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At least 1,261 records · Page 70

Cold Gas and Star Formation in the Phoenix Cluster with JWST

We present integral field unit observations of the Phoenix Cluster with the JWST Mid-infrared Instrument’s Medium Resolution Spectrometer. We focus this study on the molecular gas, dust, and star formation in the brightest cluster galaxy (BCG). We use precise spectral modeling to produce maps of the silicate dust, molecular gas, and polycyclic aromatic hydrocarbons (PAHs) in the inner ∼50 kpc of the cluster. We measure the optical depth from silicates by comparing the observed H 2 line ratios to those predicted by excitation models. We provide updated measurements of the total molecular gas mass of $1.9^{+0.5}_{-0.04}$ x 10 10 M ⊙ , which agrees with CO-based estimates, providing an estimate of the CO-to-H 2 conversion factor of α CO = 0.8 ± 0.2 M ⊙ pc -2 (K km s -1 ) -1 ; an updated stellar mass of M * = 2.6 ± 0.5 × 10 10 M ⊙ ; and star formation rates (SFRs) averaged over 10 and 100 Myr of $\langle$SFR$\rangle$ 10 = 1340 ± 100 M ⊙ yr −1 and $\langle$SFR$\rangle$ 100 = 740 ± 80 M ⊙ yr −1 , respectively. The H 2 emission seems to be powered predominantly by shocks and star formation within the central ∼20 kpc, induced by stellar feedback and radio jets from the active galactic nucleus. Additionally, we find nearly an order-of-magnitude drop in the SFRs estimated by PAH fluxes in cool core BCGs compared to field galaxies, suggesting that hot particles from the intracluster medium are destroying PAH grains even in the central-most tens of kiloparsecs.

Active galaxies↗

IEEE P2988: Recommended Practice of Use and Functions of Virtual Synchronous Machines

Power systems are going through a paradigm shift from centralized generation to distributed generation. This brings unprecedented challenges to power systems stability, reliability, and security. Operating power electronic converters as Virtual Synchronous Machines (VSMs) can bring backward compatibility to power systems, unify and harmonize the integration and interaction of future power systems players, and improve power system stability, reliability, and security. This is vital for the large-scale adoption of distributed energy resources, the advancement of sustainability, and the development of a low-carbon economy. This IEEE 2988 Recommended Practice will define the fundamental principles, mandatory functions, and optional functions of a VSM, i.e., a power electronic converter that is operated to behave like conventional synchronous machines. It will not describe or specify power semiconductor devices, hardware topologies, or micro-controllers that are used to build a VSM. This talk will discuss the activities and development plan for IEEE 2988 with the aim to engaging broad stakeholders and widening participation.

Zhong, Qing-Chang↗

The Effects of Contaminant-Aging on Decontamination Efficacy for Rapid Remediation of Concrete Surfaces - 20412

Understanding the relationship between decontamination efficacy and contaminant aging is imperative for developing effective remediation strategies following a large-scale contamination event. Non-destructive decontamination of concrete following a contamination incident becomes more difficult with increased time between contamination and decontamination because contaminants may chemically bind to concrete and/or penetrate into the concrete subsurface. In this work, we evaluated the decontamination efficacy of two decontamination methods on concrete samples contaminated with soluble Cesium-137 (Cs-137) and silica particles with 0.5 μm and 2 μm diameters. Concrete samples were aged between 1 and 59 days, with half of the coupons receiving 1 mL of artificial rainwater about once every three days. After aging, coupons were either decontaminated or analyzed to determine contaminant penetration depths. Coupons were decontaminated with 0.1 M Potassium Chloride (KCI) solution applied either by flowing solution across the contaminated coupon face or non-destructive power washing. Contaminant depth profiles were created by removing the top surface of the coupon at least 15 times, measuring the activity in each removed layer, normalizing the total activity removed to the measured decontamination efficacy following the last layer removal, and determining the penetration thickness using the coupon dimensions, bulk density, and mass of material removed for each layer. Pressurized washing effectively removed particles, but not soluble cesium, despite the majority of Cs-137 being located within the first millimeter of the subsurface. Soluble cesium removal by flowing 0.1 M KCI solution across the contaminated surface dropped to less than 12% within the first ten days. This drop in Cs-137 removal efficacy occurred within the first five days for coupons experiencing artificial rainfall events. Flowing 0.1 M KCI solution across the contaminated face was ineffective at removing particles, likely because particles had localized in surface depressions. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Lessons Learned from Open-Source Software Training Toward Expanding the Fusion Workforce

Within the United States (U.S.), the Fusion Innovation Research Engine (FIRE) Collaboratives seek to accelerate fusion technology development through wide-ranging community-driven research activities that bring together industry, laboratories, research institutes, and academia. Increasing the maturity of key components and systems for future fusion power plants (FPPs) toward commercialization, will, by necessity, increase the need for knowledgeable engineers, designers, and researchers in industry capable of integrating and further improving these technologies within industry FPP concepts. Further, various modeling and simulation packages support these programs and are under-development within them to drive design iteration and the development of FPP digital twins. To derive the greatest benefit from model output and capabilities, training these same specialists will be vital. Thus, the development of effective and accessible software onboarding and professional development opportunities focused on fusion will be key to keeping the pace of growth high in the coming decade and beyond. A similar need exists within the advanced fission reactor community, driven by an ever-growing need for carbon-free baseload power for industrial and data center applications. Within the U.S. and around the world, several open-source packages and frameworks exist to support this endeavor, and two we will highlight here are the Multiphysics Object Oriented Simulation Environment (MOOSE) framework and OpenMC. These packages, notably, are also being utilized in the FIRE Collaboratives program. In this presentation, we will highlight the lessons learned from over 30 years of combined software development and training experience, focused on developing strong technical software foundations within the nuclear workforce, from students to professional engineers & scientists. We will connect this experience to present and emerging needs in the fusion energy community, and, finally, will outline possible paths forward to develop a large, robust, global fusion workforce.

70 - PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Engineering-Scale Test of a Water-Lean Solvent for Post-Combustion Capture

EPRI, Pacific Northwest National Laboratory, RTI International, and their project collaborators developed an engineering-scale test of a new water-lean solvent, N-(2-ethoxyethyl)-3-morpholinopropan-1-amine (EEMPA or 2-EEMPA) as a post-combustion CO 2 capture solvent for power plant applications. This test was conducted using the Pilot Solvent Test Unit at the National Carbon Capture Center. The primary objective of this test was to collect long-term data operating EEMPA with both coal- and natural gas-representative flue gases at the approximately 0.5 MW e -equivalent scale (5–10 metric tons CO 2 /day captured). This report details the activities preparing for that test, data collected during the test campaign, and analyses and interpretations of that data.

20 FOSSIL-FUELED POWER PLANTS↗

Dielectrics for Power Electronics Applications

This presentation discusses the role of dielectric materials in power electronic packages. Two dielectric technologies - a dielectric material film-based substrate for insulation and a dielectric coolant - are discussed. The thermal performance benefits of dielectric film-based substrate in comparison with traditional direct-bond-copper substrates are studied through finite element analysis. Also, a novel cooling concept based on dielectric liquids that can contact electrically active surfaces are presented.

30 DIRECT ENERGY CONVERSION↗

Operational space for lower hybrid heating scenarios in the full tungsten environment of WEST

In tungsten—W—Environment in Steady-state Tokamak (WEST), the lower hybrid current drive (LHCD) system is key for achieving long pulse operation by providing most of the non-inductive plasma current, as well as a crucial source of electron heating. Therefore, determining the operational space for its application is fundamental. In the present study, the LHCD operational space is deeply analyzed for 0.5 MA pulses. This space is bounded by three limits: (i) the ratio of the LHCD power over density must be above a threshold to compensate tungsten radiation with enough core heating, (ii) the line-averaged density must be high enough to allow good coupling of the hybrid wave with the plasma, and (iii) fast electron ripple losses must be below a limit to avoid reaching a thermal threshold on plasma-facing components. If the tungsten radiation peak or burn-through phase is not safely overcome, a maximum electron temperature of 1.5 keV is obtained, confinement is degraded, and magnetohydrodynamic activity is frequently triggered, potentially causing a disruption. From experimental measurements and interpretative simulations, we highlight the main mechanisms that prevent the plasma from heating up during LHCD power ramp-up. Three parameters play a major role: plasma density, tungsten concentration and LHCD power deposition. A strategy to overcome this limitation is found: a precise density ramp-up performed simultaneously with the increase in LHCD power. Additionally, we show that boronization greatly facilitates the burn-through of tungsten by lowering its content during the heating phase. Finally, taking into account the three constraints given above, the LHCD operational space is determined at power ramp-up and during constant heating phases.

lower hybrid heating and current drive↗

System Study: Residual Heat Removal 1998–2018

This report presents an unreliability evaluation of the residual heat removal (RHR) system in two modes of operation (low-pressure injection in response to a large loss-of-coolant accident and post-trip shutdown-cooling) at 104 U.S. commercial nuclear power plants. Demand, run hours, and failure data from calendar years 1998 through 2018 for selected components were obtained from the Institute of Nuclear Power Operations (INPO) Industry Reporting and Information System (IRIS), formerly the INPO Consolidated Events Database (ICES). The unreliability results are trended for the most recent 10 year period while yearly estimates for system unreliability are provided for the entire active period. No statistically significant increasing or decreasing trends were identified in the RHR results.

99 GENERAL AND MISCELLANEOUS↗

Integration of a high oxygen permeability ionomer into polymer electrolyte membrane fuel cell cathodes for high efficiency and power density

In this work, we present a study on the integration of a high oxygen permeability ionomer (HOPI) with high durability carbon supported platinum (Pt/C) catalysts to prepare cathode catalyst layers (CCLs) for polymer electrolyte membrane fuel cells (PEMFCs). A key motivation is the production of PEMFCs with high efficiency and durability for heavy-duty fuel cell vehicles. Our results from integrating a pre-commercial HOPI with robust, state-of-the-art catalysts with medium and low surface area carbon supports show significant increases in specific activities (67% increase over the standard commercial ionomer) at low current densities and reduced oxygen (O 2 ) transport resistances (R O2 ’s) at high current densities, enabling both higher efficiency and peak power density. The reduction in the R O2 with the HOPI is most significant at low relative humidity (RH), due to its more rigid backbone structure resisting compaction at lower water contents. In our ink optimization analysis, we show that the HOPI in this study achieves its peak performance with an ionomer to carbon ratio (I/C) of 0.6 and a moderately alcohol-rich ink solvent when fabricating catalyst layers by the decal method with an automatic wet film coater.

08 HYDROGEN↗

Divertor heat flux challenge and mitigation in SPARC

Owing to its high magnetic field, high power, and compact size, the SPARC experiment will operate with divertor conditions at or above those expected in reactor-class tokamaks. Power exhaust at this scale remains one of the key challenges for practical fusion energy. Based on empirical scalings, the peak unmitigated divertor parallel heat flux is projected to be greater than 10 GW m -2 . This is nearly an order of magnitude higher than has been demonstrated to date. Furthermore, the divertor parallel Edge-Localized Mode (ELM) energy fluence projections (~11–34 MJ m -2 ) are comparable with those for ITER. However, the relatively short pulse length (~25 s pulse, with a ~10 s flat top) provides the opportunity to consider mitigation schemes unsuited to long-pulse devices including ITER and reactors. The baseline scenario for SPARC employs a ~1 Hz strike point sweep to spread the heat flux over a large divertor target surface area to keep tile surface temperatures within tolerable levels without the use of active divertor cooling systems. In addition, SPARC operation presents a unique opportunity to study divertor heat exhaust mitigation at reactor-level plasma densities and power fluxes. Not only will SPARC test the limits of current experimental scalings and serve for benchmarking theoretical models in reactor regimes, it is also being designed to enable the assessment of long-legged and X-point target advanced divertor magnetic configurations. Experimental results from SPARC will be crucial to reducing risk for a fusion pilot plant divertor design.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Soft Switching Over the Entire Line Cycle for a Quadruple Active Bridge DCX in a DC to Three-Phase AC Module

This paper is focused on a transformer-isolated quadruple active bridge (QAB) dc-dc converter loaded by three full-bridge dc-ac inverters. The QAB functions as a "DC trans-former" (DCX) in the dc-to-three-phase ac module. The QAB outputs provide time-varying power at twice the line frequency, which presents challenges in maintaining zero voltage switching (ZVS) on the secondary sides during low-power portions of the line cycle. It is shown how ZVS can be achieved in a phase, even at zero-power transfer, using a relatively small circulating current provided by the magnetizing inductance of the high-frequency transformer. The approach is particularly effective in high-voltage applications using SiC MOSFETs, where reductions in switching loss outweigh additional conduction losses due to the circulating currents. A detailed analysis of ZVS switching waveforms at the zero power transfer is presented, including effects of nonlinear device capacitances. Analytical expressions are given for the optimal values of the magnetizing inductance and dead times of the QAB primary and secondary bridges. The approach is verified by experimental results on a 600 V, 4 kW prototype, demonstrating greater than 98.5% efficiency from 1 kW to 4 kW, with a peak efficiency of 99.0%. Compared to conventionally operated prototype, a 54% reduction in total loss is achieved at rated power.

41 EE - Solar Energy Technologies Office (EE-4S)↗

Role of Renewables in Grid Resilience

This chapter focuses on revealing the impact of renewable energies, especially distributed energy resources, on modern power system resilience. It is widely recognized that the increasing adoption of renewable energy is bringing more uncertainty and variability, posing new challenges to grid resilience. However, both supply and demand are becoming more active in grid resilience management. The communities themselves would benefit from the utilization of local resources and flexible management to gain resilience during the extreme events.

grid resilience↗

Gamma-Ray Emission from Galaxies Hosting Molecular Outflows

Many star-forming galaxies and those hosting active galactic nuclei show evidence of massive outflows of material in a variety of phases including ionized, neutral atomic, and molecular. Molecular outflows in particular have been the focus of recent interest as they may be responsible for removing gas from the galaxy, thereby suppressing star formation. As material is ejected from the cores of galaxies, interactions of the outflowing material with the interstellar medium can accelerate cosmic rays and produce high-energy gamma rays. In this work, we search for gamma-ray emission from a sample of local galaxies known to host molecular outflows using data collected by the Fermi Large Area Telescope. We employ a stacking technique in order to search for and characterize the average gamma-ray emission properties of the sample. Gamma-ray emission is detected from the galaxies in our sample at the 4.4σ level with a power-law photon index of Γ ≈ 2 in the 1–800 GeV energy range. The emission is found to correlate with tracers of star formation activity, namely the 8–1000 μm infrared luminosity. We also find that the observed signal can be predominantly attributed to H II galaxies hosting energy-driven outflows. While we do not find evidence suggesting that the outflows are accelerating charged particles directly, galaxies with molecular outflows may produce more gamma rays than galaxies without outflows. In particular, the set consisting of gamma-ray-detected galaxies with molecular outflows are nearly perfect calorimeters and may be future targets for searches of high-energy neutrinos.

79 ASTRONOMY AND ASTROPHYSICS↗

Redox-Active Polymers Designed for the Circular Economy of Energy Storage Devices

Electrochemical energy storage is a keystone to support the rapid transition to a low-carbon-emission future for grid storage and transportation. While research on electrochemical energy storage devices has mostly dealt with performance improvements (energy density and power density), little attention has been paid to designing devices that can be recycled with low cost and low environmental impact. Thus, next-generation energy storage devices should also address the integration of recyclability into the device design. In this study, we demonstrate recyclable energy storage devices based on solution-processable redox-active conjugated polymers. The high electronic and ionic charge transport in these polymers enables the operation of single-phase electrodes in aqueous electrolytes with C-rates >100 with good electrochemical stability when the cell is charged to 1.2 V. Finally, we demonstrate the recyclability of these devices, achieving >85% capacity retention in each recycling step. Our work provides a framework for developing recyclable devices for sustainable energy storage technologies.

25 ENERGY STORAGE↗

Pulsed Light Synthesis of High Entropy Nanocatalysts with Enhanced Catalytic Activity and Prolonged Stability for Oxygen Evolution Reaction

The ability to synthesize compositionally complex nanostructures rapidly is a key to high-throughput functional materials discovery. In addition to being time-consuming, a majority of conventional materials synthesis processes closely follow thermodynamics equilibria, which limit the discovery of new classes of metastable phases such as high entropy oxides (HEO). Herein, a photonic flash synthesis of HEO nanoparticles at timescales of milliseconds is demonstrated. By leveraging the abrupt heating and cooling cycles induced by a high-power-density xenon pulsed light, mixed transition metal salt precursors undergo rapid chemical transformations. Hence, nanoparticles form within milliseconds with a strong affinity to bind to the carbon substrate. Oxygen evolution reaction (OER) activity measurements of the synthesized nanoparticles demonstrate two orders of magnitude prolonged stability at high current densities, without noticeable decay in performance, compared to commercial IrO 2 catalyst. This superior catalytic activity originates from the synergistic effect of different alloying elements mixed at a high entropic state. It is found that Cr addition influences surface activity the most by promoting higher oxidation states, favoring optimal interaction with OER intermediates. The proposed high-throughput method opens new pathways toward developing next-generation functional materials for various electronics, sensing, and environmental applications, in addition to renewable energy conversion.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Enhancement of low-temperature solid oxide fuel cell performance and durability via surface chemistry modification

The development of active cathodes is one of the most critical challenges to lowering the operating temperature for solid oxide fuel cells (SOFCs). Here, in this work, we demonstrated that by modifying the cathode surface chemistry at a relatively low temperature, the cathode activity and durability can be simultaneously enhanced on high-performing, low-temperature cathodes such as (La 0.6 Sr 0.4 ) 0.95 Co 0.2 Fe 0.8 O 3-δ (LSCF) and Sr 0.5 Sm 0.5 CoO 3-δ (SSC). This low-temperature modification using multi-valent cations activates the highly defected surface and maintains the nanoscale electrocatalysts by bypassing the high-temperature sintering procedure for SOFC fabrication. The modified cathode at 600°C shows an order of magnitude reduction in impedance to only 0.05 Ωcm 2 with a peak power density of 1.1 W/cm 2 and increases stability over 2000 h. The combination of in situ characterization, distribution of relaxation time analysis on impedance spectroscopy, and surface chemistry analysis reveals the importance of surface chemistry control on the gas-solid reaction activity and durability and provides the design principle for numerous future solid oxide cells.

25 ENERGY STORAGE↗

Atomically Dispersed Zn/Co–N–C as ORR Electrocatalysts for Alkaline Fuel Cells

Hydrogen fuel cells have drawn increasing attention as one of the most promising next-generation power sources for future automotive transportation. Developing efficient, durable, and low-cost electrocatalysts, to accelerate the sluggish oxygen reduction reaction (ORR) kinetics, is urgently needed to advance fuel cell technologies. Herein, we report on metal–organic frameworks-derived nonprecious dual metal single-atom catalysts (SACs) (Zn/Co–N–C), consisting of Co–N 4 and Zn–N 4 local structures. These catalysts exhibited superior ORR activity with a half-wave potential (E 1/2 ) of 0.938 V versus RHE (reversible hydrogen electrode) and robust stability (ΔE 1/2 = –8.5 mV) after 50k electrochemical cycles. Moreover, this remarkable performance was validated under realistic fuel cell working conditions, achieving a record-high peak power density of ~1 W cm –2 among the reported SACs for alkaline fuel cells. Operando X-ray absorption spectroscopy was conducted to identify the active sites and reveal catalytic mechanistic insights. The results indicated that the Co atom in the Co–N 4 structure was the main catalytically active center, where one axial oxygenated species binds to form an O ads –Co–N 4 moiety during the ORR. In addition, theoretical studies, based on a potential-dependent microkinetic model and core-level shift calculations, showed good agreement with the experimental results and provided insights into the bonding of oxygen species on Co–N 4 centers during the ORR. Furthermore, this work provides a comprehensive mechanistic understanding of the active sites in the Zn/Co–N–C catalysts and will pave the way for the future design and advancement of high-performance single-site electrocatalysts for fuel cells and other energy applications.

25 ENERGY STORAGE↗