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At least 1,261 records · Page 70

Report Viewgraphs for IC project: Is high resolution or a more realistic bathymetry necessary to simulate Maud Rise polynyas in the Southern Ocean?

Maud Rise and Weddell Sea polynyas in the Southern Ocean form because of a series of feedbacks between upper ocean high salinity anomalies, Taylor columns found near steep bathymetric features such the Maud Rise seamounts and the Astrid Ridge complex, and subsurface accumulation of ocean heat that can sustain ice openings once deep convection is triggered.

58 GEOSCIENCES↗

Supercritical Treatment Technology for Water Purification (Annual Final Report)

This project continued the development of the Supercritical Water Extraction – Enhanced Targeted Recovery (SWEETR™) technology, a novel desalination process for treating hypersaline brines. The overall objective is to demonstrate the technical and economic feasibility of an innovative, energy efficient, and robust supercritical desalination technology to treat hypersaline solutions and separating saltwater into a pure water stream and valuable recovered solids, resulting in zero liquid discharge (ZLD). The proposed technology, focuses on innovative methods of applying supercritical water to treat highly concentrated brine solutions without incurring a high energy penalty. Integrating the technology with solar energy reduces the energy cost for the system. The results obtained during the proof-of-concept testing demonstrate that the SWEETR™ concept is technically feasible and that supercritical water treatment is a viable option with strong merit for treating high salinity waters. The strategic design of the system provides the opportunity to localize the supercritical zone, which helps reduce the overall energy cost associated with the desalination process. The process can be tuned to remove only the amount of salts required to make the treated water “fit for purpose”, providing further opportunities to minimize energy costs. The ability to destroy organic compounds associated with the water while simultaneously being able to desalinate makes SWEETR™ uniquely fitted for treating aqueous streams such as produced water from oil and gas extraction which contain small amounts of organics. Such mixed contaminant streams pose an extreme challenge for other treatment options. Future work will further develop the SWEETR™ technology to take it from the bench-scale to the pilot-scale, and ready the technology for commercial application.

04 OIL SHALES AND TAR SANDS↗

SECARB Post Injection Assessment Report

The Southern States Energy Board (SSEB) managed the overall Southeast Regional Carbon Sequestration Partnership (SECARB) Phase III project and The Bureau of Economic Geology (BEG), at the University of Texas at Austin, managed all activities associated with the Early Test field site near Cranfield, Mississippi (the Early Test or Cranfield Project). The SECARB project at Cranfield was focused downdip of the oil rim and on demonstrating the stacked nature of the storage potential at this location: enhanced oil recovery (EOR) up-dip and saline downdip. Because the injection for EOR continued after the SECARB project ended, no actual post-injection period occurred. However, information collected during the SECARB-monitored injection period, including pressure and CO2 plume position, was utilized in an EOR carbon lifecycle assessment. The carbon lifecycle assessment provided insight on tracking injection fronts and production efficiencies across the field. To complete the post injection assessment, taking into account the continuing EOR period after closeout of SECARB field activities, this report provides data and analysis done under another DOE-funded project. The follow up project focused on the carbon lifecycle of EOR and included an assessment of EOR at as-operated and under possible future scenarios. This work was published by Hossieni et al. (2018) and Hosseininoosheri (2019).

01 COAL, LIGNITE, AND PEAT↗

SECARB Semi-Annual Field Review Reports - Early Test

The Southern States Energy Board (SSEB) managed the overall Southeast Regional Carbon Sequestration Partnership (SECARB) Phase III project and The Bureau of Economic Geology (BEG), at the University of Texas at Austin, managed all activities associated with the Early Test field site near Cranfield, Mississippi (the Early Test or Cranfield Project). BEG was assisted in the management of site activities by Sandia Technologies (Sandia). BEG and Sandia implemented reporting procedures that included monthly and quarterly technical progress reports, as well as periodic reporting on key field activities. Subsequent sections of this report catalog the field activities and are organized in a semiannual chronology. The Cranfield Project was located approximately 12 miles east of Natchez, Mississippi. Denbury Onshore, LLC, began operating a commercial CO 2 flood of the field (using the subsurface injection of CO 2 for EOR) in June 2008. Carbon dioxide from the Jackson Dome, a natural source near Jackson, Mississippi, was delivered to the Cranfield oilfield via pipeline. Beginning in October 2008, the SECARB Early Test team characterized the surface and subsurface of the Cranfield site. During the field test CO 2 was injected into the lower Tuscaloosa Formation, a regionally extensive saline formation with the potential to hold millions of tons of CO 2 emissions. By January 2015, the team injected more than 11 million metric tons of CO 2 and monitored a total stored CO 2 mass of 5,326,975 metric tons. SECARB’s study operations occurred in four integrated research program areas within Cranfield field: (1) the High Volume Injection Test area (HiVIT); (2) the Detailed Area of Study (DAS); (3) the Geomechanical area; and (4) the near-surface observatory, also called the “P-site.” Carbon dioxide injection activities were conducted at the HiVIT and the DAS. Figure 1.1-1 provides a depiction of the DAS.

01 COAL, LIGNITE, AND PEAT↗

SECARB 2020 Semi-Annual Field Review Reports - Anthropogenic Test

The Southern States Energy Board (SSEB) managed the overall Southeast Regional Carbon Sequestration Partnership (SECARB) Phase III project and the Electric Power Research Institute (EPRI) managed all activities associated with the Anthropogenic Test site. Advanced Resources International, Inc. (ARI) assisted EPRI with the management of site activities. EPRI and ARI followed reporting procedures that included monthly and quarterly technical progress reports, as well as periodic reporting on key field activities. Subsequent sections of this report catalog the field activities and are organized in a semi-annual chronology. The SECARB Anthropogenic Test was the largest demonstration of a fully integrated, pulverized coal-fueled carbon capture and storage (CCS) project in the United States as of 2012 and supports a commercial prototype of CO 2 capture; transportation; subsurface storage; and monitoring, verification, and accounting (MVA); and assessment. The demonstration-scale, post-combustion CO 2 capture facility at Alabama Power Company’s Plant Barry diverted flue gas (25MW equivalent) from its Unit #5 coal burning facility and captured the CO 2 using Mitsubishi Heavy Industries (MHI) KM-CDRTM advanced amine technology. The captured CO2 was compressed at Plant Barry and transported by pipeline to the injection location southeast of Citronelle, Alabama. The Citronelle Project’s geologic storage and MVA sites were located on the flanks of the Citronelle Dome, approximately three miles southeast of the city of Citronelle. The injection zone, the Paluxy Formation, a saline formation that occurs at approximately 9,400 feet and overlies the oil production horizon of the Citronelle oilfield, presents a favorable injection reservoir in terms of areal extent and petrophysical characteristics. The confining zone, the basal shale of the overlying Washita-Fredericksburg Formation, is persistent throughout the Citronelle area and possesses the appropriate criteria to act as an effective CO 2 seal.

01 COAL, LIGNITE, AND PEAT↗

CO 2 Storage Site Screening Platform Development and CO 2 Storage Resource Analysis in SECARB Offshore Reservoirs Using SAS Viya

A major goal of the SECARB Offshore Partnership (DE-FE0031557) is to screen deep saline aquifers and hydrocarbon reservoirs in the central Gulf of Mexico for CO 2 sequestration and CO 2 -enhanced oil and gas recovery (EOR/EGR) and estimate the corresponding CO 2 storage resources for select reservoirs. CO 2 storage potential associated with offshore CO 2 -EOR is considerable and likely represents “low hanging fruit” for near-term CO 2 storage given the in-place infrastructure in the region. It is for these reasons that this assessment focuses on oil and gas fields. To this end, three major objectives have been completed and include (1) managing geological data derived from different sources, (2) building a reservoir screening platform for CO 2 storage, and (3) ranking the reservoirs based on the estimated CO 2 storage resources. The SAS ® Viya platform was used for data management and analytics. The Viya platform is a cloud service platform that provides data integration, data management, quick analytics, data visualization, machine learning functions, and application programming interfaces (APIs) for multi-programming languages. Different sources of data containing geologic information, reservoir properties, and EOR/EGR information were collected, cleaned, formatted, and loaded into the SAS ® Viya platform for evaluation. The major geological characteristics of both shelf and deep-water areas of the central Gulf were examined and compared to define the appropriate reservoir screening criteria. Next, a CO 2 storage site screening system was built in the SAS ® Viya platform with the pre-defined criteria. Finally, the CO 2 storage resources of the screened reservoirs were calculated and reported at the BOEM field level to identify fields with the highest estimated CO 2 storage resource. The fields with the largest total estimated CO 2 storage resource are located in the Mississippi Canyon protraction area. Due to proximity to the Mississippi Delta (indicative of less infrastructure) and large estimated CO 2 storage resources, future development activities may wish to focus efforts in the Mississippi Canyon protraction area.

02 PETROLEUM↗

SECARB-USA: A Sub-Basin Framework for Future CO 2 Infrastructure Development

Task 4 of the SECARB-USA Project is designed to evaluate the regional needs and challenges for the development of a safe and environmentally sound CO 2 transport infrastructure. This infrastructure would transport CO 2 capture from power generating plants and/or industrial sources and distribute it to oil fields for associated storage in EOR operations, saline storage, and/or other suitable storage sites. The objective of this report on Sub-Basin Prospective Areas (Deliverable 4.1.a), is to provide the framework for understanding how regional infrastructure development could occur. The sub-basin prospective areas, in conjunction with the locations of CO 2 sources and pipeline infrastructure (for source-sink matching networks), form the basis for the analysis that will be performed in the Techno-Economic Analysis of Infrastructure Buildout Scenarios (Deliverable 4.1.b).

54 ENVIRONMENTAL SCIENCES↗

Auto Indexer for Percussive Hammers Final Report

Geothermal energy has been underutilized in the U.S., primarily due to the high cost of drilling in the harsh environments encountered during the development of geothermal resources. Drilling depths can approach 5,000 m with temperatures reaching 170 C. In situ geothermal fluids are up to ten times more saline than seawater and highly corrosive, and hard rock formations often exceed 240 MPa compressive strength. This combination of extreme conditions pushes the limits of most conventional drilling equipment. Furthermore, enhanced geothermal systems are expected to reach depths of 10,000 m and temperatures more than 300 °C. To address these drilling challenges, Sandia developed a proof-of-concept tool called the auto indexer under an annual operating plan task funded by the Geothermal Technologies Program (GTP) of the U.S. Department of Energy Geothermal Technologies Office. The auto indexer is a relatively simple, elastomer-free motor that was shown previously to be compatible with pneumatic hammers in bench-top testing. Pneumatic hammers can improve penetration rates and potentially reduce drilling costs when deployed in appropriate conditions. The current effort, also funded by DOE GTP, increased the technology readiness level of the auto indexer, producing a scaled prototype for drilling larger diameter boreholes using pneumatic hammers. The results presented herein include design details, modeling and simulation results, and testing results, as well as background on percussive hammers and downhole rotation.

15 GEOTHERMAL ENERGY↗

An Integrated Feasibility Study of Reservoir Thermal Energy Storage (RTES) in Portland, OR, USA

In regions with long cold overcast winters and sunny summers, Deep Direct-Use (DDU) can be coupled with Reservoir Thermal Energy Storage (RTES) technology to take advantage of pre-existing subsurface permeability to save summer heat for later use during cold seasons. Many aquifers worldwide are underlain by permeable regions (reservoirs) containing brackish or saline groundwater that has limited beneficial use due to poor water quality. We investigate the utility of these relatively deep, slow flowing reservoirs for RTES by conducting an integrated feasibility study in the Portland Basin, Oregon, USA, developing methods and obtaining results that can be widely applied to RTES systems elsewhere. As a case study, we have conducted an economic and social cost-benefit analysis for the Oregon Health and Science University (OHSU), a teaching hospital that is recognized as critical infrastructure in the Portland Metropolitan Area. Our investigation covers key factors that influence feasibility including 1) the geologic framework, 2) heat and fluid flow modeling, 3) capital and maintenance costs, 4) the regulatory framework, and 5) operational risks. By pairing a model of building seasonal heat demand with an integrated model of RTES resource supply, we determine that the most important factors that influence RTES efficacy in the study area are operational schedule, well spacing, the amount of summer heat stored (in our model, a function of solar array size), and longevity of the system. Generally, heat recovery efficiency increases as the reservoir and surrounding rocks warm, making RTES more economical with time. Selecting a base-case scenario, we estimate a levelized cost of heat (LCOH) to compare with other sources of heating available to OHSU and find that it is comparable to unsubsidized solar and nuclear, but more expensive than natural gas. Additional benefits of RTES include energy resiliency in the event that conventional energy supplies are disrupted (e.g., natural disaster) and a reduction in fossil fuel consumption resulting in a smaller carbon footprint. Key risks include reservoir heterogeneity and a possible reduction in permeability through time due to scaling (mineral precipitation). Lastly, a map of thermal energy storage capacity for the Portland Basin yields a total of 43,400 GWh, suggesting tremendous potential for RTES in the Portland Metropolitan Area.

14 SOLAR ENERGY↗

Computed Tomography Scanning and Petrophysical Measurements of the Wellington KGS 2-32 Core

This report describes the use of the computed tomography facilities and the Multi-Sensor Core Logger at the National Energy Technology Laboratory in Morgantown, West Virginia to characterize core from the Wellington KGS 2-32 well (API 15-191-22770). Core from the well was obtained as part of the Small-Scale Field Test Demonstrating Carbon Dioxide Sequestration in Arbuckle Saline Aquifer and by CO 2 -Enhanced Oil Recovery at Wellington Field, Sumner County, Kansas (DE-FE0006821). The primary impetus of this work was to capture a detailed a digital representation of the core from the Wellington KGS 2-32 well (Sumner County, Kansas). The collaboration between the U.S. Department of Energy’s (DOE) NETL and the Kansas Geological Survey (KGS) at the University of Kansas enables other research entities to access information about this potential carbon storage location and formations. The resultant datasets are presented in this report and can be accessed from NETL's Energy Data eXchange (EDX) online system using the following link: https://edx.netl.doe.gov/dataset/wellington2-32-core.

47 OTHER INSTRUMENTATION↗

Non-Equilibrium Plasma Interactions with Biomaterials, Biological Solutions and Tissues

Cold atmospheric pressure plasma discharges offer an abundant source of reactive oxygen and nitrogen species (RONS) at room temperature enabling unique interactions with biomaterials, biological solutions and tissues. These interactions particularly with living matter are presently an important intellectual frontier in plasma science with promising potential applications ranging from human health care to advanced biomaterial processing. Exciting case studies have been reported that illustrate the huge potential of cold atmospheric plasma technology in wound healing and cancer treatment. The interaction of plasma with conducting and dielectric biomaterials such as tissue strongly influences the plasma properties. In turn this changes the impact of the plasma on the biomaterial. Particularly in the case of living matter, liquid based solutions are ubiquitous which complicates interfacial processes. The lack of insight into the underlying mechanisms of the interaction of plasma with wounds and tumors is currently a bottleneck for the further development of the technology and gives rise to many interesting scientific questions. This project was focused on plasma properties and kinetics during plasma-biomaterial interactions. Both DC pulsed and RF driven atmospheric pressure plasma jets, extensively used by the plasma community were studied. The bio-interfaces included hydrogel as a tissue model, (saline) solutions, bacteria and virus. Plasma diagnostics used include Thomson scattering, Rayleigh scattering, Raman scattering, (two-photon absorption) laser induced fluorescence, optical emission spectroscopy, absorption spectroscopy, molecular beam mass spectrometry and fast imaging allowing to determine electron densities and temperatures, ionic species, reactive species including radicals, gas temperatures, gas composition, electric fields and solution components transferred to the gas phase.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Front-End Engineering Design Study for Retrofit Post-Combustion Carbon Capture on a Natural Gas Combined Cycle Power Plant

The objective of the project is to conduct a Front-End Engineering Design (FEED) study to determine the technical and economic feasibility of installing a retrofit, post-combustion, carbon capture facility on a commercially operating, natural gas-fired, combined cycle (NGCC) power plant. The Electric Power Research Institute (EPRI), California Resources Corporation (CRC), and Fluor Corporation used Fluor's Econamine FG Plus SM (EFG+) conducted the FEED study for capturing CO 2 produced by CRC's 550 MWe Elk Hills Power Plant (EHPP), located in the Elk Hills Oil Field near Tupman, Kern County, California. The EHPP was commissioned in 2003 and is powered by two General Electric 7FA gas turbines, with two heat recovery steam generators (HRSGs) providing steam to a General Electric D11 steam turbine. The target capture amount is 4,000 tonnes CO 2 /day for use in either enhanced oil recovery or dedicated geological saline storage located on CRC property at or nearby EHPP. This CO 2 is captured from a combination of the CO 2 emitted from the flue gas from EHPP and the flue gas generated from a natural gas-fired auxiliary boiler that supplies steam to the EFG+ process.

03 NATURAL GAS↗

Expert Elicitation for Wave Energy LCOE Futures

As the world faces increasing threats from climate change, the importance of developing renewable energy technologies and reducing their costs have similarly increased. Marine energy technologies (which include wave, tidal, ocean current, ocean thermal and salinity gradient resources) are often referred to as the most nascent and newest suite of renewable technologies under development. There are vast marine energy resources available around the world and within U.S. territorial waters, and as the technologies have continued to develop, the long-term trajectory of cost reductions and performance improvements is of particular interest. This study specifically investigates the long-term cost reduction potential for commercial wave energy technologies, as wave energy represents the largest marine energy resource available to the continental U.S. Similar studies focused on other resources and technologies may follow in the future.

16 TIDAL AND WAVE POWER↗

Intermountain West Energy Sustainability & Transitions Initiative: CO 2 Transport and Geologic Storage Modeling Results

This report and its associated Excel spreadsheet file provide the results of technoeconomic modeling of carbon dioxide (CO 2 ) pipeline transport modeling, CO 2 storage in deep saline subsurface formations, and CO 2 enhanced oil recovery (EOR). This report provides the methodology, describes the models and summarizes results for the three aspects of the analysis done for the Intermountain West Energy Sustainability and Transition (I-WEST) Initiative.

42 ENGINEERING↗

The Cypress Sandstone Seal System

The Cypress Sandstone is the youngest and shallowest unit in the Illinois Basin that was featured in the United States Carbon Utilization and Storage Atlas IV as a target for saline carbon storage with an estimated 0.2 to 2.3 GT of storage potential. Additional research on a residual oil zone (ROZ) developed within the Cypress Sandstone has delineated 27 prospects with approximately 290.8 million m3 (1.8 billion barrels) of oil in place. 21 to 31 million m 3 (144 to 196 million barrels) of oil is estimated to be recoverable using carbon dioxide enhanced oil recovery (CO 2 -EOR). Storage of CO 2 associated with EOR in these ROZ prospects alone, not accounting for associated main pay zones (MPZs), underlying brine formation, or intervals adjacent to or between prospects, is estimated to be up to 10.4 billion tonnes. The Cypress Sandstone is thus well understood to be a CO 2 injection target, both for EOR and associated storage. However, the seal system overlying the Cypress Sandstone is poorly understood. Unlike deeper formations such as the Mt. Simon Sandstone or the St. Peter Sandstone which are either in use as a CO 2 sink or being characterized for prospective storage, respectively, the Cypress is not overlain by hundreds of feet of impermeable shale. Rather, the Cypress is overlain by a lithologically variable interval that is composed generally of shales and limestones with some sandstone in the part of the Basin where the Cypress is deep enough to facilitate CO 2 storage. Also, due to its status as one of the shallowest and most prolific oil reservoirs in the Basin, the seal system overlying the Cypress Sandstone has a relatively high number of legacy well penetrations. The purpose of this report is to characterize the Cypress Sandstone seal system using well logs and available core. Gross thickness, lithology (facies), and mineralogy of seals is described and mapped across the Basin. The column height of CO 2 that can be held is calculated using capillary pressure data from a representative core.

02 PETROLEUM↗

First Ever Field Pilot on Alaska's North Slope to Validate the Use of Polymer Floods for Heavy Oil EOR a.k.a Alaska North Slope Field Laboratory (ANSFL)

Alaska’s high viscosity oil resources that range between 20–30+ billion barrels represent about a third of known North Slope original oil in place (OOIP). These resources are primarily concentrated in the Schrader Bluff formation (also called West Sak on the Western North Slope) and Ugnu reservoirs and are categorized as “viscous oils” and “heavy oils” owing to their in-situ viscosities between 5–10,000 cP and up to a million+ cP respectively. The viscous oil deposits are relatively deeper (2,000 – 5,000 ft), whereas the heavy oils are somewhat shallower (2,000 – 4,000 ft). The typically shallow depths and the proximity to the continuous permafrost results in relatively lower formation temperatures and pressures, and consequently higher viscosities. The vertical depth vs. viscosity delineated in Paskvan et al. (2016) differentiates the viscous and heavy oils. As depicted in Paskvan et al. (2016), currently the main focus (referred to as “developing”) is on the viscous oils in the Schrader Bluff formation in the Milne Point Unit (MPU). Notwithstanding this Alaska North Slope (ANS) specific categorization, we use the industry adopted, all-inclusive term “heavy oil” for all high viscosity oils. Resource characterization and additional details can be found in topical publications of Paskvan et al. (2016) and Targac et al. (2005). Despite the vast resource base, the development pace, vis-à-vis the production of heavy oils has been very slow and limited due to multiple factors such as cost, logistics, challenging arctic environment, poor waterflood sweep efficiency due to mobility contrasts, and significantly high minimum miscibility pressures (MMP). Most importantly, typical or standard thermal methods that are commonplace elsewhere (Canada, California) are inapplicable due to the continuous permafrost. As a consequence, cumulative production of heavy and viscous oils is a little over 1% of OOIP slope wide and currently, there is hardly any production from Ugnu. However, on a broader level, these unfavorable factors are outweighed by the fact that (1) these resources, within the established infrastructure, are too large to ignore because of their strategic importance to the Nation and the State of Alaska and (2) Prudhoe Bay type diluent crude oil is still available for heavy oil transport through the Trans Alaska Pipeline System (TAPS). Similarly, from a reservoir standpoint, the following factors also are important offsets: (1) favorable rock characteristics of Schrader Bluff; (2) the promise demonstrated by the initial scoping studies (Seright 2010, 2011) suggesting significant increase of heavy oil recovery using polymer flooding; (3) successful field implementation in Canada, China and elsewhere in the world, and (4) availability of the existing pairs of horizontal injector-producer in Schrader Bluff The foregoing was recognized as the best readily available opportunity for significant investment by the US Department of Energy and the field operator Hilcorp Alaska LLC to conduct the first ever field scale experiment to test the polymer flooding technology to unlock the vast heavy oil resources on ANS. With this primary goal in mind, the research team embarked on a ~4.5 years long project that focused on the field polymer pilot complemented by supporting laboratory and simulation studies. As documented in this final report, over the course of the project, many lessons have been learned and valuable field and supporting laboratory data has been collected, which also is complemented by numerical reservoir simulations. We have been able to establish the injectivity of polymer solution, evidence of significant reduction in the water cut of previously waterflooded pattern, effective propagation of a hydrolyzed polyacrylamide (HPAM), benefits of low salinity water, provide practical guidance on handling of produced fluids containing breakthrough polymer, fit-for-purpose forecast-worthy history matched simulation model, polymer EOR benefit of 700-1000 bopd over waterflood, and most importantly a low polymer utilization factor of ~1.7 lb/stb. In summary this project is deemed as a scientific, technical and economic success, having met all objectives, fulfilled deliverables and within budget, providing impetus to apply polymer EOR throughout the Milne Point Field paving the way for even heavier viscosity oils in the Ugnu area, eventually extending the economic life of TAPS.

02 PETROLEUM↗

Exploratory Analysis of Offshore CO 2 Storage Pilot Project in the Gulf of Mexico: Geologic, Infrastructure, and Cost Considerations

This analysis employs a high-level exploratory analytical approach to quantify various considerations needed for a potential CCS pilot project in the GOM, most notably the cost magnitude to develop an offshore pilot project. The scope of this analysis focuses on CO 2 storage in saline formations presented in two specific scenarios: parts of GOM Outer Continental Shelf (OCS) federal waters and Texas state waters.

29 ENERGY PLANNING, POLICY, AND ECONOMY↗

Synthetic Calcium Carbonate Production by Carbon Dioxide (CO 2 ) Mineralization of Industrial Waste Brines

The global scale of CO 2 emission has crossed 36 B tons, and the United State represents 14% of the total emissions. In light of the high cost associated with current CO 2 capture processes ($60-to-150 per ton of CO 2 ), carbon capture and utilization (CCU), wherein CO 2 is converted to beneficial products, provides a pragmatic path to overcome the economic barrier for CO 2 emissions control. In particular, CO 2 mineralization offers an attractive route as it produces high-value mineral carbonates that sequester CO 2 in a stable form. For instance, fine precipitated calcium carbonate, a valuable product with unit price in the range of $230-280/t and a global market projected to reach 99 M tons in 2020, can be produced by capturing CO 2 within aqueous Ca 2+ solution. However, two critical challenges need to be overcome—(i) the need for costly processes such as electrolysis or addition of alkali hydroxides to maintain alkalinity during mineralization, and (ii) the geographic availability of Ca-rich solutions (or brines) which often renders efficient integration with power plants impractical. To simultaneously address these challenges, this project developed two novel routes to enable carbonate production based on efficient CO 2 mineralization. In one variation, the project developed a new alkaline carbonation process to capture CO 2 and produce calcite precipitates from coal ashes. Herein, coal ash is carbonated first in a sodium carbonate solution. The carbonation reaction produces sodium hydroxide and raises the solution pH. This high-pH hydroxide solution is then used for CO 2 capture, which converts the sodium hydroxide solution back to sodium carbonate to repeat the carbonation cycle. The carbonated ash residue is refined with a CO 2 pressure swing step to produce high-purity precipitated calcium carbonate. In another variation, Ca-rich produced water brine serves as the Ca-source to mineralize CO 2 . An H + /Na + ion-exchange cycle was designed to provision alkalinity during mineralization and regenerate the ion-exchange reagent in brines with high salinity. Ca-depleted brines can then be treated within a centralized water treatment facility. Both variations beneficially utilize reject streams—such as coal ashes and brines from oil and gas extraction or CO 2 storage operations—that are available at substantial quantities in the vicinity of coal power plants within the U.S. In addition to technology development, this project included techno-economic and life-cycle analysis to identify technically and economically appropriate solutions for power plants in different geographic locations. Taken together, the project provides a unique route to integrate CO 2 emissions control and waste handling/treatment for coal power plants, while producing a high-value product to offset the economic burden associated with waste management. The developed processes utilize post-desulfurization flue gas from coal-fired power plants as is. The CO 2 conversion reactions are performed in alkaline brines at ambient pressure from the flue gas, thereby minimizing the energy burden. By beneficiation of industrial waste streams with low energy input, the processes offers significant technical advantages in energy and CO 2 footprint over the current paradigm of precipitated calcium carbonate production, which involves calcination of limestone at processing temperatures in excess of 800 °C. Overall, this project developed viable CO 2 mineralization processes while strategically maximizing the economic benefit.

01 COAL, LIGNITE, AND PEAT↗