Results for “water potential” — Page 67

DOE OSTI2023

An innovative approach for atrazine electrochemical oxidation modelling: Process parameter effect, intermediate formation and kinetic constant assessment

Water reuse for irrigation activities is becoming a crucial worldwide challenge due to the depletion of water sources. Anyway, agricultural drainage can potentially contain dangerous contaminants such as metals, pesticides, and herbicides, including atrazine. To address the need for agriculture wastewater purification, we investigated atrazine removal from simulated wastewater by electro-oxidation using platinum-coated titanium electrodes on a lab-scale experimental apparatus. The effects of electrolyte composition and concentration, i.e. ionic strength and applied current density on atrazine removal, were investigated. The results demonstrated that the electrochemical oxidation of the herbicide occurred through two routes, depending on the presence or absence of oxidizing chlorine species. The generation of intermediates during the treatment was monitored and quantified by evaluating the effect of an inert electrolyte (NaClO 4 ) versus an oxidizable chlorine species (NaCl). In both experimental conditions, five intermediates were identified, including desethyl-atrazine (DEA), hydroxyatrazine (ATZ-OH), desisopropyl-atrazine (DIA) and desethyl-desisopropyl-atrazine (DEDIA). A degradation mechanism and a model for describing hydroxyl radicals and active chlorine species contributions at ATZ oxidation were also proposed. Intermediate evolution profiles suggest that ATZ degradation can be considered as a series–parallel reaction system. Finally, the energy requirement assessment for ATZ removal was carried out. The highest ATZ removal (≅98%) was achieved with NaCl = 0.08 M, J = 60 A/m −2 , and E C = 5.83 kWh m −3 . Results highlight that atrazine removal was improved when an active chlorine species (NaCl) was present in the water solution. Moreover, the addition of chlorine species during electro-oxidation is an energy-saving strategy. Collectively, electro-oxidation technique can be efficiently applied to treat polluted water in order to meet the needs of recycling water quality and reduce resource consumption.

Electro-chemical oxidation↗

DOE OSTI2020

A short tutorial on uranium electropolishing

Electropolishing of uranium metal is best performed in a simple aqueous solution of phosphoric acid. With +3 to +10 volts of bias potential applied to the uranium (anode) relative to a Pt counter electrode (cathode). As summarized in a Pourbaix stability diagram, these conditions yield dissolution of the U surface as UOX containing solution species without the possibility of injecting hydrogen into the metal surface. However, if the uranium is biased to negative potentials relative to the counter electrode then water may be reduced at the U surface and hydrogen gas becomes available for reaction with the U metal. The stability diagram may be modified if there are other complexing species present in solution and the potential scale shifted if a different metal is use for the counter electrode. These effects can be understood in a known way as long as solution and electrochemical cell conditions are recognized.

38 RADIATION CHEMISTRY, RADIOCHEMISTRY, AND NUCLEA↗

DOE OSTI2024

Controlling Product Selectivity in Photochemical CO 2 Reduction with the Redox Potential of the Photosensitizer

The ability to selectively reduce CO 2 to a particular product or mixture of products is expected to play a key role in mitigation strategies aiming to alleviate the devastating impact of this greenhouse gas in our climate and oceans. Among those, the production of liquid solar fuels from CO 2 and H 2 O will likely need cascade strategies involving multiple catalysts carrying out different functions. This will require that the catalysts doing the initial CO 2 reduction steps deliver the right product or products to downstream catalysts. CO, H 2 and formate are the most common products in CO 2 reduction by molecular catalysts. Here, in this work, we demonstrate control over the selectivity of C 1 products in photochemical CO 2 reduction with the same catalyst, simply by changing the redox potential of the photosensitizer and/or the water concentration. Turnover numbers for CO generation with one of the photosensitizers under anhydrous conditions reached 85,000, one of the largest values reported to date. A combination of experimental results and DFT calculations show that control of the selectivity is achieved, in part, due to the interplay between regimes under kinetic or thermodynamic control. These regimes are largely dictated by the proton sources and the CO 2 reduction byproducts generated.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

DOE OSTI2026

Scalable Solar Fuels Production in A Reactor Train System by Thermochemical Redox Cycling of Novel Nonstoichiometric Perovskites

Hydrogen production via two-step thermochemical water splitting redox cycles using nonstoichiometric redox-active metal oxides has the potential to dramatically increase fuel production rates. At moderate-to-low water splitting temperatures, surface reaction kinetics co-limit the process. In such cases, stable and high surface area microstructures that allow exploitation of the full thermodynamic potential of the materials are essential as is tight thermal integration of the reactor module. This project’s goals were the development of novel nonstoichiometric perovskite oxides with high stability and favorable thermodynamic and kinetic properties, to optimize their microstructure for maximizing the fuel productivity, and to build a prototype reactor train system (RTS) comprising at least one reactor to meet specific performance targets: (1) capable of an in-house solar thermochemical hydrogen (STCH) productivity ≥ 12 mL g -1 for stable continuous operation ≥ 20 cycles; and (2) demonstration of scalable solar fuels production at practical solar reactor level in an industrial-scale concentrated solar tower (CST) using developed perovskites to achieve a hydrogen production rate ≥ 1 g h -1 .

08 HYDROGEN↗

DOE OSTI2020

BESS-STAIR: a framework to estimate daily, 30m, and all-weather crop evapotranspiration using multi-source satellite data for the US Corn Belt

Abstract. With increasing crop water demands and drought threats, mapping andmonitoring of cropland evapotranspiration (ET) at high spatial and temporalresolutions become increasingly critical for water management andsustainability. However, estimating ET from satellites for precise waterresource management is still challenging due to the limitations in bothexisting ET models and satellite input data. Specifically, the process of ETis complex and difficult to model, and existing satellite remote-sensing datacould not fulfill high resolutions in both space and time. To address theabove two issues, this study presents a new high spatiotemporal resolution ETmapping framework, i.e., BESS-STAIR, which integrates a satellite-drivenwater–carbon–energy coupled biophysical model, BESS (Breathing Earth SystemSimulator), with a generic and fully automated fusion algorithm, STAIR(SaTallite dAta IntegRation). In this framework, STAIR provides daily 30'mmultispectral surface reflectance by fusing Landsat and MODIS satellite datato derive a fine-resolution leaf area index and visible/near-infrared albedo,all of which, along with coarse-resolution meteorological and CO 2 data, are used to drive BESS to estimate gap-free 30 m resolution daily ET.We applied BESS-STAIR from 2000 through 2017 in six areas across the US CornBelt and validated BESS-STAIR ET estimations using flux-tower measurementsover 12 sites (85 site years). Results showed that BESS-STAIR daily ETachieved an overall R2=0.75, with root mean square error RMSE=0.93 mm d -1 and relative error RE =27.9 % when benchmarkedwith the flux measurements. In addition, BESS-STAIR ET estimations capturedthe spatial patterns, seasonal cycles, and interannual dynamics well indifferent sub-regions. The high performance of the BESS-STAIR frameworkprimarily resulted from (1) the implementation of coupled constraints onwater, carbon, and energy in BESS, (2) high-quality daily 30 m data from theSTAIR fusion algorithm, and (3) BESS's applicability under all-skyconditions. BESS-STAIR is calibration-free and has great potentials to be areliable tool for water resource management and precision agricultureapplications for the US Corn Belt and even worldwide given the globalcoverage of its input data.

54 ENVIRONMENTAL SCIENCES↗

DOE OSTI2020

Water and Ammonia Desorption from 5A Zeolite

Demonstrate adsorption and desorption characteristics of water and ammonia on 5A zeolite during regeneration conditions using a Thermogravimetric analyzer (TGA) on samples previously evaluated by residual gas analyzer (RGA)/mass balance. Molecular sieve (zeolite) adsorbents have the following characteristics: Crystalline alumino-silicates containing pores or 'cages' that adsorb water or other molecules. Polar compound are adsorbed with high loading even at very low concentrations of the fluid. A 5A molecular sieve was chosen for its ability to adsorb both water and ammonia (NH{sub 3}) from a carrier gas stream. Preliminary RGA/mass balance testing indicated: 5A zeolite captured both NH{sub 3} and water as anticipated based on molecular size; Reloading showed limited success after zeolite heated beyond manufacturer recommended operating conditions: Steam dealumination theorized cause; Tests were reprioritized to focus on NH{sub 3} removal and end of life potential holdup of NH{sub 3} and water on 5A zeolite material. TGA measures a sample's weight and volatile composition as it is heated or cooled in a furnace. TGA heats sample to release volatile materials, (change in mass is measured). MS detects/measures low levels of impurities. Perform TGA desorption of zeolite samples taken at the following conditions tested with RGA (RGA results not shown here): Initial Bakeout conditions: hydrogen carrier gas, slowly raise temp to approximately 300 deg. C until desired moisture content <<100 ppm is achieved. Water loading (re-loading): argon carrier gas through bubbler until breach is observed. Ammonia loading (re-loading): hydrogen carrier gas through system. Regenerations/End of life conditions: hydrogen carrier gas, raise temp to approximately 300 deg. C, then slowly to 450 deg. C (end of life). After end of life testing less than 4% of the total mass was residual ammonia or water at bakeout conditions. Peak water and ammonia removal occurred around 275 deg. C and 150 deg. C respectively.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

DOE OSTI2023

Geoelectric Characterization of Hyporheic Exchange Flow in the Bedrock‐Lined Streambed of East Fork Poplar Creek, Oak Ridge, Tennessee

Abstract A multimethod geoelectric survey was implemented between January and March 2022 along a 220‐m long reach of the bedrock‐lined streambed of East Fork Poplar Creek in Oak Ridge, Tennessee to identify locations of surface‐water and groundwater exchange and characterize the subsurface flow paths that convey water between the stream and flood plain. A waterborne self‐potential (WaSP) survey was completed in January 2022 to measure the electric streaming‐potential field in the stream. Electric resistivity tomography (ERT) was performed in March 2022 on the flood plain adjacent to the WaSP survey reach to map the electric resistivity distribution and characterize the hydrogeology and subsurface flow paths that facilitate surface‐water and groundwater exchange in the bedrock‐lined stream. The combination of WaSP and ERT data support the qualitative interpretation that surface‐water and groundwater exchange likely occurs along fractures in outcropping bedrock and along two fault lines that intersect the limestone creek bed.

54 ENVIRONMENTAL SCIENCES↗

DOE OSTI2024

Advanced Frost Sensor for HVAC Applications

Frost is a common problem in heating, ventilation, and air conditioning (HVAC) systems that can degrade their efficiencies, leading to excessive electricity consumption. Appropriate defrosting is therefore essential for heat pumps and refrigeration systems. However, these systems typically run the defrost cycle based on a predetermined time interval, a method that does not accurately identify the amount of frost and thus consume excessive electricity. To substantially improve defrosting initiation and termination, this paper describes development of a smart sensor based on a capacitive sensing technique that can quantify frost accumulation and difference between frost, ice, and water. The reported sensor adopts interdigitated comb electrodes and can be updated to a potential multifunctional sensor array for the enhancing identification of frost, ice, and water with the integrated measurement of surface temperature, frost capacitance, and resistance. The proposed frost sensor is potentially expected to have widespread applications in HVAC systems, including heat pumps, refrigerators, and commercial refrigeration systems.

Gao, Zhiming↗

DOE OSTI2022

Best Practices in PEC Water Splitting: How to Reliably Measure Solar-to-Hydrogen Efficiency of Photoelectrodes

Photoelectrochemical (PEC) water splitting, which utilizes sunlight and water to produce hydrogen fuel, is potentially one of the most sustainable routes to clean energy. One challenge to success is that, to date, similar materials and devices measured in different labs or by different operators lead to quantitatively different results, due to the lack of accepted standard operating procedures and established protocols for PEC efficiency testing. With the aim of disseminating good practices within the PEC community, we provide a vetted protocol that describes how to prepare integrated components and accurately measure their solar-to-hydrogen (STH) efficiency (η STH ). This protocol provides details on electrode fabrication, η STH test device assembly, light source calibration, hydrogen evolution measurement, and initial material qualification by photocurrent measurements under monochromatic and broadband illumination. Common pitfalls in translating experimental results from any lab to an accurate STH efficiency under an AM1.5G reference spectrum are discussed. A III–V tandem photocathode is used to exemplify the process, though with small modifications, the protocol can be applied to photoanodes as well. Dissemination of PEC best practices will help those approaching the field and provide guidance for comparing the results obtained at different lab sites by different groups.

08 HYDROGEN↗

NASA NTRSDate not supplied

Unbounded Learning Environments as an Approach to Preserving Design Flexibility Demonstrated With Nasa Stem Enhancement in Earth Science (SEES) Students

The Artemis Lunar program is providing opportunity for young scientists and engineers to contribute towards leading edge design concepts regarding early on-surface work areas that are aligned with major national initiatives. Therefore, it is imperative in any discovery process that those young scientists and engineers be provided the bandwidth or operating in a ‘greenfield’ technology environment that encourages new ideas, and perhaps the discovery of ideas that would not be realized within typical structured engineering constraints. To facilitate this concept, the use of unbounded teaching methods was utilized to provide a low-constraint environment from which students can design and discover the requirements that are bounded by the natural environment of the lunar surface, and then build up design requirements un-hindered by budgetary and/or logistics realizations of the moment funding capabilities. Specifically, this design exercise provided the students to operate with unlimited budgets, and unlimited up-mass lifts to the lunar surface to develop a preliminary feasible process for establishing a working lunar research based upon the near-area permanently shadowed regions within the lunar surface. In concept, working near PSRs will be advantageous as they receive near eternal shielding from solar radiation and may potentially host numerous volatile substances such as water ice, methane, hydrogen sulfide and helium-3 that will be the target of scientific investigation and in-situ resource utilization ISRU. The advantage of an upstream working area is that the quality of return materials could potentially be exponential when including an upstream analysis prior to earth-return missions. Furthermore, it’s well known within the scientific and engineering community that working with the base materials in front of human eyes elucidates new features and observations that may not survive when stored and shipped to Earth. Finally, it is theorized that these methods and techniques developing on the lunar surface would be applicable to other planets or cometary surfaces.

Education↗

DOE OSTI2020

Geothermal Deep Direct Use for Turbine Inlet Cooling in East Texas

The National Renewable Energy Laboratory (NREL), the Southern Methodist University Geothermal Laboratory (SMU), Eastman Chemical (Longview, TX), and TAS (Houston, TX) evaluated the feasibility of using geothermal heat to improve the performance of a natural-gas power plant in East Texas. The area of interest is the Eastman Chemical plant in Longview, Texas, which is on the northwestern margin of a geologic region known as the Sabine Uplift. The feasibility study focused on determining the potential for accessing a subsurface hot-water geothermal resource within a 10-km radius of the site to provide thermal energy for absorption chillers. Wells within a 20-km radius are included for broader geological comparison to determine the heat flow, temperature-at-depth, field porosity and permeability. The lithologies of most interest are the Lower Cretaceous Trinity Group and Upper Jurassic Cotton Valley Group. The deeper Cotton Valley formations are hotter (averaging 117 to 130°C), yet permeability and porosity are low. The shallower Trinity Group contains more variability in permeability and porosity and lower temperatures averaging about 98 to 117°C. The shallower formations are considered despite the lower temperature because of increased ability to produce larger volumes of water and extract enough heat before reinjection. The complete SMU analysis is available in the National Geothermal Data System (NGDS). Tapping such deep geothermal sources for direct heating (as opposed to power generation) is known as geothermal deep direct use (DDU). Geothermal DDU has potential across a wide swath of the United States but is underutilized due to challenging project economics associated with developing a deep geothermal resource for what are typically small-scale, variable-demand projects. This project examines the feasibility of geothermal energy integration in a natural-gas combined cycle power station in East Texas. The DDU resource is tapped to drive absorption chillers (24/7) for production of chilled water at 5-10°C (41-50°F). This chilled water is stored until needed, which allows for continuous operation with a relatively small-capacity geothermal/absorption chiller system. When conditions are favorable, the chilled water is dispatched to cool the air entering the compressor stage of a gas combustion turbine. This process, known as turbine inlet cooling (TIC), boosts power production during periods of high temperature and high-power demand. Such systems can enhance grid reliability and reduce the cost for peak-demand power. A simulation model of the power plant was developed in IPSEpro software and validated against operational data from the plant. This model allowed the team to estimate the additional power that could be produced by applying TIC under different operating and ambient conditions. Absorption chiller performance was estimated from vendor sources to determine the production rate of chilled water from the geothermal resource. Geothermal drilling and development costs were estimated using NREL's GEOPHIRES 2.0. The expected lower drilling costs in this region led to an estimated cost of geothermal heat of about $4/MMBtu (1.4 cents/kWh t ). The estimated cost for the absorption chillers and TIC hardware were obtained from literature sources and project partners. Hourly data were obtained for weather, natural gas and electricity prices, and plant operating state for 2017, which served as a representative year. NREL estimated the capital cost, operating cost, and additional electricity production and revenue for different combinations of geothermal capacity, chiller capacity, and water storage-tank size. The analysis drove toward smaller geothermal and chiller systems to reduce equipment cost. A relatively low-cost water storage tank accumulated the near-continuous chilled water output for later use when TIC was most valued.

15 GEOTHERMAL ENERGY↗

DOE OSTI2023

Chemical impacts of subsurface CO 2 and brine on shallow groundwater quality

Leakage from geologic CO 2 sequestration (GCS) sites to overlying shallow drinking water aquifers is a tangible risk. A primary purpose of this study is to assess the potential impacts of CO 2 leakage into a fresh-water aquifer with associated CO 2 -water-sediment interactions. Here, the study site is the Ogallala aquifer overlying an active demonstration-scale GCS site in north Texas, USA. Using the results of combined batch experiments and reactive transport simulations, we discuss the effects of salinity on potential trace metal release and the potential for groundwater quality recovery after leakage ceases.

54 ENVIRONMENTAL SCIENCES↗

NASA NTRSDate not supplied

To Biocide or not to Biocide? Exploring the "No Biocide" Option in Spacecraft Potable Water Systems

Residual biocide has been used to protect against microbial growth in spacecraft potable water systems since the Gemini program. Iodine, the biocide currently used on the International Space Station (ISS) has a long history of use but presents a few challenges for exploration: it must be removed using a consumable absorbent before crew consumption and is known to lose its biocidal concentration due to interactions with wetted components, especially during periods of dormancy. Biocidal silver is being considered for exploration missions as it is safe for crew consumption, but it too has challenges with proper material design to maintain sufficient disinfection residuals. An idea proposed by some in the Environmental Control and Life Support System (ECLSS) community has been that the biocide does not provide a true barrier against microbial growth, and therefore, perhaps the challenges of maintaining a residual biocide in the system could be best overcome by removing the biocide altogether. In this argument, they point to the regenerative water treatment system on the ISS which produces high purity water that theoretically meets the microbiological requirements before the iodine is added. Exploration water processing systems are expected to have similar water processing capabilities. This paper will discuss the role that residual biocide may play in controlling microbial growth and presents perspectives on the potential risks associated with removing it from exploration water systems.

biocide↗

NASA NTRSDate not supplied

To Biocide or not to Biocide? Exploring the "No Biocide" Option in Spacecraft Potable Water Systems

Residual biocide has been used to protect against microbial growth in spacecraft potable water systems since the Gemini program. Iodine, the biocide currently used on the International Space Station (ISS) has a long history of use but presents a few challenges for exploration: it must be removed using a consumable absorbent before crew consumption and is known to lose its biocidal concentration due to interactions with wetted components, especially during periods of dormancy. Biocidal silver is being considered for exploration missions as it is safe for crew consumption, but it too has challenges with proper material design to maintain sufficient disinfection residuals. An idea proposed by some in the Environmental Control and Life Support System (ECLSS) community has been that the biocide does not provide a true barrier against microbial growth, and therefore, perhaps the challenges of maintaining a residual biocide in the system could be best overcome by removing the biocide altogether. In this argument, they point to the regenerative water treatment system on the ISS which produces high purity water that theoretically meets the microbiological requirements before the iodine is added. Exploration water processing systems are expected to have similar water processing capabilities. This paper will discuss the role that residual biocide may play in controlling microbial growth and presents perspectives on the potential risks associated with removing it from exploration water systems.

biocide↗

NASA NTRSDate not supplied

To Biocide or Not to Biocide? Exploring the "No Biocide" Option in Spacecraft Potable Water Systems

Residual biocide has been used to protect against microbial growth in spacecraft potable water systems since the Gemini program. Iodine, the biocide currently used on the International Space Station (ISS) has a long history of use but presents a few challenges for exploration: it must be removed using a consumable absorbent before crew consumption and is known to lose its biocidal concentration due to interactions with wetted components, especially during periods of dormancy. Biocidal silver is being considered for exploration missions as it is safe for crew consumption, but it too has challenges with proper material design to maintain sufficient disinfection residuals. An idea proposed by some in the Environmental Control and Life Support System (ECLSS) community has been that the biocide does not provide a true barrier against microbial growth, and therefore, perhaps the challenges of maintaining a residual biocide in the system could be best overcome by removing the biocide altogether. In this argument, they point to the regenerative water treatment system on the ISS which produces high purity water that theoretically meets the microbiological requirements before the iodine is added. Exploration water processing systems are expected to have similar water processing capabilities. This paper will discuss the role that residual biocide may play in controlling microbial growth and presents perspectives on the potential risks associated with removing it from exploration water systems.

biocide↗

NASA NTRSDate not supplied

To Biocide or Not to Biocide? Exploring the "No Biocide" Option in Spacecraft Potable Water Systems

Residual biocide has been used to protect against microbial growth in spacecraft potable water systems since the Gemini program. Iodine, the biocide currently used on the International Space Station (ISS) has a long history of use but presents a few challenges for exploration: it must be removed using a consumable absorbent before crew consumption and is known to lose its biocidal concentration due to interactions with wetted components, especially during periods of dormancy. Biocidal silver is being considered for exploration missions as it is safe for crew consumption, but it too has challenges with proper material design to maintain sufficient disinfection residuals. An idea proposed by some in the Environmental Control and Life Support System (ECLSS) community has been that the biocide does not provide a true barrier against microbial growth, and therefore, perhaps the challenges of maintaining a residual biocide in the system could be best overcome by removing the biocide altogether. In this argument, they point to the regenerative water treatment system on the ISS which produces high purity water that theoretically meets the microbiological requirements before the iodine is added. Exploration water processing systems are expected to have similar water processing capabilities. This paper will discuss the role that residual biocide may play in controlling microbial growth and presents perspectives on the potential risks associated with removing it from exploration water systems.

biocide↗

DOE OSTI2022

The Press and Pulse of Climate Change: Extreme Events in the Colorado River Basin

Extremes in temperature and precipitation are associated with damaging floods, prolonged drought, destructive wildfires, agricultural challenges, compromised human health, vulnerable infrastructure, and threatened ecosystems and species. Often, the steady and progressive trends (or presses) of rising global temperature are the central focus in how climate impacts are described. However, observations of extreme weather events (or pulses) increasingly show that the intensity, duration and/or frequency of acute events are also changing, resulting in greater impacts on communities and the environment. Describing how the influence of extreme events may shape water management in the Colorado River Basin in clear terms is critical to sound future planning and efforts to manage risk. Three scenario planning workshops in 2019 and 2020 were held as part of a Colorado River Conversations series, identifying potential impacts from multiple intersecting extreme events. Water managers identified climate-related events of concern in the Colorado River Basin that necessitate greater attention and adaptive responses. To support efforts to include consideration of climate-change-driven extremes in water management and planning, we explore the current state of knowledge at the confluence of long-term climate shifts and extreme weather in the Colorado River Basin related to the events of concern that were identified by scenario planning participants.

54 ENVIRONMENTAL SCIENCES↗

NASA NTRS1986

Satellite data in aquatic area research - Some ideas for future studies

Attempts to apply aquatic remote sensing to the preparation of parametric map-like presentations, quantitative evaluations and time-related investigations in various water areas in Finland are presented. The potential use of Landsat MSS data in aquatic area studies, including limology, aquatic botany, geomorphology and engineering is evaluated using computer-aided digital remote sensing techniques. MSS data may provide information about depth, Secchi disc values, humus content in water, and productivity. Aquatic vegetation classification using MSS is possible only where vegetation units are large enough in respect to the 0.5 hectares ground resolution. Multitemporal satellite imagery has been used to evaluate alterations in the littoral areas of some Finnish water reservoirs between successive periods of high water. It is concluded that although MSS data can be of use in aquatic studies, it should be used in connection with field data and/or TM and SPOT data.

Raitala, Jouko T.↗