermal histories resulting in the wide range of textures.

Russell, W. J.↗

Static and dynamical Meissner force fields

The coupling between copper-based high temperature superconductors (HTS) and magnets is represented by a force field. Zero-field cooled experiments were performed with several forms of superconductors: 1) cold-pressed sintered cylindrical disks; 2) small particles fixed in epoxy polymers; and 3) small particles suspended in hydrocarbon waxes. Using magnets with axial field symmetries, direct spatial force measurements in the range of 0.1 to 10(exp 4) dynes were performed with an analytical balance and force constants were obtained from mechanical vibrational resonances. Force constants increase dramatically with decreasing spatial displacement. The force field displays a strong temperature dependence between 20 and 90 K and decreases exponentially with increasing distance of separation. Distinct slope changes suggest the presence of B-field and temperature-activated processes that define the forces. Hysteresis measurements indicated that the magnitude of force scales roughly with the volume fraction of HTS in composite structures. Thus, the net force resulting from the field interaction appears to arise from regions as small or smaller than the grain size and does not depend on contiguous electron transport over large areas. Results of these experiments are discussed.

Weinberger, B. R.↗

Diffusion model for the phase delay between thermospheric density and temperature.

Consideration of a two-dimensional time-dependent model in which the thermosphere dynamics is excited by the UV heat input within the thermosphere, showing that the wind-induced variations in the diurnal component of atomic oxygen dominate over its temperature-induced variations up to 200 km. The assumption of diffusive equilibrium is therefore in general not valid for O within the lower thermosphere. The effect of the diurnal wind circulation is to redistribute O so that the diurnal variations in the forbidden O/forbidden N2 and forbidden O/forbidden O2 ratios are damped by about 20%, thus contributing to the maintenance of the nighttime F2 region, and the maximum in the diurnal variation of O is shifted by one to two hours away from the temperature maximum toward noon, thus contributing significantly to the temperature-density time lag at thermospheric heights above 200 km, where O becomes the major constituent.

Mayr, H. G.↗

Constant-temperature anemometry measurements in hypersonic boundary layers

One of the major unresolved issues in fluid dynamics is the nature of apparent stresses, called Reynolds stresses, which occur in turbulent boundary layers. In hypersonic boundary layers, the flow physics is further complicated by the large temperature and density fluctuations and the concomitant contamination of the Reynold stresses by fictitious terms. Because of the severe flow environment and the extraordinary demands on sensors and instruments, the turbulence characteristics of hypersonic boundary layers were studied in only a cursory fashion. The plans for supersonic (HSCT) and hypersonic (NASP) vehicles made supersonic flow physics one of the critical pacing technologies in aerospace science. In particular, experimental data are needed to verify candidate computer models and to reach an important understanding of the turbulence physics. The presented research is the start of a substantial effort to refine existing instrumentation and develop experimental techniques to measure the various component of the Reynolds stress in hypersonic boundary layers.

Spina, Eric F.↗

The spectroscopy of the atmosphere using far-infrared emission experiment (SAFIRE)

The goal of the SAFIRE experiment is to improve understanding of the middle-atmospher ozone distribution by conducting and analyzing global-scale measurements of important chemical, radiative and dynamical processes, including coupling among these processes and atmospheric regions. This will be accomplished by observing vertical profiles of temperature and key gases in the main chemical families. A detailed listing of SAFIRE measurements, including sepctral ranges, altitude ranges, IFOV, spatial and temporal resolution, latitude coverage and estimated precision is provided. The temperature, O3, CH4, and H2O observations will be useful for deriving and studying dynamical quantities such as geopotential height, potential vorticity, balanced winds and Eliassen-Palm fluxes. The SAFIRE observations will provide important data for study of chemistry, dynamics and transport processes. This experiment was conceived in response to a need for simultaneous measurements of odd hydrogen gases. These include gases such as OH, HO2, and atomic oxygen, which have not been observed by past satellite experiments and which will not be measured by any of teh Upper Atmosophere Reserach Satellite (UARS) experiments to be launched in 1991.

Russell, J. M., III↗

Dynamics of the universe and spontaneous symmetry breaking

It is shown that the presence of a phase transition early in the history of the universe, associated with spontaneous symmetry breaking (believed to take place at very high temperatures at which the various fundamental interactions unify), significantly modifies its dynamics and evolution. This is due to the energy 'pumping' during the phase transition from the vacuum to the substance, rather than the gravitating effects of the vacuum. The expansion law of the universe then differs substantially from the relation considered so far for the very early time expansion. In particular it is shown that under certain conditions this expansion law is exponential. It is further argued that under reasonable assumptions for the mass of the associated Higgs boson this expansion stage could last long enough to potentially account for the observed isotropy of the universe.

Kazanas, D.↗

Probing the atomic dynamics of ultrafast melting with femtosecond electron diffraction

Melting is an every-day phase transition that is determined by thermodynamic parameters like temperature and pressure. In contrast, ultra-fast melting is governed by the microscopic response to a rapid energy input and, thus, can reveal the strength and dynamics of atomic bonds as well as the energy flow rate to the lattice. Accurately describing these processes remains challenging and requires detailed insights into transient states encountered. Here, we present data from femtosecond electron diffraction measurements that capture the structural evolution of copper during the ultrafast solid-to-liquid phase transformations. At absorbed energy densities 2-4 times the melting threshold, melting begins at the surface slightly below the nominal melting point followed by rapid homogeneous melting throughout the volume. Molecular dynamics simulations reproduce these observations and reveal a weak electron-lattice energy transfer rate for the given experimental conditions. Both simulations and experiments show no indications of rapid lattice collapse when its temperature surpasses proposed limits of superheating, providing evidence that the inherent dynamics limits the speed of disordering in ultrafast melting of metals.

FOS: Physical sciences↗

Development of a Computationally Efficient, High Fidelity, Finite Element Based Hall Thruster Model

This report documents the development of a two dimensional finite element based numerical model for efficient characterization of the Hall thruster plasma dynamics in the framework of multi-fluid model. Effect of the ionization and the recombination has been included in the present model. Based on the experimental data, a third order polynomial in electron temperature is used to calculate the ionization rate. The neutral dynamics is included only through the neutral continuity equation in the presence of a uniform neutral flow. The electrons are modeled as magnetized and hot, whereas ions are assumed magnetized and cold. The dynamics of Hall thruster is also investigated in the presence of plasma-wall interaction. The plasma-wall interaction is a function of wall potential, which in turn is determined by the secondary electron emission and sputtering yield. The effect of secondary electron emission and sputter yield has been considered simultaneously, Simulation results are interpreted in the light of experimental observations and available numerical solutions in the literature.

Jacobson, David↗

Temperature‐Dependent Crystallization in Two‐Step Perovskite Deposition Revealed by In Situ GIWAXS and Machine Learning‐Guided Analysis

The performance and stability of perovskite solar cells are strongly governed by the crystallization behavior of their active layer. In two-step sequential deposition, early-stage film formation plays a decisive role in determining final phase purity and device quality. Guided by a data-driven analysis of nearly 39 000 devices in the FAIR perovskite database, we identified solvent-mediated quenching and thermal processing as key variables affecting power conversion efficiency (PCE), particularly in two-step fabrication. Here, to investigate these effects in real time, we designed and implemented a custom-built, temperature-controlled spin-coating system, enabling precise thermal modulation during precursor deposition. Using this platform, we performed in situ GIWAXS measurements to study the crystallization dynamics of FA 0.5 MA 0.5 PbI 3 films over a temperature range of 30°C–90°C. Our results reveal a non-monotonic relationship between spin-coating temperature and α-phase formation, governed by the interplay between precursor interdiffusion, PbI 2 crystallinity, and δ-phase suppression. The custom thermal control enabled us to isolate and quantify these competing effects during the earliest stages of film formation, providing mechanistic insight into how spin-coating temperature governs both phase purity and kinetic pathways in two-step perovskite systems. Temperature-dependent SEM and photovoltaic device measurements further demonstrate that early-stage crystallization pathways directly translate into differences in morphology, charge-transport continuity, and device performance. These findings inform targeted strategies for optimizing deposition protocols to balance rapid nucleation, phase stability, and device performance.

Saadawy, Ahmed [King Fahd University of Petroleum ↗

Filling the Gaps: A Bayesian Mixture Model for Imputing Missing Soil Water Content Data

ABSTRACT Soil water content (SWC) data are central to evaluating how soil moisture varies over time and space and influences critical plant and ecosystem functions, especially in water‐limited drylands. However, sensors that record SWC at high frequencies often malfunction, leading to incomplete timeseries and limiting our understanding of dryland ecosystem dynamics. We developed an analytical approach to impute missing SWC data, which we tested at six eddy flux tower sites along an elevation gradient in the southwestern United States. We impute missing data as a mixture of linearly interpolated SWC between the observed endpoints of a missing data gap and SWC simulated by an ecosystem water balance model (SOILWAT2). Within a Bayesian framework, we allowed the relative utility (mixture weight) of each component (linearly interpolated vs. SOILWAT2) to vary by depth, site and gap characteristics. We explored “fixed” weights versus “dynamic” weights that vary as a function of cumulative precipitation, average temperature, and time since the start of the gap. Both models estimated missing SWC data well ( R 2 = 0.70–0.88 vs. 0.75–0.91 for fixed vs. dynamic weights, respectively), but the utility of linearly interpolated versus SOILWAT2 values depended on site and depth. SOILWAT2 was more useful for more arid sites, shallower depths, longer and warmer gaps and gaps that received greater precipitation. Overall, the mixture model reliably gap‐fills SWC, while lending insight into processes governing SWC dynamics. This approach to impute missing data could be adapted to accommodate more than two mixture components and other types of environmental timeseries.

Ogle, Kiona [School of Informatics, Computing, and↗

Contribution of the Hydroxyl Group on Interfacial Heat Conduction of Monohydric Alcohols: A Molecular Dynamics Study

Monohydric alcohols have been used as promising phase change materials (PCMs) for low-temperature latent heat storage. However, the heat storage/retrieval rates are limited due to the low thermal conductivity of such alcohols. In this work, nonequilibrium molecular dynamics (NEMD) simulations were performed to study the microscopic heat conduction in example monohydric alcohols, i.e., 1-dodecanol (C12H26O), 1-tetradecanol (C14H30O), and 1-hexadecanol (C16H34O). A simplified ideal crystal model was proposed to exploit the potential for improving the thermal conductivity of monohydric alcohols. The effect of ideal crystalline structures, especially the contribution of the hydroxyl group, on the microscopic heat conduction process was analyzed. The thermal conductivity of the ideal crystals of the various monohydric alcohols was predicted to be more than twice as compared to that of their respective solids. The major thermal resistance in the ideal crystals was found around the molecular interfaces, as a result of the excellent heat conduction performance along the linear molecular chains. The calculated vibrational density of states (VDOS) and interfacial heat transfer were then investigated. When the interfaces are surrounded by hydroxyl groups as walls, strong hydrogen bond (HB) interactions were observed. The interfacial heat transfer coefficient of the ideal crystalline structures of 1-tetradecanol was found to reach up to ~735.6 MW/m2 W. It was elucidated that the high interfacial heat transfer rate is clearly related to the stronger intermolecular interactions.

Engineering↗

The cryogenic wind tunnel for high Reynolds number testing

An improved way to increase the Reynolds numbers capability of wind tunnels has been developed at the Langley Research Center. Cooling the test gas to cryogenic temperatures by spraying liquid nitrogen into the tunnel circuit increases Reynolds number with no increase in dynamic pressure and a reduction in drive power. In addition, the ability to vary the temperature of the test gas independently of pressure and Mach number allows for the first time the independent determination of Reynolds number, Mach number, and aeroelastic effects. A new fan-driven transonic cryogenic tunnel being built at the Langley Research Center will provide an order of magnitude increase in Reynolds number capability over existing transonic tunnels in the United States when it is completed later this year.

Kilgore, R. A.↗

Comparison of high frequency, high temperature core loss and B-H loop characteristics of an 80 Ni-Fe crystalline alloy and two iron-based amorphous alloys

Limited experimental data exists for the specific core loss and dynamic B-H loops for soft magnetic materials for the combined conditions of high frequency and high temperature. This experimental study investigates the specific core loss and dynamic B-H characteristics of a nickel-iron crystalline magnetic alloy (Supermalloy) and two iron-based amorphous magnetic materials (Metglas 2605S-3A and Metglas 2605SC) over the frequency range of 1-50 kHz and temperature range of 23-300 C under sinusoidal voltage excitation. The effects of maximum magnetic flux density, frequency, and temperature on the specific core loss and on the size and shape of the B-H loops are examined. The Supermalloy and Metglass 2605S-3A and 2605SC data are used to compare the core loss of transformers with identical kVA and voltage ratings.

Wieserman, William R.↗