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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 1,153 records · Page 64
All sourcesNASA NTRSDOE OSTI
NASA NTRS1984

Advanced smoke meter development survey and analysis

Ideal smoke meter characteristics are determined to provide a basis for evaluation of candidate systems. Five promising techniques are analyzed in detail to evaluate compilance with the practical smoke meter requirements. Four of the smoke measurement concepts are optical methods: Modulated Transmission (MODTRAN), Cross Beam Absorption Counter (CBAC), Laser Induced Incandescence (LIN), and Photoacoustic Spectroscopy (PAS). A rapid response filter instrument called a Taper Element Oscillating Microbalance (TEOM) is also evaluated. For each technique, the theoretical principles are described, the expected performance is determined, and the advantages and disadvantages are discussed The expected performance is evaluated against each of the smoke meter specifications, and the key questions for further study are given. The most promising smoke meter technique analyzed was MODTRAN, which is a variation on a direct transmission measurement. The soot-laden gas is passed through a transmission cell, and the gas pressure is modulated by a speaker.

Pitz, R. W.↗
NASA NTRS1985

Light Scattering Tests of Fundamental Theories of Transport Properties in the Critical Region

The objective of this program is to measure the decay rates of critical density fluctuations in a simple fluid (xenon) very near its liquid-vapor critical point using laser light scattering and photon correlation spectroscopy. Such experiments have been severely limited on Earth by the presence of gravity which causes large density gradients in the sample when the compressibility diverges approaching the critical point. The goal is to measure decay rates deep in the critical region where the scaled wavevector is the order of 1000. This will require loading the sample to 0.01% of the critical density and taking data as close as 3 microKelvin to the critical temperature (Tc = 289.72 K). Other technical problems have to be addressed such as multiple scattering and the effect of wetting layers. The ability to avoid multiple scattering by using a thin sample (100 microns) was demonstrated, as well as a temperature history which can avoid wetting layers satisfactory temperature control and measurement, and accurate sample loading. Thus the questions of experimental art are solved leaving the important engineering tasks of mounting the experiment to maintain alignment during flight and automating the state-of-the-art temperature bridges for microcomputer control of the experiment.

Gammon, R. W.↗
NASA NTRS1985

Photothermal degradation studies

Key reaction intermediates of photooxidation identified and characterized by laser flash Electron Spin Resonance (ESR) spectroscopy were discussed. Effects of temperature and ultraviolet intensity were studied in order to develop meaningful accelerated testing procedures for encapsulant evaluation. In a program to study the failure of Tedlar/ethylene vinyl acetate (EVA)/stainless steel modules, failure modes similar to those observed outdoors in real-time conditions were simulated in accelerated testing. An experimental technique was developed to quantitatively assess the extent of degradation.

Liang, R. H.↗
NASA NTRS1988

Critical fluid light scattering

The objective is to measure the decay rates of critical density fluctuations in a simple fluid (xenon) very near its liquid-vapor critical point using laser light scattering and photon correlation spectroscopy. Such experiments were severely limited on Earth by the presence of gravity which causes large density gradients in the sample when the compressibility diverges approaching the critical point. The goal is to measure fluctuation decay rates at least two decades closer to the critical point than is possible on earth, with a resolution of 3 microK. This will require loading the sample to 0.1 percent of the critical density and taking data as close as 100 microK to the critical temperature. The minimum mission time of 100 hours will allow a complete range of temperature points to be covered, limited by the thermal response of the sample. Other technical problems have to be addressed such as multiple scattering and the effect of wetting layers. The experiment entails measurement of the scattering intensity fluctuation decay rate at two angles for each temperature and simultaneously recording the scattering intensities and sample turbidity (from the transmission). The analyzed intensity and turbidity data gives the correlation length at each temperature and locates the critical temperature. The fluctuation decay rate data from these measurements will provide a severe test of the generalized hydrodynamic theories of transport coefficients in the critical regions. When compared to equivalent data from binary liquid critical mixtures they will test the universality of critical dynamics.

Gammon, Robert W.↗
NASA NTRS1989

Frequency and intensity analysis of the nu3, nu4, and nu6 bands of formaldehyde

The infrared spectra of the nu3, nu4, and nu6 bands of formaldehyde in the region from 890/cm to 1580/cm have been obtained at high resolution using tunable diode laser and Fourier transform-infrared spectroscopy. The transition frequencies have been analyzed using a Hamiltonian including terms through sextic in centrifugal distortion and including five interstate vibration-rotation coupling terms. Excited-state pure rotational transitions are also included in the data, and their frequencies are reproduced well. Individual measured line intensities are used to determine dipole derivatives and band strengths using the fully coupled, asymmetric top eigenvectors.

Reuter, D. C.↗
NASA NTRS1989

Critical fluid light scattering

Thermal fluctuations give rise to a host of thermodynamic anomalies near critical points. The background for these phenomena is presented, and an experimental design on STS flight experiment called Zeno is described. The objective is to measure the decay rates of critical density fluctuations in a simple fluid (xenon) very near its liquid-vapor critical point using laser light scattering and photon correlation spectroscopy. Such experiments have been limited on Earth by the presence of gravity, which causes large density gradients in the sample. Fluctuation decay rates in xenon will be measured at least 100 times closer to the critical point than is possible on Earth. This will require taking data as close as 145 micro K to the critical temperature, after locating it to + or - 10 micro K. The minimum mission time of 100 hours will allow a complete range of temperature points to be covered, limited by the thermal response of the sample. An essential part of the apparatus is the thermostat. Its design principles and key features are given together with some observed performance characteristics of a prototype: + or - 20 micro K stability for 18 hours, and one minute programmed step response for steps less than 10 mK.

Gammon, Robert W.↗
NASA NTRS1989

Characterization of a thermally imidized soluble polyimide film

A soluble aromatic poly(amic acid) film was converted to a soluble polyimide by staging at 25 deg intervals to 325 C and characterized at each interval by several analytical methods. The behavior observed was consistent with an interpretation that a reduction occurred in molecular weight of the poly(amic acid) during the initial stages of cure before the ultimate molecular weight was achieved as a polyimide. This interpretation was supported by the results of solution viscosity, gel permeation chromatography, low angle laser light scattering photometry and infrared spectroscopy analysis. The results serve to increase the fundamental understanding of how polyimides are thermally formed from poly(amic acids).

Young, Philip R.↗
NASA NTRS1990

Characterization of a thermally imidized soluble polyimide film

A soluble aromatic poly(amic acid) film was converted to a soluble polyimide by staging at 25 deg intervals to 325 C and characterized at each interval by several analytical methods. The behavior observed was consistent with an interpretation that a reduction occurred in molecular weight of the poly(amic acid) during the initial stages of cure before the ultimate molecular weight was achieved as a polyimide. This interpretation was supported by the results of solution viscosity, gel permeation chromatography, low angle laser light scattering photometry and infrared spectroscopy analysis. The results serve to increase the fundamental understanding of how polyimides are thermally formed from poly(amic acids).

Young, Philip R.↗
NASA NTRS1995

Spectroscopy and excitation dynamics of the trivalent lanthanides Tm(3+) and Ho(3+) in LiYF4

A detailed study of the spectroscopy and excitation dynamics Tm3+ and Ho3+ in yttrium lithium fluoride, LiYF4 (YLF), has been done. Absorption spectroscopy is utilized in the Judd-Ofelt theory to determine radiative transition rates of spontaneous emission. Luminescence spectroscopy is studied under cw diode laser excitation at 785nm. The effect of dopant ion concentration and excitation power on the observed luminescence are considered in these measurements. An analysis of these measurements have been used to determine channels of energy transfer between Tm3+ and Ho3+ ions. The temporal response of Tm and Ho in singly and co-doped YLF to pulsed laser excitation with a Ti:Al2O3 laser and a CoMgF2 laser turned to various wavelengths have also been studied. The energy transfer mechanisms of cross relaxation, upconversion, and resonant energy transfer between Tm3+ and Ho3+ ions have been modeled, and the model parameters extracted by a fitting procedure to the measured temporal response curves. Rate equation approaches to modeling are presented that result in predictions of rate constants for energy transfer processes, as well as more conventional approaches to modeling such as the Forster-Dexter models, which give the interaction strengths in terms of microscopic interaction parameters.

Walsh, Brian M.↗
NASA NTRS1997

Kinetics of the Br2-CH3CHO Photochemical Chain Reaction

Time-resolved resonance fluorescence spectroscopy was employed in conjunction with laser flash photolysis of Br2 to study the kinetics of the two elementary steps in the photochemical chain reaction nBr2 + nCH3CHO + hv yields nCH3CBrO + nHBr. In the temperature range 255-400 K, the rate coefficient for the reaction Br((sup 2)P(sub 3/2)) + CH3CHO yields CH3CO + HBr is given by the Arrhenius expression k(sub 6)(T) = (1.51 +/- 0.20) x 10(exp -11) exp(-(364 +/- 41)/T)cu cm/(molecule.s). At 298 K, the reaction CH3CO + Br2 yields CH3CBrO + Br proceeds at a near gas kinetic rate, k(sub 7)(298 K) = (1.08 +/- 0.38) x 10(exp -10)cu cm/(molecule.s).

Nicovich, J. M.↗
NASA NTRS1994

Fullerenes in an impact crater on the LDEF spacecraft

The fullerenes C60 and C70 have been found to occur naturally on Earth and have also been invoked to explain features in the absorption spectra of interstellar clouds. But no definitive spectroscopic evidence exists for fullerenes in space and attempts to find fullerenes in carbonaceous chondrites have been unsuccessful. Here we report the observation of fullerenes associated with carbonaceous impact residue in a crater on the Long Duration Exposure Facility (LDEF) spacecraft. Laser ionization mass spectrometry and Raman spectroscopy indicate the presence of fullerenes in the crater and in adjacent ejecta. Man-made fullerenes survive experimental hypervelocity (approximately 6.1 km s-1) impacts into aluminium targets, suggesting that space fullerenes contained in a carbonaceous micrometeorite could have survived the LDEF impact at velocities towards the lower end of the natural particle encounter range (<13 km s-1). We also demonstrate that the fullerenes were unlikely to have formed as instrumental artefacts, nor are they present as contaminants. Although we cannot specify the origin of the fullerenes with certainty, the most plausible source is the chondritic impactor. If, alternatively, the impact produced the fullerenes in situ on LDEF, then this suggests a viable mechanism for fullerene production in space.

long duration↗
NASA NTRS2000

In-situ chemical imager

Explore the source record for details and available documents.

in-situ instruments scanning probe microscopy lase↗
NASA NTRS2016

Final Report: Laser-Based Optical Trap for Remote Sampling of Interplanetary and Atmospheric Particulate Matter

Applicability to Early Stage Innovation NIAC Cutting edge and innovative technologies are needed to achieve the demanding requirements for NASA origin missions that require sample collection as laid out in the NRC Decadal Survey. This proposal focused on fully understanding the state of remote laser optical trapping techniques for capturing particles and returning them to a target site. In future missions, a laser-based optical trapping system could be deployed on a lander that would then target particles in the lower atmosphere and deliver them to the main instrument for analysis, providing remote access to otherwise inaccessible samples. Alternatively, for a planetary mission the laser could combine ablation and trapping capabilities on targets typically too far away or too hard for traditional drilling sampling systems. For an interstellar mission, a remote laser system could gather particles continuously at a safe distance; this would avoid the necessity of having a spacecraft fly through a target cloud such as a comet tail. If properly designed and implemented, a laser-based optical trapping system could fundamentally change the way scientists designand implement NASA missions that require mass spectroscopy and particle collection.

Laser↗
NASA NTRS2019

Enhancing Global Change Experiments Through Integration of Remote‐Sensing Techniques

Global change experiments are often spatially and temporally limited because they are time‐ and labor‐intensive, and expensive to carry out. We describe how the incorporation of remote‐sensing techniques into global change experiments can complement traditional methods and provide additional information about system processes. We describe five emerging near‐surface remote‐sensing techniques: spectroscopy, thermal and fluorescence imaging, terrestrial laser scanning, digital repeat photography, and unmanned aerial systems. The addition of such techniques can reduce cost and effort, provide novel information, and expand existing observations by improving their context, accuracy, and completeness. In addition, we contend that use of airborne and satellite remote‐sensing data during site selection can improve the ecological representativeness of future experiments. We conclude by recommending a high level of communication and collaboration between remote‐sensing scientists and ecologists at all stages of global change experimentation.

Alexey N Shiklomanov↗
NASA NTRSDate not supplied

10-kHz PLIF Thermometry for a Turbulent Jet Flame using Single Burst-mode OPO

Two-color Planar laser-induced fluorescence (TC-PLIF) thermometry techniques that employ two laser systems and two cameras face challenges when implemented in practical combustion facilities because of experimental complexity and multiple laser and camera requirements, particularly for high-speed TC-PLIF. To circumvent those problems, we developed a fast, dual-wavelength switching, burst-mode OPO technology to significantly reduce the experimental complexity of high-speed TC-PLIF thermometry and simplify its implementation in harsh combustion and flow test facilities. A fast, dual-wavelength switched seed laser enabled a high-energy, high-repetition-rate burst-mode laser to generate two 10-kHz pulse trains at wavelengths of ~354.8 nm. The injection-seeded OPO efficiently converts the burst-mode laser output to285.62 nm and 285.67 nm to excite the Q2(12) and P1(8) OH transitions. PLIF images were collected from each of the two excitation transitions with a single camera and an UV intensifier, and intensity ratios from the images were used to determine local temperatures. Ten kHz hydroxyl radical (OH) TC-PLIF for premixedCH4/Air/H2 jet flame was demonstrated.

thermometry↗