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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 1,153 records · Page 64
All sourcesNASA NTRSDOE OSTI
NASA NTRS1981

High-resolution IUE observations of the 1981 eclipse of 32 CYG

32 Cyg shows a spectacular pure emission line spectrum during eclipse. Six weeks later, most lines, which were observed in emission during eclipse, are seen as P Cygni type profiles with strong absorption components. The lines are formed through line scattering of B star light in the extended atmosphere (wind) of the K supergiant. During eclipse, the emission parts of the P Cyg lines remain visible since the size of the line scattering sphere around the B star is larger than the red giant. Other emission lines are formed in a shock front near the B star (CIV, SiIV, FeIII) and possibly in an accretion disk. The strong FeII UV Mult. 191 lambda lambda 1785-88 A is shown to be formed through optical pumping via FeII UV Mult. 9 photons. The phase dependence of the P Cyg type profiles is modelled by means of line transfer calculations in nonspherical, 3-dimensional geometry with velocity fields.

Reimers, D.↗
NASA NTRS1990

Free convection in the Matian atmosphere

The 'free convective' regime for the Martian atmospheric boundary layer (ABL) was investigated. This state occurs when the mean windspeed at the top of the ABL drops below some critical value U(sub c) and positive buoyant forces are present. Such forces can arise either from vertical temperature or water vapor gradients across the atmospheric surface layer. During free convection, buoyant forces drive narrow plumes that ascend to the inversion height with a return circulation consisting of broad slower-moving downdraughts. Horizontal pressure, temperature, windspeed, and water vapor fluctuations resulting form this circulation pattern can be quite large adjacent to the ground (within the surface layer). The local turbulent fluctuations cause non-zero mean surface stresses, sensible heat fluxes, and latent heat fluxes, even when the mean regional windspeed is zero. Although motions above the surface layer are insensitive to the nature of the surface, the sensible and latent heat fluxes are primarily controlled by processes within the interfacial sublayer immediately adjacent to the ground during free convection. Thus the distinction between aerodynamically smooth and rough airflow within the interfacial sublayer is more important than for the more typical situation where the mean regional windspeed is greater than U(sub c). Buoyant forces associated with water vapor gradients are particularly large on Mars at low pressures and high temperatures when the surface relative humidity is 100 percent, enhancing the likelihood of free convection under these conditions. On this basis, Ingersol postulated the evaporative heat losses from an icy surface on Mars at 237 K and current pressures would exceed the available net radiative flux at the surface, thus prohibiting ice from melting at low atmospheric pressures. Schumann has developed equations describing the horizontal fluctuations and mean vertical gradients occurring during free convection. Schumann's model was generalized to include convection driven by water vapor gradients and to include the effects of circulation above both aerodynamically smooth and rough surfaces.

Clow, G. D.↗
DOE OSTI2024

Tracking the reaction networks of acetaldehyde oxide and glyoxal oxide Criegee intermediates in the ozone-assisted oxidation reaction of crotonaldehyde

The reaction of unsaturated compounds with ozone (O 3 ) is recognized to lead to the formation of Criegee intermediates (CIs), which play a key role in controlling the atmospheric budget of hydroxyl radicals and secondary organic aerosols. The reaction network of two CIs with different functionality, i.e. acetaldehyde oxide (CH 3 CHOO) and glyoxal oxide (CHOCHOO) formed in the ozone-assisted oxidation reaction of crotanaldehyde (CA), is investigated over a temperature range between 390 K and 840 K in an atmospheric pressure jet-stirred reactor (JSR) at a residence time of 1.3 s, stoichiometry of 0.5 with a mixture of 1% crotonaldehyde, 10% O 2 , at an fixed ozone concentration of 1000 ppm and 89% Ar dilution. Molecular-beam mass spectrometry in conjunction with single photon tunable synchrotron vacuum-ultraviolet (VUV) radiation is used to identify elusive intermediates by means of experimental photoionization energy scans and ab initio threshold energy calculations for isomer identification. Addition of ozone (1000 ppm) is observed to trigger the oxidation of CA already at 390 K, which is below the temperature where the oxidation reaction of CA was observed in the absence of ozone. The observed CA + O 3 product, C 4 H 6 O 4 , is found to be linked to a ketohydroperoxide (2-hydroperoxy-3-oxobutanal) resulting from the isomerization of the primary ozonide. Products corresponding to the CIs uni- and bi-molecular reactions were observed and identified. A network of CI reactions is identified in the temperature region below 600 K, characterized by CIs bimolecular reactions with species like aldehydes, i.e., formaldehyde, acetaldehyde, and crotonaldehyde and alkenes, i.e., ethene and propene. The region below 600 K is also characterized by the formation of important amounts of typical low-temperature oxidation products, such as hydrogen peroxide (H 2 O 2 ), methyl hydroperoxide (CH 3 OOH), and ethyl hydroperoxide (C 2 H 5 OOH). Detection of additional oxygenated species such as alcohols, ketene, and aldehydes are indicative of multiple active oxidation routes. This study provides important information about the initial step involved in the CIs assisted oligomerization reactions in complex reactive environments where CIs with different functionalities are reacting simultaneously. It provides new mechanistic insights into ozone-assisted oxidation reactions of unsaturated aldehydes, which is critical for the development of improved atmospheric and combustion kinetics models.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2023

Differential multi-probe thermal transport measurements of multi-walled carbon nanotubes grown by chemical vapor deposition

Carbon nanotubes (CNTs) are quasi-one dimensional nanostructures that display both high thermal conductivity for potential thermal management applications and intriguing low-dimensional phonon transport phenomena. In comparison to the advances made in the theoretical calculation of the lattice thermal conductivity of CNTs, thermal transport measurements of CNTs have been limited by either the poor temperature sensitivity of Raman thermometry technique or the presence of contact thermal resistance errors in sensitive two-probe resistance thermometry measurements. Here we report advances in a multi-probe measurement of the intrinsic thermal conductivity of individual multi-walled CNT samples that are transferred from the growth substrate onto the measurement device. The sample-thermometer thermal interface resistance is directly measured by this multi-probe method and used to model the temperature distribution along the contacted sample segment. The detailed temperature profile helps to eliminate the contact thermal resistance error in the obtained thermal conductivity of the suspended sample segment. A differential electro-thermal bridge measurement method is established to enhance the signal-to-noise ratio and reduce the measurement uncertainty by over 40%. The obtained thermal resistances of multiple suspended segments of the same MWCNT samples increase nearly linearly with increasing length, revealing diffusive phonon transport as a result of phonon-defect scattering in these MWCNT samples. The measured thermal conductivity increases with temperature and reaches up to 390 ± 20 W m –1 K –1 at room temperature for a 9-walled MWCNT. In conclusion, theoretical analysis of the measurement results suggests submicron phonon mean free paths due to extrinsic phonon scattering by extended defects such as grain boundaries. The obtained thermal conductivity is decreased by a factor of 3 upon electron beam damage and surface contamination of the CNT sample.

42 ENGINEERING↗
DOE OSTI2024

Wall modes and the transition to bulk convection in rotating Rayleigh-Bénard convection

We investigate states of rapidly rotating Rayleigh-Bénard convection in a cylindrical cell over a range of Rayleigh numbers 3 × 10 5 ≤ Ra ≤ 5 × 10 9 and Ekman numbers 10 − 6 ≤ Ek ≤ 10 − 4 for Prandtl number Pr = 0.8 and aspect ratios 1 / 5 ≤ Γ ≤ 5 using direct numerical simulations. We characterize, for perfectly insulating sidewall boundary conditions, the first transition to convection via wall mode instability and the nonlinear growth and instability of the resulting wall mode states, including a secondary transition to time dependence. We show how the radial structure of the vertical velocity u z and the temperature T is captured well by the linear eigenfunctions of the wall mode instability where the radial width of u z is δ u z ∼ Ek 1 / 3 r / H whereas δ T ∼ e − k r ( k is the wave number of a laterally infinite wall mode state). The disparity in spatial scales for Ek = 10 − 6 means that the heat transport is dominated by the radial structure of u z since T varies slowly over the radial scale δ u z . We further describe how the transition to a state of bulk convection is influenced by the presence of the wall mode states. We use temporal and spatial scales as measures of the local state of convection and the Nusselt number Nu as representative of global transport. Our results elucidate the evolution of the wall state of rotating convection and confirm that wall modes are strongly linked with the boundary zonal flow being the robust remnant of nonlinear wall mode states. We also show how the heat transport ( Nu ) contributions of wall modes and bulk modes are related and discuss approaches to disentangling their relative contributions. Published by the American Physical Society 2024

58 GEOSCIENCES↗
DOE OSTI2026

Machine Learning Vacancy Formation Energy in Nickel-Based Superalloys

Thermal vacancies play a critical role in high-temperature Ni-based superalloys and influence various properties such as creep resistance, oxidation, etc. This study systematically investigates the impact of commonly used transition metals (Cr, Co, Fe), refractory metals (Nb, Ta, Mo, W) and other elements (Al, Cu, Ti, Mn) on the thermodynamic stability of 36 binary, 20 ternary, 11 quaternary, 9 quinary, and 3 senary FCC Ni-based alloys covering various elemental combinations. Density functional theory-based studies on Ni-X binary alloys show that higher concentrations of Cr, Nb, Ta, Al, and Ti introduce significant lattice distortions and broaden the distribution of vacancy formation energies (standard deviation up to 0.15 eV). These elements partially donate electrons, reducing their self-consistent chemical potentials relative to single-element reference values and lowering vacancy formation energies, while Co, Fe, Mo, and W show lower charge localization. These trends extend from 3-6 element alloys, where Cr, Nb, and Ta-rich compositions have low-energy states (~0.5 eV) that increase vacancy concentrations. Finally, graph neural network models are developed to screen over 5000 virtual alloys. Eleven leading compositions are identified with mean vacancy formation energy higher than 1.75 eV and vacancy concentration ~2 orders of magnitude lower than pure Ni at 1000 K. These results provide valuable guidelines to achieve controlled defect engineering in structural alloys.

DFT↗
NASA NTRS1972

A global empirical model of thermospheric composition based on OGO-6 mass spectrometer measurements.

A global empirical model for magnetically quiet conditions has been developed to describe longitudinally averaged OGO-6 N2, O, and He densities (in the altitude range 400 to 600 km) by means of an expansion into spherical harmonics. The annual asymmetric component in N2 density corresponds to an increase of about 400 K between winter and summer poles, which is about a factor of three greater than in the Jacchia model. However, the corresponding oxygen component at satellite altitudes reflects an increase between winter and summer comparable to that in the Jacchia model; this implies that at 120 km atomic oxygen increases by more than a factor of two between summer and winter poles. The amplitude of the symmetric semiannual component in N2 is larger at the poles than the equator. At the poles, the N2 variation corresponds to a temperature decrease of about 70 K from mid-April to mid-July. At low latitudes, the daily temperature maximum occurs close to 16 hours local time, nearly in agreement with radar backscatter observations.

Hedin, A. E.↗
NASA NTRS1972

L-orthogonal signal transmission and detection.

Investigation of the detailed capabilities and performance characterization of systems that employ L-orthogonal signaling techniques. L-orthogonal signals represent a unified set of signals wherein the polyphase and orthogonal (bi-orthogonal) signal sets are included as special cases. This fact is important, since orthogonal (bi-orthogonal) and polyphase signaling sets represent opposing forces as far as tradeoffs between error probability, energy-to-noise ratio, and bandwidth requirements are concerned. Bounds on the performance of the optimum receiver and the performance of various suboptimum (practical) receiver structures are given. Coherent and differentially coherent detection of differentially encoded signals are also pursued. Various comparisons and tradeoffs are made by means of numerical evaluation of the error probability expressions.

Lindsey, W. C.↗
NASA NTRS1978

Nitrogen-sulfur compounds in stratospheric aerosols

Two forms of nitrosyl sulfuric acid (NOHSO4 and NOHS2O7) have been tentatively identified in stratospheric aerosols. The first of these can be formed either directly from gas reactions of NO2 with SO2 or by gas-particle interactions between NO2 and H2SO4. The second product may form when SO3 is involved. Estimates based on these reactions suggest that the maximum quantity of NO that might be absorbed in stratospheric aerosols could vary from one-third to twice the amount of NO in the surrounding air. If these reactions occur in the stratosphere, then a mechanism exists for removing nitrogen oxides from that region by aerosol particle fallout. This process may typify another natural means that helps cleanse the lower stratosphere of excessive pollutants.

Farlow, N. H.↗
NASA NTRS1982

Numerical modelling of turbulent flow in a combustion tunnel

A numerical technique is presented for the analysis of turbulent flow associated with combustion. The technique uses Chorin's random vortex method (rvm), an algorithm capable of tracing the action of elementary turbulent eddies and their cumulative effects without imposing any restriction upon their motion. In the past, the rvm has been used with success to treat nonreacting turbulent flows, revealing in particular the mechanics of large-scale flow patterns, the so-called coherent structures. Introduced here is a flame propagation algorithm, also developed by Chorin, in conjunction with volume sources modelling the mechanical effects of the exothermic process of combustion. As an illustration of its use, the technique is applied to flow in a combustion tunnel where the flame is stabilized by a back-facing step. Solutions for both nonreacting and reacting flow fields are obtained which satisfactorily describe the essential features of turbulent combustion in a lean propane-air mixture that were observed in the laboratory by means of high speed Schlieren photography.

Ghoniem, A. F.↗
NASA NTRS1982

Equatorial response to northeasterly cold surges as inferred from satellite cloud imagery

Daily convective activity in equatorial regions during Dec.-Jan., 1974-1975 was estimated from NOAA satellite data and composited in relation to the phase of cold surge episodes which then occured. Eastward and westward propagating cloud clusters displayed phase speeds of about 5 and 10 m/sec, respectively, and were generated near southwestern Borneo after a cold surge. Kelvin wave responses were indicated by confinement of the eastward-moving components to the equatorial region. Further, an analysis of symmetric and asymmetric characteristics showed that components symmetric with respect to the equator displayed a larger response amplitude, which was taken to mean that strongly trapped waves were generated from heat sources near the equator.

Lau, K.-M.↗
NASA NTRS1985

Trends in the Southern Hemisphere

The station data of monthly mean sea level pressure, surface air temperature as well as monthly mean upper air rawinsonde observations were used to study the trends in the southern winter (June, July and August) and summer (December, January and February). This study covers the period 1951 to 1981. Most of the surface data have continuous 31 year records, however, for some high latitude stations, both surface and upper air records started in 1957 or even later. The normalized anomaly for a given variable Z is defined as the departure from the 1951 to 1981 grand mean divided by the standard deviation during the same period. To eliminate the large fluctuations in the data, the 1-3-1 smoothing was applied to the time series of normalized anomalies. The trends of monthly mean temperatures and height from the surface to 200 mb level is documented.

Mo, K. C.↗
NASA NTRS1984

Stationary Rossby wave propagation through easterly layers

The zonal mean basic state sensitivity of the steady response to midlatitude mountain forcing is examined through the numerical solution of linearized shallow water equations on a sphere. The zonal mean basic state consists of meridionally varying zonal winds and meridional winds. Attention is given to cases in which the former are westerly everywhere, except within a tropical region in which they are easterly. A zonal wavenumber three mountain confined to the Northern Hemisphere midlatitudes provides the forcing. It is concluded that critical latitude effects on wave propagation are sensitive to mean meridional circulation structure in the critical latitude region of the model.

Schneider, E. K.↗
NASA NTRS1985

An FIR cooled grating spectrometer for the Kuiper Airborne Observatory

The design and performance of a liquid-He-cooled spectrometer being developed for the Kuiper Airborne Observatory (KAO) to study FIR lines originating in the interstellar medium are discussed. Currently, the spectrometer contains six Ge:Ga photoconductor detectors mounted in integrating cavities and cooled to about 3 K; the collimator focal plane has space for 39 such detectors. The instrument achieves a maximum resolving power of 6000 by means of a 45-cm long echelle grating and is optically capable of operating in the spectral range 25-300 microns. A laboratory spectrum of water vapor, an atmospheric water absorption feature measured from the KAO with Mars as a source, and the forbidden O(2+) emission from W51-IRS1 are shown.

Erickson, E. F.↗
NASA NTRS1986

Evaluation of a standard test method for total hemispherical emittance of surfaces from 293K to 1673K

Emittance tests were made on samples of Rene' 41, Haynes 188, and Inconel 625 superalloy metals in an evaluation of a standard test method for determining total hemispherical emittances of surfaces from 293 K to 1673 K. The intent of this evaluation was to address any problems encountered, check repeatability of measured emittances, and gain experience in use of the test procedure. Five test specimens were fabricated to prescribe test dimensions and surfaces cleaned of oil and residue. Three of these specimens were without oxidized surfaces and two with oxidized surfaces. The oxidized specimens were Rene' 41 and Haynes 188. The tests were conducted in a vacuum where the samples were resistance-heated to various temperature levels ranging from 503 K to 1293 K. The calculated results for emittance, in the worst case, were repeatable to a maximum spread to + or - 4% from the mean of five sets of plotted data for each specimen.

Compton, E. C.↗
NASA NTRS1985

Local density maxima - Progenitors of structure

Beginning with a short review of the observational data and of some previous theoretical ideas and numerical simulations, the question is addressed of how the large-scale structure that emerges around local density maxima depends on the nature of the primordial density perturbations field. The density contrast profile around local maxima is given, to a good approximation, by the primordial two-point correlation function. The mean number density of objects of a given core mass is calculated as a function of the primordial power spectrum, p(k). In an open universe, rich clusters should have halos steeper than galactic haloes. The observed structure is found to be consistent with omega-sub-zero less than 1.0 and n = -1.

Hoffman, Y.↗
NASA NTRS1986

NLTE-analysis of three extremely helium-rich O-type subdwarfs

Three extremely helium-rich sdO stars (LSE 153, LSE 259 and LSE 263) were analyzed spectroscopically by means of detailed NLTE model atmospheres. These stars are very hot, with effective temperatures ranging from 70,000 to 75,000 K and gravities between log g = 4.4 and 4.9. Upper limits for the hydrogen abundance were also derived. The evolutionary status of the sdO stars is discussed and it is concluded that they evolve from the asymptotic giant branch towards the white dwarf stage. A possible evolutionary link between these hot stars and the extreme helium stars of spectral type B is discussed.

Husfeld, D.↗