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At least 937 records · Page 52

Performance Assessment for the E-Area Low-Level Radioactive Waste Disposal Facility at the Savannah River Site: Appendix E

Supplemental transport model results for the LAWV from Chapter 5, Section 5.2.2 are provided in Section E.1.1 to compare concentrations at the 100-meter POA for the nominal PA case, best estimate case, and various sensitivity cases (Figure E-1 through Figure E-12). Second, Figure E-13 through Figure E-30 in Section E.1.2 display concentrations at the 100-meter POA for decay-chain daughter and parent radionuclides. Third, Figure E-31 through Figure E-34 in Section E.1.3 show maximum concentration contours for I-129. Only contour plots for I-129 from the remaining sensitivity runs are shown because I-129 is identified as the only radionuclide that impacts disposal limits for the LAWV. All concentration units, whether noted or not in the y-axis labels, are pCi L-1 per Ci parent buried.

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Corrective Action Decision Document/Corrective Action Plan for Corrective Action Unit 577: Area 5 Chromium Containing Waste Disposal Cells, Nevada National Security Site, Nevada

This Corrective Action Decision Document/Corrective Action Plan (CADD/CAP) is for Corrective Action Unit (CAU) 577, “Area 5 Chromium Containing Waste Disposal Cells,” which is located in Area 5 of the Nevada National Security Site (NNSS). CAU 577 includes five low-level waste cells at the Area 5 Radioactive Waste Management Site (RWMS) where buried waste received from Nuclear Fuel Services, Inc. (NFS), was subsequently determined to contain chromium that exceeded the Toxicity Characteristic Leaching Procedure regulatory limit, which would require the waste to carry hazardous waste code D007. To resolve issues related to this alleged violation of hazardous waste regulations, a Settlement Agreement was executed between the Nevada Division of Environmental Protection (NDEP) and the U.S. Department of Energy, National Nuclear Security Administration Nevada Field Office on April 25, 2019, which identified agreed-upon mitigation measures. The Settlement Agreement required that the chromium-containing waste received from NFS would be addressed following the closure process laid out in the Federal Facility Agreement and Consent Order (FFACO).

54 ENVIRONMENTAL SCIENCES↗

SFWST Disposal Research R&D 5-Year Plan (FY2023 Update)

This FY2023 report is the second update to the Disposal Research (DR) Research and Development (R&D) 5-year plan for the Spent Fuel and Waste Science and Technology (SFWST) Campaign DR R&D activities. In the planning for FY2020 in the U.S. Department of Energy (DOE) NE-81 SFWST Campaign, the DOE requested development of a high-level summary plan for activities in the DR R&D program for the next five (5)-year period, with periodic updates to this summary plan. The DR R&D 5-year plan was provided to the DOE based initially on the FY2020 priorities and program structure (initial 2020 version of this 5-year plan) and provides a strategic summary guide to the work within the DR R&D technical areas (Control Accounts, CA), focusing on the highest priority technical thrusts. This 5-year plan is a living document (planned to be updated periodically) that provides review of SFWST R&D accomplishments (as seen on the 2021 revision of this 5-year plan), describes changes to technical R&D prioritization based on (a) progress in each technical area (including external technical understanding) with specific accomplishments and (b) any changes in SFWST Campaign objectives and/or funding levels (i.e., Program Direction). Updates to this 5-year plan include the DR R&D adjustments to high-priority knowledge gaps to be investigated in the near-term, as well as the updated longer-term DR R&D directions for the program activities. This plan fulfills the Milestone M2SF23SN010304083 in DR Work Package (WP) SF-23SN01030408 (GDSA - Framework Development – SNL).

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

The Effect of DPC Fillers on FEPs Relevant to Disposal of SNF

The US Department of Energy (DOE) is investigating the use of different materials that could be used to fill the void space inside a dual-purpose canister (DPC) loaded with spent nuclear fuel (SNF) just before it is emplaced in a deep geologic repository. The purpose of adding filler material is to maintain subcritical conditions in the repository during the postclosure period, which can span up to 1,000,000 years. Several types of materials have been proposed, including metals, cements, particulates, and glass. Part of this investigation addresses how the presence of filler material inside a DPC will affect the performance of the repository with respect to the repository features; the consequences of events that may occur; and the multiple thermal, hydrologic, chemical, and mechanical processes that may occur in a deep geologic repository over long timescales. This report describes some of the filler materials that have been proposed and studied; identifies 11 features, 6 events, and 25 processes that may be affected by the presence of filler materials; and discusses the effects that may require consideration for each feature, event, or process. The results of this study can be used to direct appropriate research and to develop suitable models if the DOE decides to use fillers to maintain subcritical conditions in DPCs used to dispose of SNF.

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Unsaturated alluvium disposal modelling with improved geological realism

This report describes specific activities in the Fiscal Year (FY) 2023 associated with the Geologic Disposal Safety Assessment (GDSA) Repository Systems Analysis (RSA) work package funded by the Spent Fuel and Waste Science and Technology (SFWST) Campaign of the U.S. Department of Energy Office of Nuclear Energy (DOE-NE), Office of Spent Fuel and Waste Disposition (SFWD). The overall objective of the GDSA RSA work package is to develop generic deep geologic repository concepts and system performance assessment (PA) models in several potential host-rock environments, and to simulate and analyze these generic repository concepts and models using the GDSA Framework toolkit and other tools as needed. The specific GDSA goal addressed in this report is reference case development, simulation, and analysis for the unsaturated alluvium (UZ), one of the four potential host-rocks considered by the GDSA. Further, we aim to exercise the simulation tools and methodologies under development by GDSA for PA modelling.

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Hanford 200 West Area Flowsheet Data to Support Waste Treatment and Disposal Request for Proposal

This report documents the 200 West Area (200W) flowsheet supplemental data needed to support the Request for Proposal (RFP) to procure onsite and/or offsite treatment and disposal capabilities for West Area pretreated1 tank waste (PTW). The data provided in this document is based on the results of a 200W flowsheet model run evaluating single-shell tank (SST) retrievals for all S, SX, and U Farms, except for Tank S-112, which was retrieved in March of 2007 (HNF-EP-0182, Waste Tank Summary Report for Month End August 31, 2024). The evaluation also includes the waste inventory in double-shell tanks (DSTs) in SY Farm.

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Lessons Learned from Site Selection Efforts for Deep Geological Disposal

This report discusses international experiences from site selection of deep geological repositories (DGR) for radioactive waste disposal. Based on experiences from three countries with recent or ongoing site selections, the report describes different site selection approaches and summarizes lessons learned. The German and Swiss programs are two slightly different examples of one end of the spectrum of potential siting approaches: Starting with the entire country, a technically based downselection is performed to select the repository site. The Canadian program is an example of the other end of the spectrum: Here, the program started with an extensive engagement program with Canadians to collaboratively develop a socially acceptable and technically sound national approach for the long-term management of used nuclear fuel. This was followed by the launch of a collaboratively developed consent-based siting process designed to seek an informed and willing host with suitable sites, considering both technical and community well-being site requirements.

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International collaboration in disposal research: comparative modeling of coupled processes in the DECOVALEX project

Abstract. This presentation gives an overview of an international research collaboration for advancing the understanding and modeling of coupled thermo-hydro-mechanical-chemical (THMC) processes in geological systems. The creation of the international DECOVALEX project, now running for more than 25 years, was motivated by the recognition that prediction of these coupled effects is an essential part of the performance and safety assessment of geologic disposal systems for radioactive waste and spent nuclear fuel. DECOVALEX emphasizes joint analysis and comparative modeling of state-of-the-art field and laboratory experiments, across a range of host rock options and repository designs. Participating research teams are from radioactive waste management organizations, national research institutes, regulatory agencies, universities, and consulting groups, providing a wide range of perspectives and solutions to these complex problems. The presentation provides examples of the research contributions made collectively in past DECOVALEX tasks and also touches on the unique modeling challenges tackled in the ongoing project phase, referred to as DECOVALEX-2023. The current phase comprises 17 partner organizations, about 50 modeling teams, and 7 modeling tasks, which cover a broad portfolio from fundamental studies on gas migration to full-scale in situ heater experiments in different host rocks to performance assessment studies. Together, these examples illustrate that the insight and scientific knowledge gained within the DECOVALEX project would not have been possible if one group had studied these complex THMC modeling challenges alone rather than within a truly collaborative setting.

Birkholzer, Jens T.↗

Catalytic reactor with disposable cartridge

Catalytic reactor, disposable cartridge enclosing iron catalyst, acts as container for solid carbon formed by decomposition of carbon monoxide. Deposition of carbon in other parts of oxygen recovery system does not occur because of lack of catalytic activity; filters trap carbon particles and prevent their being transported outside reaction zone.

Mccullough, C. M.↗

Analysis of temperature and pressure distribution of containers for nuclear waste material disposal in space

A computer program was adapted from a previous generation program to analyze the temperature and internal pressure response of a radioactive nuclear waste material disposal container following impact on the earth. This program considers component melting, LiH dissociation, temperature dependent properties and pressure and container stress response. Analyses were performed for 21 cases with variations in radioactive power level, container geometry, degree of deformation of the container, degree of burial and soil properties. Results indicated that the integrity of SS-316 containers could be maintained with partial burials of either underformed or deformed containers. Results indicated that completely buried waste containers, with power levels above 5 kW, experienced creep stress rupture failures in 4 to 12 days.

Vanbibber, L. E.↗

Studies of Current Circulation at Ocean Waste Disposal Sites

The author has identified the following significant results. Circulation processes at the acid waste disposal site are highly event-dominated, with the majority of the water transport occurring during strong northeasters. There is a mean flow to the south alongshore. This appears to be due to the fact that northeasterly winds produce stronger currents than those driven by southeasterly winds and by the thermohaline circulation. During the warm months, the ocean stratifies with warm water over cold water. A distinct thermocline was observed with expendable bathythermographs during all summer cruises at depths ranging from 10 to 21 meters. During stratified conditions, the near-bottom drogues showed very little movements. The duPont waste plume was observed in LANDSAT satellite imagery during dump up to 54 hours after dump.

Klemas, V.↗

Studies of Current Circulation at Ocean Waste Disposal Sites

The author has identified the following significant results. Acid waste plume was observed in LANDSAT imagery fourteen times ranging from during dump up to 54 hours after dump. Circulation processes at the waste disposal site are highly storm-dominated, with the majority of the water transport occurring during strong northeasterlies. There is a mean flow to the south along shore. This appears to be due to the fact that northeasterly winds produce stronger currents than those driven by southeasterly winds and by the thermohaline circulation. During the warm months (May through October), the ocean at the dump site stratifies with a distinct thermocline observed during all summer cruising at depths ranging from 10 to 21 m. During stratified conditions, the near-bottom currents were small. Surface currents responded to wind conditions resulting in rapid movement of surface drogues on windy days. Mid-depth drogues showed an intermediate behavior, moving more rapidly as wind velocities increased.

Klemas, V.↗

Low cost disposal of MMH

Concentration of gaseous toxic monomethylhydrazine (MMH) can be removed at 99.9% efficiency using scrubbers containing acetylacetone solutions as scrubbing liquors. Resulting product is easily disposable and expensive liners for protecting scrubber from strong oxidizing agents are not needed.

Thomas, J. J.↗