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At least 127 records · Page 7
All sourcesNASA NTRSDOE OSTI
DOE OSTI2022

2021 Annual Site Environmental Report

This report provides the U.S. Department of Energy (DOE) and the public with information on the level of radioactive and non-radioactive pollutants (if any) that are added to the environment as a result of Princeton Plasma Physics Laboratory’s (PPPL) operations. The results of PPPL’s 2021 environmental surveillance and monitoring program are presented and discussed. The report also summarizes environmental initiatives, assessments, and community involvement programs that were undertaken in 2021. PPPL’s on-site operations were significantly curtailed in 2021 due to the global coronavirus pandemic. PPPL has engaged in fusion energy research since 1951. The Laboratory’s mission is to develop the scientific knowledge and advanced engineering to enable fusion to power the U.S. and the world, and to developing the understanding of plasmas from the nano- to the astrophysical scale. PPPL’s primary experiment, the National Spherical Torus Experiment-Upgrade (NSTX-U) is a collaboration among national laboratories, universities, and national and international research institutions and is a major element in the US Fusion Energy Sciences Program. Its design tests the physics principles of spherical torus (ST) plasmas, playing an important role in the development of smaller, more economical fusion reactors. Due to previous operational issues, NSTX-U did not operate in 2021. PPPL is engaged in a project to replace key NSTX-U components and systems to enable operation of this international fusion user facility. In 2021, PPPL’s radiological environmental monitoring program measured tritium in the air at the NSTX-U Stack and at onsite sampling stations. Using highly sensitive air monitors, PPPL is capable of detecting small changes in the ambient levels of tritium. The operation of an in-stack monitor located on D-site is used to demonstrate compliance with the National Emission Standard for Hazardous Air Pollutants (NESHAPs) regulations. Also included in PPPL’s radiological environmental monitoring program, are water monitoring – ground, surface, and waste waters. PPPL’s radiological monitoring program characterized the background levels of tritium in the environment and those data are presented in this report. Ground water monitoring continued under New Jersey Department of Environmental Protection’s (NJDEP) Site Remediation Program regulations. PPPL monitored for non-radiological contaminants, mainly volatile organic compounds (components of common degreasing solvents). In 2021, PPPL complied with permit limits for surface and sanitary discharges. PPPL was honored with awards for EPEAT-certified electronics purchasing and use of peracetic acid as an alternative water treatment chemical in its non-potable process water systems an NJDEP recycling award.

54 ENVIRONMENTAL SCIENCES↗
DOE OSTI2025

The imprint of cosmic voids from the DESI Legacy Survey DR9 Luminous Red Galaxies in the Planck 2018 lensing map through spectroscopically calibrated mocks

The cross-correlation of cosmic voids with the lensing convergence (κ) map of the Cosmic Microwave Background (CMB) fluctuations provides a powerful tool to refine our understanding of the current cosmological model. However, several studies have reported a moderate tension (up to ∼2σ) between the lensing imprint of cosmic voids on the observed CMB and the ΛCDM signal predicted by simulations. To address this “lensing-is-low” tension and to obtain new, precise measurements of the signal, we exploit the large DESI Legacy Survey Luminous Red Galaxy (LRG) data set, covering approximately 19 500 deg 2 of the sky and including about 10 million LRGs at z < 1.05. Our ΛCDM template was created using the Buzzard mocks, which we specifically calibrated to match the clustering properties of the observed galaxy sample by exploiting more than one million DESI spectra. We identified our catalogs of 3D voids in the range 0.35 < z < 0.95 and cross-correlated them through a stacking methodology, dividing the sample into bins according to the redshift and λv values of the voids. For the full void sample, we report a 14σ detection of the lensing signal, with A κ = 1.016 ± 0.054, which increases to 17σ when considering the void-in-void (A κ = 0.944 ± 0.064) and the void-in-cloud (A κ = 0.975 ± 0.060) populations individually, the highest detection significance for studies of this kind. We observe a full agreement between observations and ΛCDM mocks across all redshift bins, sky regions, and void populations considered. In addition to these findings, our analysis highlights the importance of accurately matching sparseness and redshift error distributions between mocks and observations, as well as the role of λ v in enhancing the signal-to-noise ratio through void population discrimination.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2015

FAINT CO LINE WINGS IN FOUR STAR-FORMING (ULTRA)LUMINOUS INFRARED GALAXIES

We report the results of a search for large velocity width, low-intensity line wings—a commonly used signature of molecular outflows—in four low redshift (ultra)luminous infrared galaxies that appear to be dominated by star formation. The targets were drawn from a sample of fourteen targets presented in Chung et al., who showed the stacked CO spectrum of the sample to exhibit 1000 km s{sup −1}-wide line wings. We obtained sensitive, wide bandwidth imaging of our targets using the IRAM Plateau de Bure Interferometer. We detect each target at very high significance but do not find the claimed line wings in these four targets. Instead, we constrain the flux in the line wings to be only a few percent. Casting our results as mass outflow rates following Cicone et al. we show them to be consistent with a picture in which very high mass loading factors preferentially occur in systems with high active galactic nucleus contributions to their bolometric luminosity. We identify one of our targets, IRAS 05083 (VII Zw 31), as a candidate molecular outflow.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2015

Effect of Na presence during CuInSe{sub 2} growth on stacking fault annihilation and electronic properties

While presence of Na is essential for the performance of high-efficiency Cu(In,Ga)Se{sub 2} thin film solar cells, the reasons why addition of Na by post-deposition treatment is superior to pre-deposition Na supply—particularly at low growth temperatures—are not yet fully understood. Here, we show by X-ray diffraction and electron microscopy that Na impedes annihilation of stacking faults during the Cu-poor/Cu-rich transition of low temperature 3-stage co-evaporation and prevents Cu homogeneity on a microscopic level. Lower charge carrier mobilities are found by optical pump terahertz probe spectroscopy for samples with remaining high stacking fault density, indicating a detrimental effect on electronic properties if Na is present during growth.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗
DOE OSTI2018

Aerosol and Cloud Experiments in the Eastern North Atlantic (ACE-ENA) Winter Intensive Operational Period: Aerodynamic Particle Sizer Field Campaign Report

An aerodynamic particle sizer spectrometer (APS, model 3321 by TSI Inc., Shoreview, Minnesota) was deployed at the U.S. Department of Energy (DOE) Atmospheric Radiation Measurement (ARM) user facility Eastern North Atlantic (ENA) observatory during the second (winter) intensive operational period (IOP) of the Aerosol and Cloud Experiments in the Eastern North Atlantic (ACE-ENA) field campaign. Data were collected from January 9 through February 26, 2018, covering the second deployment of the ARM Aerial Facility (AAF) aircraft within ACE-ENA. The standard ENA instrument suite does not provide measurements of aerosol particle size distribution for diameters greater than one micron. Properties of coarse-mode (super-micron) aerosols are rarely measured, although super-micron particles can play an important role in the aerosol life cycle, affecting aerosol optical properties and cloud nuclei activity (e.g., Clarke et al. 2003). The APS was deployed to fill this gap in particle size measurements: it is capable of measuring size-resolved concentration of the aerosols in the 0.5-20 μm range (aerodynamic diameter). The APS was installed in the aerosol trailer to sample through the main stack. Special attention was given to selection of the instrument location (just below the main stack) to minimize particle losses in the connecting lines. Most atmospheric aerosols are hygroscopic, so the measurement of the aerosol size distributions should either be performed in a controlled humidity environment or accompanied by concurrent measurement of the temperature and humidity of the sample air. The latter strategy was used during this deployment: a high-precision humidity/temperature transmitter (model EE08 by E+E Elektonik GMBH, Engerwitzdorf, Germany) was mounted in the APS sampling line immediately upstream of the APS inlet. A dedicated laptop computer was used for data collection and communications. The APS was controlled with vendor-supplied software (Aerosol Instrument Manager, ver. 10.1, TSI); aerosol size distribution data were collected over a period of 55 seconds and converted to one-minute averages. Temperature and humidity analog signals were acquired via analog-to-digital converter (ADC) module (model WTAIN-M by Weeder Technologies, Fort Walton Beach, Florida) using vendor-supplied software (ModCom) with 1- sec resolution. In post-processing, the APS data were exported from TSI proprietary format into “comma-separated value” American Standard Code for Information Interchange (ASCII) files and matched with appropriately averaged temperature and humidity data. Two significant periods of missing data were caused by local power outages. Vendor-supplied software was not designed for unattended operation: it needs to be manually restarted including sensor configuration setup.

ACE-ENA, Azores, ultra-high-sensitivity aerosol sp↗
DOE OSTI2011

SPECTRAL ENERGY DISTRIBUTION FITTING WITH MARKOV CHAIN MONTE CARLO: METHODOLOGY AND APPLICATION TO z = 3.1 Ly{alpha}-EMITTING GALAXIES

We present GalMC, a Markov Chain Monte Carlo (MCMC) algorithm designed to fit the spectral energy distributions (SEDs) of galaxies to infer physical properties such as age, stellar mass, dust reddening, metallicity, redshift, and star formation rate. We describe the features of the code and the extensive tests conducted to ensure that our procedure leads to unbiased parameter estimation and accurate evaluation of uncertainties. We compare its performance to grid-based algorithms, showing that the efficiency in CPU time is {approx}100 times better for MCMC for a three-dimensional parameter space and increasing with the number of dimensions. We use GalMC to fit the stacked SEDs of two samples of Lyman alpha emitters (LAEs) at redshift z = 3.1. Our fit reveals that the typical LAE detected in the IRAC 3.6 {mu}m band has age = 0.67 [0.37-1.81] Gyr and stellar mass = 3.2 [2.5-4.2] x 10{sup 9} M{sub sun}, while the typical LAE not detected at 3.6 {mu}m has age = 0.06 [0.01-0.2] Gyr and stellar mass = 2 [1.1-3.4] x 10{sup 8} M{sub sun}. The SEDs of both stacks are consistent with the absence of dust. The data do not significantly prefer exponential with respect to constant star formation history. The stellar populations of these two samples are consistent with the previous study by Lai et al., with some differences due to the improved modeling of the stellar populations. A constraint on the metallicity of z = 3.1 LAEs from broadband photometry, requiring Z < Z{sub sun} at 95% confidence, is found here for the first time.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2016

Planck intermediate results: XLIII. Spectral energy distribution of dust in clusters of galaxies

Although infrared (IR) overall dust emission from clusters of galaxies has been statistically detected using data from the Infrared Astronomical Satellite (IRAS), it has not been possible to sample the spectral energy distribution (SED) of this emission over its peak, and thus to break the degeneracy between dust temperature and mass. By complementing the IRAS spectral coverage with Planck satellite data from 100 to 857 GHz, we provide in this paper new constraints on the IR spectrum of thermal dust emission in clusters of galaxies. We achieve this by using a stacking approach for a sample of several hundred objects from the Planck cluster sample. This procedure averages out fluctuations from the IR sky, allowing us to reach a significant detection of the faint cluster contribution. We also use the large frequency range probed by Planck, together with component-separation techniques, to remove the contamination from both cosmic microwave background anisotropies and the thermal Sunyaev-Zeldovich effect (tSZ) signal, which dominate at ν ≤ 353 GHz. By excluding dominant spurious signals or systematic effects, averaged detections are reported at frequencies 353 GHz ≤ ν ≤ 5000 GHz. We confirm the presence of dust in clusters of galaxies at low and intermediate redshifts, yielding an SED with a shape similar to that of the Milky Way. Planck’s resolution does not allow us to investigate the detailed spatial distribution of this emission (e.g. whether it comes from intergalactic dust or simply the dust content of the cluster galaxies), but the radial distribution of the emission appears to follow that of the stacked SZ signal, and thus the extent of the clusters. Finally, the recovered SED allows us to constrain the dust mass responsible for the signal and its temperature.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2017

The Mass–Concentration Relation and the Stellar-to-halo Mass Ratio in the CFHT Stripe 82 Survey

We present a new measurement of the mass–concentration relation and the stellar-to-halo mass ratio over the halo-mass range 5 × 10{sup 12} to 2 × 10{sup 14} M {sub ⊙}. To achieve this, we use weak lensing measurements from the Canada–France–Hawaii Telescope Stripe 82 Survey (CS82), combined with the central galaxies from the redMaPPer cluster catalog and the LOWZ/CMASS galaxy sample of the Sloan Digital Sky Survey-III Baryon Oscillation Spectroscopic Survey Tenth Data Release. The stacked lensing signals around these samples are modeled as a sum of contributions from the central galaxy, its dark matter halo, and the neighboring halos, as well as a term for possible centering errors. We measure the mass–concentration relation: c{sub 200c}(M)=A(((M{sub 200c})/(M{sub 0}))){sup B} with A = 5.24 ± 1.24, B = −0.13 ± 0.10 for 0.2 < z < 0.4, and A = 6.61 ± 0.75, B = −0.15 ± 0.05 for 0.4 < z < 0.6. These amplitudes and slopes are completely consistent with predictions from recent simulations. We also measure the stellar-to-halo mass ratio for our samples, and find results consistent with previous measurements from lensing and other techniques.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2018

Development of a lithium fluoride zinc sulfide based neutron multiplicity counter

Past 3He shortages led to investigations into replacement options for neutron detectors in systems that previously used 3He-based technologies. The goal of this research was to investigate the feasibility of a full-scale lithium fluoride with silver activated zinc sulfide (LiF/ZnS) based neutron multiplicity counter. The LiF/ZnS based neutron multiplicity counter (LiNMC) was developed based on an iterative process between modeling and experimental measurements. Each active region of the LiNMC contains five sheets of LiF/ZnS sandwiched between six sheets of wavelength shifting plastic to form neutron detection stacks. The wavelength shifted scintillation light was collected by photomultiplier tubes located on each end of the stacks. Twelve such detector stacks were placed around a sample chamber in a square arrangement with lithiated high density polyethylene blocks in the corners to reflect high energy neutrons and capture low energy neutrons. Preliminary calibration with a 252Cf neutron source showed that the LiNMC was able to achieve 36% neutron detection efficiency (ε) and an 11.7 μs neutron die-away time (τ) for a doubles Figure-of-merit (ε2/ τ) of 109. This is the highest doubles Figure-of-merit performance measured to-date for a 3He-free neutron multiplicity counter system. By the end of this project, the LiNMC’s basic components were integrated into a single laboratory scale system capable of proof-of-concept measurements.

3He-free↗
DOE OSTI2024

EMP, Attachment 1: Sampling and Analysis Plan (Rev.1)

This Sampling and Analysis Plan (SAP) is written for the Environmental Radiation Task activities related to radioactive air emissions (stack) monitoring and environmental radiological ambient air surveillance of Pacific Northwest National Laboratory (PNNL) operations at the PNNL-Richland campus and PNNL-Sequim campus. PNNL is a U.S. Department of Energy Office of Science laboratory in Richland, Washington. This plan is an attachment to PNNL’s Environmental Radiological Air Monitoring Plan (EMP) (PNNL-20919) and addresses a discrete, vital subject area that is subject to revision independent of the main text of the EMP document. This SAP provides the requirements for planning sampling events and the requirements imposed on the services provided by the analytical laboratory to the PNNL Environmental Radiation Task.

40 CFR 61 Subpart H↗
DOE OSTI2020

Localized Excitons in NbSe 2 -MoSe 2 Heterostructures

Neutral and charged excitons (trions) in atomically thin materials offer important capabilities for photonics, from ultrafast photodetectors to highly efficient light-emitting diodes and lasers. Recent studies of van der Waals (vdW) heterostructures comprised of dissimilar monolayer materials have uncovered a wealth of optical phenomena that are predominantly governed by interlayer interactions. Here, we examine the optical properties in NbSe 2 -MoSe 2 vdW hetero- structures, which provide an important model system to study metal–semiconductor interfaces, a common element in optoelectronics. Through low-temperature photoluminescence (PL) microscopy, we discover a sharp emission feature, L1, that is localized at the NbSe 2 -capped regions of MoSe 2 . L1 is observed at energies below the commonly studied MoSe 2 excitons and trions and exhibits temperature- and power-dependent PL consistent with exciton localization in a confining potential. This PL feature is robust, observed in a variety of samples fabricated with different stacking geometries and cleaning procedures. Using first-principles calculations, we reveal that the confinement potential required for exciton localization naturally arises from the in-plane band bending due to the changes in the electron affinity between pristine MoSe 2 and NbSe 2 -MoSe 2 heterostructure. Here, we discuss the implications of our studies for atomically thin optoelectronics devices with atomically sharp interfaces and tunable electronic structures.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2024

Effect of ground-state charge transfer on photoexcited charge transfer in transition metal dichalcogenide heterostructures

We report an experimental investigation on the effect of ground-state charge transfer and its induced electric field on photoexcited charge transfer in van der Waals heterostructures. Two heterostructure samples were fabricated by stacking an undoped WSe 2 monolayer with either a Nb-doped or undoped MoSe 2 monolayer. While no ground-state charge transfer is expected in the MoSe 2 /WSe 2 heterostructure, the doped holes in the MoSe 2 :Nb/WSe 2 heterostructure can transfer to WSe 2 , creating a space-charge electric field. By comparing the photoluminescence and time-resolved differential reflectance of the two heterostructures, we find that photoexcited hole transfer from MoSe 2 to WSe 2 is largely blocked by this field, whereas photoexcited electron transfer from WSe 2 to MoSe 2 is less affected. Furthermore, these results provide insight into the impact of doping on the charge-transfer performance of van der Waals heterostructures.

2D materials↗
DOE OSTI2025

Type-I and type-II interfaces in a MoSe 2 /WS 2 van der Waals heterostructure

We report experimental evidence that MoSe 2 and WS 2 allow the formation of type-I and type-II interfaces, according to the thickness of the former. Heterostructure samples are obtained by stacking a monolayer WS 2 flake on top of a MoSe 2 flake that contains regions of thickness from one to four layers. Photoluminescence spectroscopy and transient absorption measurements reveal a type-II interface in the regions of monolayer MoSe 2 in contact with monolayer WS 2 . In other regions of the heterostructure formed by multilayer MoSe 2 and monolayer WS 2 , features of type-I interface are observed, including the absence of charge transfer and dominance of intralayer excitons in MoSe 2 . Furthermore, the coexistence of type-I and type-II interfaces in a single heterostructure offers opportunities to design sophisticated two-dimensional materials with finely controlled photocarrier behaviors.

2D materials↗
DOE OSTI2011

PROBING THE OFF-STATE OF CLUSTER GIANT RADIO HALOS

We derive the best characterization to date of the properties of radio quiescent massive galaxy clusters through a statistical analysis of their average synchrotron emissivity. We stacked 105 radio images of clusters from the 843 MHz Sydney University Molonglo Sky Survey, all with L{sub X} > 10{sup 44} erg s{sup -1} and redshifts z < 0.2, after removing point-source contamination and rescaling to a common physical size. Each stacked cluster individually shows no significant large-scale diffuse radio emission at current sensitivity levels. Stacking of sub-samples leads to the following results: (1) clusters with L{sub X} > 3 x 10{sup 44} erg s{sup -1} show a 6{sigma} detection of Mpc-scale diffuse emission with a 1.4 GHz luminosity of (2.4 {+-} 0.4) x10{sup 23} W Hz{sup -1}. This is 1.5-2 times lower than the upper limits for radio quiescent clusters from the GMRT Radio Halo Survey and is the first independent confirmation of radio halo bi-modality. (2) Clusters with low X-ray concentrations have a mean radio luminosity (2.6 {+-} 0.6 x 10{sup 23} W Hz{sup -1}) that is at least twice that of high X-ray concentration clusters, and (3) both of these detections are likely close to the low-level 'off-state' of giant radio halos (GRHs) in most or all luminous X-ray clusters, and not due to contributions from a much smaller subset of 'on-state' GRHs following the radio/X-ray luminosity correlation. Upcoming deep radio surveys will conclusively distinguish between these two options. We briefly discuss possible origins for the 'off-state' emission and its implications for magnetic fields in most or all luminous X-ray clusters.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2014

LOCATING THE ''MISSING'' BARYONS WITH EXTRAGALACTIC DISPERSION MEASURE ESTIMATES

Recently, Thornton and coworkers confirmed a class of millisecond radio bursts likely of extragalactic origin that is well-suited for estimating dispersion measures (DMs). We calculate the probability distribution of DM(z) in different models for how the cosmic baryons are distributed (both analytically and with cosmological simulations). We show that the distribution of DM is quite sensitive to whether the ''missing'' baryons lie around the virial radius of 10{sup 11}-10{sup 13} M{sub ☉} halos or further out, which is not easily constrained with other observational techniques. The intrinsic contribution to DM from each source could complicate studies of the extragalactic contribution. This difficulty is avoided by stacking based on the impact parameter to foreground galaxies. We show that a stacking analysis using a sample of ∼100 DM measurements from arcminute-localized, z ≳ 0.5 sources would place interesting constraints at 0.2-2 halo virial radii on the baryonic mass profile surrounding different galaxy types. Conveniently for intergalactic studies, sightlines that intersect intervening galactic disks should be easily identified owing to scattering. A detectable level of scattering may also result from turbulence in the circumgalactic medium.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2024

Heterostructural interface engineering for ultrawide-gap nitrides from first principles: Ta C / Al N and Ta C / Ga N rocksalt-wurtzite interfaces

Epitaxial lattice matching is an important condition for the formation of coherent interfaces with low defect densities. However, lattice-matched substrates with the same crystal structure as the active layer are often not available, suggesting opportunities for utilizing heterostructural interfaces. For example, at high Al contents that are interesting for ultrawide-gap applications in power electronics, Al x ⁢Ga 1-x ⁢N semiconductor alloys in the (0001) orientation of the wurtzite (wz) structure become lattice-matched to (111)-oriented rocksalt (rs) Ta⁢C substrates. To predict the expected interface atomic structures under different synthesis conditions, we perform high-throughput density-functional-theory calculations, using an algorithm for systematic sampling of the possible stacking sequences of the atomic layers on the in-plane hexagonal lattice. The approach considers octahedral, tetrahedral, and prismatic coordination motifs, and is generally applicable for the modeling of commensurate rs/wz heterostructural interfaces. Our results provide guidance for synthesis control of substrate-film bonding and the polarity of ultrawide-gap Al x⁢ Ga 1-x⁢ N alloys on Ta⁢C substrates.

36 MATERIALS SCIENCE↗
DOE OSTI2017

Neutron and x-ray scattering study of phonon dispersion and diffuse scattering in ( Na , Bi ) Ti O 3 - x BaTi O 3 single crystals near the morphotropic phase boundary

Neutron and x-ray scattering measurements were performed on (Na 1/2 Bi 1/2 )TiO 3-x at % BaTiO 3 (NBT-xBT) single crystals (x = 4, 5, 6.5, and 7.5) across the morphotropic phase boundary (MPB), as a function of both composition and temperature, and probing both structural and dynamical aspects. In addition to the known diffuse scattering pattern near the gamma points, our measurements revealed new, faint superlattice peaks, as well as an extensive diffuse scattering network, revealing a short-range ordering of polar nanoregions (PNR) with a static stacking morphology. Furthermore, in samples with compositions closest to the MPB, our inelastic neutron scattering investigations of the phonon dynamics showed two unusual features in the acoustic phonon branches, between the superlattice points, and between the superlattice points and gamma points, respectively. Finally, these critical elements are not present in the other compositions away from the MPB, which suggests that these features may be related to the tilt modes coupling behavior near the MPB.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
DOE OSTI2019

Physical properties and thermal stability of Fe 5 - x GeTe 2 single crystals

The magnetic and transport properties of Fe-deficient Fe 5 GeTe 2 single crystals (Fe 5-x GeTe 2 with x≈0.3) were studied and the impact of thermal processing was explored in this work. Quenching crystals from the growth temperature has been previously shown to produce a metastable state that undergoes a strongly hysteretic first-order transition upon cooling below ≈100 K. The first-order transition impacts the magnetic properties, yielding an enhancement in the Curie temperature $T_C$ from 270 to 310 K. In the present work, $T_{HT}$ ≈ 550 K has been identified as the temperature above which metastable crystals are obtained via quenching. Diffraction experiments reveal a structural change at this temperature, and significant stacking disorder occurs when samples are slowly cooled through this $\textit{T}$ range. The transport properties are demonstrated to be similar regardless of the crystal's thermal history. The scattering of charge carriers appears to be dominated by moments fluctuating on the Fe(1) sublattice, which remain dynamic down to ≈100–120 K. Maxima in the magnetoresistance and anomalous Hall resistance are observed near 120 K. The Hall and Seebeck coefficients are also impacted by magnetic ordering on the Fe(1) sublattice. The data suggest that both electrons and holes contribute to conduction above 120 K, but that electrons dominate at lower $\textit{T}$ when all of the Fe sublattices are magnetically ordered. This study demonstrates a strong coupling of the magnetism and transport properties in Fe 5-x GeTe 2 and complements the previous results that demonstrated strong magnetoelastic coupling as the Fe(1) moments order.

36 MATERIALS SCIENCE↗