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At least 1,171 records · Page 65

MARMOT update for oxide fuel modeling

This report summarizes the lower-length-scale research and development progresses in FY16 at Idaho National Laboratory in developing mechanistic materials models for oxide fuels, in parallel to the development of the MARMOT code which will be summarized in a separate report. This effort is a critical component of the microstructure based fuel performance modeling approach, supported by the Fuels Product Line in the Nuclear Energy Advanced Modeling and Simulation (NEAMS) program. The progresses can be classified into three categories: 1) development of materials models to be used in engineering scale fuel performance modeling regarding the effect of lattice defects on thermal conductivity, 2) development of modeling capabilities for mesoscale fuel behaviors including stage-3 gas release, grain growth, high burn-up structure, fracture and creep, and 3) improved understanding in material science by calculating the anisotropic grain boundary energies in UO$_2$ and obtaining thermodynamic data for solid fission products. Many of these topics are still under active development. They are updated in the report with proper amount of details. For some topics, separate reports are generated in parallel and so stated in the text. The accomplishments have led to better understanding of fuel behaviors and enhance capability of the MOOSE-BISON-MARMOT toolkit.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Process Systems Engineering-Informed Design and Scale-Up of Multi-stage Diafiltration Cascades for Lithium and Cobalt Recovery from Spent Lithium-Ion Batteries

These slides present work jointly completed by Tasks in PrOMMiS. The first half of the presentation motivates the importance of critical materials for national security and how the recovery of critical minerals via membrane separations can be more cost effective than currently used technology. The second half of the presentation presents cost-optimal results for the custom cost model for diafiltration using the superstructure flowsheet developed by CMU. These results highlight how PSE can inform process targets (i.e., product purity targets) and suitable design strategies for scaled-up membrane cascades.

critical materials↗

Cluster, classify, regress: A general method for learning discontinuous functions

This paper presents a method for solving the supervised learning problem in which the output is highly nonlinear and discontinuous. Here, it is proposed to solve this problem in three stages: (i) cluster the pairs of input-output data points, resulting in a label for each point; (ii) classify the data, where the corresponding label is the output; and finally (iii) perform one separate regression for each class, where the training data corresponds to the subset of the original input-output pairs which have that label according to the classifier. It has not yet been proposed to combine these 3 fundamental building blocks of machine learning in this simple and powerful fashion. This can be viewed as a form of deep learning, where any of the intermediate layers can itself be deep. The utility and robustness of the methodology is illustrated on some toy problems, including one example problem arising from simulation of plasma fusion in a tokamak.

96 KNOWLEDGE MANAGEMENT AND PRESERVATION↗

Effects of radiation environment on reusable nuclear shuttle system

Parametric tradeoff analyses of a wide spectrum of alternate tank configurations to minimize both primary and secondary, direct and scattered radiation sources emanating from the NERVA are reported. The analytical approach utilizing point kernel techniques is described and detailed data are presented on the magnitude of neutron/gamma doses for different locations. Single-tank configurations utilizing smaller cone angles and end cap radii were found to minimize integral radiation levels, hence, stage shielding-weight penalties for shuttle missions. Hybrid configurations employing an upper tank with a reduced cone angle and end cap radius result in low integral payload doses primarily due to the increased separation distance caused by the elongation of the larger capacity upper tank. A preliminary radiation damage assessment is discussed of possible reusable nuclear shuttle materials, components, and subsystems, and the possible effects of the radiation environment on various phases of RNS mission operations.

Lane, A. G.↗

Energy Efficient Engine Preliminary Design and Integration Studies

The technology and configurational requirements of an all new 1990's energy efficient turbofan engine having a twin spool arrangement with a directly coupled fan and low-pressure turbine, a mixed exhaust nacelle, and a high 38.6:1 overall pressure ratio were studied. Major advanced technology design features required to provide the overall benefits were a high pressure ratio compression system, a thermally actuated advanced clearance control system, lightweight shroudless fan blades, a low maintenance cost one-stage high pressure turbine, a short efficient mixer and structurally integrated engine and nacelle. A conceptual design analysis was followed by integration and performance analyses of geared and direct-drive fan engines with separate or mixed exhaust nacelles to refine previously designed engine cycles. Preliminary design and more detailed engine-aircraft integration analysis were then conducted on the more promising configurations. Engine and aircraft sizing, fuel burned, and airframe noise studies on projected 1990's domestic and international aircraft produced sufficient definition of configurational and advanced technology requirements to allow immediate initiation of component technology development.

Gray, D. E.↗

An analytical pilot rating method for highly elastic aircraft

An analytical method was developed to predict pilot ratings for highly elastic aircraft subject to severe mode interactions between rigid body and elastic dynamics. An extension of the standard optimal control model of pilot response was made to include the hypothesis that the pilot controls the system with an internal model consisting of the slowly varying part of the aircraft dynamics. This modified optimal control model was analytically evaluated for a longitudinal pitch tracking task on a large flexible aircraft. Parametric variations in the undamped natural frequencies of two symmetric elastic modes were made to induce varying amounts of mode interaction. The model proved successful in discriminating when the pilot can or cannot visually separate rigid from elastic pitch response in the turbulence excited tracking task. This method shows considerable promise in making it possible to investigate such mode interaction effects on handling qualities in the preliminary design stage of new aircraft.

Swaim, R. L.↗

Aerodynamic performance of a fan stage utilizing Variable Inlet Guide Vanes (VIGVs) for thrust modulation

An experimental research program was conducted in the Lewis Research Center's 9x15-foot (2.74x4.57 m) low speed wind tunnel to evaluate the aerodynamic performance of an inlet and fan system with variable inlet guide vanes (VIGVs) for use on a subsonic V/STOL aircraft. At high VIGV blade angles (lower weight flow and thrust levels), the fan stage was stalled over a major portion of its radius. In spite of the stall, fan blade stresses only exceeded the limits at the most extreme flow conditions. It was found that inlet flow separation does not necessarily lead to poor inlet performance or adverse fan operating conditions. Generally speaking, separated inlet flow did not adversely affect the fan blade stress levels. There were some cases, however, at high VIGV angles and high inlet angles-of-attack where excessive blade stress levels were encountered. An evaluation term made up of the product of the distortion parameter, K alpha, the weight flow and the fan pressure ratio minus one, was found to correlate quite well with the observed blade stress results.

Woollett, R. R.↗

Aerodynamic performance of a fan stage utilizing variable inlet guide vanes (VIGV's) for thrust modulation

An experimental research program was conducted in the Lewis Research Center's 9 x 15-foot (2.74 x 4.57 m) low speed wind tunnel to evaluate the aerodynamic performance of an inlet and fan system with variable inlet guide vanes (VIGVs) for use on a subsonic V/STOL aircraft. At high VIGV blade angles (lower weight flow and thrust levels), the fan stage was stalled over a major portion of its radius. In spite of the stall, fan blade stresses only exceeded the limits at the most extreme flow conditions. It was found that inlet flow separation does not necessarily lead to poor inlet performance or adverse fan operating conditions. Generally speaking, separated inlet flow did not adversely affect the fan blade stress levels. There were some cases, however, at high VIGV angles and high inlet angles-of-attack where excessive blade stress levels were encountered. An evaluation term made up of the product of the distortion parameter, K alpha, the weight flow and the fan pressure ratio minus one, was found to correlate quite well with the observed blade stress results. Previously announced in STAR as N83-27957

Woollett, R. R.↗

Facility and Methods Developed for Simulated Space Vacuum Ultraviolet Exposure Testing of Polymer Films

Vacuum ultraviolet (VUV) radiation of wavelengths between 115 and 200 nm produced by the Sun in the space environment can degrade polymer films, producing changes in their optical, mechanical, and chemical properties. These effects are particularly important for thin polymer films being considered for ultralightweight space structures, because, for most polymers, VUV radiation is absorbed in a thin surface layer. The NASA Glenn Research Center has developed facilities and methods for long-term ground testing of polymer films to evaluate space environmental VUV radiation effects. VUV exposure can also be used as part of combined or sequential simulated space environmental exposures to determine combined damaging effects with other aspects of the space environment, which include solar ultraviolet radiation, solar flare x-rays, electron and proton radiation, atomic oxygen (for low-Earth-orbit missions), and temperature effects. Because the wavelength sensitivity of VUV damage is not well known for most materials, Glenn's VUV facility uses a broad-spectrum deuterium lamp with a magnesium fluoride window that provides output between 115 and 200 nm. Deuterium lamps of this type were characterized by the National Institute of Standards and Technology and through measurements at Glenn. Spectral irradiance measurements show that from approximately 115 to 160 nm, deuterium lamp irradiance can be many times that of air mass zero solar irradiance, and as wavelength increases above approximately 160 nm, deuterium lamp irradiance decreases in comparison to the Sun. The facility is a cryopumped vacuum chamber that achieves a system pressure of approximately 5310(exp -6) torr. It contains four individual VUV-exposure compartments in vacuum, separated by water-cooled copper walls to minimize VUV radiation and any sample contamination cross interactions between compartments. Each VUV-exposure compartment contains a VUV deuterium lamp, a motor-controlled sample stage coupled with a moveable cesium iodide VUV phototube, and two thermocouples for temperature measurement. The vacuum chamber and exterior equipment is shown. Each VUV lamp is located at the top of the chamber with its projection-tube pushed through an O-ring compression fitting. The lamp assemblies are located on ports that can be isolated from the rest of the vacuum chamber, permitting maintenance or replacement of the lamps without breaking vacuum in the main chamber where the samples are located. A view of two of the four interior VUV-exposure compartments, including the moveable sample stages and detector holders is also shown. Glenn is using this facility to support testing of Next Generation Space Telescope sunshield materials that is being led by the NASA Goddard Space Flight Center and to develop an understanding of the wavelength, intensity, and temperature dependence of VUV-induced polymer degradation.

Dever, Joyce A.↗

A 90 GHz Amplifier Assembled Using Flip-Chip Technology

This letter reports the performance of a novel single-stage W-band amplifier fabricated utilizing flip-chip bump-bonding. We have bump-bonded a high-speed, low-noise InP high electron mobility transistor (HEMT) device onto a separately fabricated passive circuit having a GaAs substrate.

FET amplifiers Millimeter wave FETs bump-bonding m↗

Real-Time Detection Methods to Monitor TRU Compositions in UREX+Process Streams

The U.S. Department of Energy has developed advanced methods for reprocessing spent nuclear fuel. The majority of this development was accomplished under the Advanced Fuel Cycle Initiative (AFCI), building on the strong legacy of process development R&D over the past 50 years. The most prominent processing method under development is named UREX+. The name refers to a family of processing methods that begin with the Uranium Extraction (UREX) process and incorporate a variety of other methods to separate uranium, selected fission products, and the transuranic (TRU) isotopes from dissolved spent nuclear fuel. It is important to consider issues such as safeguards strategies and materials control and accountability methods. Monitoring of higher actinides during aqueous separations is a critical research area. By providing on-line materials accountability for the processes, covert diversion of the materials streams becomes much more difficult. The importance of the nuclear fuel cycle continues to rise on national and international agendas. The U.S. Department of Energy is evaluating and developing advanced methods for safeguarding nuclear materials along with instrumentation in various stages of the fuel cycle, especially in material balance areas (MBAs) and during reprocessing of used nuclear fuel. One of the challenges related to the implementation of any type of MBA and/or reprocessing technology (e.g., PUREX or UREX) is the real-time quantification and control of the transuranic (TRU) isotopes as they move through the process. Monitoring of higher actinides from their neutron emission (including multiplicity) and alpha signatures during transit in MBAs and in aqueous separations is a critical research area. By providing on-line real-time materials accountability, diversion of the materials becomes much more difficult. The objective of this consortium was to develop real time detection methods to monitor the efficacy of the UREX+ process and to safeguard the separated TRUs against unlawful diversion from within a processing facility. To achieve this, a comprehensive strategy was implemented to incorporate traditional detectors and advanced Tensioned Metastable Fluid (TMFD) metastable fluid detectors (developed, in part, under this project) into a novel detector assembly coupled to the UREX+ centrifugal contactor array. The sections below provide a brief summary of the technical achievements completed during this project. The principal outcomes are documented in more complete details contained the doctoral dissertations and masters theses, journal papers, conference proceedings and additional items for more than the 35 publications that are listed in the program bibliography in Section 3.

McDeavitt, Sean M.↗

Launch Order, Launch Separation, and Loiter in the Constellation 1 1/2-Launch Solution

The NASA Constellation Program (CxP) is developing a two-element Earth-to-Orbit launch system to enable human exploration of the Moon. The first element, Ares I, is a human-rated system that consists of a first stage based on the Space Shuttle Program's solid rocket booster (SRB) and an upper stage that consists of a four-crew Orion capsule, a service module, and a Launch Escape System. The second element, Ares V, is a Saturn V-plus category launch system that consists of the core stage with a cluster of six RS-68B engines and augmented with two 5.5-segment SRBs, a Saturn-derived J-2X engine powering an Earth Departure Stage (EDS), and the lunar-lander vehicle payload, Altair. Initial plans called for the Ares V to be launched first, followed the next day by the Ares I. After the EDS performs the final portion of ascent and subsequent orbit circularization, the Orion spacecraft then performs a rendezvous and docks with the EDS and its Altair payload. Following checkout, the integrated stack loiters in low Earth orbit (LEO) until the appropriate Trans-Lunar Injection (TLI) window opportunity opens, at which time the EDS propels the integrated Orion Altair to the Moon. Successful completion of this 1 1/2-launch solution carries risks related to both the orbital lifetime of the assets and the probability of achieving the launch of the second vehicle within the orbital lifetime of the first. These risks, which are significant in terms of overall system design choices and probability of mission success, dictated a thorough reevaluation of the launch strategy, including the order of vehicle launch and the planned time period between launches. The goal of the effort described in this paper was to select a launch strategy that would result in the greatest possible expected system performance, while accounting for launch risks and the cost of increased orbital lifetime. Discrete Event Simulation (DES) model of the launch strategies was created to determine the probability of a second launch not occurring in a timely fashion (i.e., before the assets waiting in LEO expire). An overview of the launch strategy evaluation process is presented, along with results of specific cases that were analyzed. A high-level comparison of options is then presented, along with the conclusion derived from the analysis.

Stromgren, Chel↗

Life cycle assessment of construction and demolition waste management

Highlights: • LCA of C&DW utilisation in road vs. C&DW landfilling. • C&DW utilisation in road better than landfilling for most categories. • Transportation is the most important process in non-toxic impact categories. • Leaching of oxyanions is the critical process in toxic impact categories. • Modelling of Cr fate in the subsoil is highly influential to the results. - Abstract: Life cycle assessment (LCA) modelling of construction and demolition waste (C&DW) management was carried out. The functional unit was management of 1 Mg mineral, source separated C&DW, which is either utilised in road construction as a substitute for natural aggregates, or landfilled. The assessed environmental impacts included both non-toxic and toxic impact categories. The scenarios comprised all stages of the end-of-life management of C&DW, until final disposal of all residues. Leaching of inorganic contaminants was included, as was the production of natural aggregates, which was avoided because of the use of C&DW. Typical uncertainties related to contaminant leaching were addressed. For most impact categories, utilisation of C&DW in road construction was preferable to landfilling; however, for most categories, utilisation resulted in net environmental burdens. Transportation represented the most important contribution for most nontoxic impacts, accounting for 60–95 per cent of these impacts. Capital goods contributed with negligible impacts. Leaching played a critical role for the toxic categories, where landfilling had lower impacts than utilisation because of the lower levels of leachate per ton of C&DW reaching the groundwater over a 100-year perspective. Leaching of oxyanions (As, V and Sb) was critical with respect to leaching. Typical experimental uncertainties in leaching data did not have a pivotal influence on the results; however, accounting for Cr immobilisation in soils as part of the impact assessment was critical for modelling the leaching impacts. Compared with the overall life cycle of building and construction materials, leaching emissions were shown to be potentially significant for toxicity impacts, compared with contributions from production of the same materials, showing that end-of-life impacts and leaching should not be disregarded when assessing environmental impacts from construction products and materials. CO{sub 2} uptake in the C&DW corresponding to 15 per cent carbonation could out-balance global warming impacts from transportation; however, carbonation would also likely result in increased toxicity impacts due to higher leaching of oxyanions.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Tunnel diode resonator for precision magnetic susceptibility measurements in a mK temperature range and large DC magnetic fields

Precision radio-frequency measurements of the magnetic susceptibility using the tunnel diode resonator (TDR) technique are used to study the delicate effects in magnetic and superconducting materials. High resolution (in ppb range) measurements are particularly important for studies of the London and Campbell penetration depths in a superconductor and for the investigation of magnetic transitions in (anti)ferromagnets. Due to the small rf magnetic-excitation in a mOe range, the TDR is especially useful at low-temperatures in a mK range, if Joule heating generated in the TDR circuitry is efficiently removed and the circuit is stabilized with sub-mK precision. Unfortunately, the circuit has significant magnetic field dependence, and therefore, most of the precision TDR measurements at low-temperatures were conducted in zero magnetic field. In this work, we describe the design of a setup for precision TDR measurements in a dilution refrigerator down to ~40 mK with a 14 T superconducting magnet. The key features of our design are the separated electronics components and the placement of the most field sensitive parts in the field-compensated zone far from the center of solenoid as well as the heat-sinking at a higher temperature stage. As a result, the performance of the working setup is demonstrated using several superconductors.

47 OTHER INSTRUMENTATION↗

Calcium Phosphate Constraints in HLW Glasses: Phosphate Liquidus Model

About 50 million gallons of high-level mixed waste is currently stored in underground tanks at the United States Department of Energy’s (DOE’s) Hanford site in the State of Washington. The Hanford Tank Waste Treatment and Immobilization Plant (WTP) will provide DOE’s Office of River Protection (ORP) with a means of treating this waste by vitrification for subsequent disposal. The tank waste will be separated into low- and high-activity waste fractions, which will then be vitrified respectively into Immobilized Low Activity Waste (ILAW) and Immobilized High Level Waste (IHLW) products. The ILAW product will be disposed in an engineered facility on the Hanford site while the IHLW product is designed for acceptance into a national geological disposal facility for high-level nuclear waste. The ILAW and IHLW products must meet a variety of requirements before they can be accepted for disposal. Glass property-composition models will be used to control the vitrification process at the WTP to ensure that the glass meets product quality and processability requirements. The quality and the validity ranges of the property-composition models and the supporting database will greatly influence waste treatment operations, including the waste loading that is achievable in the glass for each waste composition. The current baseline models for operation of the WTP were developed under the Bechtel National, Inc. (BNI) WTP contract. These models were based on LAW and HLW glass property data over a range of compositions that was guided primarily by the WTP contract and the set of tanks specified therein. The HLW testing was directed towards waste streams from the then-planned early feed tanks for the WTP (i.e., AZ-101, AZ-102, C-106/AY-102, and C-104/AY-101). These wastes are high in iron (AZ-101, AZ-102, and C-106/AY-102) or thorium (C-104/AY-101). While the baseline models may be adequate for commissioning of the facility and processing of the specified tanks, refinements and extensions or augmentations of these models will be required to process the balance of the tank waste inventory. The overall mission of the WTP will require the immobilization of tank waste compositions that are variously dominated by mixtures of aluminum, chromium, bismuth, iron, phosphorous, zirconium, and sulfur compounds as waste-loading-limiting components. Further, the WTP contract includes minimum waste loading requirements that are generally rather modest while loadings significantly higher than those in the current baseline are likely achievable. In order to achieve these higher waste loadings and to expand the applicable composition regions, new models will be needed to support the optimized operation of the WTP. Since the development of the baseline WTP models, ORP directed a program of work at the Vitreous State Laboratory (VSL) to examine various approaches for optimization of the performance of the WTP, including increasing the waste loadings in the LAW and HLW glass products. That work involved HLW rich in Al, Al+Na, Cr, Bi, S, Zr, Sr, P and Fe, in contrast to old baseline models that were based mostly on HLW tanks that were high in Fe, with one other that was also high in Th. Glass property data collected under the ORP program were compiled and combined with data collected to develop the WTP models. The combined databases have been used to update pre-existing HLW composition models or to develop new models for properties such as Product Consistency Test (PCT) responses, spinel crystallization (one-percent crystal fraction temperature, T 1% ), melt viscosity, melt electrical conductivity, nepheline formation upon slow cooling (i.e., Canister Centerline Cooling [CCC]), and Toxicity Characteristic Leach Procedure (TCLP) Cd response. While spinel is typically the most commonly occurring phase in HLW glasses, other phases can be limiting depending on the waste and glass composition. For example, various phosphate phases can become important as the phosphorus content increases. Lithium phosphate crystallization can impact PCT releases of HLW glasses, while calcium phosphate phases forming in the cold-cap can deleteriously impact feed processing in the melter. At present, however, no models exist that relate glass composition and crystallization of phosphate phases in general and calcium phosphate in particular. The present work was therefore directed towards the initial development of such models. Future work may be directed at studying amorphous phase separation in high phosphate HLW glasses. Within the River Protection Project, feed compositions are projected using the Hanford Tank Waste Operations Simulator (HTWOS), a dynamic computer model that tracks the waste through storage, retrieval, feed staging, and treatment processes. A review of the HTWOS data shows that WTP will process 4106 batches of HLW glass for the overall mission (System Plan Rev. 6, ORP-11242), each with its own waste feed and glass composition. Some of the projected HTWOS feed batches are expected to have relatively high concentrations of phosphorous compared to typical HLW streams. In the 4106 batches of HLW for the overall WTP mission P 2 O 5 varies from 0.59 wt% to 13.00 wt%, with 95 batches containing at least 10 wt% P 2 O 5 . Occurrences of phosphate crystals have commonly been noted in glasses with high bismuth and phosphorus contents. In addition, recently collected data from a set of statistically designed HLW matrix glasses prepared and characterized to support enhancement of the HLW glass property-composition models identified apatite in a number of glass samples. However, the current HLW model for crystallization (one-percent crystal fraction temperature) is applicable only to spinel crystallization in glasses. Previous projections of waste loadings and glass volume (such as those in System Plan Rev. 6, ORP-11242) have used preliminary constraints for calcium phosphate crystallization that are based on the limited available data. Additional data and improved constraints or, preferably, models that relate glass composition to crystallization of phosphate-containing phases, are therefore needed to support HLW vitrification at the WTP. The present study focuses on the development of such a model based on data from previously characterized glasses and a set of newly fabricated glasses.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

A separable fluid connector system effectiveness evaluation technique

An analytical technique is presented for evaluating the relationship among existing numerous separable fluid connector designs to find that configuration which is best (optimal). The data utilized in this research was acquired from approximately 900 flanges designed for six sub-systems of the S-1B stage of the Saturn 1B Space Vehicle. The method is general enough to be useful in optimizing design and systematizing decision-making in a variety of related technical fields.

Prasthofer, W. P.↗

Thermal performance of a modularized replaceable multilayer insulation system for a cryogenic stage

A rugged modularized MLI system for a 2.23-meter-diameter (87.6-in.-diam) liquid hydrogen tank was designed, fabricated, and tested under simulated near-earth and deep-space environments. The two blankets of the system were each composed of 17 double-aluminized Mylar radiation shields separated by silk net. The unit area weight of the installed system was 1.54 kg/sqm (0.32 lb/sq ft). The overall average heat transferred into the insulated tank was 22.7 and 0.98 watts (77.4 and 3.3 Btu/hr) during simulated near-earth and deep-space testing, respectively. The near-earth result was only 2.6 times that predicted for an undisturbed insulation system (i.e., no seams or penetrations). Tests indicate that this insulation concept could be useful for a cryogenic space tug or orbit transfer vehicle application.

Knoll, R. H.↗

An experimental investigation of boundary layer transition in an adverse pressure gradient

The evolution of a small perturbation introduced periodically into a boundary layer with a moderately strong adverse pressure gradient (APG) was investigated experimentally using the hot-wire method. The magnitude of the disturbance is found to decay with the streamwise distance in the APG before undergoing rapid growth and triggering transition in a very repetitive manner. The evidence suggests that the laminar layer separates and that the transition mechanism is an inviscid shear-layer type of instability. Contours of spanwise vorticity in the plane of the disturbance show the formation of roll-ups in the initial stages. Subsequent interaction with the wall leads to the formation of large-scale vortex loops which merge into a single vortex loop further downstream.

Watmuff, Jonathan H.↗