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At least 1,117 records · Page 62

Design of a Molten Salt Flow Cell for Combined Absorbance and Laser-Induced Breakdown Spectroscopy for Online Measurements

A novel flow cell allowing for multiple optical spectroscopy measurements on flowing molten salts was designed, and demonstrative calibrations of impurities in aqueous samples were performed. Online compositional measurements of molten salts are of high interest to monitor the state of relevant solar and nuclear systems. Here, the Spectroscopic Configuration for Optical Real-Time Characterization of High-Temperature (SCORCH) fluids cell was designed to meet this need by providing optical access to a high-temperature molten salt sample stream without physical contact between the sample and window materials. Laser-induced breakdown spectroscopy (LIBS) was utilized to quantify Li, Cr, Fe, Ni, Sr, and Pr at concentrations ranging nominally from 0 to 315 mmol L −1 . Laser power, frequency, and plasma position were optimized to mitigate challenges associated with sample splashing. Univariate calibration models were built with R 2 > 0.98, percent root mean square error of cross-validation (%RMSECV) as low as 2.7%, and limits of quantification (LOQs) down to 4.1 mmol L −1 . Simultaneously, absorbance calibrations were developed for the applicable analytes (Cr, Ni, and Pr) using Beer’s law with a pathlength of 4.41 ± 0.10 mm. These models provide excellent quantification performance with R 2 > 0.999, %RMSECV as low as 0.6%, and LODs down to 0.08 mmol L −1 . Although these calibrations were performed for each spectroscopic technique separately, the two methods may be combined in the future through multivariate modeling and sensor fusion to provide more robust models with the benefits of both techniques (e.g., absorbance: oxidation state concentrations, LIBS: elemental concentration). Additionally, optimized spectrometers may be deployed to enhance sensitivity.

absorbance spectroscopy↗

A Comparison of Satellite Based, Modeled Derived Daily Solar Radiation Data with Observed Data for the Continental US

Many applications of simulation models and related decision support tools for agriculture and natural resource management require daily meteorological data as inputs. Availability and quality of such data, however, often constrain research and decision support activities that require use of these tools. Daily solar radiation (SRAD) data are especially problematic because the instruments require electronic integrators, accurate sensors are expensive, and calibration standards are seldom available. The Prediction Of Worldwide Energy Resources (NASA/POWER; power.larc.nasa.gov) project at the NASA Langley Research Center estimates daily solar radiation based on data that are derived from satellite observations of outgoing visible radiances and atmospheric parameters based upon satellite observations and assimilation models. The solar data are available for a global 1 degree x 1 degree coordinate grid. SRAD can also be estimated based on attenuation of extraterrestrial radiation (Q0) using daily temperature and rainfall data to estimate the optical thickness of the atmosphere. This study compares daily solar radiation data from NASA/POWER (SRADNP) with instrument readings from 295 stations (SRADOB), as well as with values that were estimated with the WGENR solar generator. WGENR was used both with daily temperature and precipitation records from the stations reporting solar data and records from the NOAA Cooperative Observer Program (COOP), thus providing two additional sources of solar data, SRADWG and SRADCO. Values of SRADNP for different grid cells consistently showed higher correlations (typically 0.85 to 0.95) with SRADOB data than did SRADWG or SRADCO for sites within the corresponding cells. Mean values of SRADOB, SRADWG and SRADNP for sites within a grid cell usually were within 1 MJm-2d-1 of each other, but NASA/POWER values averaged 1.1 MJm-2d-1 lower than SRADOB. The magnitude of this bias was greater at lower latitudes and during summer months and may be at least partially explained by assumptions in ambient aerosol properties. Overall, the NASA/POWER solar radiation data are a promising resource for regional modeling studies where realistic accounting of historic variation is required.

White, Jeffrey W.↗

The Impact of Circumsolar Diffuse Radiation on the Numerical Computation and Forecasting of DNI

Weather Research and Forecasting model with solar extensions (WRF-Solar) uses the Fast All-sky Radiation Model for Solar applications (FARMS) to predict solar radiation from the forecasted atmospheric gases, aerosols, and clouds. The Beer-Bouguer-Lambert law utilized by FARMS as well as other radiative transfer models assumes Direct Normal Irradiance (DNI) is a narrow beam only covering the sun disk. This assumption is interpreted differently in solar observations by pyrheliometers where the circumsolar diffuse radiation is accounted. This study precisely computes circumsolar diffuse radiation in all-sky conditions using a radiative transfer model based on a parameterization of precomputed cloud transmittance and reflectance. The model is implemented in WRF-Solar to provide day-ahead DNI forecast in the north America. The computation and forecasting of DNI is compared with the Beer-Bouguer-Lambert law to understand the impact of circumsolar diffuse radiation.

aerosols↗

Mount St. Helens dust veil observed at Boulder, Colorado by optical techniques

Following the May 18, 1980, eruption of Mount St. Helens, photometric and photograhic observations were taken at Boulder, Colorado, to record the optical effects of volcanic dust atmospherically transported to this area. The instruments used included a narrow-beamwidth solar photometer which recorded solar irradiance in eight narrow-bandwidth channels in the wavelength range 0.3 to 1.1 microns, a solar aureole photometer, and two time-lapse camera systems. The eight-channel solar photometer data have been analyzed to obtain the wavelength dependence of optical thickness. At the longer wavelengths, on May 20, 1980, the optical thickness was as much as nine times that expected from a 'clean atmosphere' model. During the first several days following the eruption, the dust veil sometimes exhibited sufficient spatial structure that its motion can be seen on the time-lapse films. The results of analysis to date are presented and the plans for additional analysis are outlined.

Lerfald, G.↗

Observational Evidence of a Suppressed Planetary Boundary Layer in Northern Gale Crater, Mars as Seen by the Navcam Instrument Onboard the Mars Science Laboratory Rover

The Navigation Cameras (Navcam) of the Mars Science Laboratory rover, Curiosity, have been used to examine two aspects of the planetary boundary layer: vertical dust distribution and dust devil frequency. The vertical distribution of dust may be obtained by using observations of the distant crater rim to derive a line-of-sight optical depth within Gale Crater and comparing this optical depth to column optical depths obtained using Mastcam observations of the solar disc. The line of sight method consistently produces lower extinctions within the crater compared to the bulk atmosphere. This suggests a relatively stable atmosphere in which dust may settle out leaving the air within the crater clearer than air above and explains the correlation in observed column opacity between the floor of Gale Crater and the higher elevation Meridiani Planum. In the case of dust devils, despite an extensive campaign only one optically thick vortex (tau = 1.5 +/- 0.5 10(exp -3)) was observed compared to 149 pressure events greater than 0.5 Pa observed in REMS pressure data. Correcting for temporal coverage by REMS and geographic coverage by Navcam still suggests 104 vortices should have been viewable, suggesting that most vortices are dustless. Additionally, the most intense pressure excursions observed on other landing sites (pressure drop greater than 2.5 Pa) are lacking from the observations by the REMS instrument. Taken together, these observations are consistent with pre-landing circulation modeling of the crater showing a suppressed, shallow boundary layer. They are further consistent with geological observations of dust that suggests the northern portion of the crater is a sink for dust in the current era.

Navcam↗

The Development of New Solar Indices for use in Thermospheric Density Modeling

New solar indices have been developed to improve thermospheric density modeling for research and operational purposes. Out of 11 new and 4 legacy indices and proxies, we have selected three (F10.7, S10.7, and M10.7) for use in the new JB2006 empirical thermospheric density model. In this work, we report on the development of these solar irradiance indices. The rationale for their use, their definitions, and their characteristics, including the ISO 21348 spectral category and sub-category, wavelength range, solar source temperature region, solar source feature, altitude region of terrestrial atmosphere absorption at unit optical depth, and terrestrial atmosphere thermal processes in the region of maximum energy absorption, are described. We also summarize for each solar index, the facility and instrument(s) used to observe the solar emission, the time frame over which the data exist, the measurement cadence, the data latency, and the research as well as operational availability. The new solar indices are provided in forecast (http://SpaceWx.com) as well as real-time and historical (http://sol.spacenvironment.net/~jb2006/) time frames. We describe the forecast methodology, compare results with actual data for active and quiet solar conditions, and compare improvements in F10.7 forecasting with legacy High Accuracy Satellite Drag Model (HASDM) and NOAA SEC forecasts.

Tobiska, W. Kent↗

Hybrid Ground Station Technology for RF and Optical Communication Links

To support future enhancements of NASA's deep space and planetary communications and tracking services, the Jet Propulsion Laboratory is developing a hybrid ground station that will be capable of simultaneously supporting RF and optical communications. The main reason for adding optical links to the existing RF links is to significantly increase the capacity of deep space communications in support of future solar system exploration. It is envisioned that a mission employing an optical link will also use an RF link for telemetry and emergency purposes, hence the need for a hybrid ground station. A hybrid station may also reduce operations cost by requiring fewer staff than would be required to operate two stations. A number of approaches and techniques have been examined. The most promising ones have been prototyped for field examination and validation.

Radio frequency (RF) communications↗

System Advisor Model (SAM) Improvements for Emerging Solar Thermal Applications

The System Advisor Model (SAM) is an open-source tool developed by NREL to simulate the techno-economic performance of technologies like photovoltaics, solar thermal, wind, and geothermal. NREL has recently completed, active, and planned projects to improve the solar thermal models in SAM and its underlying code base to represent emerging component technologies, systems, and applications. This poster describes new capabilities in the SolarPILOT optical modeling tool, supercritical carbon dioxide (sCO2) power cycles, and solar industrial process heat.

14 SOLAR ENERGY↗

A Solar Aspect System for the HEROES Mission

A new Solar Aspect System (SAS) has been developed to provide the ability to observe the Sun on an existing balloon payload HERO (short for High Energy Replicated Optics). Developed under the HEROES program (High Energy Replicated Optics to Explore the Sun), the SAS aspect system provides solar pointing knowledge in pitch, yaw, and roll. The required precision of these measurements must be better than the HEROES X-ray resolution of approximately 20 arcsec Full Width at Half Maximum (FWHM) so as to not degrade the image resolution. The SAS consists of two separate systems: the Pitch-Yaw Aspect System (PYAS) and the Roll Aspect System (RAS). The PYAS functions by projecting an image of the Sun onto a screen with precision fiducials. A CCD camera takes an image of these fiducials, and an automated algorithm determines the location of the Sun as well as the location of the fiducials. The spacing between fiducials is unique and allows each to be identified so that the location of the Sun on the screen can be precisely determined. The RAS functions by imaging the Earth's horizon in opposite directions using a silvered prism imaged by a CCD camera. The design and first results of the performance of these systems during the HEROES flight which occurred in September 2013 are presented here.

HEROES↗

Effective albedo of an optically thin scattering layer

An examination of the sensitivity of the effective albedo of an optically thin scattering layer for day-long solar irradiation at equinox to (1) the anisotropy parameter, which is controlled by the size of the scatterers, (2) the exclusion of the sun-near-horizon irradiation, and (3) the assumption of a spherical vs an irregular shape of the scatterers, is discussed. The albedo is analyzed assuming that for a specified phase function, which is split into a point-symmetrical component and an asymmetrical remainder, the albedo is proportional to the vertical optical thickness. It is shown that if the optical thickness and the phase function are not accurately known, lidar measurements of a thin dust layer can provide useful information for the climatic effect of the scatterers.

Otterman, J.↗

Airborne lidar observations of smoke haze during SCAR-B 1995

The Smoke, Clouds, Aerosol, and Radiation Brazil(SCAR-B) field campaign was conducted to study the effects that widespread and persistent biomass burning have upon radiative and chemical processes in the atmosphere. The radiative transfer characteristics of the atmosphere are altered by the introduction of particulate and gaseous materials which are the products of the combustion of vegetative material at ground level. These substances are transported and distributed horizontally and vertically by atmospheric dynamical processes which may be perturbed by the heat energy from the fires. As the pollutants disperse, their physical and chemical properties change substantially. A complete description of the effects of smoke requires that the evolution back to the natural situation be fully examined. A most important component of smoke haze investigation is finding its vertical and horizontal distribution in relation to the driving factors of dynamics and the related horizontal transport. In this presentation, we employ data from the Cloud Lidar System(CLS), carried aboard the NASA ER-2 aircraft, to provide a unique view of the particulate or aerosol loading produced by fires, especially with regard to the geometrical distribution of the aerosols in the vertical plane. The lidar has the ability to measure aerosol optical properties in a continuous fashion at quite fine vertical and horizontal resolution. The results from the lidar provide measurements that are largely independent of influences that corrupt passive instruments and thus it can serve to corroborate their results. The extended horizontal and vertical range of lidar results can also augment ground based and airborne in situ measurements which have limited horizontal and vertical scope. We present the results of our analysis of CLS observations taken during the SCAR-B field campaign. Observations of the the aerosol optical thickness from the Aerosol Robotic Network(AERONET) of solar photometers are employed in conjunction with CLS data to derive extinction to backscatter ratio values which are used to convert the lidar backscatter coefficient into extinction coefficient. The extinction coefficient is integrated vertically to find aerosol optical thickness along ER-2 flight tracks. We use images of the CLS derived extinction coefficient to depict its horizontal and vertical distribution. Multispectral photometer optical thickness is used to compute the Angstrom exponent. With these, we examine the hypothesis that the values of extinction to backscatter ratio can be related to the Anstrom coefficient since both of these would be a function of the refractive index and size distribution of the aerosols.

Hart, William D.↗

Accretion Disk Spectra of the Ultra-luminous X-ray Sources in Nearby Spiral Galaxies and Galactic Superluminal Jet Sources

Ultra-luminous Compact X-ray Sources (ULXs) in nearby spiral galaxies and Galactic superluminal jet sources share the common spectral characteristic that they have unusually high disk temperatures which cannot be explained in the framework of the standard optically thick accretion disk in the Schwarzschild metric. On the other hand, the standard accretion disk around the Kerr black hole might explain the observed high disk temperature, as the inner radius of the Kerr disk gets smaller and the disk temperature can be consequently higher. However, we point out that the observable Kerr disk spectra becomes significantly harder than Schwarzschild disk spectra only when the disk is highly inclined. This is because the emission from the innermost part of the accretion disk is Doppler-boosted for an edge-on Kerr disk, while hardly seen for a face-on disk. The Galactic superluminal jet sources are known to be highly inclined systems, thus their energy spectra may be explained with the standard Kerr disk with known black hole masses. For ULXs, on the other hand, the standard Kerr disk model seems implausible, since it is highly unlikely that their accretion disks are preferentially inclined, and, if edge-on Kerr disk model is applied, the black hole mass becomes unreasonably large (greater than or approximately equal to 300 Solar Mass). Instead, the slim disk (advection dominated optically thick disk) model is likely to explain the observed super- Eddington luminosities, hard energy spectra, and spectral variations of ULXs. We suggest that ULXs are accreting black holes with a few tens of solar mass, which is not unexpected from the standard stellar evolution scenario, and their X-ray emission is from the slim disk shining at super-Eddington luminosities.

White, Nicholas E.↗

LADEE UVS Observations of Solar Occulation by Exospheric Dust above the Lunar Limb

The Lunar Atmosphere and Dust Environment Explorer (LADEE) is a lunar orbiter launched in September 2012 that investigates the composition and temporal variation of the tenuous lunar exosphere and dust environment. The primary goals of the mission are to characterize the pristine gas and dust exosphere prior to future lunar exploration activities, which may alter the lunar environment. To address this goal, the LADEE instrument suite includes an Ultraviolet/ Visible Spectrometer (UVS), which searches for dust, Na, K, and trace gases such as OH, H2O, Si, Al, Mg, Ca, Ti, Fe, as well as other previously undetected species. UVS has two sets of optics: a limb-viewing telescope, and a solar viewing telescope. The solar viewer is equipped with a diffuser (see Figure 1a) that allows UVS to stare directly at the solar disk as the Sun starts to set (or rise from) behind the lunar limb. Solar viewer measurements generally have very high signal to noise (SNR>500) for 20-30 ms integration times. The 1-degree solar viewer field of view subtends a diameter of ~8 km at a distance of 400-450 km

pristine gas↗

LADEE UVS Observations of Solar Occultation by Exospheric Dust Above the Lunar Limb

The Lunar Atmosphere and Dust Environment Explorer (LADEE) is a lunar orbiter launched in September 2012 that investigates the composition and temporal variation of the tenuous lunar exosphere and dust environment. The primary goals of the mission are to characterize the pristine gas and dust exosphere prior to future lunar exploration activities, which may alter the lunar environment. To address this goal, the LADEE instrument suite includes an Ultraviolet/ Visible Spectrometer (UVS), which searches for dust, Na, K, and trace gases such as OH, H2O, Si, Al, Mg, Ca, Ti, Fe, as well as other previously undetected species. UVS has two sets of optics: a limb-viewing telescope, and a solar viewing telescope. The solar viewer is equipped with a diffuser (see Figure 1a) that allows UVS to stare directly at the solar disk as the Sun starts to set (or rise from) behind the lunar limb. Solar viewer measurements generally have very high signal to noise (SNR greater than 500) for 20-30 ms integration times. The 1-degree solar viewer field of view subtends a diameter of approximately 8 km at a distance of 400-450 km.

LADEE↗

Astrophysics from the moon; Proceedings of the Workshop, Annapolis, MD, Feb. 5-7, 1990

The present conference on astrophysics from the moon encompasses the study of the Galaxy, external planetary systems, solar physics, stars and stellar evolution, the frontiers of Galactic, extragalactic, and cosmological astronomy, an introduction to lunar-based astronomy, concepts for lunar observatories including high-energy observatories, solar observatories, and observatories for particle astrophysics and gravitational studies. Specific issues addressed include the dynamics of Jovian atmospheres, planetary magnetospheres, flare physics, exobiology and SETI from the lunar farside, and the study of interactive stars, star formation, H II regions in absorption at low frequencies, and normal galaxies. Also addressed are the potential lunar investigation of quasars, the formation epoch, and the large-scale structure of the universe, and observational issues related to X-ray large arrays, optical interferometers, VLF radio astronomy, a UV-solar reflecting coronagraph, and a heavy-nucleus detector.

Mumma, Michael J.↗

Optical properties of poly-HCN and their astronomical applications

Matthews (1992) has proposed that HCN "polymer" is ubiquitous in the solar system. We apply vacuum deposition and spectroscopic techniques previously used on synthetic organic heteropolymers (tholins), kerogens, and meteoritic organic residues to the measurement of the optical constants of poly-HCN in the wavelength range 0.05-40 micrometers. These measurements allow quantitative comparison with spectrophotometry of organic-rich bodies in the outer solar system. In a specific test of Matthews' hypothesis, poly-HCN fails to match the optical constants of the haze of the Saturnian moon, Titan, in the visible and near-infrared derived from astronomical observations and standard models of the Titan atmosphere. In contrast, a tholin produced from a simulated Titan atmosphere matches within the probable errors. Poly-HCN is much more N-rich than Titan tholin.

Optics↗

Investigation of Flux Spreading in a Light-Trapping, Planar-Cavity Receiver for Enclosed Solar Particle Heating

Concentrating solar thermal power (CSP) technology development has recently focused on increasing the operating temperatures to accommodate high efficiency power cycles and thermochemical processes. Inert solid particles as heat transfer media enable solar receivers to operate above 700 degrees Celsius resulting in increased system thermal efficiency compared to the conventional molten salt based CSP system. An open-cavity falling-particle solar receiver that can efficiently heat particles by direct heating from concentrated solar radiation faces challenges with large particle losses from wind and unable to support thermochemical reactions. A light-trapping, planar cavity reiver (LTPCR) where particles are indirectly heated can significantly minimize the particle losses during the operation, support thermochemical reactions, and offer scalability potential. The LTPCR features an array of vertical planar receiver/absorber panels arranged within a cavity configuration. Concentrated solar radiation from heliostats is focused onto the receiver walls, where heat is indirectly transferred to solid particles flowing inside the receiver channels. Heat transfer occurs through direct contact between the receiver panel walls and particles, and can be enhanced by fluidizing particles with air. This fluidization increases particle-wall contact and extends particle residence time, maximizing heat transfer efficiency. The unique vertical planar receiver structure originated from a near-blackbody tubular light absorber, effectively distributing the incoming solar beam spread across the panel walls and trapping light. This flux spreading effect, driven by cosine projection, converts high incident solar flux into a lower, more uniform heat flux on the panel walls. This redistribution enhances heat transfer efficiency between particle-wall or reaction gases-wall, while preventing localized overheating of the receiver panel. Indirect planar cavity solar receivers completely separate solid particles from the ambient environment that can greatly reduce the thermal losses in heated particles resulting in high efficiency at high temperatures above 700 degrees Celsius. This design ensures no particle losses to the environment during the operation while open-cavity designs can experience significant particle losses from wind. An experimental investigation was conducted to observe flux spreading on the receiver panel wall. A lab-scale prototype planar receiver, fabricated using Haynes 230 alloy, was tested under direct concentrated solar radiation using the high-flux solar furnace (HFSF) facility at NREL. The experiment was performed under normal peak radiative heat fluxes ranging from 800 to 1900 kW/m2. A temperature distribution on the panel wall was measured using a thermal imaging camera (FLIR A 6600). To prevent overheating at the receiver front tip, prism-shaped heat shields (Zircar UNIFROM C1) were placed in front of the receiver, and their influence on flux spreading was also studied. Absorbed flux distribution on the panel wall was modeled using SolTrace. The total solar power and flux distributions delivered from HFSF were determined based on the heliostat mirror optical properties, direct normal irradiance (DNI) on the on-sun testing days, peak flux measurement during the on-sun testing, and shutter/attenuator settings Due to the large incident angles of the solar beam on the panel wall, the angular optical properties of Haynes 230 alloy and Zircar heat shields were incorporated into the model. This flux distribution model was then integrated into a computational fluid dynamics (CFD) simulation to predict the receiver panel wall temperature, which was compared with the experimental measurements. Both prediction and measurements identified a temperature hotspot at the backside of the panel, indicating that the incident solar beam can fully reach to the rear of the receiver. The heat shields positioned at the front of the receiver effectively reduced the excessive temperature rise at the receiver front tip. Overall, the temperature was well distributed over the panel wall, with a minor hotspot at the back of the receiver. The model slightly overpredicted the temperature, possibly due to discrepancies in optical properties of the panel and an underprediction of thermal loss in the receiver. The advancement of the particle LTPCR offers a viable alternative to open-cavity receivers by addressing particle loss issues. Additionally, it presents a pathway for enabling solar thermochemical processes, extending CSP technology beyond power generation to fuel and chemical production.

14 SOLAR ENERGY↗

Saturn's rings - Infrared brightness variation with solar elevation

The main subject of the discussed investigation is the infrared brightness variation of the A, B, and C rings, as a function of solar elevation. Existing models for the B ring are not entirely satisfactory. A description is presented of a model applicable to all three rings. This model and other existing models are compared with the available data. Particular attention is given to the 20-micrometer observations of Saturn's rings. It is found that the brightness variation of the A and B rings with solar elevation angle can be well modeled by an optically thick monolayer of particles, or equivalently, a flat sheet, emitting on one side only. This points to a temperature contrast between the two sides of the ring plane. The infrared brightness of the C ring increases as the solar elevation angle with respect to the ring plane decreases.

Froidevaux, L.↗