Engineering Papers⌕ Search

SEARCH · Engineering Papers

Results for “Particle Size”

Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

Quote a phrase for an exact phrase match. Source license links do not imply unrestricted reuse.

At least 1,027 records · Page 57
All sourcesNASA NTRSDOE OSTI
NASA NTRS1985

Measurements in the flow field of a cylinder with a laser transit anemometer and a drag rake in the Langley 0.3 m transonic cryogenic tunnel

An experiment was conducted at the 0.3 m Transonic Cryogenic Tunnel using a Laser Transit Anemometer (LTA) to probe the flow field around a 3.05 centimeter-diameter circular cylinder. Measurements were made along the stagnation line and determination of particle size was evaluated by their ability to follow the flow field. The LTA system was also used to scan into the boundary layer near the 45 degree point on the model. Results of these scans are presented in graphic and tabular form. Flow field particle seeding was accomplished by inbleeding dry service air. The residual moisture (5-10 ppm) condensed and formed ice particles which served as Mie scattering centers for the LTA detection system. Comparison of data taken along the stagnation streamline with theory indicated that these particles tracked the velocity gradient of the flow. Tunnel operating conditions for the tests were a Mach number of 0.3, a pressure of 1.93 x 100000 n/m squared, and a temperature of 225 degrees K. Free stream Mach number and pressure were varied for the particle size determination.

Honaker, W. C.↗
DOE OSTI2022

Pre-combustion mercury removal with co-production of hydrogen via coal electrolysis

Here, pre-combustion mercury removal via coal electrolysis was performed and investigated on a bench-scale coal electrolytic cell (CEC) systemically, and factorial design was used to determine the effect of different operating conditions (coal particle size, operating temperature, operating cell voltage, and flow rate of slurry) on the percentage of mercury removal, percentage of ash removal, and dry heating value change. The results showed that the operating cell voltage, as well as the interaction between operating cell voltage and coal particle size, are significant factors in the percentage of mercury removal. There is no significant factor in the percentage of ash removal and the dry heating value change, but the coal could be purified while keeping the dry heating value almost constant after electrolysis. A co-product of hydrogen could be produced during coal electrolysis with 50% lower energy consumption compared with water electrolysis. Meanwhile, a mechanism for mercury removal in coal was proposed. The facts indicate that coal electrolysis is a promising method for pre-combustion mercury removal.

54 ENVIRONMENTAL SCIENCES↗
NASA NTRS1994

The viability of photovoltaics on the Martian surface

The viability of photovoltaics (PV) on the Martian surface may be determined by their ability to withstand significant degradation in the Martian environment. Probably the greatest threat is posed by fine dust particles which are continually blown about the surface of the planet. In an effort to determine the extent of the threat, and to investigate some abatement strategies, a series of experiments were conducted in the Martian Surface Wind Tunnel (MARSWIT) at NASA Ames Research Center. The effects of dust composition, particle size, wind velocity, angle of attack, and protective coatings on the transmittance of light through PV coverglass were determined. Both initially clear and initially dusted samples were subjected both to clear winds and simulated dust storms in the MARSWIT. It was found that wind velocity, particle size, and angle of attack are important parameters affecting occlusion of PV surfaces, while dust composition and protective coatings were not. Neither induced turbulence nor direct current biasing up to 200 volts were effective abatement techniques. Abrasion diffused the light impinging on the PV cells, but did not reduce total coverglass transmittance by more than a few percent.

Gaier, James R.↗
DOE OSTI2021

Experimental study on rheological and settling properties of shape memory polymer for fracture sealing in geothermal formations

This article studies the rheology and annular flow of a smart lost circulation material (LCM) at 160 °C, using a high-temperature flow loop. The smart LCM is a shape memory polymer (SMP) that activates at high temperatures, and its particle size increases to seal fractures in geothermal formations. SMP was mixed with the base fluid in two different concentrations, 1.0 and 3.0 wt%, to study rheology, wellbore hydraulics, activation process, and settling behavior under different testing conditions. The results of this study showed that the SMP could be activated at high temperatures. An increase of 80–100% in the particle size was observed at 160 °C. The mud samples showed a high shear-thinning behavior at the two concentrations with a Power-law flow index (n) ranging between 0.025 and 0.101. No additional frictional pressure losses were observed when SMP was added to the base fluid. SMP particles showed an excellent suspension at 1.0 wt% while, at 3.0 wt%, a bed was formed at a low flow rate and without pipe rotation. Increasing the drill pipe rotational speed or flow rate effectively removed the bed and homogeneously dispersed the SMP particles, ensuring a better sealing efficiency. SMP particle dispersion in inclined wells was better than in horizontal wells. Moreover, the findings of this study help optimize the lost circulation treatment by considering a wide range of operating parameters that can further be extended to different systems and geometries.

02 PETROLEUM↗
DOE OSTI2023

The impact of feedstock size and composition on the hydrothermal growth of (U,Th)O 2

Bulk crystal growth of refractory oxides requires unique approaches, and the U x Th 1-x O 2 solid solution is no exception. Hydrothermal transport reactions of U 0.1 Th 0.9 O 2 onto ThO 2 seeds with feedstocks comprised of U 0.1 Th 0.9 O 2 or mixtures of UO 2 and ThO 2 with a nominal composition of U 0.1 Th 0.9 O 2 are investigated with µ-Raman spectroscopy and X-ray fluorescence. In each case, the trends in stoichiometry as a function of distance from the seed are analyzed and the deviations from the nominal stoichiometry discussed. When the feedstock is composed of mixed oxides, the particle surface area’s influence on the feedstock dissolution rate is the dominant factor and can produce U-rich stoichiometries as high as U 0.75 Th 0.25 O 2 . When composed solely of U 0.1 Th 0.9 O 2 , the total growth amount depends on the particle size, but the obtained stoichiometry is the product of differing solubilities. Although the U0.1Th0.9O 2 feedstock produces the most homogeneous growth, the ending growth of the smallest particle UO 2 /ThO 2 mixture yields the stoichiometry closest to U 0.1 Th 0.9 O 2 . How to obtain desired stoichiometries from mixtures by matching the particle size and solubilities is briefly discussed.

36 MATERIALS SCIENCE↗
DOE OSTI2024

Size-resolved particle and black carbon deposition over the cryosphere (Final Report)

Our project focused on providing observational constraints and investigation of aerosol deposition by performing the first unambiguous direct eddy flux covariance measurements of aerosol dry deposition over the cryosphere. The project aimed to make eddy covariance flux measurements of dry deposition and off-line wet deposition measurements of black carbon containing aerosol plus eddy covariance measurements of size-resolved accumulation mode scattering aerosol over the DOE ARM AMF3 Oliktok Point site in Fall 2020. We aimed to compare our measurements to model parameterizations to constrain uncertainties and systematic bias, and improve deposition parameterizations in models. Due to disruptions in field work from COVID-19, our work was delayed and moved to an alternate site on the North Slope of Alaska. This report summarizes the key findings from the project, including data analysis from previous field projects and from the North Slope of Alaska.

54 ENVIRONMENTAL SCIENCES↗
NASA NTRS1980

Theoretical and experimental studies of microwave radiation from a natural snow field

The brightness temperature of a natural snow field in northern Europe was studied theortically and experimentally at 5, 12, and 37 GHz for satellite remote sensing applications. A snow model consisting of ice spheres covered by a water shell was used in calculation, taking into account scattering and absorption. The brightness temperature of a natural snow field as a function of view angle was measured from a tower in 1978 and 1979. The measured brightness temperature curves can be fitted with calculated ones by assuming reasonable values for the wetness and the particle size of snow. Experimental results also show that relatively small changes in the snow conditions cause large changes in the brightness temperature. In order to obtain a more controlled situation, experiments were continued in 1980 using a measuring site covered with aluminum sheets and determining the wetness and the particle size in addition to the density and physical temperature.

Tiuri, M.↗
NASA NTRS1971

Rock sampling

A method for sampling rock and other brittle materials and for controlling resultant particle sizes is described. The method involves cutting grooves in the rock surface to provide a grouping of parallel ridges and subsequently machining the ridges to provide a powder specimen. The machining step may comprise milling, drilling, lathe cutting or the like; but a planing step is advantageous. Control of the particle size distribution is effected primarily by changing the height and width of these ridges. This control exceeds that obtainable by conventional grinding.

Blum, P.↗
NASA NTRS2011

In Situ Aerosol Detector

An affordable technology designed to facilitate extensive global atmospheric aerosol measurements has been developed. This lightweight instrument is compatible with newly developed platforms such as tethered balloons, blimps, kites, and even disposable instruments such as dropsondes. This technology is based on detection of light scattered by aerosol particles where an optical layout is used to enhance the performance of the laboratory prototype instrument, which allows detection of smaller aerosol particles and improves the accuracy of aerosol particle size measurement. It has been determined that using focused illumination geometry without any apertures is advantageous over using the originally proposed collimated beam/slit geometry (that is supposed to produce uniform illumination over the beam cross-section). The illumination source is used more efficiently, which allows detection of smaller aerosol particles. Second, the obtained integral scattered light intensity measured for the particle can be corrected for the beam intensity profile inhomogeneity based on the measured beam intensity profile and measured particle location. The particle location (coordinates) in the illuminated sample volume is determined based on the information contained in the image frame. The procedure considerably improves the accuracy of determination of the aerosol particle size.

Vakhtin, Andrei↗
DOE OSTI2021

Degradation of Adsorbed Bisphenol A by Soluble Mn(III)

Bisphenol A (BPA), a high production volume chemical and potential endocrine disruptor, is found to be associated with sediments and soils due to its hydrophobicity (log K OW of 3.42). Here, we used superfine powdered activated carbon (SPAC) with a particle size of 1.38 ± 0.03 μm as a BPA sorbent and assessed degradation of BPA by oxidized manganese (Mn) species. SPAC strongly sorbed BPA, and desorption required organic solvents. No degradation of adsorbed BPA (278.7 ± 0.6 mg BPA g –1 SPAC) was observed with synthetic, solid α-MnO 2 with a particle size of 15.41 ± 1.35 μm; however, 89% mass reduction occurred following the addition of 0.5 mM soluble Mn(III). Small-angle neutron scattering data suggested that both adsorption and degradation of BPA occurred in SPAC pores. The findings demonstrate that Mn(III) mediates oxidative transformation of dissolved and adsorbed BPA, the latter observation challenging the paradigm that contaminant desorption and diffusion out of pore structures are required steps for degradation. Soluble Mn(III) is abundant near oxic-anoxic interfaces, and the observation that adsorbed BPA is susceptible to degradation has implications for predicting, and possibly managing, the fate and longevity of BPA in environmental systems.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
NASA NTRS1997

A New Probe to Change Curie Temperature of PbTiO3 Sensors

High temperature Raman spectra of nanocrystalline Pb(0.8)Ba(0.2)TiO3, Pb(0.8)Sr(0.2) TiO3, Pb(0.8)La(0.2)TiO3 and Pb(0.8)Ba(0.2)TiO3, have been measured, as a function of particle size. There appears respectively a distinct temperature-induced soft mode phase transition in every sample whose Curie temperature can be determined from the mean-field theory. The detailed Curie temperature shift in modified PbTi03 ceramics by Ba, Sr, La, and Zr, has also been investigated as a function of particle size. This study will favor preparations of high efficiency PbTi03 sensors with an adjustable Curie temperature.

Katiyar, R. S.↗
NASA NTRS1995

Pinatubo Global- to Micro-Scale Evolution: A Unified Picture from Space, Air, and Ground Measurements

We combine space, air, and ground measurements to develop a composite picture of the post-Pinatubo aerosol, and assess the consistency and uncertainties of various measurement and retrieval techniques. impactor and optical counter measurements, as well as retrievals from optical depth spectra, paint a generally consistent picture of the evolution of particle effective radii, R(sub eff). In the first month after the eruption, although particle numbers increased by orders of magnitude, R(sub eff) was similar to the preeruption value of 4.2 micrometers, because both small (r less than 0.25 micrometers) and large (r greater than 0.6 micrometers) particles increased in number, Over the next 3-6 months, R(sub eff) increased rapidly to about 0.5 micrometers. In general, R(sub eff) continued to increase for about a year after the eruption. The peak wavelength of optical depth spectra increased from initial values of less than 0.42 micrometers to values between 0.78 and 1 micrometer. This coupled evolution in particle size distribution and optical depth spectra helps explain the relationship between the global maps of 0.5 and 1.0-micrometer optical depth derived from the AVHRR and SAGE satellite measurements. It also sets a context for evaluating remaining uncertainties in each of these satellite data products. We also make consensus recommendations for particle composition, shape, and temperature- and wavelength-dependent refractive index, and show how the latter effect on backscatter spectra can influence particle sizes retrieved from multiwavelength lidar measurements.

Russell, Philip B.↗
DOE OSTI2020

Methods for preparing superalloy articles and related articles

A method for preparing an improved article including a nickel-based superalloy is presented. The method includes heat-treating a workpiece including a nickel-based superalloy at a temperature above the gamma-prime solvus temperature of the nickel-based superalloy and cooling the heat-treated workpiece with a cooling rate less than 50 degrees Fahrenheit/minute from the temperature above the gamma-prime solvus temperature of the nickel-based superalloy so as to obtain a cooled workpiece. The cooled workpiece includes a coprecipitate of a gamma-prime phase and a gamma-double-prime phase, wherein the gamma-prime phase of the coprecipitate has an average particle size less than 250 nanometers. An article having a minimum dimension greater than 6 inches is also presented. The article includes a material having a coprecipitate of a gamma-prime phase and a gamma-double-prime phase, wherein the gamma-prime phase of the coprecipitate has an average particle size less than 250 nanometers.

36 MATERIALS SCIENCE↗
NASA NTRS2015

Early Size Distributions of Chondrule Subgroups Overprinted by the Final Accumulation Process of Particle Components in Allende

Populations of compositionally distinct particles are fundamental components of undifferentiated chondritic meteorites. Many theories explain the formation of chondrites, one class of which includes mechanisms for sorting the component particles in the solar nebula prior to their accretion. Mechanisms include sorting by mass, turbulent concentration, X-winds, and photophoresis, which will produce characteristic distributions of observable properties such as particle size. Distinguishing processes that occur in specific astrophysical environments requires characterization of particle types, which include refractory Ca-Al-rich Inclusions (CAIs) and less-refractory chondrules. Previous investigations of modal abundances of CAIs and chondrules exist, but differences within and between these two groups, both of which are made up of diverse subgroups with different thermal histories and chemical compositions, remain mostly unstudied. The presence of rims, a significant event occurring after the formation of at least some chondrules, have also yet to be considered with respect to sorting. Here we present the sizes of CAIs and chondrules in Allende with attention to the smallest sizes, subgroups, and particle rims.

McCain, K. A.↗
NASA NTRS2021

An Evaluation of Size-Resolved Cloud Microphysics Scheme Numerics for use with Radar Observations Part II: Condensation and Evaporation

Accurate numerical modeling of clouds and precipitation is essential for weather forecasting and climate change research. While size-resolved (bin) cloud microphysics models predict particle size distributions without imposing shapes, results are subject to artificial size distribution broadening owing to numerical diffusion associated with various processes. Whereas Part 1 addressed collision-coalescence, here we investigate numerical diffusion that occurs in solving condensation and evaporation. In a parcel model framework, all of the numerical schemes examined converge to one solution of condensation and evaporation as the mass grid is refined, and the advection-based schemes are recommended over the reassigning schemes. Including Eulerian vertical advection in a column limits the convergence to some extent, but that limitation occurs at a sufficiently fine mass grid, and the number of iterations in solving vertical advection should be minimized to reduce numerical diffusion. Insubstantial numerical diffusion in solving condensation can be amplified if collision-coalescence is also active, which in turn can be substantially diminished if turbulence effects on collision are incorporated. Large-eddy simulations of a drizzling stratocumulus field reveal that changes in moments of Doppler spectra obtained using different mass grids are consistent with those obtained from the simplified framework, and that spectral moments obtained using a mass grid designed to effectively reduce numerical diffusion are generally closer to observations. Notable differences between the simulations and observations still exist, and our results suggest a need to consider whether factors other than numerical diffusion in the fundamental process schemes employed can cause such differences.

Cloud microphysics↗
NASA NTRS1983

The clouds are hazes of Venus

Pioneer Venus and Venera probe data for the clouds of Venus are considered. These clouds consist of a main cloud deck at 45-70 km altitude, with thinner hazes above and below, although the microphysical properties of the main cloud are further subdivided into upper, middle and lower cloud levels. Much of the cloud exhibits a multimodal particle size distribution, with the mode most visible from the earth being H2SO4 droplets having 2-3 micron diameters. Despite variations, the vertical structure of the clouds indicates persistent features at sites separated by years and by great distances. The clouds are more strongly affected by radiation than by latent heat release, and the small particle size and weak convective activity observed are incompatible with lightning of cloud origin.

Esposito, L. W.↗
NASA NTRS1998

Raman and Photoluminescence Spectroscopy of Nano-crystalline PbTiO3 Sensor Materials with Different Doping Ions

Raman spectra & photoluminescence studies in PbTiO3, have been carried out, as a function of particle size, temperature, pressure and dopants. There appears respectively a distinct temperature-induced soft mode phase transition in each sample whose Curie temperature can be determined from the mean-field theory. The detailed Curie temperature shift in the modified PbTiO3 ceramics by Ba, Sr, La and Zr, has been investigated as a function of particle size. Pressure-induced phase transitions display an obvious diffuse behavior. Room temperature photoluminescence for nanocrystalline Ba(1-x)Pb(x)TiO3 have been observed. These studies favor preparations of high efficiency PbTiO3 sensors.

Katiyar, R. S.↗
NASA NTRS1999

Dynamic Light Scattering of Diabetic Vitreopathy

Diabetes induces pathology throughout the body via nonenzymatic glycation of proteins. Vitreous, which is replete with type 11 collagen, undergoes significant changes in diabetes. The resultant diabetic vitreopathy plays an important role in diabetic retinopathy. Detecting these molecular changes could provide insight into diabetic eye disease as well as molecular effects elsewhere in the body. Human eyes were obtained at autopsy and studied in the fresh, unfixed state. Sclera, choroid, and retina were dissected off the vitreous for dark-field slit microscopy and dynamic light scattering (DLS). For the former, the entire vitreous was exposed. For the latter, only a window at the equator was dissected in some specimens, and the anterior segment was removed leaving the posterior lens capsule intact in others. DLS was performed to determine particle sizes at multiple sites 0.5 mm apart, spanning the globe at the equator (window dissections) and along the antero-posterior axis. Dark-field slit microscopy in diabetic subjects detected findings typical of age-related vitreous degeneration, but at much younger ages than nondiabetic controls. Noninvasive DLS measurements found a greater heterogeneity and larger particle sizes in vitreous of subjects with diabetes as compared to age-matched controls. DLS can detect and quantify the early molecular effects that cause vitreous collagen fibrils to cross-link and aggregate. This could provide valuable insight into ocular and systemic effects of hyperglycemia, because the molecular changes in diabetic vitreopathy could serve as an index of such effects throughout the body. In addition to the diagnostic implications, this methodology could provide a rapid, reproducible way to monitor the response to therapy with novel agents intended to prevent the complications of diabetes on a molecular level.

Sebag, J.↗