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At least 865 records · Page 48

Submicron and Nanoparticulate Matter Removal by HEPA-Rated Media Filters and Packed Beds of Granular Materials

Contaminants generated aboard crewed spacecraft by diverse sources consist of both gaseous chemical contaminants and particulate matter. Both HEPA media filters and packed beds of granular material, such as activated carbon, which are both commonly employed for cabin atmosphere purification purposes have efficacy for removing nanoparticulate contaminants from the cabin atmosphere. The phenomena associated with particulate matter removal by HEPA media filters and packed beds of granular material are reviewed relative to their efficacy for removing fine (less than 2.5 micrometers) and ultrafine (less than 0.01 micrometers) sized particulate matter. Considerations are discussed for using these methods in an appropriate configuration to provide the most effective performance for a broad range of particle sizes including nanoparticulates.

Perry, J. L.↗

GEOS-CF Model Assessment of PM2.5 During Wildfires: Inferring the Impact of PM2.5 Exposure on Adverse Respiratory & Cardiovascular Conditions

Exposure to fine particulate matter (PM2.5) can aggravate pre-existing respiratory and cardiovascular conditions. When PM2.5 is inhaled it can cause damage to the lungs such as reduced lung function and shortness of breath. After being inhaled PM2.5 can enter the bloodstream and cause harm to the heart. One major natural source of PM2.5 exposure is from wildfire smoke. The particulates within the smoke from the wildfires can spread from the initial source region, potentially impacting communities both near and far. During and after wildfire events, PM2.5 levels can exceed the WHO air quality guidelines (10 gm^3 annual mean; 25 gm^3 daily mean), becoming hazardous to an individual's health. Global models can be used to simulate the emission and transport of these particulates and subsequently they can be valuable to air quality forecasting in highly polluted areas. The NASA Goddard Earth Observing System (GEOS) version 5 Composition Forecast (GEOS-CF) system has been used to produce near-real time air quality forecasts of atmospheric composition at a high global resolution of 25 km. The GEOS-CF system utilizes the GEOS weather forecast model coupled with GEOS-Chem (version 11) chemistry module to provide analyses and forecasts of various toxic air pollutants, including PM2.5. The GEOS-CF simulated high levels of PM2.5 (40 gm^3 to 250 gm^3 ), exceeding the WHO guidelines, during multiple recent regional and global wildfire seasons, including the 2017 Seattle, WA and Los Angeles, CA wildfire seasons, and biomass burning events in India. Furthermore, the GEOS-CF simulated PM2.5 applied to a human health assessment model, BenMAP (The Environmental Benefits Mapping and Analysis Program, version 1.3), estimates the impact on adverse respiratory health conditions due to PM2.5 exposure from wildfires. The GEOS-CF predicted PM2.5 during the wildfire season with the corresponding BenMAP results provides an assessment of the human health impact of PM2.5 exposure.

Saunders, Emily↗

An Improved UAV-Based Fog Collector for Local-Scale Aerobiological Sampling

The use of unmanned air vehicles (UAVs) to passively collect fog for microbiological analysis is being investigated at NASA Ames, contributing to our understanding of the dynamics and limits of the biosphere. Current improvements to a preliminary payload design include physically modifying the mesh of the passive impactor collection unit (PICU) to increase fog-capture efficiency and a quick- mounting system to improve sample turnaround and contamination control. Increasing the water-capture efficiency of the PICU involved changing the surface roughness of the polypropylene mesh by abrasive sanding. Four scale models of the PICU were created, with three of those models sanded with 80-, 150-, and 240-grit sand paper for a minimum of thirty seconds on each side. Each mesh was individually tested in a fog-simulation chamber to measure collection efficiency. Tests showed that sanding the mesh will increase the water-capture efficiency by at least 3-fold for the 150- and 240-grit. Next steps are to determine the scaling laws and minimum amount of exposure time as a function of the fog density, to acquire enough microorganisms for analysis; a light-weight ground module for the PICU has been developed to allow rapid, easy field testing. Developing a mounting system that will ensure sterile deployment, as well as prompt changes of PICUs, for collection of fog water, utilized computational fluid dynamics (CFD) for the UAV to ensure that the location of the impactors will not be contaminated by particulates in the UAV downwash. The original design allowed the impactors to remain within sterile packaging until mounted on the UAV but did not address the concerns of contamination from aerodynamic ground effects and particulate lofting during takeoff. Design for a raised launch pad would allow for the sterile PICU to be attached to UAV and launched from outside the region of projected particulate lofting. California coastal sites have been scouted for appropriate testing locations. The improvements to the PICU design and operations will allow for multiple sampling points within a single fog event. The returned fog samples will undergo ion chromatography, qPCR, ATP quantification, and other tests to characterize microbial species and relevant biochemistry.

Wong, Amber↗

Scroll Filter System Development for Crewed Deep Space Missions

On board the International Space Station, particulate HEPA filters known as Bacterial Filter Elements (BFE's) are used as the main ventilation filters on the US modules. They consist of two stages of filtration, a static screen filter and a HEPA filter element. Historically, these filters have performed well during the life of the ISS. However, as NASA sets its sights towards mission beyond low earth orbit, or deep space, more capable filters requiring minimal maintenance will be essential because of the nature of these remote and of long duration missions. Therefore NASA is currently developing new filter systems for these mission. One of the filter designs being considered is a new filter system, coined the Scroll BFE. This filter provides two stages of filtration. The first stage is a pre-filter stage using a roll of screen media on a motorized spooling, or scrolling, mechanism to automate the change-out of the screen media in the flow. The second and finishing stage is a static HEPA filter element similar to the ones used on the ISS BFE's. The volume and dimensional format of the filter matches that of the ISS BFE which facilitates is deployment as potential future flight technology demonstration on board the ISS. Ground tests are underway to assess the filter system's performance under industrial standard test protocols applied in a custom designed filtration test stand. In addition, a method of generating relevant particulate matter loads, such as loose fibrous matter, is also being devised to challenge the filter in testing. The latter test challenge will help determine the pre-filter's capacity for handling layers of lint, or fibrous, particulate matter. Early results confirm HEPA efficiency performance of the HEPA stage. This paper will present the results of ground testing of the Scroll Filter System prototype.

Agui, Juan H.↗

A Model Study of the Relative Influences of Scavenging and Circulation on 230Th and 231Pa in the Western North Atlantic

The oceanic cycles of thorium-230 and protactinium-231 are affected by a number of processes, such as removal by adsorption to settling particles and transport by ocean currents. Measurements obtained as part of GEOTRACES and earlier programs have shown that, in the North Atlantic, the activities of dissolved 230Th (230Thd) and 231Pa (231Pad) at abyssal depths are lower near the western margin than in the basin interior. At least two factors could explain the lower 230Thd and 231Pad near the margin: (i) intensified scavenging in benthic nepheloid layers (BNLs) extending a thousand meters or more above the seafloor; and (ii) ventilation by relatively 230Thd- and 231Pad-poor waters emanating from the Deep Western Boundary Current (DWBC).Here a regional ocean circulation model with ?eddy-permitting' resolution (1/4) that incorporates 230Th and 231Pa is used in an effort to reproduce the observed distributions of 230Th and 231Pa in the western North Atlantic. In this model, 230Th and 231Pa removal from solution is governed by a prescribed distribution of particulate matter that is derived from a recent synthesis of nephelometer and transmissometer data. The model simulates a meandering Gulf Stream and a DWBC along the continental slope and rise, although noticeable differences with physical observations also exist. A model solution is found that explains most of the variance of 230Thd measurements (85%) and 231Pad measurements (81%) from (pre-)GEOTRACES cruises. On the other hand, measurements of particulate 230Th (230Thp) and 231Pa (231Pap) are more difficult to reproduce, with the same solution accounting for only 49% (11%) of the 230Thp (231Pap) variance. Sensitivity experiments suggest that the low 230Thd and 231Pad activities observed near the western margin are due to enhanced removal rates of both nuclides in BNLs rather than to deep water ventilation from the western boundary. The radionuclide activities present in the DWBC at its inflow location are also found to strongly influence the basin-scale distributions of 230Th and 231Pa. Overall, our study points to BNLs as important sites of 230Th and 231Pa scavenging in the ocean and illustrates the difficulty to explain simultaneously radionuclide measurements in dissolved and particulate forms in the studied area.

Lerner, Paul↗

Ocean Subsurface Study from ICESat-2 Mission

NASA has launched the ICESat-2 mission in September 2018 with the primary purpose of monitoring changes in the cryosphere. Fortunately, the measured photons over ocean region provide great opportunity for the ocean subsurface study. We have proposed a novel algorithm to determine ocean subsurface optical properties, such as, diffuse attenuated coefficient, kd (/m), total backscattering coefficients bb (/m), attenuated backscatter coefficient and particulate backscattering coefficients b(sub bp) (/m) from ICESat-2/ATLAS lidar measurements. Our ICESat-2 ocean subsurface results reveal high vertical resolution of these optical properties through the water column that are hidden from the passive ocean color record. Moreover, we can estimate the particulate organic carbon (POC) and phytoplankton carbon biomass based on the ICESat-2 retrieved particulate backscattering coefficients b( sub bp) results. We will present and discuss the first ICESat-2 ocean subsurface profile results, especially in polar region where passive ocean color measurements are difficult to make. We will also present the multiple scattering effects on the ocean subsurface optical properties retrieval.

Xiaomei Lu↗

Influence of sediment resuspension on deep-ocean Pa-231 and Th-230 cycling: A PROGRESS REPORT

The naturally-occurring particle-reactive radionuclides protactinium-231 (231Pa) and thorium-230 (230Th) are used as tracers of a variety of oceanic processes, both at present and in the past. Most notably, the sediment 231Pa/230Th ratio has been used to infer changes in the Atlantic Meridional Overturning Circulation over the last (de)glaciation. However, recent measurements along the U.S. GEOTRACES North Atlantic transect (GA03) revealed two features which are at odds with current understanding about 231Pa and 230Th behaviour in the ocean: (i) a sharp decrease in dissolved 231Pa and 230Th activities with depth below 2000-4000 m and (ii) very large particulate 231Pa and 230Th activities near the bottom, at a number of stations between the New England continental shelf and Bermuda. Concomitant measurements of particulate matter concentration and potential temperature showed that both features are associated with the benthic nepheloid layer (BNL) and the bottom mixed layer (BML) that are present at these stations. Here we develop and apply a simplified model of the exchange of particles, 231Pa, and 230Th between the BNL and the upper sediment, to explore the extent to which the radionuclide anomalies observed near the bottom at a number of GA03 stations can be explained by local sediment resuspension. We find that the model can broadly reproduce the observed anomalies at two stations where samples for radionuclide analyses were collected near the seafloor. Sensitivity tests with the model show that the 231Pa/230Th ratio of particles in the BML and the sediment varies by a factor of 3 as the sediment resuspension rate fluctuates within a range consistent with observational estimates. The modelled variability is comparable to the spatial variability of 231Pa/230Th of suspended particles in the modern North Atlantic and to the variability of Atlantic sediment 231Pa/230Th records across the last (de)glacial period. Two factors are found to contribute to the modelled sensitivity of the sediment 231Pa/230Th to sediment resuspension rate: the vertical turbulent mixing in the BML and the differential scavenging intensity of Pa and Th due to variation in particle concentration. Overall, our study indicates that the exchange of material between the BNL and the upper sediment can affect the particulate 231Pa/230Th ratio in the bottom water and the sediment, which may complicate the use of sediment 231Pa/230Th as a palaeoceanographic tracer.

particle-reactive radionuclides↗

Airborne High Spectral Resolution Lidar-2 Measurements of Enhanced Depolarization in Marine Aerosols

Airborne NASA Langley Research Center (LaRC) High Spectral Resolution Lidar-2 (HSRL-2) measurements acquired during the recent NASA EVS-3 Aerosol Cloud Meteorology Interactions over the Western Atlantic Experiment (ACTIVATE) revealed enhanced particulate linear depolarization associated with aerosols within the marine boundary layer. These HSRL-2 observations were acquired off the east coast of the United States in February and March 2020 when this lidar was deployed on the NASA LaRC UC-12 aircraft. HSRL-2 measured profiles of aerosol backscattering, extinction,and depolarization at 355 and 532nm and aerosol backscattering and depolarization at 1064nm. Typically HSRL-2 measures low (<5%) linear particulate depolarization associated with marine sea salt aerosols. However, during several ACTIVATE flights, particularly those that occurred with outbreaks of cold, dry air, linear particulate depolarization exceeded 15-20% (532nm) for aerosols within a few hundred meters above the surface. These high values indicated that these particles were nonspherical. Elevated depolarization values were also observed at 355 and 1064 nm. HSRL-2 measured aerosol extinction/backscatter ratio (“lidar ratio”) values around 20-25 sr (355 and 532 nm) that are typically associated with sea salt particles. Coincident measurements of relative humidity from dropsondes released from the UC-12and in situ Diode Laser Hygrometer (DLH) measurements flown on the NASA HU-25 aircraft showed that highest depolarization values of these nonspherical particles were found when the relative humidity (RH)was below 50-60%.These lidar observations of elevated depolarization associated with sea salt aerosol are consistent with previous lidar measurements of sea salt aerosols in dry conditions. We discuss these HSRL-2 measurements also in the context of coincident airborne in situ measurements of particle size and composition acquired on the HU-25 aircraft. We also found that CALIOP satellite measurements observed elevated depolarization during some similar cold air outbreaks. In such cases, the operational CALIOP algorithms attributed the elevated depolarization to nonspherical dust particles rather than the more likely scenario of nonspherical sea salt particles associated with low RH.

aerosols↗

Enhanced Monitoring and Forecasting of South Asian Air Quality Episodes with Multi-Sensor Satellite Products and Dispersion Modeling

Air pollution and particulates represent a serious environmental, public health, and overarching societal concern in the Hindu Kush Himalaya (HKH) region of south-central Asia, especially during the boreal winter and spring months. Frequent contributors to poor air quality of the region include dust and particulate matter transport from the Middle East region and western India, persistent nocturnal fog and smog during the stable dry monsoon months, and biomass burning during the pre-monsoon months of boreal spring. Nocturnal and multi-day persistent stable fog and smog events can occur during the stable conditions of the dry monsoon months that lead to hazardous visibility reductions (e.g., at major airports such as Delhi, India)and poor air quality, particularly in urban corridors.Our project goal is therefore to design and implement a robust air quality and chemistry observation and modeling system using the Hybrid Single-Particle Lagrangian Integrated Trajectory (HYSPLIT) and the Weather Research and Forecasting coupled with Chemistry (WRF-Chem) models. This system effectively assimilates aerosol and trace gas retrievals from geostationary and polar-orbiting satellites to advance the monitoring and prediction capabilities of air quality and visibility reductions throughout the HKH region. For this presentation, we highlight several[multi-spectral] geostationary satellite products and dispersion modeling capabilities being developed and implemented for improved situational awareness and forecasting of air quality episodes.Launched in December 2018, the Advanced Meteorological Imager (AMI) aboard the Geostationary-Korean Multi-Purpose Satellite-2A (GEO-KOMPSAT-2A, or GK2A) provides 16 channels of multi-spectral information similar to the U.S. GOES-16/17 satellites. Proven community recipes for generating multi-spectral Red-Green-Blue (RGB) composite products to detect specific meteorological phenomena are applied to the AMI data for the HKH region. We implemented four such RGB products consisting of truecolor with Rayleigh correction to aid in smoke detection; dust RGB for monitoring larger particulate matter; nighttime microphysics for fog/smog detection;and natural color fire RGB and the shortwave 3.8 micron channel for fire hot-spot detection.We additionally configured HYSPLIT for dust/sand dispersion and concentration forecasts over HKH. The HYSPLIT dispersion simulations are initially being conducted with two different methodologies: (1) dust/sand lofting based on initializing plume releases from visual inspection of the dust RGB imagery; and (2) dust/sand release and dispersion using the internal HYSPLIT algorithm that determines lofting from input wind speeds and prescribed land use. The goal is to develop a near real-time HYSPLIT modeling solution for routinely simulating the transport and dispersion of dust plumes across the HKH region. This presentation illustrates these products and capabilities for various use cases from the 2019 to 2021 period, highlighting a particularly unhealthy episode during late March 2021 across Nepal.

Remote Sensing↗

Predicting contamination accumulation in facilities with limited data

In preparation for the James Webb Space Telescope (JWST) launch at Centre Spatial Guyanias (CSG) in French Guiana, particulate contamination accumulation predictions were necessary for each facility in which the hardware would be exposed because the Telescope would be uncovered in each of the facilities and had strict particulate requirements. These included facilities for final integration and testing, fueling, transportation and encapsulation. Minimal heritage data existed from CSG and previous launch campaigns to use as a basis for contamination predictions. Data from the Automatic Transfer Vehicle and Herschel & Planck launch campaigns were used in conjunction with facility monitoring data provided by ESA and data collected during JWST working group visits to CSG. These campaigns were conducted at varying cleanliness levels that were typically less stringent than JWST requirements. Each facility was evaluated using the data provided and likely performance improvement with the addition of High Efficiency Particulate Air filter (HEPA) banks operating when possible. Once the launch campaign was completed, the predicted fallout was compared with actual data collected throughout the campaign. Based on the actual measurements, JWST’s primary and secondary mirrors turned out to be much cleaner than what was predicted.

James Webb Space Telescope, contamination, cleanro↗

Predicting contamination accumulation in facilities with limited data

"In preparation for the James Webb Space Telescope (JWST) launch at Centre Spatial Guyanias (CSG) in French Guiana, particulate contamination accumulation predictions were necessary for each facility in which the hardware would be exposed because the Telescope would be uncovered in each of the facilities and had strict particulate requirements. These included facilities for final integration and testing, fueling, transportation and encapsulation. Minimal heritage data existed from CSG and previous launch campaigns to use as a basis for contamination predictions. Data from the Automatic Transfer Vehicle and Herschel & Planck launch campaigns were used in conjunction with facility monitoring data provided by ESA and data collected during JWST working group visits to CSG. These campaigns were conducted at varying cleanliness levels that were typically less stringent than JWST requirements. Each facility was evaluated using the data provided and likely performance improvement with the addition of High Efficiency Particulate Air filter (HEPA) banks operating when possible. Once the launch campaign was completed, the predicted fallout was compared with actual data collected throughout the campaign. Based on the actual measurements, JWST’s primary and secondary mirrors are likely much cleaner than was expected with the predicted fallout in each facility. "

James Webb Space Telescope, contamination, cleanro↗

Characterizing Fit Factor of a One Size Fits-Most Emergency Mask using Subjects with Smaller Neck Circumferences

The Emergency Mask (EM) is an integral part of fire response on ISS, Orion and Gateway. The EM is a hood type protection respirator sealing around the subject’s neck, with an additional nose cup covering the subject’s oral nasal region. When integrated with a pair of Fire Cartridges (FCs), this system can be used to provide safe breathing air in a post-fire environment. The initial EM was certified as a ‘one size fits most’, however a recent requirements scrub discovered that the neck circumferences of the smallest possible crew population were not included in the initial requirement set. The test described in this paper uses the same slightly modified industry standard respirator test called a ‘Fit Factor’ used to certify the existing EM for larger subjects. Tests were performed on eight test subjects with neck circumference smaller than the initial EM requirement to determine if the current EM provided adequate protection during post-fire scenarios. The test included subjects donning an EM and then performing a number of head movements in a tent filled with approximately 50,000 particles/cm3 of smoke particulate. During these motions, particulate measurements were obtained from within the EM and compared with particulate measurements in the surrounding environment to determine the protection the EM provided in a simulated post-fire environment. This paper provides descriptions of the test hardware, methodology and results, which have provided rationale to design and build an EM to accommodate subjects with smaller necks.

Respirator↗

Harvesting Microgreens in Microgravity: Analysis of Six Different Methods

In long duration space missions, crops will be used to supplement the astronaut diet. One such proposed crop type is microgreens, the young seedlings of edible plants that are known for their high nutritional levels, intense flavors, colorful appearance, and variety of textures. While these characteristics make microgreens a great candidate for space crop production, their small size presents a unique challenge within the microgravity environment. To ensure that astronauts will be able to harvest microgreens in microgravity with ease while avoiding the introduction of debris to the spacecraft cabin, multiple harvesting methods were developed by the Space Crop Production Team at NASA’s Kennedy Space Center. Three parabolic flights were conducted in November and December of 2021 and during those flights three different microgreen cutting methods (guillotine, pepper grinder, scissors) as well as two different bagging methods (attached and manual) were tested. In each flight, the microgreens were contained inside of a glovebox and footage of all the microgreen harvests was recorded. The cutting and bagging method combination that introduced the lowest average number of particulates into the glovebox was the scissors with attached bagging, closely followed by the pepper grinder with attached bagging. However, the scissors with attached bagging may had introduced fewer particulates into the glovebox because on average, 27% of the microgreens were never cut using the scissors method, so there were fewer free-floating particulates generated. The cutting and bagging method combination that left the lowest average percentage of microgreens remaining on the hardware post-harvest was the pepper grinder with an attached bag. Future directions include involving microgreen harvests in analog environments and further development of the different microgreen cutting and bagging methods. This research was funded by multiple NASA grants at the Kennedy Space Center.

Haley O Boles↗

New Insights on the 7[superscript]Be Cycle in the Ocean

The cosmogenic radionuclide 7[superscript]Be has been applied as a tracer of dynamical processes in the upper ocean and of atmospheric deposition of trace elements at the sea surface. These applications usually assume that 7[superscript]Be is entirely in the dissolved form, and that scavenging and downward export of 7[superscript]Be by settling particles can be neglected. In this work, we explore these assumptions and more generally assess the significance of the 7[superscript]Be activity in the particulate fraction, through the generation of vertical profiles of particulate 7[superscript]Be in the open ocean. From detailed measurements obtained from low-background gamma spectrometers placed in underground facilities, we report vertical profiles of 7[superscript]Be activity in suspended particles (7[superscript]Bep[subscript]) collected in various oceanic regions: the Mediterranean Sea (DYFAMED station), the Indian Sector of the Southern Ocean (station A3-2 from the KEOPS2 cruise), the Sargasso Sea (OFP station), and the subpolar North Atlantic Ocean (GEOVIDE cruise). We find that, in each oceanic region, 7[superscript]Bep[subscript] activities are generally higher in the mixed layer than in the thermocline. They vary in the mixed layer from 3.0 dpm/m3 at DYFAMED to 33.1dpm/m3 at GEOVIDE cross-over station 51/60, i.e., within a range consistent with previous 7[superscript]Bep[subscript] measurements for the open ocean. For the GEOVIDE cruise, the 7[superscript]Bep[subscript] activities measured on different filter types at different depths are corrected for filter offsets derived from multiple 7[superscript]Bep[subscript] measurements at a near-coastal station in the western Mediterranean Sea. We then combine measurements of total 7[superscript]Be activity (Shelley et al., 2017) with our measurements of 7[superscript]Bep[subscript] activity to estimate the solid/solution partitioning of 7[superscript]Be. On average, the particulate fraction would represent 6% of total 7[superscript]Be activity at 5-m water depth (n = 6), 22% at 20 m (n = 2) and 9% at 70 m (n = 3). At GEOVIDE stations, 7[superscript]Bep[subscript] inventories range from 5% to 19% of the total 7[superscript]Be inventories. In the Labrador Sea, the measured 7[superscript]Bep[subscript] inventories are lower than the dry 7[superscript]Be deposition fluxes estimated from aerosol samples collected during GEOVIDE, suggesting that a significant portion of 7[superscript]Bep[subscript] may be removed by sinking particles. The distribution coefficient Kd for 7Be increases with depth, with log10Kd averaging 5.2 ± 0.1 at 5 m to 6.1 ± 0.1 between 70 and 150 m, suggesting that scavenging of dissolved 7[superscript]Be by particles is more pronounced in the thermocline than in the mixed layer when differences in particle concentrations are taken into account. Overall, our study suggests that, at least in some oceanic regions, the removal of 7[superscript]Be by marine particles may be significant and that it may need to be considered in applications of 7[superscript]Be as a tracer of oceanic processes and atmospheric deposition.

Beryllium-7↗

Waste Container Filtration To Minimize Microbial Escape During Long-Term Storage On Mars

In the search for life on Mars, keeping its surface pristine and free of microbes due to human presence is of utmost importance. Astronauts will use emptied logistics containers during their Martian stay to store waste. These containers will be left on the planet’s surface and are a potential source of microbial contamination. It is desired for these containers to be free from leaks for a minimum of 50 years. If leaks do occur a likely location will be at the port. At this location the mating surfaces will be sealed using a flexible gasket material like a thin metal or a polymer. Eventually these seals will fail. To mitigate these effects, a particulate filter can be employed to equilibrate the pressure between the Martin environment and inside the container. To meet planetary protection requirements, the filter can only allow particulates smaller than 0.2 um diameter to pass. This paper discusses why a particulate filter may be needed and how such a filter would be tested to survive and operate in the harsh Martian environment.

Planetary Protection Waste Containment↗

Waste Container Filtration to Minimize Microbial Escape During Long-Term Storage on Mars

In the search for life on Mars, keeping its surface pristine and free of microbes due to human presence is of utmost importance. Astronauts will use emptied logistics containers during their Mars stay to store waste. These containers will be left on the planet’s surface and are a potential source of microorganism contamination. It is desired for these containers to be free from leaks for a minimum of 50 years. If leaks do occur, a likely location will be at any ports. At these locations the mating surfaces will be sealed using a flexible gasket material like a thin metal or a polymer. Eventually these seals will fail. To mitigate these effects, a particulate filter can be employed to equilibrate the pressure between the Martin environment and inside the container. To meet planetary protection requirements, the filter can only allow particulates smaller than 0.2 m diameter to pass. This paper discusses why a particulate filter may be needed and how such a filter could be tested to survive and operate in the harsh Martian environment.

planetary protection↗

Waste Container Filtration to Minimize Microbial Escape During Long-Term Storage on Mars

In the search for life on Mars, keeping its surface pristine and free of microbes due to human presence is of utmost importance. Astronauts will use emptied logistics containers during their Mars stay to store waste. These containers will be left on the planet’s surface and are a potential source of microorganism contamination. It is desired for these containers to be free from leaks for a minimum of 50 years. If leaks do occur, a likely location will be at any ports. At these locations the mating surfaces will be sealed using a flexible gasket material like a thin metal or a polymer. Eventually these seals will fail. To mitigate these effects, a particulate filter can be employed to equilibrate the pressure between the Martin environment and inside the container. To meet planetary protection requirements, the filter can only allow particulates smaller than 0.2 μm diameter to pass. This paper discusses why a particulate filter may be needed and how such a filter could be tested to survive and operate in the harsh Martian environment.

planetary protection↗

Critical Load Exceedances for North America and Europe using an Ensemble of Models and an Investigation of Causes for Environmental Impact Estimate Variability: An AQMEII4 Study

Exceedances of critical loads for deposition of sulphur (S) and nitrogen (N) to different ecosystems were estimated using European and North American ensembles of air quality models, under Phase 4 of the Air Quality Model Evaluation International Initiative (AQMEII4), to identify where risk of ecosystem harm is expected to occur based on model deposition estimates. The ensembles were driven by common emissions and lateral boundary condition inputs. Model output was regridded to common North American and Europe 0.125° resolution domains, which were then used to calculate critical load exceedances. New, targeted deposition diagnostics implemented in AQMEII4 allowed an unprecedented level of post-simulation analysis to be carried out and facilitated the identification of specific causes of model-to-model variability in critical load exceedance estimates. New datasets for North American critical loads for acidity for forest soil water and aquatic ecosystems were combined with the ensemble deposition predictions to show a substantial decrease in the area and number of locations in exceedance between 2010 and 2016 (forest soils: 13.2 % to 6.1 %; aquatic ecosystems: 21.2 % to 11.4 %). All models agreed in the direction of the ensemble exceedance change between 2010 and 2016. The North American ensemble also predicted a decrease in both severity and total area in exceedance between the years 2010 and 2016 for eutrophication-impacted ecosystems in the USA (sensitive epiphytic lichen: 81.5 % to 75.8 %). The exceedances for herbaceous community richness also decreased between 2010 and 2016, from 13.9 % to 3.9 %. The uncertainty associated with the North American eutrophication results is high; there were sharp differences between the models in both predictions of total N deposition and the change in N deposition, and hence in the predicted eutrophication exceedances between the two years. The European ensemble was used to predict relatively static exceedances of critical loads with respect to acidification (4.48 % to 4.32 % from 2009 to 2010) while eutrophication exceedance increased slightly (60.2 % to 62.2 %). While most models showed the same changes in critical load exceedances as the ensemble between the two years, the spatial extent and magnitude of exceedances varied significantly between the models. The reasons for this variation were examined in detail by first ranking the relative contribution of different sources of sulphur and nitrogen deposition in terms of deposited mass and model-to-model variability in that deposited mass, followed by their analysis using AQMEII4 diagnostics, along with evaluation of the most recent literature. All models in both the North American and European ensembles had net annual negative biases with respect to observed wet deposition of sulphate, nitrate and ammonium. Diagnostics and recent literature suggest that this bias may stem from insufficient cloud scavenging of aerosols and gases, and may be improved through the incorporation of multiphase hydrometeor scavenging within the modelling frameworks. The inability of North American models to predict the timing of the seasonal peak in wet ammonium ion deposition (observed maximum was in April, while all models predicted a June maximum) may also relate to the need for multiphase hydrometeor scavenging (absence of snow scavenging in all models employed here). High variability in the relative importance of particulate sulphate, nitrate and ammonium deposition fluxes between models was linked to the use of updated particle dry deposition parameterizations in some models. However, recent literature and further development of some of the models within the ensemble suggests these particulate biases may also be ameliorated via the incorporation of multiphase hydrometeor scavenging. Annual sulphur and nitrogen deposition prediction variability was linked to SO 2 and HNO 3 dry deposition parameterizations, and diagnostic analysis showed that the cuticle and soil deposition pathways dominate the deposition mass flux of these species. Further work improving parameterizations for these deposition pathways should reduce variability in model acidifying gas deposition estimates. The absence of base cation chemistry in some models was shown to be a major factor in positive biases in fine mode particulate ammonium and particle nitrate concentrations. Models employing ammonia bidirectional fluxes had both the largest and the smallest magnitude biases, depending on the model and bidirectional flux algorithm employed. A careful analysis of bidirectional flux models suggests that those with poor NH 3 performance may underestimate the extent of NH 3 emissions fluxes from forested areas. Based on these results, an increased process-research focus is therefore recommended for the following model processes and on observations which may assist in model evaluation and improvement: multiphase hydrometeor scavenging combined with updated particle dry deposition, cuticle and soil deposition pathway algorithms for acidifying gases, base cation chemistry and emissions, and NH 3 bidirectional fluxes. Comparisons with satellite observations suggest that oceanic NH 3 emissions sources should be included in regional chemical transport models. The choice of land use database employed within any given model was shown to significantly influence deposition totals in several instances, and employing a common land use database across chemical transport models and critical load calculations is recommended for future work.

critical loads↗