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Materials and Fuels Complex (FY2021-2025 Five-Year Mission Strategy)

The Idaho National Laboratory (INL), through its designated mission of advancing innovative nuclear energy solutions, is actively engaged in the research, development, demonstration and deployment of advanced nuclear technology, as well as in fostering private-public partnership for technology development. Key to the success of INL’s mission is the Materials and Fuels Complex (MFC), the only complex in the U.S. that hosts a world-class assemblage of facilities, capabilities and instruments for handling, testing, and characterizing radioactive materials. Driven by its mission/vision of “Engineering and Experiments that Drive the World’s Nuclear Energy Future,” MFC is at the center of INL’s – and indeed the Department of Energy’s – advanced nuclear technology development initiatives, providing essential capabilities such as engineering-scale high-assay low-enriched uranium (HALEU) fuel production, reactor demonstration facilities, post-irradiation examination, and transient irradiation testing. Furthermore, MFC provides an ideal environment for test beds that are utilized for research, development and demonstration (RD&D) activities on used fuel treatment, nuclear non-proliferation, forensics, and nuclear power sources used for space exploration missions conducted by the National Aeronautics and Space Administration (NASA).

99 GENERAL AND MISCELLANEOUS↗

Validating Intra-Plate Power Distributions in the Advanced Test Reactor

We report that the neutronics software, HELIOS, was validated in 2015 for performing core reload design and safety analysis of the Advanced Test Reactor. However, when HELIOS was benchmarked against historic fission-wire measurements (i.e., zero-power full-core measurements) a statistically resolved calculation-to-measurement bias was discovered. The azimuthal power along each fuel plate computed by HELIOS has consistently shown to under-predict measurements made by fission-wires in historic zero-power tests near the fuel element side-plates. It was hypothesized during the HELIOS software validation work, that this bias is attributable to local moderation in coolant vents in the side-plates axially just above and below the fission-wires on the fuel-plate edges. This work used detailed MCNP and MC21 models of the side-plate vents to test this hypothesis. By comparing the average azimuthal biases between HELIOS, and 2D and 3D MCNP models, and a 3D MC21 model, it was found that the HELIOS azimuthal bias is not due to the measurement.

21 SPECIFIC NUCLEAR REACTORS AND ASSOCIATED PLANTS↗

Performance and Stability of HyBRID Process - 19115

The HyBRID (Hydrazine Base Reductive metal Ion Decontamination) process shows good decontamination performance on radioactively contaminated specimens gathered from Hanul nuclear power plant and from the HANARO research reactor. The effect of γ-ray irradiation on the decomposition of decontamination solution is investigated. In an oxidation step, KMnO{sub 4} decomposes entirely when the absorbed dose exceeds 20 KGy. The addition of Cu{sup 2+} ion to SP retards slightly the decomposition of KMnO{sub 4}. Less than 20 % of hydrazine in the HyBRID solution, however, decomposes at 20 KGy. To treat the secondary waste generated from the HyBRID process by filtration, it is necessary to demonstrate the integrity of polypropylene filters by γ-ray irradiation. The absorbed dose is in the range of 0 KGy to 80 KGy. The variation of tensile strength and the variation of surface morphology of the irradiated PP filters are investigated. The mechanical test results show that the filters can be used safely in the test range. Hydrazine is decomposed into nitrogen and water by hydrogen peroxide. Tests on the decomposition of hydrazine by a hydrogen peroxide solution are carried out by varying the solution pH in the temperature range between 50 deg. C and 70 deg. C. The decomposition of hydrazine becomes effective as the increase of pH and the repetitive injections of hydrogen peroxide, and hydrazine is satisfactorily decomposed. The effect of copper ion on the decomposition of hydrazine is negligible. (authors)

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Fabrication and Testing of Micro Flux Monitors in the High Flux Isotope Reactor

Neutron dosimetry is a critical technique to measure the neutron flux, fluence, and energy spectrum of nuclear reactors and can be used to indicate fuel reloading, high-power operations, or changes in cycle length. This work presents results of a novel device named the micro flux monitor, which is a miniaturized neutron dosimeter made from small quantities (100s of nanograms) of Ti, Al, Ni, and Au metals deposited on Si and high-purity fused silica substrates using standard semiconductor fabrication techniques. Approximately 1,250 of these devices were produced, and 40 were irradiated in the pneumatic tube facility of the Neutron Activation Analysis Laboratory at the High Flux Isotope Reactor. Testing demonstrated that dosimeter metals can be deposited predictably and repeatedly in multiple geometries, including as quick response (QR) codes. Neutron flux measurements with these devices were within 3% of measurements made using standard flux monitors, demonstrating the efficacy of these devices. Devices were also tested at 500°C under a N2 atmosphere and showed minimal degradation, suggesting they could be deployed for neutron dosimetry measurements in high-temperature advanced reactors.

21 SPECIFIC NUCLEAR REACTORS AND ASSOCIATED PLANTS↗

Measure Effects of Molten Halide Salt on Creep Rupture Lifetime for 316H, 709 and 617

Ongoing commercialization of different molten salt reactor concepts can considerably benefit from quantitative information on the impact of molten halide salts on the engineering properties such as creep and fatigue strength of materials of interest. Limited legacy data from the molten salt reactor experiment (MSRE) program showed a significant reduction in creep rupture strength of a Ni-base alloy in molten fluoride salt. This task evaluated the creep behavior of candidate structural materials 316H, 709 and 617 for advanced nuclear reactors under molten halide salt environments at 650, 700 and 750°C respectively. Creep tests were conducted in air, Ar, fluoride (FLiNaK) and chloride (NaCl-MgCl 2 ) salts. The molten salt environment caused a 50% reduction in creep rupture lifetime for 316H in FLiNaK and an 80% reduction in creep rupture lifetime in NaCl-MgCl 2 compared to air exposures. The molten fluoride salt environment resulted in almost a 90% and 50% reduction in creep rupture time for 709 and 617 irrespective of the cover gas environment (air and Ar). Significant differences in the compositional changes between the salt- and air-facing surfaces were observed in the alloy subsurface which might have potentially lead to formation of phases detrimental to the creep behavior.

22 GENERAL STUDIES OF NUCLEAR REACTORS↗

GNF fuel technology update

In 2015, Global Nuclear Fuel (GNF) launched the GNF3 fuel design by inserting lead-use assemblies into two boiling water reactors (BWRs) in the U.S. A lead use assembly is a nuclear fuel assembly which is inserted in a reactor core to confirm its performance. A third set of GNF3 lead-use assemblies are scheduled to be inserted into another reactor in the spring of 2017. GNF3 is a robust next-generation 10*10 fuel design that will improve both fuel cycle and fuel reliability. In addition, GNF3 will be delivered in a fully assembled condition - forgoing the need to insert fuel channels over the bundles at the site. The process of shipping BWR fuel in a channeled configuration is complex and requires an understanding of the potential high-cycle and low-cycle fatigue conditions that can occur during shipping, as characterized by accelerometer data from ship tests. The key component in evaluating channeled fuel shipping is the spacer, and the GNF3 spacer fatigue performance was found to be approximately twice that of GNF2. While fuel reliability has traditionally been related to the avoidance of fuel leakers, for the past 15 years channel - control blade interference has been a close second for concern. To eliminate this problem, GNF3 will come standard with NSF (a zirconium alloy) channels that are effectively resistant to fluence gradient-induced bow and shadow corrosion-induced bow. In addition to the development of GNF3, GNF is evaluating the use of advancing 3D metal printing or additive manufacturing for manufacturing fuel bundle components. Additive manufacture offers the hope of more flexibility in design and shorter manufacturing development cycles. However, since there is little experience with this technology in the nuclear industry, GNF has been evaluating the use of additive manufacture to fabricate small scale components that are easily retrieved from the reactor for testing. (authors)

21 SPECIFIC NUCLEAR REACTORS AND ASSOCIATED PLANTS↗

Capabilities Development for Transient Testing of Advanced Nuclear Fuels at TREAT

The TREAT facility is a unique capability at the Idaho National Laboratory currently being prepared for resumption of nuclear transient testing. Accordingly, designs for several transient irradiation tests are being pursued to enable development of advanced nuclear fuels and materials. In addition to the reactor itself, the foundation for TREAT’s capabilities also include a suite of irradiation vehicles and supporting infrastructure to provide the desired specimen boundary conditions while supporting a variety of instrumentation needs. The challenge of creating these vehicles, especially since many of the modern data needs were not historically addressed in TREAT experiment vehicles, has necessitated a sizeable engineering effort. This effort is currently underway and maturing rapidly. This paper summarizes the status, future plans, and rationale for TREAT experiment vehicle capabilities. Much of the current progress is focused around understanding and demonstrating the behavior of fuel design with enhanced accident tolerance in water-cooled reactors. Additionally, several related efforts are underway to facilitate transient testing in liquid sodium, inert gas, and steam environments. This paper discusses why such a variety of capabilities are needed, outlines plans to accomplish them, and describes the relationship between transient data needs and the irradiation hardware that will support the gathering of this information.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

AGC 3 Irradiated Material Properties Analysis

This report documents the analysis of the irradiated material property data from the Advanced Graphite Creep (AGC)-3 graphite specimens. This is the third in a series of six irradiation test trains planned as part of the AGC experiment to fully characterize the neutron irradiation effects and radiation creep behavior of current nuclear graphite grades. The AGC-3 capsule was irradiated in the Idaho National Laboratory Advanced Test Reactor at a nominal temperature of 800°C, beginning with irradiation Cycle 152B on November 28, 2012 and ending with Cycle 155B on April 12, 2014, with a total received dose range of 0.9–3.7 dpa. Larger creep and control specimens located more centrally in the capsule received a dose of 1.0 – 3.7 dpa. AGC-3 was designed to provide irradiation conditions similar to AGC-1 and AGC-2 capsules (similar graphite grades tested, specimen dimensions, mechanical loading conditions) but at a different nominal irradiation temperature of 800°C. AGC-3 was irradiated for a short duration to provide material property values at lower dose levels. AGC-4 will have a longer duration and provide material property values at higher dose levels. After irradiation, material property and dimensional strain measurements were conducted on all AGC-3 specimens (from 11 nuclear graphite grades) using the same equipment and approved standards as were conducted before irradiation. The specimen loading configuration for all graphite grades within AGC-3 followed a similar pattern as earlier AGC capsules to provide easy future comparison of all irradiated material property data.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Information on the Advanced Plant Experiment (APEX) Test Facility

The purpose of this report provides information related to the design of the Oregon State University Advanced Plant Experiment (APEX) test facility. Information provided in this report have been pulled from the following information sources: Reference 1: R. Nourgaliev and et.al, "Summary Report on NGSAC (Next-Generation Safety Analysis Code) Development and Testing," Idaho National Laboratory, 2011. Note that this is report has not been released as an external report. Reference 2: O. Stevens, Characterization of the Advanced Plant Experiment (APEX) Passive Residual Heat Removal System Heat Exchanger, Master Thesis, June 1996. Reference 3: J. Reyes, Jr., Q. Wu, and J. King, Jr., Scaling Assessment for the Design of the OSU APEX-1000 Test Facility, OSU-APEX-03001 (Rev. 0), May 2003. Reference 4: J. Reyes et al, Final Report of the NRC AP600 Research Conducted at Oregon State University, NUREG/CR-6641, July 1999. Reference 5: K. Welter et al, APEX-1000 Confirmatory Testing to Support AP1000 Design Certification (non-proprietary), NUREG-1826, August 2005.

21 SPECIFIC NUCLEAR REACTORS AND ASSOCIATED PLANTS↗

Status of New Models Hosted on the Virtual Test Bed (VTB) in 2022

The VTB hosts 20 distinct models, 8 of which were recently developed during 2022 and will be discussed in more detail here. This article provides an overview of the various models hosted and their capabilities. Part of the intent of the VTB is to showcase a ‘block’ style approach to modeling and simulation: if a capability is not showcased for a specific reactor type, it could, in theory, be easily ported/replicated from another. The breadth of advanced reactor types considered is representative of the large variety of concepts being proposed for demonstration.

22 GENERAL STUDIES OF NUCLEAR REACTORS↗

Integration of real-time measurements and atomistic modeling to license nuclear components

An improved testing and data gathering method is described herein with reference to testing a new fuel, as an exemplary component to be tested for licensure purposes. The method includes generally: generating models for the new system; making samples and getting them accepted for a reactor; and testing the samples in a test or commercial reactor until the exposure time is reached for the expected cycle length of the fuel at final use. The method is preferably done concurrent to submitting a license application for commercial use of the new component to the relevant government body to expedite license testing review.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

2025 Intern Poster

The Hot Fuel Examination Facility (HFEF) at the Materials and Fuels Complex (MFC) houses the largest U.S. inert atmosphere hot cell for nuclear material research. Key features include the precision gamma scanning (PGS), Fuel Accident Condition Simulator (FACS), Neutron Radiography Reactor (NRAD), and the focus of this project, the Metallograph Loading Cell (MET Cell). The MET Cell performs tests on spent nuclear fuel, such as microhardness testing, microscopy, and neutron radiography. However, the MET Cell’s existing pressure and lighting control systems are outdated and inefficient, with inadequate documentation for system changes over time. This project aims to design a new automated control system for the MET Cell, ensuring longevity (minimum ten years), ease of troubleshooting/repair, and integration into the building monitoring system. The design process addressed challenges such as space restrictions, varied voltages within enclosures, sourcing new components, and security limitations. Compliance with NFPA 70, UL508A, MFC Physical Security, and INL Engineering standards was essential. The project involves repurposing an existing PLC to manage lighting and pressure control using digital and analog signals, simplifying wiring, and ensuring thorough documentation for future reference.

42 - ENGINEERING↗

Weibull and Bootstrap-Based Data-Analytics Framework for Fatigue Life Prognosis of the Pressurized Water Nuclear Reactor Component Under Harsh Reactor Coolant Environment

In general, the fatigue life of a safety critical pressure component is estimated using best-fit fatigue life curves (S-N curves). These curves are estimated based on underlying in-air condition fatigue test data. The best-fitting approach requires a large safety factor to accommodate the uncertainty associated with large scatter in fatigue test data. In addition to this safety factor, reactor component fatigue life prognostics requires an additional correction factor that in general is also estimated deterministically. This additional factor known as the environmental correction factor F en is to cater the effect of the harsh coolant environment that severely reduces the life of these components. The deterministic F en factor may also lead to further conservative estimation of fatigue life leading to unnecessary early retirement of costly reactor components. To address the above-mentioned issues, we propose a data-analytics framework which uses Weibull and Bootstrap probabilistic modeling techniques for explicitly quantifying the uncertainty/scatter associated with fatigue life rather than estimating the lives based on a best-fit based deterministic approach. We assume the proposed probabilistic approach would provide the first hand information for assessing the maximum and minimum effects of pressurized water reactor water on the reactor component. In the discussed approach, in addition to the probabilistic fatigue curves, we suggest using a probabilistic environment correction factor F en . Here, we assume the probabilistic fatigue curve and F en would capture the S-N data scatter associated with the bulk effect of material grades, surface finish, strain rate, etc. on the material/component fatigue life.

22 GENERAL STUDIES OF NUCLEAR REACTORS↗

Improved Heat Transfer and Volume Scaling through Novel Heater Design

In 2014, the University of California, Berkeley, Nuclear Engineering Thermal Hydraulics Laboratory completed construction of the Compact Integral Effects Test (CIET) facility, a scaled thermal hydraulics scaled integral effects test facility designed to model the Mark-1 pebble-bed fluoride-salt-cooled high-temperature reactor (Mk1 PB-FHR or simply Mk1). CIET uses an organic simulant fluid, Dowtherm A, to match the Prandtl, Reynolds, Froude, and Grashof numbers of important fluoride salt candidates for molten salt reactors, such as flibe. The FHR reactor core is simulated using a resistively heated tube, which heats the oil flowing through the annulus between the heated tube and a non-heated inner tube. However, the volume fraction of the coolant in the CIET heater was dramatically lower than the volume fraction of the primary coolant in the Mk1 PB-FHR design (3% in CIET vs. 17% in Mk1) because the CIET heater was initially scaled to match an earlier FHR design. Also, the maximum core heater power in CIET is limited by the melting point of Teflon components in CIET, approximately 330 deg. C. For conservatism, the CIET heater power is limited to keep the maximum surface temperature of the heater below 250 deg. C. At the nominal mass flow rate of 0.18 kg/s, this power was about 5 kW. A higher heat transfer coefficient from the heater wall to the oil was needed to increase the effective power delivered to the oil. In order to alleviate these two limitations, a new heater insert was designed and constructed for CIET. This new heater insert uses a twisted tape to augment heat transfer. The twisted tape is supported inside a perforated inner tube that has the same diameter as the original inner tube of the heater, in order to make it compatible with CIET's original heater design. The heat transfer and pressure drop properties of the new heater insert designs were tested in CIET and compared to the previous design in terms of pressure drop and convective heat transfer coefficient. The new heater inserts are intended to increase the range of power levels and mass flow rates that can be tested in CIET in order to augment understanding of FHR thermal hydraulic phenomena. Also, obtaining different data points for CIET response dynamics under different heater coolant residence times will be valuable in evaluating the Mk1 design.

21 SPECIFIC NUCLEAR REACTORS AND ASSOCIATED PLANTS↗

WEC Irradiation Can Thermal Testing Report

With renewed interest for the next generation of small modular reactors and space-based nuclear reactors, metal hydrides have been a focus of research for moderating materials to reduce the need for highly enriched fuel to maintain small core sizes. Yttrium hydride (YH) is an attractive candidate for these metal hydrides due to its ability to retain hydrogen at elevated temperatures as well as the low neutron absorption cross section of yttrium metal. Given the necessity for reactors to operate at elevated temperatures for extended periods of time, understanding hydrogen retention in moderator channels in simulated operating thermal conditions is paramount in predicting reactor performance and the long-term stability of YH. Additionally, coating strategies on the moderator encapsulating will be explored to ascertain if it aids in retention of hydrogen within the capsule and moderator.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Overview of Virtual Test Bed (VTB)

The Virtual Test Bed (VTB) was established to support the deployment of advanced reactors by facilitating the use of state-of-the-art modeling and simulation capabilities. These tools can solve previously prohibitive challenge problems with greater levels of fidelity and in a multiphysics framework. A VTB repository was recently set up to host models for a wide variety of reactor types and using a range of Nuclear Energy Advanced Modeling and Simulation-developed software. The repository currently includes models for High-Temperature Gas-Cooled Reactors, Sodium Fast Reactors, Fluoride-salt-cooled High-temperature Reactors, Molten Salt Reactors, and Heat-Pipe Microreactors. This article provides an overview of the capabilities currently in the VTB repository.

22 GENERAL STUDIES OF NUCLEAR REACTORS↗

Neutron characterization of UN/U-Si accident tolerant fuel prior to irradiation

Neutron imaging and tomographic reconstructions provide non-destructive three-dimensional characterization of nuclear fuel pellets that are typically about a cubic centimeter in volume with energy-resolved neutron imaging at a pulsed neutron source offering unique characterization not possible at a reactor source. Recent measurements at the Los Alamos Neutrons Science Center (LANSCE) studied a series of uranium nitride / uranium silicide ceramic composite pellets. This paper provides examples of spatially resolved measurements of cracks, isotopic enrichment and density with a (current) spatial resolution of approximately 75 microns. Phase and texture measurements were also performed but are not discussed in this paper. The UN/U-Si systems are under consideration as candidate systems for accident tolerant fuel. The examples are taken from measurements on a total of 9 pellets of differing UN/U-Si formulations (2 enrichment levels), U{sub 3}Si{sub 5} reference formulations (two enrichment levels) and pellets with known flaws. The {sup 235}U enrichments ranged from 0.2 to 8.8 wt.%. Pellets of the same composition are scheduled for irradiation in the Advanced Test Reactor this year. (authors)

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗