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At least 1,405 records · Page 78

Progress in advanced high temperature turbine materials, coatings, and technology

Advanced materials, coatings, and cooling technology is assessed in terms of improved aircraft turbine engine performance. High cycle operating temperatures, lighter structural components, and adequate resistance to the various environmental factors associated with aircraft gas turbine engines are among the factors considered. Emphasis is placed on progress in development of high temperature materials for coating protection against oxidation, hot corrosion and erosion, and in turbine cooling technology. Specific topics discussed include metal matrix composites, superalloys, directionally solidified eutectics, and ceramics.

Freche, J. C.↗

Secondary lithium batteries for space applications

Secondary lithium cells which use a LiAsF6-2-Me-THF electrolyte and a TiS2 intercalatable cathode exhibit encouraging cycle life at ambient temperature. Electrochemical and surface analytical studies indicate that the electrolyte is unstable in the presence of metallic lithium, leading to the formation of a lithium passivating film composed of lithium arsenic oxyfluorides and lithium fluorsilicates. The lithium cyclability remains as the most important problem to solve. Different electrolyte solvents, such as sulfolane, exhibit promising characteristics but lead to new compatibility problems with the other cell component materials.

Carter, B.↗

Size distributions and aerodynamic equivalence of metal chondrules and silicate chondrules in Acfer 059

The CR2 chondrite Acfer 059 is unusual in that the original droplet shapes of metal chondrules are well preserved. We determined separate size distributions for metal chondrules and silicate chondrules; the two types are well sorted and have similar size distributions about their respective mean diameters of 0.74 mm and 1.44 mm. These mean values are aerodynamically equivalent for the contrasting densities, as shown by calculated terminal settling velocities in a model solar nebula. Aerodynamic equivalence and similarity of size distributions suggest that metal and silicate fractions experienced the same sorting process before they were accreted onto the parent body. These characteristics, together with depletion of iron in Acfer 059 and essentially all other chondrites relative to primitive CI compositions, strongly suggest that sorting in the solar nebula involved a radial aerodynamic component and that sorting and siderophile depletion in chondrites are closely related.

Skinner, William R.↗

A teleoperated system for remote site characterization

The detection and characterization of buried objects and materials is an important step in the restoration of burial sites containing chemical and radioactive waste materials at Department of Energy (DOE) and Department of Defense (DOD) facilities. By performing these tasks with remotely controlled sensors, it is possible to obtain improved data quality and consistency as well as enhanced safety for on-site workers. Therefore, the DOE Office of Technology Development and the US Army Environmental Center have jointly supported the development of the Remote Characterization System (RCS). One of the main components of the RCS is a small remotely driven survey vehicle that can transport various combinations of geophysical and radiological sensors. Currently implemented sensors include ground-penetrating radar, magnetometers, an electromagnetic induction sensor, and a sodium iodide radiation detector. The survey vehicle was constructed predominantly of non-metallic materials to minimize its effect on the operation of its geophysical sensors. The system operator controls the vehicle from a remote, truck-mounted, base station. Video images are transmitted to the base station by a radio link to give the operator necessary visual information. Vehicle control commands, tracking information, and sensor data are transmitted between the survey vehicle and the base station by means of a radio ethernet link. Precise vehicle tracking coordinates are provided by a differential Global Positioning System (GPS).

Sandness, Gerald A.↗

Bismuth Propellant Feed System Development at NASA-MSFC

NASA-MSFC has been developing liquid metal propellant feed systems capable of delivering molten bismuth at a prescribed mass flow rate to the vaporizer of an electric thruster. The first such system was delivered to NASA-JPL as part of the Very High Isp Thruster with Anode Layer (VHITAL) program. In this system, the components pictured were placed in a vacuum chamber and heated while the control electronics were located outside the chamber. The system was successfully operated at JPL in conjunction with a propellant vaporizer, and data was obtained demonstrating a new liquid bismuth flow sensing technique developed at MSFC. The present effort is aimed at producing a feed-system for use in conjunction with a bismuth-fed Hall thruster developed by Busek Co. Developing this system is more ambitious, however, in that it is designed to self-contain all the control electronics inside the same vacuum chamber as an operating bismuth-fed thruster. Consequently, the entire system, including an on-board computer, DC-output power supplies, and a gas-pressurization electro-pneumatic regulator, must be designed to survive a vacuum environment and shielded to keep bismuth plasma from intruding on the electronics and causing a shortcircuit. In addition, the hot portions of the feed system must be thermally isolated from the electronics to avoid failure due to high heat loads. This is accomplished using a thermal protection system (TPS) consisting of multiple layers of aluminum foil. The only penetrations into the vacuum chamber are an electrically isolated (floating) 48 VDC line and a fiberoptic line. The 48 VDC provides power for operation of the power supplies and electronics co-located with the system in the vacuum chamber. The fiberoptic Ethernet connection is used to communicate user-input control commands to the on-board computer and transmit real-time data back to the external computer. The partially assembled second-generation system is shown. Before testing at Busek, a more detailed flow sensor calibration will be performed to accurately quantify the flow monitoring capabilities. This effort is funded under a Technology Innovation Program (TIP) award from NASA-MSFC's Technology Transfer office and performed under SAA8-061060.

Polzin, Kurt A.↗

The Development of Erosion and Impact Resistant Turbine Airfoil Thermal Barrier Coatings

Thermal barrier coatings are used in gas turbine engines to protect engine hot-section components in the harsh combustion environments and extend component lifetimes. For thermal barrier coatings designed for turbine airfoil applications, further improved erosion and impact resistance are crucial for engine performance and durability. Advanced erosion resistant thermal barrier coatings are being developed, with a current emphasis on the toughness improvements using a combined rare earth- and transition metal-oxide doping approach. The performance of the doped thermal barrier coatings has been evaluated in burner rig and laser heat-flux rig simulated engine erosion and thermal gradient environments. The results have shown that the coating composition optimizations can effectively improve the erosion and impact resistance of the coating systems, while maintaining low thermal conductivity and cyclic durability. The erosion and impact damage mechanisms of the thermal barrier coatings will also be discussed.

Zhu, Dongming↗

Advanced manufacturing development of a composite empennage component for L-1011 aircraft. Phase 2: Design and analysis

The composite fin design consists of two one-piece cocured covers, two one-piece cocured spars and eleven ribs. The lower ribs are truss ribs with graphite/epoxy caps and aluminum truss members. The upper three ribs are a sandwich design with graphite/epoxy face sheets and a syntactic epoxy core. The design achieves a 27% weight saving compared to the metal box. The fastener count has been reduced from over 40,000 to less than 7000. The structural integrity of the composite fin was verified by analysis and test. The static, fail-safe and flutter analyses were completed. An extensive test program has established the material behavior under a range of conditions and critical subcomponents were tested to verify the structural concepts.

Jackson, A. C.↗

Two-layer thermal barrier coating for high temperature components

A simple two-layer plasma-sprayed thermal barrier coating system was developed which has the potential for protecting high temperature air-cooled gas turbine components. Of the initially examined coatings, the most promising system is an Ni-16Cr-6Al-0.6Y (in wt%) bond coating (about 0.005 to 0.010 cm thick) and a ZrO2-12Y2O3 (in wt%) thermal barrier coating (about 0.025 to 0.064 cm thick). This thermal barrier substantially lowered the metal temperature of the air-cooled airfoil. The coating withstood 3200 cycles (80 s at 1280 C surface temperature) and 275 cycles (1 hr at 1490 C surface temperature) without cracking or spalling. No separation of the thermal barrier from the bond coating or the bond coating from the substrate was observed.

Stecura, S.↗

Implanted Silicon Resistor Layers for Efficient Terahertz Absorption

Broadband absorption structures are an essential component of large format bolometer arrays for imaging GHz and THz radiation. We have measured electrical and optical properties of implanted silicon resistor layers designed to be suitable for these absorbers. Implanted resistors offer a low-film-stress, buried absorber that is robust to longterm aging, temperature, and subsequent metals processing. Such an absorber layer is readily integrated with superconducting integrated circuits and standard micromachining as demonstrated by the SCUBA II array built by ROE/NIST (1). We present a complete characterization of these layers, demonstrating frequency regimes in which different recipes will be suitable for absorbers. Single layer thin film coatings have been demonstrated as effective absorbers at certain wavelengths including semimetal (2,3), thin metal (4), and patterned metal films (5,6). Astronomical instrument examples include the SHARC II instrument is imaging the submillimeter band using passivated Bi semimetal films and the HAWC instrument for SOFIA, which employs ultrathin metal films to span 1-3 THz. Patterned metal films on spiderweb bolometers have also been proposed for broadband detection. In each case, the absorber structure matches the impedance of free space for optimal absorption in the detector configuration (typically 157 Ohms per square for high absorption with a single or 377 Ohms per square in a resonant cavity or quarter wave backshort). Resonant structures with -20% bandwidth coupled to bolometers are also under development; stacks of such structures may take advantage of instruments imaging over a wide band. Each technique may enable effective absorbers in imagers. However, thin films tend to age, degrade or change during further processing, can be difficult to reproduce, and often exhibit an intrinsic granularity that creates complicated frequency dependence at THz frequencies. Thick metal films are more robust but the requirement for patterning can limit their absorption at THz frequencies and their heat capacity can be high. patterned absorber structures that offer low heat capacity, absence of aging, and uniform, predictable behavior at THz frequencies. We have correlated DC electrical and THz optical measurements of a series of implanted layers and studied their frequency dependence of optical absorption from .3 to 10 THz at cryogenic temperatures. We have modeled the optical response to determine the suitability of the implanted silicon resistor as a function of resistance in the range 10 Ohms/sq to 300 Ohms/sq.

Chervenak, J. A.↗

Innovative Tools Advance Revolutionary Weld Technique

The iconic, orange external tank of the space shuttle launch system not only contains the fuel used by the shuttle s main engines during liftoff but also comprises the shuttle s backbone, supporting the space shuttle orbiter and solid rocket boosters. Given the tank s structural importance and the extreme forces (7.8 million pounds of thrust load) and temperatures it encounters during launch, the welds used to construct the tank must be highly reliable. Variable polarity plasma arc welding, developed for manufacturing the external tank and later employed for building the International Space Station, was until 1994 the best process for joining the aluminum alloys used during construction. That year, Marshall Space Flight Center engineers began experimenting with a relatively new welding technique called friction stir welding (FSW), developed in 1991 by The Welding Institute, of Cambridge, England. FSW differs from traditional fusion welding in that it is a solid-state welding technique, using frictional heat and motion to join structural components without actually melting any of the material. The weld is created by a shouldered pin tool that is plunged into the seam of the materials to be joined. The tool traverses the line while rotating at high speeds, generating friction that heats and softens but does not melt the metal. (The heat produced approaches about 80 percent of the metal s melting temperature.) The pin tool s rotation crushes and stirs the plasticized metal, extruding it along the seam as the tool moves forward. The material cools and consolidates, resulting in a weld with superior mechanical properties as compared to those weld properties of fusion welds. The innovative FSW technology promises a number of attractive benefits. Because the welded materials are not melted, many of the undesirables associated with fusion welding porosity, cracking, shrinkage, and distortion of the weld are minimized or avoided. The process is more energy efficient, safe (no toxic smoke or shielding gas, liquid metal splatter, arcing, dangerous voltage, or radiation), and environmentally sound (no consumables, fumes, or noise) than fusion welding. Under computer control, an automated FSW machine can create welds with high reproducibility, improving efficiency and overall quality of manufactured materials. The process also allows for welding dissimilar metals as well as those metals considered to be "unweldable" such as the 7xxx series aluminum alloys. Its effectiveness and versatility makes FSW useful for aerospace, rail, automotive, marine, and military applications. A downside to FSW, however, is the keyhole opening left in the weld when the FSW pin tool exits the weld joint. This is a significant problem when using the FSW process to join circumferential structures such as pipes and storage containers. Furthermore, weld joints that taper in material thickness also present problems when using the conventional FSW pin tool, because the threaded pin rotating within the weld joint material is a fixed length. There must be capability for the rotating pin to both increase and decrease in length in real time while welding the tapered material. (Both circumferential and tapered thickness weldments are found in the space shuttle external tank.) Marshall engineers addressed both the keyhole and tapered material thickness problems by developing the auto-adjustable pin tool. This unique piece of equipment automatically withdraws the pin into the tool s shoulder for keyhole closeout. In addition, the auto-adjustable pin tool retracts, or shortens, the rotating pin while welding a weld joint that tapers from one thickness to a thinner thickness. This year, the impact of the Marshall innovation was recognized with an "Excellence in Technology Transfer Award" from the Federal Laboratory Consortium.

Source record↗

Ion mixing

Recent experimental studies of the ion-mixing phenomenon are summarized. Ion mixing is differentiated from ion implantation and shown to be a useful technique for overcoming the sputter-dependent limitations of implantation processes. The fundamental physical principles of ion/solid interactions are explored. The basic experimental configurations currently in use are characterized: bilayered samples, multilayered samples, and samples with a thin marker layer. A table listing the binary systems (metal-semiconductor or metal-metal) which have been investigated using each configuration is presented. Results are discussed, and some sample data are plotted. The prospects for future application of ion mixing to the alteration of solid surface properties are considered. Practical applications are seen as restricted by economic considerations to the production of small, expensive components or to fields (such as the semiconductor industry) which already have facilities for ion implantation.

Matteson, S.↗

IUE spectroscopy of the degenerate components in the Hyades close binaries V471 Tauri and HZ9

Effective temperatures and gravities have been determined for the degenerate components in the Hyades close binaries V471 Tauri and HZ9 from model atmosphere analysis of IUE ultraviolet spectra. For V471 Tauri, T(e) = 35,000 K and log g is about 8. For HZ9, T(e) = 20,000 K and log g = 8. Both systems contain DA2 white dwarfs. No photospheric metal lines were detected at low IUE resolution in either DA2 star. The 1400 A and 1600 A features are absent in the HZ9 degenerate, despsite being within the temperature range of some other DA stars with the 1400 A absorption feature.

Guinan, E. F.↗

Atmospheric electrical modeling in support of the NASA F106 Storm Hazards Project

With the use of composite (non-metallic) and microelectronics becoming more prevalent in the construction of both military and commercial aircraft, the control systems have become more susceptible to damage or failure from electromagnetic transients. One source of such transients is the lightning discharge. In order to study the effects of the lightning discharge on the vital components of an aircraft, NASA Langley Research Center has undertaken a Storm Hazards Program in which a specially instrumented F106B jet aircraft is flown into active thunderstorms with the intention of being struck by lightning. One of the specific purposes of the program is to quantify the environmental conditions which are conductive to aircraft lightning strikes.

Helsdon, J. H.↗

Implementation of an Associative Flow Rule Including Hydrostatic Stress Effects Into the High Strain Rate Deformation Analysis of Polymer Matrix Composites

A previously developed analytical formulation has been modified in order to more accurately account for the effects of hydrostatic stresses on the nonlinear, strain rate dependent deformation of polymer matrix composites. State variable constitutive equations originally developed for metals have been modified in order to model the nonlinear, strain rate dependent deformation of polymeric materials. To account for the effects of hydrostatic stresses, which are significant in polymers, the classical J2 plasticity theory definitions of effective stress and effective inelastic strain, along with the equations used to compute the components of the inelastic strain rate tensor, are appropriately modified. To verify the revised formulation, the shear and tensile deformation of two representative polymers are computed across a wide range of strain rates. Results computed using the developed constitutive equations correlate well with experimental data. The polymer constitutive equations are implemented within a strength of materials based micromechanics method to predict the nonlinear, strain rate dependent deformation of polymer matrix composites. The composite mechanics are verified by analyzing the deformation of a representative polymer matrix composite for several fiber orientation angles across a variety of strain rates. The computed values compare well to experimentally obtained results.

Goldberg, Robert K.↗

Far-Infrared and Submillimeter Spectroscopy of Low to Moderate Redshift Normal and Active Galaxies

Broadband surveys with planned observatories such as SIRTF, ASTRO-F, NGST, Herschel, SMA, and ALMA will provide large samples of dust-enshrouded galaxies undergoing varying proportions of star formation and accretion onto supermassive black holes. Recent evidence suggests that the mass of supermassive central black holes are proportional to central velocity dispersions of their host galaxy bulges, but it is not yet known how these properties are evolutionarily connected. To trace the evolution of these components during the important luminous, dusty merger episodes as a function of redshift, sensitive mid- to far-infrared spectroscopic diagnostic observations from space will be necessary. The high sensitivity and spatial resolution of a large aperture, natural background limited far-infrared/submillimeter telescope such as SAFAIR will allow detection and identification of the far-infrared/submillimeter components of galaxies and of a multitude of rest-frame mid- to far-infrared recombination, fine-structure, and molecular lines toward dusty galactic nuclei. The line diagnostics beginning to be developed from ISO work will help determine important parameters such as the intrinsic spectral energy distribution, ionization parameters, metallicities, densities, extinction to the embedded energy sources, and ultimately the star-formation and accretion rates in these galaxies. Ultimately, the higher spatial resolution provided by a cold, far-infrared submillimeter interferometer is needed to view the distribution of structure in galaxies in order to unravel the as yet untold story of the evolution of galaxies over the lifetime of the Universe.

Fischer, Jacqueline↗

Acoustic Emission Weld Monitoring in the 2195 Aluminum-Lithium Alloy

Due to its low density, the 2195 aluminum-lithium alloy was developed as a replacement for alloy 2219 in the Space Shuttle External Tank (ET). The external tank is the single largest component of the space shuttle system. It is 154 feet long and 27.6 feet in diameter, and serves as the structural backbone for the shuttle during launch, absorbing most of the 7 million plus pounds of thrust produced. The almost 4% decrease in density between the two materials provides an extra 7500 pounds of payload capacity necessary to put the International Space Station components into orbit. The ET is an all-welded structure; hence, the requirement is for up to five rewelds without hot cracking. Unfortunately, hot cracking during re-welding or repair operations was occurring and had to be dealt with before the new super lightweight tank could be used. Weld metal porosity formation was also of concern because it leads to hot cracking during weld repairs. Accordingly, acoustic emission (AE) nondestructive testing was employed to monitor the formation of porosity and hot cracks in order to select the best filler metal and optimize the weld schedule. The purpose of this work is to determine the feasibility of detecting hot cracking in welded aluminum-lithium (Al-Li) structures through the analysis of acoustic emission data. By acoustically characterizing the effects of reheating during a repair operation, the potential for hidden flaws coalescing and becoming "unstable" as the panel is repaired could be reduced. Identification of regions where microcrack growth is likely to occur and the location of active flaw growth in the repair weld will provide the welder with direct feedback as to the current weld quality enabling adjustments to the repair process be made in the field. An acoustic emission analysis of the source mechanisms present during welding has been conducted with the goals of locating regions in the weld line that are susceptible to damage from a repair operation, identifying the formation of critically sized flaws and providing accept/reject criteria for the quality of a weld as it is performed.

Walker, James L.↗

Novel Super-Elastic Materials for Advanced Bearing Applications

Tribological surfaces of mechanical components encounter harsh conditions in terrestrial, marine and aerospace environments. Brinell denting, abrasive wear and fatigue often lead to life-limiting bearing and gear failures. Novel superelastic materials based upon Ni-Ti alloys are an emerging solution. Ni-Ti alloys are intermetallic materials that possess characteristics of both metals and ceramics. Ni-Ti alloys have intrinsically good aqueous corrosion resistance (they cannot rust), high hardness, relatively low elastic modulus, are chemically inert and readily lubricated. Ni-Ti alloys also belong to the family of superelastics and, despite high hardness, are able to withstand large strains without suffering permanent plastic deformation. In this paper, the use of hard, resilient Ni-Ti alloys for corrosion-proof, shockproof bearing and gear applications are presented. Through a series of bearing and gear development projects, it is demonstrated that Ni-Tis unique blend of materials properties lead to significantly improved load capacity, reduced weight and intrinsic corrosion resistance not found in any other bearing materials. Ni-Ti thus represents a new materials solution to demanding tribological applications.

materials↗

Electrostatic Discharge Testing of Carbon Composite Solar Array Panels for Use in the Jovian Environment

NASA is currently considering a mission to investigate the moons of Jupiter. When designing a spacecraft for this type of mission, there are a number of engineering challenges, especially if the mission chooses to utilize solar arrays to provide the spacecraft power. In order for solar arrays to be feasible for the mission, their total mass needed to fit within the total budget for the mission, which strongly suggested the use of carbon composite facesheets on an aluminum core for the panel structure. While these composite structures are a good functional substitution for the metallic materials they replace, they present unique challenges when interacting with the harsh Jovian space environment. As a composite material, they are composed of more than one material and can show different base properties depending in differing conditions. Looking at the electrical properties, in an Earth-based environment the carbon component of the composite dominates the response of the material to external stimulus. Under these conditions, the structures strongly resembles a conductor. In the Jovian environment, with temperatures reaching 50K and under the bombardment from energetic electrons, the non-conducting pre-preg binding materials may come to the forefront and change the perceived response. Before selecting solar arrays as the baseline power source for a mission to Jupiter, the response of the carbon composites to energetic electrons while held at cryogenic temperatures needed to be determined. A series of tests were devised to exam the response of a sample solar array panel composed of an M55J carbon weave layup with an RS-3 pre-preg binder. Test coupons were fabricated and exposed to electrons ranging from 10 keV to 100 keV, at 1 nA/cm2, while being held at cryogenic temperatures. While under electron bombardment, electrical discharges were observed and recorded with the majority of discharges occurring with electron energies of 25 keV. A decrease in temperature to liquid nitrogen temperatures showed a marked increase in the magnitude of these discharges. The results indicate that dielectric discharges are primarily produced due to the presence of large regions of the non-conductive pre-preg on the surface of the carbon sheets. The frequency and magnitude of discharges decreased when layers of the pre-preg material were removed from the composite surface. These tests indicate that solar array panels may be used in the Jovian environment, but that electrostatic discharges can be expected on the carbon composite solar arrays.

Jupiter↗