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At least 1,135 records · Page 63
All sourcesNASA NTRSDOE OSTI
NASA NTRS1988

Fluid oscillation in the Drop Tower

An interfluid meniscus oscillates within a cylindrical container when suddenly released from earth's gravity and taken into a microgravity environment. Oscillations damp out from energy dissipative mechanisms such as viscosity and interfacial friction. Damping out of the oscillations by the latter mechanism is affected by the nature of the interfacial junction between the fluid-fluid interface and the container wall. Perfluoromethylcyclohexane and isopropanol in glass were the materials used for the experiment. The wetting condition of the fluids against the wall changes at the critical wetting transition temperature. This change in wetting causes a change in the damping characteristics.

Kaukler, William F.↗
NASA NTRS1990

Critical point wetting drop tower experiment

The 100 m Drop Tower at NASA-Marshall was used to provide the step change in acceleration from 1.0 to 0.0005 g. An inter-fluid meniscus oscillates vertically within a cylindrical container when suddenly released from earth's gravity and taken into a microgravity environment. Oscillations damp out from energy dissipative mechanisms such as viscosity and interfacial friction. Damping of the oscillations by the later mechanism is affected by the nature of the interfacial junction between the fluid-fluid interface and the container wall. In earlier stages of the project, the meniscus shape which developed during microgravity conditions was applied to evaluations of wetting phenomena near the critical temperature. Variations in equilibrium contact angle against the container wall were expected to occur under critical wetting conditions. However, it became apparent that the meaningful phenomenon was the damping of interfacial oscillations. This latter concept makes up the bulk of this report. Perfluoromethyl cyclohexane and isopropanol in glass were the materials used for the experiment. The wetting condition of the fluids against the wall changes at the critical wetting transition temperature. This change in wetting causes a change in the damping characteristics of the interfacial excursions during oscillation and no measurable change in contact angle. The effect of contact line friction measured above and below the wetting transition temperature was to increase the period of vertical oscillation for the vapor-liquid interface when below the wetting transition temperature.

Kaukler, William F.↗
NASA NTRS2004

Determining the Oxygen Fugacity of Lunar Pyroclastic Glasses Using Vanadium Valence - An Update

We have been developing an oxygen barometer based on the valence state of V (V(2+), V(3+), V(4+), and V(5+)) in solar system basaltic glasses. The V valence is determined by synchrotron micro x-ray absorption near edge structure (XANES), which uses x-ray absorption associated with core-electronic transitions (absorption edges) to reveal a pre-edge peak whose intensity is directly proportional to the valence state of an element. XANES has advantages over other techniques that determine elemental valence because measurements can be made non-destructively in air and in situ on conventional thin sections at a micrometer spatial resolution with elemental sensitivities of approx. 100 ppm. Recent results show that fO2 values derived from the V valence technique are consistent with fO2 estimates determined by other techniques for materials that crystallized above the IW buffer. The fO2's determined by V valence (IW-3.8 to IW-2) for the lunar pyroclastic glasses, however, are on the order of 1 to 2.8 log units below previous estimates. Furthermore, the calculated fO2's decrease with increasing TiO2 contents from the A17 VLT to the A17 Orange glasses. In order to investigate these results further, we have synthesized lunar green and orange glasses and examined them by XANES.

Karner, J. M.↗
NASA NTRSDate not supplied

Flow Regime Transitions and Pressure Drop in Gas-Liquid Flows through Packed Beds in Microgravity

The Packed Bed Reactor Experiment (PBRE) focused on the hydrodynamics of gas-liquid flow in porous media, specifically on flow regime transition and pressure drop correlation. The reactor included a cylindrical test section of 60 cm in length, 5 cm in diameter and filled with 2 mm spherical glass beads. Liquid water and Nitrogen gas were flowed into a centrifugal phase separator after exiting the test section. Five absolute pressure transducers and two high-speed video cameras spanned the test section to measure the pressure drop and capture flow regime behavior. Video observations, analysis of pressure traces, and pressure drop data were used to identify flow patterns. It was found that the slope of pressure gradient data when plotted versus the gas or liquid Reynolds numbers changed when the flow regime changed. This observation was used to identify the flow regime boundaries. At high liquid flow rates (high interaction regime), dispersed bubble and pulse flow regimes were detected. At low liquid flow rates (low interaction regime), large bubble and gas channeling regimes were observed. The transition from the big bubble regime to the gas channeling regime occurred at a critical gas flow rate independent of the liquid flow rate. Similarly, the transition from the low interaction to the high interaction regime occurred at a critical liquid flow rate. For these different flow regimes, different two-phase flow friction factors and pressure gradient correlations were fitted as a function of the gas and liquid modified Reynolds numbers and Suratman number. It was found that in all the flow regimes the capillary contribution to the pressure drop is significant and can be as high as 90% of the total pressure drop.

Brian Motil↗
NASA NTRS1983

Application of laser anemometry to cryogenic wind tunnels

The installation and tests conducted with the laser Doppler and transit anemometer in the 0.3-Meter Transonic Cryogenic Tunnel are described. Using residual particulates in the flow field, a series of free stream velocity measurements were conducted which agreed to within 1-percent of predicted values for a range of Mach numbers, 0.2 to 0.85, and temperatures, 100 to 250 K. Measurements about a shock wave provided an estimate of scattering particulate size of 4 microns or less. The particle concentration is approximately 3 x 10 to the 5th to 1.6 x 10 to the 6th/cu m. Necessary isolation of the plenum wall windows from ambient air with slightly positive pressure of dry nitrogen gas to prevent condensation on the window surface was achieved. This was accomplished through the use of large enclosures fixed to the tunnel wall. A second method used an additional sheet of thin plate glass to create the dry gas pocket next to the plenum window. The installation of a laser anemometer in the National Transonic Facility is examined. The laser transit anemometer has been tentatively selected for the initial entry because of its compact laser-optics package.

Hunter, W. W., Jr.↗
DOE OSTI2022

Competition between energy- and entropy-driven activation in glasses

In simplified models of glasses we clarify the existence of two different kinds of coexisting activated dynamics, with one of the two dominating over the other. One is the energy barrier hopping that is typically used to understand activation, and the other, which we call entropic activation, is driven by the scarcity of convenient directions in phase space. When entropic activation dominates, the height of the energy barriers is no longer the primary factor governing the system's slowdown. In our analysis, dominance of one mechanism over the other depends on temperature and the shape of the density of states. Herein, we also find that at low temperatures a phase transition between the two kinds of activation can occur. Our observations are used to provide a scenario that can harmonize the facilitation and thermodynamic pictures of the slowdown of glasses into a single description.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
DOE OSTI2020

Dirty bosons on the Cayley tree: Bose-Einstein condensation versus ergodicity breaking

Building on large-scale quantum Monte Carlo simulations, we investigate the zero-temperature phase diagram of hard-core bosons in a random potential on site-centered Cayley trees with branching number K=2. In order to follow how the Bose-Einstein condensate (BEC) is affected by the disorder, we focus on both the zero-momentum density, probing the quantum coherence, and the one-body density matrix (1BDM) whose largest eigenvalue monitors the off-diagonal long-range order. We further study its associated eigenstate which brings useful information about the real-space properties of this leading eigenmode. Upon increasing randomness, we find that the system undergoes a quantum phase transition at finite disorder strength between a long-range ordered BEC state, fully ergodic at large scale, and a new disordered Bose glass regime showing conventional localization for the coherence fraction while the 1BDM displays a nontrivial algebraic vanishing BEC density together with a nonergodic occupation in real space. These peculiar properties can be analytically captured by a simple phenomenological description on the Cayley tree which provides a physical picture of the Bose glass regime.

36 MATERIALS SCIENCE↗
NASA NTRS1991

Ablation of silicate particles in high-speed continuum and transition flow with application to the collection of interplanetary dust particles

The ablative deceleration of spheres in the continuum and slip regimes is studied using spherical 7.1-micron-diam soda-lime glass particles launched from vacuum at about 4500 m/sec speed through a 13-micron-thick plastic film into a capture chamber containing Xe at 0.1 or 0.2 atm pressure and 295 K temperature. The results of SEM examinations of the collected ablated particles showed that the ratio of the ablated-particle radius (Rf) to the initial radius (R0) increased with gas pressure (from Rf/R0 about 0.67 at 0.1 atm, to about 0.88 at 0.2 atm). A model was developed to describe the ablation and deceleration of spheres in high-speed continuum and slip flow. The pressure dependence predicted by the model agreed with experimental results.

Rulison, Aaron J.↗
DOE OSTI2025

Nature of temperature chaos in spin glasses

Temperature chaos (TC) in spin glasses has been claimed to exist no matter how small the temperature change, Δ⁢T. However, experimental studies have exhibited a finite value of Δ⁢T for a transition to TC. This paper explores the onset of TC with much higher resolution than before and over a larger temperature range. We find that TC is always present, though small at the smallest Δ⁢T that we can reliably measure. However, it grows rapidly as Δ⁢T increases, the region of rapid growth coinciding with the Δ⁢T predicted from renormalization group arguments and observed experimentally. Here, we are able to transcend the full range of TC, from the completely reversible state to one that is maximally decorrelated from the initially prepared state.

36 MATERIALS SCIENCE↗
DOE OSTI2024

Empirical Characterization and Modeling of Cohesive – to – Adhesive Shear Fracture Mode Transition due to Increased Adhesive Layer Thicknesses of Fiber Reinforced Composite Single – Lap Joints

Here, to ensure a strong adhesive bond, most standards and adhesive manufacturers specify a maximum adhesive gap of 1 mm when bonding fiber reinforced composite structures. In manufacturing large components, such as joining two halves of wind turbine blades, meeting this gap tolerance specification is impractical; gaps larger than 10 mm are common in large adhesively bonded composite structures using state-of-the-art manufacturing techniques. Currently, there is a lack of fundamental understanding of the failure mechanics of adhesive gaps larger than 3 mm. To create such understanding, glass fiber - acrylic thermoplastic composite panels bonded using different epoxy adhesives within single-lap joint samples with adhesive thicknesses of 0.1 mm, 0.3 mm, 1 mm, 3 mm, 5 mm, and 10 mm were sheared to failure. A transition from cohesive to adhesive failure was observed to occur about 1 mm to 3 mm joint thicknesses. Plotting the shear stress normalized by the ratio of the joint width to thickness as a function of the joint thickness normalized by the joint length is shown to result in the ability to fit simple empirically derived models of the cohesive-to-adhesive failure transition, regardless of the adhesive. Furthermore, using these normalized variables, all the observed cohesively failed specimens collapse to a single master curve, as do the adhesively failed specimens.

36 MATERIALS SCIENCE↗
DOE OSTI2023

Antenna With Embedded Die in Glass Interposer for 6G Wireless Applications

This article presents the antenna-integrated glass interposer for D-band 6G wireless applications using dieembedding technology. Here, we implement the die-embedded package on glass substrates and characterize the electrical performance in the D-band. The electrical characterization employs embedded test dies with the 50-Ω ground–signal–ground (GSG) ports and coplanar waveguides. We achieve low-loss die-to-package transitions by using staggered dielectric vias, which are compared with the transitions of wire-bonding and flip-chip assembly. This article provides detailed information on the design, modeling, fabrication, and characterization of the die-to-package interconnects. This article also demonstrates the integration of microstrip patch antenna array and embedded dies in the D-band. The results show superior electrical performance provided by the die-embedded glass interposer. The die-to-package interconnect exhibits good matching (less than —10-dB S11) and low loss (0.2-dB loss) in the D-band. The integrated 1 × 8 patch antenna array shows 11.6-dB broadside gain and good matching with the embedded die. In addition, by using a temporary carrier, the antenna-integrated glass interposer also has great potential for further heterogeneous integration and thermal management.

42 ENGINEERING↗
NASA NTRS2001

Impact and Collisional Processes in the Solar System

A series of impact experiments on anhydrite CaSO4, in which vaporized sample accelerates an element in a velocity interferometer, generate velocity data that we have recently reanalyzed using an explicit entropy generating finite difference code. The shock pressure required from the onset, and complete vaporization of 30% porous and 70% crystal density anhydrite is 52 +/- 3 and 122 +/- 13 GPa. Using observed acid leaching in non-marine K/T ejecta in North America, and the sharp global increase in Sr-87/Sr-86 ratios recorded at 65 Ma in marine rocks, we demonstrated that global acidification is primarily due to the SO2 released by anhydrite volatilization, and not HNO3 formed from bolide-induced air pyrolysis. Shock temperatures for crystal CaCO3 are measured from 3000 to 7000 K in the 90 to 160 GPa pressure range. These temperatures are much lower than calculated theoretically indicating that possibly bond breakdown at the shock front is occurring. This is the first mineral in which this effect has ever been seen. New data defining the ion species which are produced upon impact of volatilization of metals and minerals using a pulse ultraviolet laser to simulate intense shock heating from a projectile impact indicate that in shock experiments we can for the first time study the speciation of neutrals using a moderate resolution time-of-flight mass spectrometer. Measurements of the gas species from a series of proposed impact experiments appear to be quite feasible. We will attempt these experiments in the next year. Measurements of the impact induced shock wave decay in SiO2 and GeO2 glass are underway to measure these pure oxide properties. Predictive calculations indicate that the pressure will decay as r(exp -2.7) in the phase transition regime, versus a much lower rate of r(exp -1.18), if a phase transition does not occur.

Ahrens, Thomas J.↗
DOE OSTI2022

Folded network and structural transition in molten tin

The fundamental relationships between the structure and properties of liquids are far from being well understood. For instance, the structural origins of many liquid anomalies still remain unclear, but liquid-liquid transitions (LLT) are believed to hold a key. However, experimental demonstrations of LLTs have been rather challenging. Here, we report experimental and theoretical evidence of a second-order-like LLT in molten tin, one which favors a percolating covalent bond network at high temperatures. The observed structural transition originates from the fluctuating metallic/covalent behavior of atomic bonding, and consequently a new paradigm of liquid structure emerges. The liquid structure, described in the form of a folded network, bridges two well-established structural models for disordered systems, i.e., the random packing of hard-spheres and a continuous random network, offering a large structural midground for liquids and glasses. Our findings provide an unparalleled physical picture of the atomic arrangement for a plethora of liquids, shedding light on the thermodynamic and dynamic anomalies of liquids but also entailing far-reaching implications for studying liquid polyamorphism and dynamical transitions in liquids.

36 MATERIALS SCIENCE↗
DOE OSTI2025

Novel white light-emitting CdSe:Mn 2+ synthesized by photo-assisted chemical bath deposition

Nowadays, white light-emitting materials have attracted extensive research due to their potential applications in lighting devices and displaying images. Several semiconductor nanoparticles have been explored to achieve efficient white light emission. In this work, we report on novel white light-emitting CdSe:Mn 2+ thin films synthesized by photo-assisted chemical bath deposition. The effect of varying the Mn 2+ ion concentrations on the thin film structure, morphology, and optical properties was investigated. X-ray powder diffraction results indicated that all the films annealed at 250 degrees C possessed a cubic structure, with crystallite sizes in the range of 1-130 nm. Scanning electron microscopy demonstrated spherical nanoparticles with no significant changes with varying Mn 2+ doping concentrations. Energy dispersive X-ray spectroscopy confirmed the presence of the anticipated elements. The atomic force microscope revealed that the surface roughness has decreased with an increase in Mn 2+ ion concentrations but decreased for 0.7 %Mn 2+ . The UV-Vis absorption spectra showed absorption edges around 600-650 nm. Photoluminescence emission spectra excited at 3.8 eV (325 nm) showed emission bands at around 1.75 eV (709 nm), and 1.88 eV (659 nm), which were attributed to the band-to-band emission, and 4 T 1 ( 4 G)-> 6 A 1 ( 6 S) transitions of Mn 2+ ions, respectively, while emission bands at 2.35 eV (528 nm), and prominent at 3.17 eV (391 nm) were due to the glass substrate. The temperature-dependent luminescence showed a decrease in relative emission intensity with the increase in the operating temperature. The chromaticity colour coordinates showed white light-emitting thin films. These present findings open a new door to developing white light using CdSe thin films.

36 MATERIALS SCIENCE↗
DOE OSTI2026

Spinon mediation of witness spin dynamics in herbertsmithite

The kagome lattice of spin-1/2 copper atoms in herbertsmithite is conjectured to sustain a quantum spin liquid state with spinon quasiparticles. Ideally, the kagome crystal planes are each separated by a plane of spinless zinc atoms. However, in real crystals, some spin-1/2 copper atoms substitute randomly onto these inter-kagome zinc sites. Here we reconceptualize such ‘impurity’ atoms as quantum witness spins whose dynamics is designed to probe the spin liquid state. We then introduce spin noise spectroscopy to measure the frequency and temperature dependence of witness spin dynamics, demonstrating that their phenomenology is consistent with extensive interactions between witness spins mediated by propagation of spinons through a quantum spin liquid. Ultimately, a sharp transition occurs at around 260 mK, below which the properties of both spin noise and magnetic susceptibility suggest that the witness spins form a spin glass phase. Among the theoretical models considered, we demonstrate that our observations are only consistent with spinon-mediated interactions between witness spins by either a Z 2 or U(1) quantum spin liquid, with the former model more closely matching the data. Our work demonstrates that quantum mechanical witness spins may now conceivably be used as a widely applicable probe of quantum spin liquid physics.

Takahashi, Hiroto [University of Oxford (United Ki↗
DOE OSTI2022

A Combined Machine Learning and High-Energy X-ray Diffraction Approach to Understanding Liquid and Amorphous Metal Oxides

Determining the structure-property relations of liquid and amorphous metal oxides is challenging, due to their variable short-range order and polyhedral connectivity. To predict chemically realistic structures, we have developed a Machine Learned, Gaussian Approximation Potential (GAP) for HfO 2 , with a focus on enhanced sampling of the training database and accurate density functional theory calculations. By using training datasets for the GAP model at the level of Density Functional Theory-Strongly Constrained and Appropriately Normed (DFT-SCAN) level of theory, our results show that the topology of both the low viscosity liquid and the amorphous form are dominated by edge-shared chains and small corner-shared rings of polyhedra. This topology is shown to be consistent with the structure of other liquid and amorphous transition metal oxides of variable ion size, such as TiO 2 and ZrO 2 . Current limitations of the ML-GAP modeling method for obtaining glass structures and future perspectives are also discussed.

36 MATERIALS SCIENCE↗
NASA NTRS1986

Shock temperatures in anorthite glass

Shock-temperature data and the high-pressure thermal behavior of anorthite glass are examined. Temperatures of anorthite glass shocked to pressures between 48-117 GPa were measured in the temperature range 2500-5600 K using optical pyrometry techniques. The time dependence observed in the emitted light of the glass is analyzed in terms of temperature dependence, emissivity dependences, and the time dependence of absorption or scattering of an intervening layer. The three phase transitions at pressures of about 55, 85, and 100 GPa and with transition energies of about 0.5 MJ/kg are studied.

Boslough, M. B.↗
NASA NTRS1990

Photophysical behavior of doubly bridged d7-d7 metal-metal bonded compounds - The crystal structure and the excited- and ground-state electronic spectra of Re2(CO)6(dmpm)2 (dmpm = bis/dimethylphosphino/ methane)

Re2(CO)6(dmpm)2 shows photophysical behavior in a rigid medium that differs dramatically from that observed in fluid solution. In a hydrocarbon glass at 77 K, metal-metal bond homolysis is suppressed and an intense phosphorescence is observed. The transient absorption spectrum, which shows only weak transitions to the red of the ground state 1(sigma-sigma asterisk) transition, permits assignment of the emitting state to a 3(sigma-sigma asterisk) transition. The crystal structure of Re2(CO)6(dmpm)2 is also reported. The ground-state electronic structure is discussed relative to the structural data.

Milder, Steven J.↗