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At least 1,189 records · Page 66

Broad-band polarization in molecular spectra

The rotational lines of the CN(0,0) red system have been observed to show a strongly asymmetric Zeeman profile. Certain molecules are very susceptible to magnetic perturbation because of the weakness of their spin-rotation coupling; a fairly weak magnetic field can cause a complete Paschen-Back effect. The calculation of transition probabilities incorporating this effect into the Hamiltonian is discussed, and the detailed calculation is then given. The resulting transition probabilities are transformed into synthetic line profiles by using the Unno (1956) model of polarized radiation transfer. The dependence of the net polarized flux on magnetic field and equivalent width is investigated. It is shown that entire band systems may be significantly polarized. Broad-band circular polarization of sunspots may be due, in part, to molecular bands. Analysis of the CH G band indicates a magnetic field of 0.25-0.50 x 10 to the 6th gauss in the white dwarf G99-37, an order of magnitude lower than previous estimates.

Illing, R. M. E.↗

Theoretical studies of AlF, AlCl, and AlBr

Spectroscopic constants have been obtained for the lowest six singlet and lowest five triplet states of AlF and AlCl. The results suggest that the correct ordering of the triplet manifold in these molecules is: a 3Pi, b 3Sigma(+), c 3Sigma(+), d 3Pi, and e 3Delta. Radiative lifetimes have been determined for the excited states, and the A 1Pi to X 1Sigma(+) transition in AlF, AlCl, and AlBr has been examined in detail. A-X transition moment functions, Einstein coefficients, and A 1Pi vibrational lifetimes have been obtained for AlF and AlCl.

Langhoff, Stephen R.↗

Atmospheric Trace Molecule Spectroscopy (ATMOS)

The Atmospheric Trace Molecule Spectroscopy (ATMOS) experiment is a space-borne investigation designed to obtain fundamental information related to the chemistry and physics of the earth's upper atmosphere (20 to 120 km altitude). The instrument, a high resolution (0.01/cm) interferometric spectrometer, measures the atmospheric absorption of solar radiation over the wavelength range from 2 to 16 micrometers, a spectral band which encompasses active transitions of all of the molecular species of current importance in upper atmospheric studies. There are two major aspects to the experiment: (1) the determination of the detailed compositional structure of the stratosphere and mesosphere, and its global, seasonal, and long-term variability; and (2) the study of the partitioning of absorbed solar energy at levels in the atmosphere characterized by dissociation of many of the constituents and by the breakdown of thermodynamic equilibrium. Characteristics of ATMOS are given. This experiment will be part of the atmospheric science research payload flown on the Atmospheric Laboratory for Applications and Science (ATLAS 1) NASA mission planned for late 1990.

Farmer, C. B.↗

Noise considerations for tiltrotor

A projection is made of the technology-development requirements faced by aircraft designers contemplating the evolution of V-22-type tilt-rotor aircraft technology into a civilian tilt-rotor commuter aircraft of the requisite scale and payload. These research challenges are noted to often involve the reduction of noise level to values tolerated by passengers within the cabin and communities in the vicinity of airports, especially during hover and in the course of transition from vertical to horizontal flight (and vice-versa). Noise-generation and noise-radiation characteristics research has been undertaken using the XV-15 tilt-rotor proof-of-concept aircraft.

Huston, Robert J.↗

VLA observations of the coronal plasma

VLA observations at 20 cm wavelength specify the brightness temperature and magnetic structure of plasma constrained within coronal loops in solar active regions. Comparisons with simultaneous SMM observations at soft x ray wavelengths lead to measurements of physical parameters like electron density, electron temperature and magnetic field strength. Such comparisons also indicate coronal loops can be detected at either radio or x ray wavelengths while remaining invisible in the other spectral domain, and that the dominant radiation mechanisms can be thermal bremsstrahlung or thermal gyroresonance radiation. VLA observations at the longer 90 cm wavelength reveal the thermal emission of a hot transition sheath enveloping a cooler, underlying H alpha filament seen in absorption. The 20 cm VLA observations indicate that the precursor, impulsive and post-flare components of solar flares originate in spatially separated and resolved sources. The 90 cm VLA data indicate that time-correlated radio bursts can occur in active regions on opposite sides of the solar equator. These regions are apparently linked by large scale, trans-equatorial magnetic loops at least 2.6 x 10(exp 5) km (or 6 feet) long; these loops act as magnetic conduits for relativistic electrons moving at one-third the velocity of light.

Lang, Kenneth R.↗

VLA observations of the coronal plasma

VLA observations at 20 cm wavelength specify the brightness temperature and magnetic structure of plasma constrained within coronal loops in solar active regions. Comparisons with simultaneous SMM observations at soft X-ray wavelengths lead to measurements of physical parameters like electron density, electron temperature and magnetic field strength. Such comparisons also indicate coronal loops can be detected at either radio X-ray wavelengths while remaining invisible in the other spectral domain and that the dominant radiation mechanisms can be thermal bremsstrahlung or thermal gyroresonance radiation. VLA observations at the longer 90 cm wavelength reveal the thermal emission of a hot transition sheath enveloping a cooler, underlying H alpha filament seen in absorption. The 20 cm VLA observations indicate that the precursor, impulsive and post-flare components of solar flares originate in spatially separated and resolved sources. The 90 cm VLA data indicate that time-correlated radio bursts can occur in active regions on opposite sides of the solar equator. These regions are apparently linked by large scale, trans-equatorial magnetic loops at least 2.6 x 10(exp 5) km (or 6 feet) long; these loops act as magnetic conduits for relativistic electrons moving at one-third the velocity of light.

Lang, Kenneth R.↗

Nuclear concepts/propulsion

Nuclear thermal and nuclear electric propulsion systems will enable and/or enhance important space exploration missions to the moon and Mars. Current efforts are addressing certain research areas, although NASA and DOE still have much work yet to do. Relative to chemical systems, nuclear thermal propulsion offers the potential of reduced vehicle weight, wider launch windows. and shorter transit times, even without aerobrakes. This would improve crew safety by reducing their exposure to cosmic radiation. Advanced materials and structures will be an important resource in responding to the challenges posed by safety and test facility requirements, environmental concerns, high temperature fuels and the high radiation, hot hydrogen environment within nuclear thermal propulsion systems. Nuclear electric propulsion (NEP) has its own distinct set of advantages relative to chemical systems. These include low resupply mass, the availability of large amounts of onboard electric power for other uses besides propulsion, improved launch windows, and the ability to share technology with surface power systems. Development efforts for NEP reactors will emphasize long life operation of compact designs. This will require designs that provide high fuel burnup and high temperature operation along with personnel and environmental safety.

Miller, Thomas J.↗

The Low-Lying States of AlCu and AlAg

The singlet and triplet states of AlCu and AlAg below about 32 000/cm are studied using the internally contracted multireference configuration-interaction method. A more elaborate study of the X(sup 1)Sum(sup +) ground state of AlCu is undertaken using extended Gaussian basis sets, including the effect of inner-shell correlation and including a perturbational estimate of relativistic effects. Our best estimate of the spectroscopic constants (r(sub 0), DeltaG(sub 1/2), and D(sub 0)) for the X(sup 1)Sum(sup+) state with the experimental values in parentheses are: 4.416(4.420) a(sub 0), 295 (294) /cm, and 2.318 (2.315) eV. The calculations definitively assign the upper state in the observed transition at 14 892/cm to the lowest (sup 1)Prod state. The calculated spectroscopic constants and radiative lifetime for the (sup 1)Prod state are in good agreement with experiment. The calculations support the tentative assignments of Behm et al. for three band systems observed in the visible region between 25 000 and 28 000 / cm. However, the computed spectroscopic constants are in very poor agreement with those deduced from an analysis of the spectra. Analogous theoretical results for AlAg suggest that the (2)(sup 3)Prod, (3)(sup 3)Prod, and (3)(sup 1)Sum(sup +) states account for the bands observed, but not assigned, by Duncan and co-workers.

Bauschlicher, Charles W., Jr.↗

An Empirical Model of Coronal Heating Deduced from SOHO Observations of Transition Region Dynamics

The research carried out under the above award was concerned with the analysis of "explosive events" in the solar atmosphere. Explosive events are small energy releases that reveal themselves as skewed, broadened line profiles in the 10(exp 5) K degree material of the solar transition region. Using a data set of such events from the Solar Ultraviolet Measurements of Emitted Radiation (SUMER) instrument on the NASA SoHo satellite, with unprecedented temporal, spatial and spectral resolution, we have evaluated (Winebarger, Emslie, Mariska, & Warren 1999, Ap. J., 526, 471) the energetics of these events through application of the Velocity Differential Emission Measure (VDEM) analysis technique introduced by Newton, Emslie & Mariska, (1995, Ap. J, 447, 915). This work has allowed us to evaluate the contribution of various terms (such as enthalpy flux, free-streaming of high-energy electrons, etc.) to the energy budget of these events.

Emslie, A. Gordon↗

Biomedical Aspects of Lunar and Mars Exploration Missions

Recent long-range planning for exploration-class missions has emphasized the need for anticipating the medical and human factors aspects of such expeditions. Missions returning Americans to the moon for stays of up to 6 months at a time will provide the opportunity to demonstrate the means to function safely and efficiently on another planet. Details of mission architectures are still under study, but a typical Mars design reference mission comprises a six-month transit from Earth to Mars, eighteen months in residence on Mars, and a six-month transit back to Earth. Physiological stresses will come from environmental factors such as prolonged exposure to radiation, weightlessness en route to Mars and then back to Earth, and low gravity and a toxic atmosphere while on Mars. Psychological stressors will include remoteness from Earth, confinement, and potential interpersonal conflicts, all complicated by circadian alterations. Medical risks including trauma must be considered. The role of such risk-modifying influences as artificial gravity and improved propulsion technologies to shorten round-trip time will also be discussed. Results of planning for assuring human health and performance will be presented.

Charles, John B.↗

An Ultrasensitive Hot-Electron Bolometer for Low-Background SMM Applications

We are developing a hot-electron superconducting transition-edge sensor (TES) that is capable of counting THz photons and operates at T = 0.3K. The main driver for this work is moderate resolution spectroscopy (R approx. 1000) on the future space telescopes with cryogenically cooled (approx. 4 K) mirrors. The detectors for these telescopes must be background-limited with a noise equivalent power (NEP) approx. 10(exp -19)-10(exp -20) W/Hz(sup 1/2) over the range v = 0.3-10 THz. Above about 1 THz, the background photon arrival rate is expected to be approx. 10-100/s), and photon counting detectors may be preferable to an integrating type. We fabricated superconducting Ti nanosensors with a volume of approx. 3x10(exp -3) cubic microns on planar substrate and have measured the thermal conductance G to the thermal bath. A very low G = 4x10(exp -14) W/K, measured at 0.3 K, is due to the weak electron-phonon coupling in the material and the thermal isolation provided by superconducting Nb contacts. This low G corresponds to NEP(0.3K) = 3x10(exp -19) W/Hz(sup 1/2). This Hot-Electron Direct Detector (HEDD) is expected to have a sufficient energy resolution for detecting individual photons with v > 0.3 THz at 0.3 K. With the sensor time constant of a few microseconds, the dynamic range is approx. 50 dB.

bolometers↗

Fabrication of Compact Superconducting Lowpass Filters for Ultrasensitive Detectors

It is extremely important for current and future far-infrared and sub-millimeter ultrasensitive detectors, which include transition edge sensors (TES) and microwave kinetic inductance detectors, to be adequately filtered from stray electromagnetic radiation in order to achieve their optimal performance. One means of filtering stray radiation is to block leakage associated with electrical connections in the detector environment. Here we discuss a fabrication methodology for realizing non-dissipative planar filters imbedded in the wall of the detector enclosure to limit wave propagation modes up to far-infrared frequencies. Our methodology consists of fabricating a boxed stripline transmission line, in which a superconducting (Nb, Mo, or Al) transmission line is encased in a silicon dioxide dielectric insulator coated with a metallic shell. We report on achieved attenuation and return loss and find that it replicates the simulated data to a high degree.

Brown, Ari↗

An Enhanced Seasonal Transition that Intensified Summer Drought in the Central U.S.

Precipitation in the central U.S. decreases by about 25% during the seasonal transition from June to July, and this precipitation decrease has been observed to have intensified since 1979. Such an intensification could enhance future spring drought occurrences such as was the case in the 2012 "flash drought" in the Midwestern U.S., where conditions evolved quickly from being abnormally dry to exceptionally dry within a mere month from June to July. In this study, various atmospheric and land reanalysis datasets were analyzed to examine the trend calculated from 1979 to 2012 in the June-to-July seasonal transition. It was found that the change in precipitation deficit was accompanied by increased downward shortwave radiation flux and tropospheric subsidence, enhanced evaporative fraction, as well as an elevated planetary boundary layer height. The change in the tropospheric circulation encompassed an anomalous ridge over the western U.S. and a trough on either side; this wave-form circulation pattern is known to induce dry conditions in the central U.S. Possibly, the trends in the June-to-July seasonal shifts in precipitation, drought severity and tropospheric circulation intensified the 2012 "flash drought" in timing and extent. The knowledge of the trends allows one to anticipate the evolution of spring onset of drought into the summer.

Drought↗

Direct Aerosol Radiative Effect Derived From CERES Data Products

The CERES team uses MODIS and VIIRS derived aerosol optical thickness to compute surface and in atmosphere irradiances. In producing the data products, aerosol optical thicknesses derived by Dark Target and Deep Blue algorithms are assimilated in an aerosol transport model. In addition, the aerosol transport model provides aerosol optical thicknesses under cloudy conditions and aerosol optical thicknesses over polar regions. These aerosol optical thicknesses are used for hourly irradiance computations in 11 grids. Global mean top-of-atmosphere direct aerosol radiative effects are -5.2 Wm-2 and -2.2 Wm-2 for, respectively, clear-sky and all-sky conditions. Spatial pattern of the trend of the computed clear-sky direct aerosol radiative effect agrees with that derived from CERES observations. In this presentation, the importance of seamless transition of aerosol optical thicknesses derived from MODIS to those derived from VIIRS is emphasized. Currently, the CERES team is working with MODIS dark target and deep blue teams to achieve the seamless transition in producing CERES Edition 4 data products.

Seiji Kato↗

Making Every Microgram Count: Nanocalorimetry for Nuclear and Ultra-Rare Materials

The thermal analysis of nuclear and ultra-rare materials plays an important role in nuclear energy, planetary, environmental, and technological settings. Heat effects associated with the sample temperature, heat capacity, phase transformation, radiation damage and crystallographic defects are some of the thermochemistry measurements made with conventional differential scanning calorimeters. However, the measurement capabilities of the of traditional DSCs are often restricted when studying limited ultra-rare accessory minerals or materials submitted to extreme conditions, such as radiation in the nuclear fuel cycle and high pressure. We investigate the usage of nanocalorimetry for the energetic analysis of nuclear or ultra-rare materials, such as irradiated materials and high-pressure phases, with an emphasis on radiation damage and heat capacity measurements. Examples of how nanocalorimetry has been previously used for phase transitions, melting, and nucleation in ultra-fast heating and cooling rates are presented. Finally, an outlook of the field and future work, including beneficial safety and environmental outcomes from the potential usage of nanocalorimetry, are shown.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

A Study of Space Environment Effect on Highly Thermally Conductive Hybrid Carbon Fiber Polymer Composites

A set of novel highly thermally conductive hybrid carbon fiber (CF) polymer composites has been developed for lightweight thermal radiator applications in space missions. This study investigates the effects of the space environment on these materials following exposure in low-Earth orbit (LEO) during the Materials International Space Station Experiment (MISSE)-17 flight mission, where samples experienced 159 days of combined atomic oxygen (AO), ultraviolet (UV) radiation, high vacuum, space radiation and thermal cycling. Post-flight characterization included weight loss, surface morphology, thermo-optical properties, molecular structures, glass transition temperature, thermal degradation and thermal conductivity analyses. The pyrolytic graphite sheet (PGS) samples exhibited negligible weight loss, stable thermo-optical property, and only minor oxidation signature on the exposed surface. Although AO erosion of the epoxy polymer matrix was evident, carbon nanotube (CNT)-infused PGS/CF epoxy composites retained high thermal emissivity and preserved their high thermal conductivities. These results demonstrate that the novel highly thermally conductive hybrid CF composites possess strong environmental resilience and are promising candidates for lightweight thermal radiators and thermal management components in future space exploration missions.

Space Environment↗

Atomic to molecular hydrogen transition in interstellar clouds

The photodestruction of molecular hydrogen is reexamined in the context of recent observational data. Improvements in the theory of radiation transfer are made by using a more accurate self-shielding integral, treating anisotropic scattering by dust grains, and including photodissociation from excited rotational states. The total column density of hydrogen required to obtain 10% conversion decreases with a parameter, epsilon, the ratio of the formation rate to the destruction rate, as epsilon to the -m power, with m in the range 1.4-1.6. Satisfactory agreement with the data for thicker diffuse clouds is obtained for epsilon of about 0.00006.

Federman, S. R.↗

The Radio-to-X-Ray Spectrum of GRB 970508 on 1997 May 21.0 UT

We have reconstructed the spectrum of the afterglow of GRB 970508 on 1997 May 21.0 UT (12.1 days after the gamma-ray burst) on the basis of observations spanning the X-ray-to-radio range. The low-frequency power-law index of the spectrum, alpha = 0.44 +/- 0.07 (F(sub nu) proportional to nu(exp alpha)), is in agreement with the expected value alpha = 1/3 for optically thin synchrotron radiation. The 1.4 GHz emission is self-absorbed. We infer constraints on the break frequencies nu(sub c) and nu(sub m) on 1997 May 21.0 UT from a spectral transition from F(sub nu) approx. nu(exp -0.6) to F(sub nu) approx. nu(exp -1.1) in the optical passband around 1.4 days. A model of an adiabatically expanding, blast wave emitting synchrotron radiation, in which a significant fraction of the electrons cool rapidly, provides a successful and consistent description of the afterglow observations over nine decades in frequency, ranging in time from trigger until several months later.

Galama, T. J.↗