Factors that Impact Extraction and Separation : Guiding Development for Materials to Sequester PFAS
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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.
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The UNCLE-SAM project, under the Biotechnologies to Ensure a Robust Supply of Critical Materials for Clean Energy program, examined the biomining applications of seaweeds for sustainable, domestic production of critical mineral feedstocks. The ocean is a vast reserve of mineralogical wealth including rare earth elements (REEs) and platinum group metal (PGMs). These elements, categorized as “critical minerals”, are used in telecommunication devices, lasers, LED lighting, turbine generators, electric car motors, jet engine alloys, and many other applications. These critical elements are increasingly vital to a thriving, efficient and sustainable society. However, only a few countries in the global market currently produce and export REEs, leading to potential geopolitical supply disruptions. Marine macroalgae, often referred to as seaweeds, bioconcentrate critical minerals from seawater, including REEs and PGMs. Marine algae cultivation can generate a significant amount of biomass with minimal freshwater, fertilizer, and land requirements. In summary, the UNCLE-SAM project successfully evaluated the technological feasibility for marine macroalgal cultivation as a feedstock for critical minerals, explored the biological capacity of different seaweeds to provide economically relevant domestic mineral production, assessed processing techniques for thermal co-conversion of seaweeds into renewable fuel and mineral feedstocks, and executed techno-economic and lifecycle assessments for identifying the most critical gaps in our current understanding to move the technology into commercially relevant deployment. Further development of this technology could transform the bioproduct and REE mining industries and catalyze the development of a more sustainable future.
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This analysis expands upon previous life cycle analyses (LCAs) of natural gas systems performed by the National Energy Technology Laboratory (NETL). It provides a complete inventory of emissions to air and water, water consumption, and land use change. These environmental burdens are detailed for all supply chain steps from natural gas production through natural gas distribution. This package includes the report, the NETL Natural Gas Model, and appendices that include several Excel workbooks and a python script to provide transparent access to the calculations and resulting data. This is revision 1 of the 2024 study (published December 17, 2024 and updated on January 24, 2025) and corrects a modeling error in natural gas composition. See the errata on page 2 for more information.
This document describes results from the WAMOR Chesapeake Bay collection in October 2024, a data collection from the Arkeus HSOR hyperspectral sensor. The calibration array was staged at USCG Station Little Creek, Virginia. With the provided HSOR imagery and data, our analysis does not show a capability to effectively detect materials of interest from non-materials of interest as well as differentiate materials of interest from each other, the materials of interest being polypropylene, polyester, and cotton. The fundamental reasons are (1) the spectral bands of HSOR do not reside in specific wavelength locations to allow for material identification and (2) the provided imagery appears to not have consistent band-to-band relationships indicative of a lack of calibration (gain/offsets) or some other calibration issues. With regard to analyzing a subset of the delivered HSOR, HSOR can make general statements about materials not being water and have the capability to make color assessments.
The goal of the salt sampling program at Argonne is to develop and deploy automated molten salt sampling approaches for interfacing relevant unit operations with salt analysis to improve the timeliness of sampling-based accountancy measurements. Two technologies under development in support of this goal are a vacuum sampling loop module and a high-throughput pneumatic sample generator module. Compared to traditional point sampling approaches (i.e., dip probes), the vacuum sampling loop facilitates the collection of a larger cross-section of the bulk salt in order to collect more representative samples. The vacuum sampling approach also eliminates the risk of dross contamination of samples and avoids the use of moving parts in the salt. The pneumatic sample generator module is used to facilitate high-throughput sample analysis to improve the measurement precision of any given analytical technique by averaging out random sampling and measurement errors. In FY21, two methods for integrating these two modules were tested including direct fluidic coupling and coupling using a solid salt transfer mechanism. Solid salt transfer was ultimately selected over fluidic coupling, primarily to enable the transport of samples over longer distances to support automated at-line integration with high-precision techniques (such as microcalorimetry) that cannot withstand the conditions near an electrorefining process. To facilitate rapid solid salt coupling, new mechanisms were developed for rapidly charging and discharging salt sample tubes at the vacuum sampling loop and pneumatic sample generator modules, respectively. While the charging mechanism will be deployed in FY22, the discharge mechanism was tested in FY21 and is described here. The solid salt tube transfer method was deployed at one of Argonne’s engineering-scale electrorefiners to implement at-line high-throughput pneumatic micro-sample generation capabilities. The approach was used to generate precise uranium- and lanthanide-bearing electrorefiner micro-samples with the specific dimensions requested by researchers at Los Alamos National Laboratory for use in testing their novel microcalorimeter x-ray techniques. The solid salt transfer mechanism proved not only to be an effective means of integrating the precision sample generator with vacuum sampling, but also improved the performance of the sampler generator. To discharge salt from the sample tubes at the sampler generator, tube segments were inserted directly into the sample generator’s Helmholtz chamber and pressure pulse actuations were used to generate precision molten salt samples directly from the tube segments. The direct insertion of sample tubes into the sample generator enabled rapid loading of the salt and prevented salt from contacting most of the interior surfaces of the sample generator, which eliminated cross-contamination between runs. The vacuum sampling-loop tube charging mechanism will support high-throughput tube sampling operations by employing a dynamic vacuum filling process to fill short charge tubes that are configured to be rapidly connected and disconnected from the loop. The dynamic vacuum sampling operation will be automated, and sample tube handling can be executed with simple overhead actuation. Because the modular sampling approach described here eliminates the need for new high-radiation sample handling capabilities, salt-wetted seals, salt-wetted moving parts, and heated transfer lines outside the electrorefiner, it will address most of the remaining technical challenges for the at-line deployment of high-precision analytical techniques which will enable significant reductions in the time delay for sampling-based high-precision accountancy measurements.
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Littoral Power Systems (LPS) has been granted a FERC preliminary permit for the Upper Cook Inlet Tidal Energy Project in an area that includes existing non-producing natural gas platforms. LPS is working to understand the feasibility of a 2 MW tidal energy project and is considering multiple technologies, the viability of using the platforms to support deployment and operation of the technologies, as well as the environmental conditions that will interact with tidal energy devices. The proposed TEAMER work will conduct a modeling study to understand 1) current velocity and turbulence; 2) the distribution of sea ice trajectories around the platform; and 3) the likelihood of seabed erosion and deposition through an analysis of shear stress in the seabed near the platforms. The results of this work will contribute to determining the feasibility of the site for tidal energy development.
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