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At least 1,729 records · Page 96

Comparison of Machine Learning Approaches for Prediction of the Equivalent Alkane Carbon Number for Microemulsions Based on Molecular Properties

The chemical properties of oils are vital in the design of microemulsion systems. The hydrophilic–lipophilic difference equation used to predict microemulsions’ phase behavior expresses the oils’ physiochemical properties as the equivalent alkane carbon number (EACN). The experimental determination of EACN requires knowledge of the temperature dependence of the microemulsion system and the effects of different surfactant concentrations. Thus, the experimental determination is time-intensive and tedious, requiring days to months for proper separations. Furthermore, the experiments require high purity of chemicals because microemulsions are sensitive to impurities. Our work focuses on the quick and reliable predictions of the EACN with machine learning (ML) models. Due to the immaturity of ML chemical predictions, we compare three graph neural networks (GNNs) and a gradient-boosted tree algorithm, known as XGBoost. The GNNs use the molecular structures represented as simplified molecular-input line-entry system (SMILES) codes for the initial input, which allows us to assess whether geometry optimization is necessary for reliable results. The XGBoost model also begins with the SMILES representations of the molecules but uses molecular descriptors instead of geometry optimizations. As a result, the best model tested (crystal graph convolutional neural network with Merck molecular force field-94) has an error of 1.15 EACN units of the true EACN for unknown data with the errors skewed toward zero and an R² score of 0.9

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Experimental Investigations into the Corrosion of Alloy 625 Using NaCl-PuCl3 Molten Salt in a Natural Circulation Microloop

Molten salt reactors (MSRs) can potentially revolutionize the nuclear industry by providing a path to a near-zero nuclear waste fuel cycle, contributing to more sustainable energy sources. As a plethora of MSR developers in the United States work toward an aggressive commercialization timeline, many of their fueled-salts—notably, chloride-based compositions—have limited operational testing with nuclear material. Licensing and operating these reactors require an understanding of corrosion effects on reactor materials of construction under operational conditions. The TerraPower Molten Chloride Fast Reactor (MCFR) is a liquid-fueled chloride-salt fast reactor which has received notable interest from the utility sector based on its desirable economic characteristics. The reactor operates at low pressure but does not require the use of highly reactive chemicals, leading to a reduced use of concrete and steel during construction. Additionally, liquid fuel allows for inherently stable behavior and natural circulation during a loss-of-site-power scenario. MCFR can be refueled while operating which makes it compatible with variable generation sources such as wind and solar. MCFR is a breed-and-burn in-situ reactor that does not implement any chemical processing or separations in the fuel cycle. Only mechanical filtration of noble metals and off-gassing of noble gases are utilized while the actinides stay mixed with the fuel at all times. The MCFR will require technology development to reach commercialization. With a breed-and-burn in-situ reactor like MCFR, the transmutation of fertile U-238 to fissile Pu-239 allows for much greater fuel utilization.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Effect of temperature on composite sandwich structures subjected to low velocity impact

The effect of low velocity projectile impact on sandwich-type structural components was investigated. The materials used in the fabrication of the impact surface were graphite-, Kevlar-, and boron-fibers with appropriate epoxy matrices. The testing of the specimens was performed at moderately low- and high-temperatures as well as at room temperature to assess the impact-initiated strength degradation of the laminates. Eleven laminates with different stacking sequences, orientations, and thicknesses were tested. The low energy projectile impact is considered to simulate the damage caused by runway debris, the dropping of the hand tools during servicing, etc., on the secondary aircraft structures fabricated with the composite materials. The results show the preload and the impact energy combinations necessary to cause catastrophic failure in the laminates tested. A set of faired curves indicating the failure thresholds is shown separately for the tension-and compression-loaded laminates. The specific-strengths and -modulii for the various laminates tested are also given.

Sharma, A. V.↗

Countercurrent distribution of biological cells

Detailed physiochemical studies of dextran/poly(ethylene glycol) (PEG) two phase systems were carried out to characterize and provide understanding of the properties of the systems which determine cell partition and the electrophoretic behavior of phase drops responsible for electric field driven phase separation. A detailed study of the electrostatic and electrokinetic potentials developed in these systems was carried out. The salt partition was examined both in phase systems and with pure polymer solutions via equilibrium dialysis and mechanism of sulfate, chloride and phosphate partition shown to be exclusion by PEG rather than binding by dextran. Salt partition was shown to have a strong effect on the polymer compositions of the phases as well, an effect which produces large changes in the interfacial tension between them. These effects were characterized and the interfacial tension shown to obey a power law with respect to its dependence on the length of the tie line describing the system composition on a phase diagram. The electrostatic potential differences measured via salt bridges were shown to obey thermodynamic predictions. The electrophoretic mobilities measured were utilized to provide a partial test of Levine's incomplete theory of phase drop electrophoresis. The data were consistent with Levine's expression over a limited range of the variables tested.

Brooks, D. E.↗

Dilution Jets in Accelerated Cross Flows

Results of flow visualization experiments and measurements of the temperature field produced by a single jet and a row of dilution jets issued into a reverse flow combustor are presented. The flow in such combustors is typified by transverse and longitudinal acceleration during the passage through its bending section. The flow visualization experiments were designed to examine the separate effects of longitudinal and transverse acceleration on the jet trajectory and spreading rate. A model describing a dense single jet in a lighter accelerating cross flow is developed. The model is based on integral conservation equations, including the pressure terms appropriate to accelerating flows. It uses a modified entrainment correlation obtained from previous experiments of a jet in a cross stream. The flow visualization results are compared with the model calculations in terms of trajectories and spreading rates. Each experiment is typified by a set of three parameters: momentum ratio, density ratio, and the densimetric Froude number. When injection velocities are large or densities are small, the Froude number becomes very large and hence, unimportant. Therefore, the Froude number is generally significant in describing liquid experiments but is unimportant for the gas experiments in the combustor. Agreement between test and calculated results is encouraging but tends to become poorer with increasing momentum ratio. The temperature measurements are presented primarily in the form of consecutive normalized temperature profiles. Some interpolated isothermal contours are also shown. The single jet trajectories are consistently found to be swept towards the inner wall of the bend, whether injection is from the outer or the inner wall. This behavior is explained by a drifting effect which consists of a transverse velocity component across the combustor due to the developing nature of the flow along it. Plots of lateral temperature distributions of the jet indicate that under longitudinal acceleration conditions the thermal spreading of the jet may be completely suppressed. Comparison between combustor experimental results and model calculations shows poor agreement due to the drifting effect which is not taken into consideration in the model calculations. The row of jets experiments are characterized by two additional parameters: spacing ratio and confinement parameter. The results are shown in the form of consecutive normalized temperature profiles. The confinement parameter appears to become increasingly important with decreasing spacing ratio, in particular when its effect is enhanced by the drifting phenomenon and associated pressure field. A tightly spaced row of jets injected from the inner wall, prior to the bend, is surprisingly kept attached to the inner wall in spite of the strong turning. A similar attachment for a jet injected from the outer wall is not observed.

Lipshitz, Abraham↗

Parabolic Deformable Mirror Testbed for the ExoSpec Project

The ExoSpec Project is a NASA Headquarters directed work package that links four different tasks at Goddard Space Flight Center to enable future missions to more efficiently characterize directly imaged exoplanets. One of the tasks is the development of parabolic deformable mirrors to improve on the current state-of-the-art wavefront sensing and control implementations, which are baselined to have two flat deformable mirrors (DMs) with high actuator count. To effectively control both amplitude and phase aberrations, the flat DMs need to have a large separation, which poses packaging challenges to missions designed to image rocky exoplanets. To eliminate this large separation, the parabolic DM architecture makes the off-axis imaging elements in the optical train controllable. Simulations also show performance enhancements with the architecture change; larger bandwidths have been shown to be controllable with the parabolic DMs and the number of required actuators can be reduced. With a 32×32 pupil flat DM and two 16x16 parabolic DMs, we could obtain a 5 - 12λ/D dark hole at 35%bandwidth. In addition to addressing the packaging challenge faced by future coronagraph missions, reducing the number of actuators reduces both cost and risk of having the entire coronagraph instrument’s performance depend on two high-actuator count DMs. To test these simulations, Goddard is building a testbed and has a vendor developing the parabolic DM. Here we present these simulations, the current testbed performance, and the development plan to incorporate and test the parabolic DMs

Coronagraph↗

Data from: "Soil moisture mediates alpine life form and community productivity responses to warming"

This dataset contains values that were used to support conclusions drawn in the publication “Soil moisture mediates alpine life form and community productivity responses to warming”, originally published in 2016 by Winkler et al. All data were collected in the alpine site of the Alpine Treeline Warming Experiment (ATWE), located on Niwot Ridge, in the Front Range of the Colorado Rocky Mountains, USA. The file types in this archive include comma-separated-values (.csv) files, and two types of geospatial files: .kml and shapefiles (.shp). The csv files can be opened by R, Microsoft Excel, or any simple text editor software. The geospatial files can be opened by Google Earth/Google Maps, and the ESRI shapefiles can be opened by geographic information systems softwares that can read shapefiles, including ESRI’s ArcGIS Desktop suite, and QGIS.Climate warming is expected to alter primary production and community composition in alpine systems around the globe. Whether production will increase in response to warming in the absence of additional precipitation remains underexplored. We experimentally warmed an alpine plant community on Niwot Ridge, Colorado to test whether warming increases or decreases productivity of multiple plant life form groups and the entire plant community. We also provided supplemental water to a subset of plots to alleviate potential drying effects of warming. We predicted alpine community above-ground productivity would increase in response to warming only when combined with supplemental water to limit soil drying. We also predicted plant life form groups would vary in their responses and would like buffer changes in community productivity.

54 ENVIRONMENTAL SCIENCES↗

Conditional Pseudo-Reversible Normalizing Flow for Surrogate Modeling in Quantifying Uncertainty Propagation

We introduce a conditional pseudo-reversible normalizing flow (PR-NF) that directly learns conditional probability distributions from noisy physical models to efficiently quantify both forward and inverse uncertainty propagation. Traditional surrogate modeling approaches approximate only the deterministic component of physical models, requiring separate noise characterization and computationally expensive sampling methods for inverse problems. Here, in this work, we develop the conditional PR-NF model to directly learn and efficiently generate samples from the conditional probability density functions (PDFs). The training process utilizes dataset consisting of input-output pairs without requiring prior knowledge about the noise and the function. Once trained, our model efficiently generates samples from conditional PDFs for any input within the training domain. Moreover, the pseudo-reversibility feature allows for the use of fully connected neural network architectures, which simplifies the implementation and enables theoretical analysis. We provide a rigorous convergence analysis of the conditional PR-NF model, showing its ability to converge to the target conditional PDF using the Kullback−Leibler divergence. To demonstrate the effectiveness of our method, we apply it to several benchmark tests and a real-world geologic carbon storage problem.

97 MATHEMATICS AND COMPUTING↗

Laser velocimeter measurements of the flow field generated by a forward-swept propfan during flutter

Results are presented from an investigation to measure the flow field generated by a forward-swept propfan operating in flutter at a low forward velocity. For comparison to the flutter condition, flow field data are also presented for a slightly reduced rotational speed just below flutter. The forward-swept propfan was tested as the front rotor of a counterrotating pusher propeller. A laser Doppler velocimeter (LDV) was used to measure the velocity field in planes normal to the model centerline downstream of the rotor and in planes of constant radius within the blade passages at each operating condition. The mean time-averaged flow about the blades did not change drastically as the propfan rotational speed was increased from the stable operating point to the flutter condition. No regions of flow separation could be identified in the data plots of the mean intrablade flow field. The relative flow about the blades remained subsonic during flutter operation. The blades were found to have a higher than expected tip loading at both operating conditions. This is thought to have been caused by the outer blade sections twisting under load to higher than expected effective blade angles. This high tip loading resulted in strong vortices and a very nonuniform flow downstream of the tips of the forward-swept blades. This high tip loading may also have caused the blade flutter.

Podboy, Gary G.↗

Bleed Roughness Mechanism

Suction applied through wall bleed is expected to reduce boundary-layer thickness and lead to a profile that can resist separation. However, experiments with rows of suction holes or slots have shown that the benefits of suction are not realized under certain circumstances. Lee, Sloan and Paynter attributed this to a 'bleed roughness', and modeled the phenomena using a modified inner-length scale with convective lag for the eddy viscosity. Test information was required to determine the roughness values at each Mach number and bleed rate. The present work used numerical calculation, subsonic and supersonic experimentation, and physical modeling were used to explore bleed roughness. It was found that the phenomena can exist in the absence of bleed, that it is a function of geometry and Mach number, and that it does not appear in low subsonic flow. The inner-length scale/convective lag approach was found to be inconsistent with recent physical observation. Alternate steady models for the roughness effect disagreed with mass flux trends and the choked flow limit, and suggested that non-steady mechanisms are present. While new supersonic experiments did exhibit low-frequency plenum oscillations, high-frequency unsteadiness associated with the orifice flow scale appears to be the cause of bleed roughness. In fact, boundary-layer calculations with an oscillatory orifice flow produced the same effect in the time-averaged downstream profile for incompressibile flow. A new empirical turbulence-model was proposed which increased the eddy viscosity throughout the entire boundary-layer by a constant which was calibrated using the zero-bleed profile. Preliminary calculations agreed with the experimental data. The model significantly reduced the test information required to determine roughness values for turbulence modeling, and provided prediction capability for supersonic bleed flows. An abstract of a thesis entitled 'Boundary-Layer Bleed Roughness' is included.

Russell, David A.↗

A New Interferometer for Monitoring Atmospheric Phase Fluctuations

Water vapor in the Earth's troposphere introduces an extra electrical path in the propagation of radio signals through the atmosphere. The distribution of water vapor is irregular and distorts the wavefronts of incoming radio waves, limiting the angular resolution that can be achieved with ground-based telescopes. The level of fluctuations depends both on the location of the site ,and on the prevailing atmospheric conditions. The ability to measure the fluctuations is therefore important when choosing a site for a new instrument, and for scheduling observations of existing telescopes. Existing phase monitors are radio interferometers that monitor monochromatic beacon tones from geostationary communications satellites at a frequency of about 12 GHz. They have a classical heterodyne design based on two satellite receiving antennas; each has a front-end for amplifying and down-converting the incoming signals using a local oscillator that is phase-locked to a common reference frequency. In addition to multiple phase-locked loops these instruments require expensive phase-stable cabling to reduce the effects of thermal drift. The new system uses two consumer 18" digital satellite TV dishes to monitor satellite TV broadcast signals over a bandwidth of 500 MHz (12.2 to 12.7 GHz). The novel design eliminates the need for phase-locked loops and thermally stable components, and uses a pair of Gilbert Cell multipliers to perform the broadband correlation. A phase monitor has been been built and deployed at the site of the Berkeley-Illinois-Maryland Association Millimeter Array in Northern California, and has been operating successfully since June 1998, measuring the difference in electrical path length for parallel lines of sight to the satellite separated by a baseline of 100 m. With a hardware cost of approximately $4000, it is much cheaper than previous instruments, and the low power requirements and high reliability make the system suitable for site testing in remote locations.

Lay, Oliver↗

Boundary-Layer-Ingesting Inlet Flow Control

This paper gives an overview of a research study conducted in support of the small-scale demonstration of an active flow control system for a boundary-layer-ingesting (BLI) inlet. The effectiveness of active flow control in reducing engine inlet circumferential distortion was assessed using a 2.5% scale model of a 35% boundary-layer-ingesting flush-mounted, offset, diffusing inlet. This experiment was conducted in the NASA Langley 0.3-meter Transonic Cryogenic Tunnel at flight Mach numbers with a model inlet specifically designed for this type of testing. High mass flow actuators controlled the flow through distributed control jets providing the active flow control. A vortex generator point design configuration was also tested for comparison purposes and to provide a means to examine a hybrid vortex generator and control jets configuration. Measurements were made of the onset boundary layer, the duct surface static pressures, and the mass flow through the duct and the actuators. The distortion and pressure recovery were determined by 40 total pressure measurements on 8 rake arms each separated by 45 degrees and were located at the aerodynamic interface plane. The test matrix was limited to a maximum free-stream Mach number of 0.85 with scaled mass flows through the inlet for that condition. The data show that the flow control jets alone can reduce circumferential distortion (DPCPavg) from 0.055 to about 0.015 using about 2.5% of inlet mass flow. The vortex generators also reduced the circumferential distortion from 0.055 to 0.010 near the inlet mass flow design point. Lower inlet mass flow settings with the vortex generator configuration produced higher distortion levels that were reduced to acceptable levels using a hybrid vortex generator/control jets configuration that required less than 1% of the inlet mass flow.

Owens, Lewis R.↗

Boundary-Layer-Ingesting Inlet Flow Control

This paper gives an overview of a research study conducted in support of the small-scale demonstration of an active flow control system for a boundary-layer-ingesting (BLI) inlet. The effectiveness of active flow control in reducing engine inlet circumferential distortion was assessed using a 2.5% scale model of a 35% boundary-layer-ingesting flush-mounted, offset, diffusing inlet. This experiment was conducted in the NASA Langley 0.3-meter Transonic Cryogenic Tunnel at flight Mach numbers with a model inlet specifically designed for this type of testing. High mass flow actuators controlled the flow through distributed control jets providing the active flow control. A vortex generator point design configuration was also tested for comparison purposes and to provide a means to examine a hybrid vortex generator and control jets configuration. Measurements were made of the onset boundary layer, the duct surface static pressures, and the mass flow through the duct and the actuators. The distortion and pressure recovery were determined by 40 total pressure measurements on 8 rake arms each separated by 45 degrees and were located at the aerodynamic interface plane. The test matrix was limited to a maximum free-stream Mach number of 0.85 with scaled mass flows through the inlet for that condition. The data show that the flow control jets alone can reduce circumferential distortion (DPCP(sub avg)) from 0.055 to about 0.015 using about 2.5% of inlet mass flow. The vortex generators also reduced the circumferential distortion from 0.055 to 0.010 near the inlet mass flow design point. Lower inlet mass flow settings with the vortex generator configuration produced higher distortion levels that were reduced to acceptable levels using a hybrid vortex generator/control jets configuration that required less than 1% of the inlet mass flow.

Owens, Lewis R.↗

Ignition propagation and heat effects of propellant chips embedded in castable inhibitor using a laser flux test bomb

A castable inhibitor is applied to the aft face of the Space Shuttle Redesigned Solid Rocket Motor (RSRM) forward segment propellant grain to control propellant surface burn area. During fabrication, the propellant surface is trimmed prior to the inhibitor application. This produces a potential for small propellant chips to remain undetected on the propellant surface and contaminate the inhibitor during application. The concern was that undetected propellant chips in the inhibitor might provide a fuse path for premature propellant ignition underneath the inhibitor. To evaluate the fuse path potential, testing was performed on inhibitor samples with embedded propellant. The internal motor environment was simulated with a calibrated CO2 laser beam directed onto a sample which was placed in a 4100 kPa (600 psi) nitrogen pressurized bomb (laser bomb). The testing showed definitive results pertaining to fuse path formation. Embedded propellant chips did not autoignite until the receding heat affected inhibitor surface reached, or passed, the propellant chip. Samples with embedded propellant chips in alignment did not propagate ignition from one chip to another with separation distances as small as 0.010 cm(0.004 inc) and some as little as 0.0051 cm (0.002 in). Propellant chips with volumes approximately less than 0.025 cu cm (0.0015 cu in) (which did not propagate ignition) did not increase the inhibitor material decomposition depth more than the resulting void cavity of the burned out propellant chip. In addition, the depth of this void cavity did not increase until it was overtaken by the surrounding material decomposition depth. This was due, in part, to the retention of the protective inhibitor char layer. Samples with embedded propellant strings, whose thicknesses were below 0.023 cm (0.009 in), did not propagate ignition. Propellant string thicknesses above 0.038 cm (0.015 in) did propagate ignition. Test sample char and heat affected layer measurements and observations compared well with those from the Space Shuttle Solid Rocket Motor (SRM) Technical Evaluation Motor no. 9(TEM-9).

Bolton, Douglas E., Jr.↗

Cryogenic Carbon Capture Development (Final Report)

This project extends and leverages the work completed under funding from ARPA-E and other sources by exploring aspects of the Cryogenic Carbon Capture™ (CCC) process and issues discovered during those projects, but that were not within the scope or budget of previous projects or that became apparent during field tests. Our successful completion of the tasks outlined in this project has increased the reliability, efficiency, and scalability of the CCC process and we are better prepared for pilot-scale testing. The first phase of this project improved key areas of the process through iterative design and experiment, culminating with recommendations for improvements to the existing skid-scale system developed under non-federal funding. The second phase of this project implemented the improved unit operations into the Cryogenic Carbon Capture External Cooling Loop (CCC ECL™) skid and field tests the improved system at a coal-fired power plant. The specific areas of work in this project are: Budget Period 1: 1) Selection of the most energy-efficient drying system for ambient-pressure flue gas. Sustainable Energy Solutions, LLC (SES) has successfully demonstrated a dryer that removes bulk water using a low-temperature brine to remove about 99% of the water followed by a mol sieve 3A desiccant dryer to remove the remaining 1% water; 2) Selection and demonstration of efficient solution to fouling due to dissolved CO 2 . SES has tested several commercial heat exchangers that purport to be able to handle fouling issues similar to those experienced in the contact liquid chiller. Replicated tests using the CCC ECL™ skid and dimpled brazed plate heat exchangers demonstrate that quick throttling of refrigerant combined with a burst of clean gas mitigate the fouling caused by CO 2 solubility in contact liquid with only minor increases in parasitic load. SES models indicate that parasitic load would increase by approximately 0.0125 GJ/tonne, an order of magnitude less than what was determined to be the maximum allowable additional parasitic load caused by this system; 3) Selection and demonstration of efficient and scalable solid–liquid separation system. The screw press technology met or exceeded the 70% solids loading benchmark during several test runs exceeding 24 hours on the CCC ECL™ skid. The average solids loading during the entire 50-hour run was 67%. The energy demand for this system is less than 0.1 GJ e /tonne of CO 2 processed; 4) Optimize design and demonstration of patented desublimating heat exchangers. We designed and built a hybrid spray tower that was tested over many hundreds of hours and a 50-hour continuous test run was completed capturing over 0.5 tonne CO 2 /day at >90% capture; (5) Plan for safe dilution of oxygen-depleted, cleaned flue-gas stream. The AERSCREEN simulator developed by the EPA modeled the dispersion of oxygen-depleted flue gas from the CCC process at a commercial plant. The results indicate that this plan effectively mitigates the flue gas hazards; (6) Simulation of and experimental work related to multi-pollutant capture. SES programmed an upgrade to its solid/vapor/liquid equilibrium (SVLE) algorithm. This enables simultaneous modeling of multiple pollutants (i.e., CO 2 , SO x , NO x , Hg, HCl). Budget Period 2; (7) Modify the CCC ECL™ skid for field testing and complete shakedown testing. The plans for modifying the CCC ECL™ skid were finalized and put into place. Shakedown testing of the updated CCC ECL™ skid occurred at SES using closed-loop mode (i.e., using a synthetic flue gas consisting of only N 2 and CO 2 ) and at the Hunter Power Plant using flue gas from the coal-fired boiler. Shakedown testing took longer than expected due to delays in receiving equipment and unexpected equipment performance in the field; (8) Operate the CCC ECL™ skid in the field. Longer testing of the CCC ECL™ skid occurred at the Hunter Power Plant. Multiple tests exceeding 35 hours were completed, with a total of over 600 hours of CO 2 capture completed using flue gas at the Hunter Power Plant with an average CO 2 capture rate of over 91% during those hours. Extensive notes and documentation were acquired informing improved methods for controls, startup, operation, and shut down; (9) Determine figures of merit and quantify process improvement. SES defined figures of merit for unit operation performance and overall CCC ECL™ process performance. All figures of merit were achieved or surpassed, except for 500 continuous hours of demonstration at the Hunter Power Plant; (10) Complete an Environmental Health and Safety Risk assessment by a third party. Tri-State completed an Environmental Health and Safety Risk assessment; (11) Update techno-economic analysis with third-party validation. The techno-economic analysis has been completed. It confirms the potential large reduction in energy and cost of the CCC process compared with leading alternatives and that the estimates and estimation techniques are reliable.

20 FOSSIL-FUELED POWER PLANTS↗

High-Speed, High-Resolution Time-to-Digital Conversion

This innovation is a series of time-tag pulses from a photomultiplier tube, featuring short time interval between pulses (e.g., 2.5 ns). Using the previous art, dead time between pulses is too long, or too much hardware is required, including a very-high-speed demultiplexer. A faster method is needed. The goal of this work is to provide circuits to time-tag pulses that arrive at a high rate using the hardwired logic in an FPGA - specifically the carry chain - to create what is (in effect) an analog delay line. High-speed pulses travel down the chain in a "wave." For instance, a pulse train has been demonstrated from a 1- GHz source reliably traveling down the carry chain. The size of the carry chain is over 10 ns in the time domain. Thus, multiple pulses will travel down the carry chain in a wave simultaneously. A register clocked by a low-skew clock takes a "snapshot" of the wave. Relatively simple logic can extract the pulses from the snapshot picture by detecting the transitions between logic states. The propagation delay of CMOS (complementary metal oxide semiconductor) logic circuits will differ and/or change as a result of temperature, voltage, age, radiation, and manufacturing variances. The time-to-digital conversion circuits can be calibrated with test signals, or the changes can be nulled by a separate on-die calibration channel, in a closed loop circuit.

Katz, Richard↗