Engineering Papers⌕ Search

SEARCH · Engineering Papers

Results for “Produced Waters”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 1,279 records · Page 71

History Matching and Performance Prediction of a Polymer Flood Pilot in Heavy Oil Reservoir on Alaska North Slope

The first-ever polymer flood pilot to enhance heavy oil recovery on Alaska North Slope (ANS) is ongoing. After more than 2.5 years of polymer injection, significant benefit has been observed from the decrease in water cut from 65% to less than 15% in the project producers. The primary objective of this study is to develop a robust history-matched reservoir simulation model capable of predicting future polymer flood performance. In this work, the reservoir simulation model has been developed based on the geological model and available reservoir and fluid data. In particular, four high transmissibility strips were introduced to connect the injector-producer well pairs, simulating short-circuiting flow behavior that can be explained by viscous fingering and reproducing the water cut history. The strip transmissibilities were manually tuned to improve the history matching results during the waterflooding and polymer flooding periods, respectively. It has been found that higher strip transmissibilities match the sharp water cut increase very well in the waterflooding period. Then the strip transmissibilities need to be reduced with time to match the significant water cut reduction. The viscous fingering effect in the reservoir during waterflooding and the restoration of injection conformance during polymer flooding have been effectively represented. Based on the validated simulation model, numerical simulation tests have been conducted to investigate the oil recovery performance under different development strategies, with consideration for sensitivity to polymer parameter uncertainties. The oil recovery factor with polymer flooding can reach about 39% in 30 years, twice as much as forecasted with continued waterflooding. Besides, the updated reservoir model has been successfully employed to forecast polymer utilization, a valuable parameter to evaluate the pilot test’s economic efficiency. All the investigated development strategies indicate polymer utilization lower than 3.5 lbs/bbl in 30 years, which is economically attractive.

Wang, Xindan↗

Reflectance of vegetation, soil, and water

The author has identified the following significant results. A study was conducted in a 340-acre (139 hectares) field of grain sorghum (Sorghum bicolor (L.) Moench) to determine if multispectral data from ERTS-1 could be used to detect differences in chlorophyll concentration between iron-deficient (chlorotic) and apparently normal (green) grain sorghum. Chlorotic sorghum areas 2.8 acres (1.1 hectares) or larger in size were identified on a computer printout of band 5 data which contains the chlorophyll absorption band at the 0.65 micron wavelength. ERTS resolution is sufficient for practical applications in detecting iron-deficient sorghum in otherwise uniform fields. The first classification map of the study county has been produced. Vegetation (crops), rangeland, bare soil, water, and an undefined (all other) category occupied 15.2, 45.0, 19.1, 0.02, and 20.6% of the land area, respectively.

Wiegand, C. L.↗

The Multi-Stage History of Mt. Sharp

The Curiosity rover is exploring Gale crater and Mt. Sharp, Gale's 5‐km high central mound. We are investigating the history of alteration and erosion of Mt. Sharp using orbital imagery, spectroscopy and rover observations. Our results suggest a significant time gap between emplacement of the upper and lower sections of the mound. Crater counts show that the lower mound was formed soon after Gale itself, and that it contains distinct units ranging in altitude from approximately ‐4,500 to ‐1,800 m. Spectral data suggest that many units contain phyllosilicates. We found that these clay‐bearing rocks occur in distinct layers concentrated below ‐2,900 m. Parts of the lower mound exhibit a transition from clays to sulfates with increasing altitude. The lower mound shows evidence of flowing water, including canyons and inverted channels. Wind erosion produced km‐scale yardangs and scalloped cliffs. Our mapping shows that many yardangs in the lower mound are clay‐bearing, with a predominant orientation of around N‐S. Curiosity's ground‐level images show myriad fine‐scale, mainly horizontal layers in the lower mound. The rover has found stream beds and conglomerates, indicating that water once flowed on the crater floor. Drilling near the deepest point in Gale produced abundant clay, providing additional evidence of aqueous alteration. Upper mound units range in altitude from ‐2,100 m to +500 m, and mantle the lower mound above an angular unconformity. Most upper mound units are composed of layers. The formation age of the upper mound is unknown, since few craters are preserved. Clay‐bearing layers are detectable in several locations, mainly at altitudes near ‐2,000 m. There is no evidence of water flow, but wind erosion has scalloped the surfaces and edges of layers, and fine‐scale yardangs are common. Correlations between yardangs and clay spectra are apparent only in the lowermost units of the upper mound. Yardang orientations vary, and include N‐S, NW‐SE, and NE‐SW. Upper mound units resemble the planet‐wide Medusae Fossae formation, dated as Hesperian and argued to be composed of ignimbrites. Medusae Fossae layers are easily eroded by wind, and our mapping demonstrates their resemblance to upper mound fine‐scale yardangs. The history of Mt. Sharp started with deposition and lithification of sediments shortly after crater formation. Some lower mound layers were partially altered to clays and sulfates, and water formed streams and canyons. Wind erosion of the lower mound produced large‐scale yardangs, particularly in clay‐rich layers, oriented generally N‐S. Upper mound units were emplaced following a considerable period of wind erosion. The absence of water flow on the upper mound suggests that these units were emplaced after atmospheric loss rendered water unstable at the surface. The shift in dominant wind direction, as indicated by yardang orientations, also argues for a time gap between erosion of the lower and upper mound. These observations are consistent with upper mound units being related to the Hesperian Medusae Fossae formation. During 2014 Curiosity is expected to reach the foot of Mt. Sharp and ascend through the clay‐rich layers, into the sulfate‐rich layers, and possibly past the interface with the upper mound. This will be a unique opportunity to field check geologic models on the surface of Mars.

Allen, C.↗

Integrated Bosch Process System Models for In-Situ Oxygen and Carbon Production

In-Situ Resource Utilization (ISRU) technology is a vital component to NASA’s mission of a sustainable presence on the Moon and Mars. Local resources can be leveraged to reduce resupply frequency and mass. Elements of the Bosch process, combined with the carbothermal reduction process, can produce oxygen on the lunar surface with minimal consumables. The Bosch process can also produce oxygen on the Martian surface by using the CO 2 -rich environment. Between both systems, adsorption pump, solar thermal energy, carbon formation reactor, and water recovery subsystems are modeled and integrated to create a functional model in MATLAB software. The model is used to simulate performance of the system and reduce mass, power, and volume requirements. This integrated system model provides a tool to scale ISRU technologies for oxygen and carbon production. The MATLAB model is created by developing a system of independent subsystem models that are solved for their quasi-steady state values which can be integrated with respect to time to determine the change in current states. A flexible time stepping method is used to ensure a high level of accuracy during periods of rapid change while still making use of a simple explicit integration method. The flexible time step is calculated for each independent subsystem and the minimum value from those is used as the overall time step. A flexible time step is calculated by dividing a resolution value, or the maximum change per time step, by the variables current rate of change. The maximum value from all points in space is used for subsystem models that contain multiple values. The process is done for every variable that is being monitored in each subsystem and the global minimum is used as that iteration’s timestep. Several assumptions used in the MATLAB model for fluid flow dynamics, such as 1-D gas flow through the sorption pump, are supported by modeling in Ansys Fluent software. The Lunar oxygen production system is outlined in Fig. 1. The carbothermal reduction subsystem uses solar energy to heat a mixture of lunar regolith and carbon powder to produce carbon monoxide. To begin, the carbon monoxide feeds to the modified Bosch subsystem along with hydrogen gas. The reactants then enter the carbon formation reactor where water and carbon powder are produced. Solar thermal energy is used to add energy to the reactor, but waste heat from the carbothermal process is another potential heat source. The water is collected and electrolyzed to produce hydrogen which reenters the Bosch subsystem, and the oxygen is stored for downstream use. The carbon powder is collected and feeds back into the carbothermal subsystem. The Martian oxygen production system uses the full Bosch process and is outlined in Fig 2. A CO 2 adsorption pump thermally cycles to scrub and pressurize CO 2 from the environment. Along with an initial supply of hydrogen, the reactants enter the Reverse Water Gas Shift Reactor (RWGSR) which produces carbon monoxide and water. Carbon monoxide and unreacted hydrogen enter the carbon formation reactor to produce water and carbon powder. The water is collected from both reactors and electrolyzed to reintroduce hydrogen and store oxygen for propellant production or life support. Carbon is removed from the carbon formation reactor and stored. The adsorption pump utilizes rapid cycle temperature swings within a stack of zeolite coated surfaces. The subsystem model solves 1-D quasi-steady conservation laws of the quasi-steady form, shown in Eq. 1, for the gas stream and heat exchange liquid to predict performance parameters such as breakthrough capacity and optimum cycle time. The source term S is used to capture interactions between the fluid flows and the sorbent. A quasi-steady-state scheme is used where no time derivatives appear in the governing equations, except for those in the source terms. This results in an autonomous system, where ∂F/∂x = ƒ(F). The fluxes F are provided at the inlet, and an explicit method is used to solve for the spatial distribution of F. The heat and mass flows to the sorbent are then extracted from the source terms. These flows are numerically integrated to produce a 1-D solution for the system’s state as a function of both time and space. The body of the adsorption pump is separated into two semi-independent models: the heat exchanger fluid flow and gas flow through the zeolite coated surfaces. Both models are solved using the above-described method to find a 1-D solution as a function of space and interact only once a timestep is taken. The interaction point is the sorbent through which all heat transfer between the two models must occur. Sorbent mass adsorption is calculated using the Lagergren model, shown in Eq. 2, where the transfer coefficient, λ D , is found by solving a system of nondimensionalized equations derived by using the heat and mass transfer analogy for transport phenomena. Using Grade 544 Type 13X zeolite as the sorbent material, the equilibrium concentration, θ eq , is calculated using the k-site Langmuir isotherm and fit parameters. Additionally, the enthalpy of adsorption used in the model is computed by interpolation of available data [1]. The subsystem model was validated using the Rapid Cycle Temperature Swing Adsorption (RC-TSA) pump. The solar thermal energy subsystem focuses on a solar concentrator concept with a heat exchanger to heat the reactants before entering the carbon formation reactor. The subsystem model assumes a fixed solar flux and reflector efficiency to calculate the reactant temperature given the incoming temperature, pressure, and exchanger geometry. The receiver is a custom manufactured series of copper blocks with serpentine channels to increase its surface area and the residence time of the reactants to heat up to 550 °C. The subsystem model was validated using a heat exchanger developed at NASA Glenn Research Center (GRC). The solar thermal energy subsystem focuses on a solar concentrator concept with a heat exchanger to heat the reactants before entering the carbon formation reactor. The subsystem model assumes a fixed solar flux and reflector efficiency to calculate the reactant temperature given the incoming temperature, pressure, and exchanger geometry. The receiver is a custom manufactured series of copper blocks with serpentine channels to increase its surface area and the residence time of the reactants to heat up to 550 °C. The subsystem model was validated using a heat exchanger developed at NASA Glenn Research Center (GRC).

In situ Resource Utilization↗

Biophysical model of eelgrass and water quality in Coos Bay, OR shows greater mitigation potential for ocean acidification than hypoxia

Seagrass beds provide important ecosystem services and are valued, in part, for their potential to mediate stressors such as ocean acidification and hypoxia (OAH) for sensitive species. However, the susceptibility of seagrasses to anthropogenic impacts and recent declines motivate the need to better understand the drivers of seagrass and the water quality consequences that occur with variation in seagrass abundance. To meet this need, we leveraged existing monitoring data (water quality and seagrass), hydrodynamic circulation model, and biogeochemical model framework with seagrass submodel, to produce a biophysical model of Coos Bay estuary, Oregon, U.S. The model includes biogeochemical processes involving water quality, plankton, seagrass, and sediment-water interactions. Ecosystem models like this are useful for evaluating complex estuarine systems because they allow us to extend our understanding of system dynamics beyond existing observations and perform experiments to identify the processes driving observed patterns. We used the biophysical model of Coos Bay to evaluate the dynamics of water quality and native eelgrass (Zostera marina) under three eelgrass abundance scenarios (zero eelgrass, current extent, and maximum observed extent) to elucidate the relationship between eelgrass and OAH. Including eelgrass in the Coos Bay model produced results that more closely resembled water quality observations - dissolved oxygen (DO) and pH were more dynamic in simulations with eelgrass, often having both higher highs and lower lows. While there were some areas of the estuary where DO improved with the addition of eelgrass to the model there was overall a small net increase in harmful DO conditions (based on a salmon physiological threshold). In contrast, ocean acidification conditions, pH and calcium carbonate saturation state for aragonite (Ω), were improved (based on oyster requirements) with the addition of eelgrass - although the magnitude of improvement differed seasonally and spatially. Our new model represents a useful tool - one which accounts for and controls the relevant physical and biogeochemical processes - to evaluate conditions that confer resilience or enhance vulnerability to OAH in an important Pacific Northwest coastal estuary and results can inform the OAH-related dynamics occurring in other eastern boundary current estuaries.

FVCOM-ICM↗

GDSA - Modeling and Integration – ORNL: PFLOTRAN modeling

This report summarizes work done at Oak Ridge National Laboratory (ORNL) related to post-closure criticality consequence analysis of dual-purpose canister (DPC) direct disposal in unsaturated alluvium. PFLOTRAN software was used to model the behavior of a breached DPC with low water infiltration rates and unsaturated conditions in alluvial deposits such that a low-power criticality event occurs with a focus on thermal hydrological constraints on criticality timing and power output. This summary describes initial exploration of those thermal hydrological processes and of the long-term average power output from a criticality event that could be sustained without driving water out of the DPC package and thereby terminating the criticality event. The objectives are (1) to identify, for different groundwater infiltration rates, the time at which the DPC fills with water sufficiently to potentially initiate criticality; (2) to bound the power output that could be produced by a criticality event that would thermally drive water out of the package at various percolation rates; and (3) provide an estimate of how the size of a package breach affects the water infiltration and therefore the possibility timing of criticality.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Investigation of porous polydimethylsiloxane structures with tunable properties induced by the phase separation technique

This article reports the fabrication and characterization of porous polydimethylsiloxane (PDMS) structures developed by the solvent evaporationinduced phase separation technique. Here, ternary systems containing water/ tetrahydrofuran (THF)/PDMS with various concentrations are produced to form a stable solution. The porous PDMS structures are formed by removing the solvent (THF) and nonsolvent (water) phases during the stepping heat treatment procedure. The analytical ternary phase diagram is constructed based on the thermodynamic equilibrium state in the polymer solution to explain the stable/unstable formulations and the possible composition change path. The results show that the isolated pores with the adjustable pore size ranging from 330 to 1900 μm are obtained by tuning the water to the THF ratio. The mechanical properties of the porous PDMS structures are determined by conducting the tensile tests on the prepared dog bone-shaped specimens. A wide range of elastic modulus ranging between 0.49 and 1.05 MPa was achieved without affecting the density of the porous sample by adjusting the solvent and non-solvent content in the solution. It is shown that the flexibility of the porous structures can be improved by reducing the ratio of water to THF and decreasing the PDMS content. The porosity measurements reveal that the PDMS concentration is the major phase controlling the porosity of the structure, while the effect of water/THF is negligible.

42 ENGINEERING↗

Suspended Membrane Evaporators Integrating Environmental and Solar Evaporation for Oily Wastewater Purification

Solar-driven evaporation is promising in oily wastewater treatment, in particular for emulsions, but conventional evaporators suffer from pore blocking by residual oil or contamination by volatile oil compounds in the condensed water. In the current research, we develop a suspended membrane evaporator integrating solar evaporation with oil-in-water emulsion separation. The heating and evaporating interface is separated from the rejecting interface to avoid oil escape and improve heat management. A temperature gradient forms on the membrane surface that can promote evaporation performance by combining both solar and environmental evaporation. Such an evaporator achieves a maximum evaporation rate of 1.645 kg/(m 2 ·h) as well as an apparent evaporation efficiency of 111.9%. Moreover, the superhydrophilic and superoleophobic membrane shows excellent oil repellence and emulsion rejection, which can achieve an oil removal efficiency above 98.8% in oil-in-water emulsion separation, and high evaporation rate recovery in cycling tests. Furthermore, a scaled-up membrane evaporator array produces ~8 kg/(m 2 ·d) of clean water from oily wastewater in outdoor experiments, further demonstrating the strong purification performance of this evaporator in oily wastewater treatment.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Local and Remote Sources of Precipitation during the 1993 Midwestern United States Flood

During June and July of 1993, devastating and persistent rainfall caused substantial damage in the Midwest United States primarily focused on the Mississippi River Basin. Above noma1 springtime rains primed the region for flooding. The resulting wet soil was thought to be a major source of water for the heavy summer precipitation. On the other hand, northward moisture transport was extremely intense during the summer. In this study, we have implemented passive tracers to diagnose the geographic source of water for precipitation, called Water Vapor Tracers (WVT), into the NASA Data Assimilation Office (DAO) Data Assimilation System (DAS). The WVT diagnostics can produce detailed budgets of the geographical sources of water that precipitates in any region, and they consider physical and dynamical tendencies at the model time step. The 1993 summer has been reanalyzed with the new WVT diagnostics to better understand the local and remote source of water for precipitation during the flood. Because the DAS also uses observations of water in the atmospheric hydrologic budget, we will also evaluate the impact of the observations on the local and remote sources of water in the DAS.

Bosilovich, Michael↗

Cosmic Complexity

What explains the extraordinary complexity of the observed universe, on all scales from quarks to the accelerating universe? My favorite explanation (which I certainty did not invent) ls that the fundamental laws of physics produce natural instability, energy flows, and chaos. Some call the result the Life Force, some note that the Earth is a living system itself (Gaia, a "tough bitch" according to Margulis), and some conclude that the observed complexity requires a supernatural explanation (of which we have many). But my dad was a statistician (of dairy cows) and he told me about cells and genes and evolution and chance when I was very small. So a scientist must look for me explanation of how nature's laws and statistics brought us into conscious existence. And how is that seemll"!gly Improbable events are actually happening a!1 the time? Well, the physicists have countless examples of natural instability, in which energy is released to power change from simplicity to complexity. One of the most common to see is that cooling water vapor below the freezing point produces snowflakes, no two alike, and all complex and beautiful. We see it often so we are not amazed. But physlc!sts have observed so many kinds of these changes from one structure to another (we call them phase transitions) that the Nobel Prize in 1992 could be awarded for understanding the mathematics of their common features. Now for a few examples of how the laws of nature produce the instabilities that lead to our own existence. First, the Big Bang (what an insufficient name!) apparently came from an instability, in which the "false vacuum" eventually decayed into the ordinary vacuum we have today, plus the most fundamental particles we know, the quarks and leptons. So the universe as a whole started with an instability. Then, a great expansion and cooling happened, and the loose quarks, finding themselves unstable too, bound themselves together into today's less elementary particles like protons and neutrons, liberating a little energy and creating complexity. Then, the expanding universe cooled some more, and neutrons and protons, no longer kept apart by immense temperatures, found themselves unstable and formed helium nuclei. Then, a little more cooling, and atomic nuclei and electrons were no longer kept apart, and the universe became transparent. Then a little more cooling, and the next instability began: gravitation pulled matter together across cosmic distances to form stars and galaxies. This instability is described as a "negative heat capadty" in which extracting energy from a gravitating system makes it hotter -- clearly the 2nd law of thermodynamics does not apply here! (This is the physicist's part of the answer to e e cummings' question: what is the wonder that's keeping the stars apart?) Then, the next instability is that hydrogen and helium nuclei can fuse together to release energy and make stars burn for billions of years. And then at the end of the fuel source, stars become unstable and explode and liberate the chemical elements back into space. And because of that, on planets like Earth, sustained energy flows support the development of additional instabilities and all kinds of complex patterns. Gravitational instability pulls the densest materials into the core of the Earth, leaving a thin skin of water and air, and makes the interior churn incessantly as heat flows outwards. And the heat from the sun, received mostly near the equator and flowing towards the poles, supports the complex atmospheric and oceanic circulations. And because or that, the physical Earth is full of natural chemical laboratories, concentrating elements here, mixing them there, raising and lowering temperatures, ceaselessly experimenting with uncountable events where new instabilities can arise. At least one of them was the new experiment called life. Now that we know that there are at least as many planets as there are stars, it is hard to imagine that nature's ceasess experimentation would not be able to produce life elsewhere -- but we don't know for sure. And life went on to cause new Instabilities, constantly evolving, with living things in an extraordinary range of environments, changing the global environment, with boom-and-bust cycles. with predators for every kInd of prey, with criminals for every possible crime, with governments to prevent them, and instabilities of the governments themselves. One of the instabilities Is that humans demand new weapons and new products of all sort, leading to serious investments in science and technology. So the natural/human world of competition and combat is structured to lead to advanced weaponry and cell phones. So here we are In 2012, with people writing essays and wondering whether their descendents will be artificial life forms travelling back into space. And, pondering what are the origins of those forces of nature that give rise to everything. Verllnde has argued that gravitation, the one force that has so far resisted our efforts at a Quantum description, is not even a fundamental force, but is itself it a statistical force, like osmosis. What an amazing turn of events! But after all I've just said, I should not be surprised a bit.

Mather, John C.↗

Dynamical Evolution of Saturn’s Rings Driven by Micrometeoroid Bombardment

After more than a dozen years in orbit about Saturn, the Cassini mission provided key measurements that are important for determining the age of Saturn’s rings. These include the extrinsic micrometeoroid flux at Saturn, the volume fraction of non-icy pollutants in the rings, and the total ring mass. These factors help to constrain the ring age to be no more than a few 100 Myr. The Cassini Grand Finale also provided a suite of observations that demonstrate that the rings are losing mass to the planet at a surprising rate. Some of the mass flux falls as “ring rain” at higher latitudes consistent with the H3+ infrared emission pattern thought to be produced by an influx of charged water products from the rings. The contribution needed to account for the ring rain phenomenon though is considerably less than the total equatorial measured mass influx of 4800 – 45000 kg/s. Taken together, these observations imply that the rings are not only young, but also ephemeral. Here we demonstrate that bombardment by micrometeoroids, and ballistic transport of their impact ejecta can account for these observations. That is, assuming the rings began as pure ice, incoming non-icy micrometeoroids can darken the rings to their current state in the given timescale, while the dynamical effects of this bombardment process can concomitantly produce the observed mass inflow rates implying the rings were initially more massive than today. Such high continuous mass loss also suggests the rings may effectively disappear in no more than a few 100 Myr.

Paul Estrada↗

Dynamical Evolution of Saturn’s Rings Driven by Micrometeoroid Bombardment

After more than a dozen years in orbit about Saturn, the Cassini mission provided key measurements that are important for determining the age of Saturn’s rings. These include the extrinsic micrometeoroid flux at Saturn, the volume fraction of non-icy pollutants in the rings, and the total ring mass. These factors help to constrain the ring age to be no more than a few 100 Myr. The Cassini Grand Finale also provided a suite of observations that demonstrate that the rings are losing mass to the planet at a surprising rate. Some of the mass flux falls as “ring rain” at higher latitudes consistent with the H3+ infrared emission pattern thought to be produced by an influx of charged water products from the rings. The contribution needed to account for the ring rain phenomenon though is considerably less than the total equatorial measured mass influx of 4800 – 45000 kg/s. Taken together, these observations imply that the rings are not only young, but also ephemeral. Here we demonstrate that bombardment by micrometeoroids, and ballistic transport of their impact ejecta can account for these observations. That is, assuming the rings began as pure ice, incoming non-icy micrometeoroids can darken the rings to their current state in the given timescale, while the dynamical effects of this bombardment process can concomitantly produce the observed mass inflow rates implying the rings were initially more massive than today. Such high continuous mass loss also suggests the rings may effectively disappear in no more than a few 100 Myr.

Paul Estrada↗

Water Innovation and R&D Concept Exploration and Preliminary Assessment: Water Scoping Project Report Deliverable

Pacific Northwest National Laboratory and Idaho National Laboratory produced a cursory review and initial framework to support the US Department of Energy’s Water Power Technologies Office (WPTO) in considering options for program development related to water. The laboratories provided a suite of tools – rationales, evaluation criteria, and visual maps – as well as R&D concepts that could be applied at various scales over short- and long-term time horizons. The effort is, by DOE request, largely the result of the authors’ creative efforts and not intended to be a comprehensive or detailed analytical exercise. This report summarizes the work provided to WPTO and is not intended for broad distribution.

54 ENVIRONMENTAL SCIENCES↗

An Assessment of the Regional Distribution of the Oxygen-Isotope Ratio in Northeastern Canada

A compilation of mean values of the oxygen-isotope ratio relative to standard mean ocean Water for 22 sites representative of conditions in north-eastern Canada is complemented with data on mean annual surface temperature, latitude, surface elevation, and mean annual shortest distance to open ocean denoted by the 10% sea-ice concentration boundary. Stepwise regression analysis is used to develop a multivariate model suitable to infer the distribution of 6 1"0 in an area of complex topography and possibly mixed source of advected water vapor. The best model is produced by a run in the backward mode at the 95% confidence level in which only temperature, latitude and distance to the open ocean remain in the model (the correlation coefficient is 0.915, the adjusted coefficient of determination is 0.809, the root mean square residual is 1.62). This model is similar to the best 6180 predictive model derived elsewhere for Greenland, suggesting a common principal source of advected moisture.

Giovinetto, Mario B.↗

Water vapor from a lunar breccia - Implications for evolving planetary atmospheres.

The exposure of a typical complex lunar breccia to hydrogen after a through outgassing produces a fully reduced surface state. Subsequent outgassing over a wide temperature range results in the production of water vapor formed from the chemisorbed hydrogen and oxygen from the lunar sample; the proposed mechanism has been confirmed in terms of the chemisorption of deuterium and the release of heavy water. Since the conditions of the experiments are consistent with those on the lunar surface, it is postulated that water vapor will be produced on the moon through the interaction of the solar wind with lunar soil. It is also proposed that such a process could play an important role in the early history of many planets where an oxygen-rich soil is exposed to a reducing atmosphere.

Cadenhead, D. A.↗

Strategic Petroleum Reserve Cavern Leaching Monitoring CY21

Th e U.S. Strategic Petroleum Reserve (SPR) is a crude oil storage system administered by the U.S. Department of Energy. The reserve consists of 60 active storage caverns located in underground salt domes spread across four sites in Louisiana and Texas, near the Gulf of Mexico. Beginning in 2016, the SPR started executing C ongressionally mandated oil sales. The configuration of the reserve, with a total capacity of greater than 700 million barrels ( MMB ) , re quires that unsaturated water (referred to herein as ?raw? water) is injected into the storage caverns to displace oil for sales , exchanges, and drawdowns . As such, oil sales will produce cavern growth to the extent that raw water contacts the salt cavern walls and dissolves (leaches) the surrounding salt before reaching brine saturation. SPR injected a total of over 45 MMB of raw water into twenty - six caverns as part of oil sales in CY21 . Leaching effects were monitored in these caverns to understand how the sales operations may impact the long - term integrity of the caverns. While frequent sonars are the most direct means to monitor changes in cavern shape, they can be resource intensive for the number of caverns involved in sales and exchanges. An interm ediate option is to model the leaching effects and see if any concerning features develop. The leaching effects were modeled here using the Sandia Solution Mining Code , SANSMIC . The modeling results indicate that leaching - induced features do not raise co ncern for the majority of the caverns, 15 of 26. Eleven caverns, BH - 107, BH - 110, BH - 112, BH - 113, BM - 109, WH - 11, WH - 112, WH - 114, BC - 17, BC - 18, and BC - 19 have features that may grow with additional leaching and should be monitored as leaching continues in th ose caverns. Additionally, BH - 114, BM - 4, and BM - 106 were identified in previous leaching reports for recommendation of monitoring. Nine caverns had pre - and post - leach sonars that were compared with SANSMIC results. Overall, SANSMIC was able to capture the leaching well. A deviation in the SANSMIC and sonar cavern shapes was observed near the cavern floor in caverns with significant floor rise, a process not captured by SANSMIC. These results validate that SANSMIC continues to serve as a useful tool for mon itoring changes in cavern shape due to leaching effects related to sales and exchanges.

02 PETROLEUM↗

Integration of In-Situ Resource Utilization Into Lunar/Mars Exploration Through Field Analogs

The NASA project to develop In-Situ Resource Utilization (ISRU) technologies, in partnership with commercial and international collaborators, has achieved full system demonstrations of oxygen production using native regolith simulants. These demonstrations included robotic extraction of material from the terrain, sealed encapsulation of material in a pressurized reactor; chemical extraction of oxygen from the material in the form of water, and the electrolysis of water into oxygen and hydrogen for storage and reuse. These successes have provided growing confidence in the prospects of ISRU oxygen production as a credible source for critical mission consumables in preparation for and during crewed missions to the moon and other destinations. Other ISRU processes, especially relevant to early lunar exploration scenarios, have also been shown to be practical, including the extraction of subsurface volatiles, especially water, and the thermal processing of surface materials for civil engineering uses and for thermal energy storage. This paper describes these recent achievements and current NASA ISRU development and demonstration activity. The ability to extract and process resources at the site of exploration into useful products such as propellants, life support and power system consumables; and radiation and rocket exhaust plume debris shielding, known as In-Situ Resource Utilization or ISRU, has the potential to significantly reduce the launch mass, risk, and cost of robotic and human exploration of space. The incorporation of ISRU into missions can also significantly influence technology selection and system development in other areas such as power, life support, and propulsion. For example. the ability to extract or produce large amounts of oxygen and/or water in-situ could minimize the need to completely close life support air and water processing system cycles, change thermal and radiation protection of habitats, and influence propellant selection for ascent vehicles and surface propulsive hoppers. While concepts and even laboratory work on evaluating and developing ISRU techniques such as oxygen extraction from lunar regolith have been going on since before the Apollo 11 Moon landing, no ISRU system has ever flown in space, and only recently have ISRU technologies been developed at a scale and at a system level that is relevant to actual robotic and human mission applications. Because ISRU hardware and systems have never been demonstrated or utilized before on robotic or human missions, architecture and mission planners and surface system hardware developers are hesitant to rely on ISRU products and services that are critical to mission and system implementation success. To build confidence in ISRU systems for future missions and assess how ISRU systems can best influence and integrate with other surface system elements, NASA, with international partners, are performing analog field tests to understand how to take advantage of ISRU capabilities and benefits with the minimum of risk associated with introducing this game-changing approach to exploration. This paper will describe and review the results of four analog field tests (Moses Lake in 6/08, Mauna Kea in 11/08. Flagstaff in 9/09; and Mauna Kea in 1/10) that have begun the process of integrating ISRU into robotic and human exploration systems and missions, and propose future ISRU-related analog field test activities that can be performed in collaboration with international space agencies.

Sanders, Gerald B.↗

Theoretical Calculation and Validation of the Water Vapor Continuum Absorption

The primary objective of this investigation is the development of an improved parameterization of the water vapor continuum absorption through the refinement and validation of our existing theoretical formalism. The chief advantage of our approach is the self-consistent, first principles, basis of the formalism which allows us to predict the frequency, temperature and pressure dependence of the continuum absorption as well as provide insights into the physical mechanisms responsible for the continuum absorption. Moreover, our approach is such that the calculated continuum absorption can be easily incorporated into satellite retrieval algorithms and climate models. Accurate determination of the water vapor continuum is essential for the next generation of retrieval algorithms which propose to use the combined constraints of multispectral measurements such as those under development for EOS data analysis (e.g., retrieval algorithms based on MODIS and AIRS measurements); current Pathfinder activities which seek to use the combined constraints of infrared and microwave (e.g., HIRS and MSU) measurements to improve temperature and water profile retrievals, and field campaigns which seek to reconcile spectrally-resolved and broad-band measurements such as those obtained as part of FIRE. Current widely used continuum treatments have been shown to produce spectrally dependent errors, with the magnitude of the error dependent on temperature and abundance which produces errors with a seasonal and latitude dependence. Translated into flux, current water vapor continuum parameterizations produce flux errors of order 10 W/sq m, which compared to the 4 W/sq m magnitude of the greenhouse gas forcing and the 1-2 W/sq m estimated aerosol forcing is certainly climatologically significant and unacceptably large. While it is possible to tune the empirical formalisms, the paucity of laboratory measurements, especially at temperatures of interest for atmospheric applications, preclude tuning, the empirical continuum models over the full spectral range of interest for remote sensing and climate applications. Thus, we propose to further develop and refine our existing, far-wing formalism to provide an improved treatment applicable from the near-infrared through the microwave. Based on the results of this investigation, we will provide to the remote sensing/climate modeling community a practical and accurate tabulation of the continuum absorption covering the near-infrared through the microwave region of the spectrum for the range of temperatures and pressures of interest for atmospheric applications.

Ma, Qiancheng↗