Observation of hyperfine level crossing in stimulated emission.
Level crossing effect in stimulated emission and application to determination of hyperfine splitting in Xe 129 excited electronic state during laser transition
Bonczyk, P. A.↗
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Results for “ELECTRON TRANSITION”
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Effective masses in Zr-doped superconducting ceramic SrTiO sub 3.
Zr doped superconducting ceramic strontium titanate, noting effective electron mass variations and transition temperature
Eagles, D. M.↗
Excitation of N2 and N2/+/ systems by electrons. 2 - Excitation cross sections and N2 1PG low pressure afterglow
Characteristics of Meinel systems excited by electrons and measurement of transition probabilities, excitation cross sections, and afterglow effects
Broadfoot, A. L.↗
Ordering Effects in NbC and TaC
By means of transmission electron microscopy and electron diffraction, evidence has been obtained for the existence of long range carbon atom ordering in single-crystal niobium carbide that has a carbon-to-metal ratio close to the integral composition Nb6C5. The ordering, which gives rise to superlattice and domain structures similar to those observed in V6C5, appears, however, only in samples that have been cooled slowly through the order-disorder temperature of 1025 C. In TaC of similar composition, the ordering, although present, remains very imperfect even after the crystals are subjected to the same thermal treatment. The results are interpreted in terms of the electronic structure of the transition metal carbides as it is currently understood, and their relevance to the mechanical properties of NbC and TaC are discussed.
Venables, J. D.↗
Deformed Brueckner-Hartree-Fock calculations
The renormalized Brueckner-Hartree-Fock (RBHF) theory for many-body nuclear systems is generalized to permit calculations for intrinsic states having permanent deformation. Both Hartree-Fock and Brueckner self-consistencies are satisfied, and details of the numerical techniques are discussed. The Hamada-Johnston interaction is used in a study of deformations, binding, size, and separation energies for several nuclei. Electromagnetic transition rates, moments, and electron scattering form factors are calculated using nuclear wave functions obtained by angular momentum projection. Comparison is made to experiment as well as to predictions of ordinary and density-dependent Hartree-Fock Theory.
Ford, W. F.↗
Deactivation of N2 A/super 3/Sigma/sub u/+ molecules in the aurora.
Recent rocket observations of the molecular nitrogen Vegard-Kaplan system in the aurora have been reinterpreted using an atmospheric model based on mass spectrometer measurements in an aurora of similar intensity at the same time of year. It is found that the population rates of the considered levels in the aurora are accurately determined by radiative cascade from two other states excited by direct electron impact. In some bright auroras the role of NO in quenching the lower vibrational levels of the A state is significant. The conclusions are based on a number of relevant auroral observations in combination with calculations using electron cross section and transition probability measurements by Shemansky and Broadfoot (1971).
Shemansky, D. E.↗
Deformed Brueckner-Hartree-Fock calculations.
The renormalized Brueckner-Hartree-Fock (RBHF) theory for many-body nuclear systems has been generalized to permit calculations for intrinsic states having permanent deformation. Both Hartree-Fock and Brueckner self-consistencies are satisfied, and details of the numerical techniques are discussed. The Hamada-Johnston interaction is used in a study of deformations, binding, size, and separation energies for several nuclei. Electromagnetic transition rates, moments, and electron scattering form factors are calculated using nuclear wave functions obtained by angular momentum projection. Comparison is made to experiment as well as to predictions of ordinary and density-dependent Hartree-Fock theory.
Ford, W. F.↗
Excitation and dissipation of Pc-1 micropulsations
A theoretical model based on hydromagnetic instabilities (including Alfven firehose and magnetoacoustic mirror instabilities), in the region where the electrons are in the transition from collisional to collisionless and ions are in the collisionless region, is proposed as a possible wave emission mechanism for Pc-1 pulsations. The model is compared with recent observations with good agreement between the theory and observations, especially for an emission source located at a distance L less than 5. Furthermore, a suggestion is made that the hydromagnetic instabilities could be relevant to the night and early morning hours emissions while the ion cyclotron instabilities could be responsible for the daytime emission of Pc-1 pulsations.
Hung, R. J.↗
Work function determination of promising electrode materials for thermionic energy converters
The work function determinations of candidate materials for low temperature (1400 K) thermionics through vacuum emission tests are discussed. Two systems, a vacuum emission test vehicle and a thermionic emission microscope are used for emission measurements. Some nickel and cobalt based super alloys were preliminarily examined. High temperature physical properties and corrosion behavior of some super alloy candidates are presented. The corrosion behavior of sodium is of particular interest since topping cycles might use sodium heat transfer loops. A Marchuk tube was designed for plasma discharge studies with the carbide and possibly some super alloy samples. A series of metal carbides and other alloys were fabricated and tested in a special high temperature mass spectrometer. This information coupled with work function determinations was evaluated in an attempt to learn how electron bonding occurs in transition alloys.
Jacobson, D.↗
Measurement of the fundamental vibration-rotation spectrum of ClO
The ClO fundamental absorption band near 850/cm is observed, with a tunable PbSnTe diode laser used as a source of monochromatic radiation. The chlorine monoxide concentration in the absorption tube was measured indirectly via a UV transmission technique. Frequencies and assignments for the ClO lines, and band centers and rotational constants for the ClO fundamental vibration, are tabulated. Diatomic vibration-rotation transitions within and between electronic substates are discussed. The tunable diode laser is valuable for studying the hyperfine structure. The IR spectroscopic technique is developed in order to monitor chlorine monoxide concentration in the stratosphere, since the short-lived ClO is a crucial intermediate participant in reactions involving destruction of stratospheric ozone.
Menzies, R. T.↗
Semiclassical study of reactive scattering in a laser field - F + H2 + barred-h times omega times /1.06 microns/ system
Semiclassical calculations of collinear F+H2(nu = 0) reactive and inelastic scattering in an Nd-glass laser field of various intensities are described. The decoupling approximation developed for the Miller-George theory is used for nonadiabatic transitions between the electronic-field surfaces, and special attention is paid to the choice of a proper coordinate system for applying the decoupling approximation. An increase in the total reaction probability and population ratio of the nu = 3 over nu = 2 vibrational state of HF occurs suddenly as the field intensity increases beyond 10 TW/sq cm. It is found that in a laser field the H2 molecule can be vibrationally excited while the F atom is electronically excited.
Yuan, J.-M.↗
Effect of rotational excitation on the band oscillator strength of OH
In the study described, a single-frequency tunable CW dye laser was used to obtain accurate absorption measurements of the band oscillator strength for various rotational-electronic lines in some transitions of OH. The band oscillator strength is shown to decrease linearly with the energy of rotational excitation. This decrease is attributed exclusively to the lengthening of the internuclear distance due to rotation.
Wang, C. C.↗
Parity-violating electric-dipole transitions in helium
The paper examines parity-violating electric-dipole transitions in He in order to gain insight into the reliability of approximate calculations which are carried out for transitions in many-electron atoms. The contributions of the nearest-lying states are computed with a variety of wave functions, including very simple product wave functions, Hartree-Fock functions and Hylleraas-type wave functions with up to 84 parameters. It is found that values of the matrix elements of the parity-violating interaction can differ considerably from the values obtained from the good wave functions, even when these simple wave functions give accurate values for the matrix elements in question
Hiller, J.↗
Statistical equilibrium in cometary C2. III - Triplet-singlet, Phillips, Ballik-Ramsay, and Mulliken bands
A new series of vibrational bands is predicted which arises from transitions between the lowest electron states of the triplet and singlet states of homonuclear C2. The predictions are useful for C2 identifications and for disentangling congested low resolution spectra that characterize new observations. Predictions are also made for Mulliken, Phillips, and Ballik-Ramsay band sequences, and all calculations are made with the assumed molecular constants and computational methods of KSO-II.
Swamy, K. S. K.↗
Exciton effects in the index of refraction of multiple quantum wells and superlattices
Theoretical calculations of the index of refraction of multiple quantum wells and superlattices are presented. The model incorporates both the bound and continuum exciton contributions for the gamma region transitions. In addition, the electronic band structure model has both superlattice and bulk alloy properties. The results indicate that large light-hole masses, i.e., of about 0.23, produced by band mixing effects, are required to account for the experimental data. Furthermore, it is shown that superlattice effects rapidly decrease for energies greater than the confining potential barriers. Overall, the theoretical results are in very good agreement with the experimental data and show the importance of including exciton effects in the index of refraction.
Kahen, K. B.↗
Dual-spacecraft measurements of plasmasphere-ionosphere coupling
An extensive set of plasmaspheric measurements by the DE 1 satellite and ionospheric measurements by the DE 2 satellite are presented. The developments in the ionosphere and plasmasphere during the recovery phase of a magnetospheric storm are described. Isolated profile comparisons are used to indicate some of the structural relations and complexities involving the ionosphere and plasmasphere latitudinal profiles. A transition in the ionospheric electron temperature Te from a relatively smooth profile of low Te at the base of the inner plasmasphere to enhanced and highly structured Te at higher invariant latitudes occurs near or along a plasmaspheric density gradient. Plasmaspheric enhancements of the heavy ions O(+) and O(2+) are often closely aligned with distinct ionospheric Te enhancements.
Horwitz, J. L.↗
New electronic states of NH and ND observed by resonance enhanced multiphoton ionization spectroscopy
Resonance Enhanced MultiPhoton Ionization (REMPI) spectra of NH and ND, which reveal four new electronic states are presented. Transitions from NH a 1 delta to 3s and 3p Rydberg states in both NH and ND have been observed and rotationally analyzed. The transitions were observed in the wavelength range of 258 to 288 nm. The state assignments are: e 1 pi (3s sigma) at 82857/cm, f 1 pi (3p sigma) at 86378/cm, g 1 delta (3p pi) at 88141/cm and h 1 sigma (3p pi) at 89151/cm.
Johnson, Russell D., III↗
Composition dependence of superconductivity in YBa2(Cu(3-x)Al(x))Oy
Eleven different compositions in the system YBa2(Cu(3-x)Al(x))O(y) (x = 0 to 0.3) have been synthesized and characterized by electrical resistivity measurements, powder x-ray diffraction, and scanning electron microscopy. The superconducting transition temperature T sub c (onset) was almost unaffected by the presence of alumina due to its limited solubility in YBa2Cu3O(7-x). However, T sub c(R = 0) gradually decreased, and the resistive tails became longer with increasing Al2O3 concentration. This was probably due to formation of BaAl2O4 and other impurity phases from chemical decomposition of the superconducting phase by reaction with Al2O3.
Bansal, Narottam P.↗