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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 847 records · Page 47
All sourcesNASA NTRSDOE OSTI
NASA NTRS1997

Surfactant/Supercritical Fluid Cleaning of Contaminated Substrates

CFC's and halogenated hydrocarbon solvents have been the solvents of choice to degrease and otherwise clean precision metal parts to allow proper function. Recent regulations have, however, rendered most of these solvents unacceptable for these purposes. New processes which are being used or which have been proposed to replace these solvents usually either fail to remove water soluble contaminants or produce significant aqueous wastes which must then be disposed of. In this work, a new method for cleaning surfaces will be investigated. Solubility of typical contaminants such as lubricating greases and phosphatizing bath residues will be studied in several surfactant/supercritical fluid solutions. The effect of temperature, pressure, and the composition of the cleaning mixture on the solubility of oily, polar, and ionic contaminants will be investigated. A reverse micellar solution in a supercritical light hydrocarbon solvent will be used to clean samples of industrial wastes. A reverse micellar solution is one where water is dissolved into a non-polar solvent with the aid of a surfactant. The solution will be capable of dissolving both water-soluble contaminants and oil soluble contaminants. Once the contaminants have been dissolved into the solution they will be separated from the light hydrocarbon and precipitated by a relatively small pressure drop and the supercritical solvent will be available for recycle for reuse. The process will be compared to the efficacy of supercritical CO2 cleaning by attempting to clean the same types of substrates and machining wastes with the same contaminants using supercritical CO2. It is anticipated that the supercritical CO2 process will not be capable of removing ionic residues.

White, Gary L.↗
NASA NTRSDate not supplied

Overview of NASA Gateway Lunar Dust Mitigation and Contamination Modeling and Analysis

The planned NASA Artemis campaign has several lunar surface missions in which the NASA Gateway is the waypoint between lunar orbit and the lunar surface for Human Lander System (HLS). Each of these missions is an opportunity for lunar dust to be introduced into the Gateway environment, post surface mission, potentially causing end of life (EOL) performance degradation due to lunar dust contamination of sensitive hardware and systems on the exterior of Gateway and Visiting Vehicles. The Gateway Systems Engineering and Integration (SE&I) and Induced Environments teams are addressing the challenge of lunar dust with a two-pronged approach. Characterization of the lunar dust induced environment around Gateway and contamination risk is accomplished with a comprehensive physics-based framework, the Gateway On-orbit Lunar Dust Modeling and Analysis Program (GOLDMAP), which is currently in development. Analysis results from GOLDMAP define Gateway-level induced environments requirements and are flowed to elements and subsystems. In parallel, a dust mitigation strategy is being developed with a focus on lunar dust protection, dust mitigation technologies, mitigation and testing guidance, and cross-program coordination and is informed by outputs from GOLDMAP analyses. Activities supporting both components include hardware susceptibility assessments and testing, and scientific experiments on lunar regolith.

Gateway↗
NASA NTRS2000

Mechanical Abrasion as a Low Cost Technique for Contamination-Free Sample Acquisition from a Category IVA Clean Platform

The proposed Mars Sample Transfer Chain Architecture provides Planetary Protection Officers with clean samples that are required for the eventual release from confinement of the returned Martian samples. At the same time, absolute cleanliness and sterility requirement is not placed of any part of the Lander (including the deep drill), Mars Assent Vehicle (MAV), any part of the Orbiting Sample container (OS), Rover mobility platform, any part of the Minicorer, Robotic arm (including instrument sensors), and most of the caching equipment on the Rover. The removal of the strict requirements in excess of the Category IVa cleanliness (Pathfinder clean) is expected to lead to significant cost savings. The proposed architecture assumes that crosscontamination renders all surfaces in the vicinity of the rover(s) and the lander(s) contaminated. Thus, no accessible surface of Martian rocks and soil is Earth contamination free. As a result of the latter, only subsurface samples (either rock or soil) can be and will be collected for eventual return to Earth. Uncontaminated samples can be collected from a Category IVa clean platform. Both subsurface soil and rock samples can be maintained clean if they are collected by devices that are self-contained and clean and sterile inside only. The top layer of the sample is removed in a manner that does not contaminate the collection tools. Biobarrier (e.g., aluminum foil) covering the moving parts of these devices may be used as the only self removing bio-blanket that is required. The samples never leave the collection tools. The lids are placed on these tools inside the collection device. These single use tools with the lid and the sample inside are brought to Earth in the OS. The lids have to be designed impenetrable to the Earth organisms. The latter is a well established art.

Dolgin, B.↗
NASA NTRS2001

Computer Simulation of the Forces Acting on the Polystyrene Probe Submerged into the Succinonitrile Near Phase Transition

Modeling approach to simulate both mesoscale and microscopic forces acting in a typical AFM experiment is presented. At mesoscale level interaction between the cantilever tip and the sample surface is primarily described by the balance of attractive Van der Waals and repulsive forces. The model of cantilever oscillations is applicable to both non-contact and "tapping" AFM. This model can be farther enhanced to describe nanoparticle manipulation by cantilever. At microscopic level tip contamination and details of tip-surface interaction can be simulated using molecular dynamics approach. Integration of mesoscale model with molecular dynamic model is discussed.

Bune, Andris V.↗
NASA NTRS1980

A fundamental approach to adhesion: Synthesis, surface analysis, thermodynamics and mechanics

Several techniques were used to study pretreated Ti 6-4 surfaces including scanning electron microscopy (SEM), electron spectroscopy of chemical analysis (ESCA), and, reflectance visible spectroscopy. Each pretreatment type gave a characteristic surface morphology as seen by SEM. Elemental analysis of the Ti 6-4 surfaces was done using ESCA. Trace residual contaminants from particular chemical pretreatments were identified readily. Results indicate that reflectance visible spectroscopy using indicator dyes placed on Ti 6-4 surfaces appears to be a feasible approach to establish surface acidity. Differences in surface acidity were observed using bromthymol blue on Ti 6-4 surfaces pretreated by two different methods.

Beck, B.↗
NASA NTRS2015

Enhanced Cleaning of Genesis Solar Wind Sample 61348 for Film Residue Removal

The Genesis mission returned to Earth on September 8, 2004, experiencing a nonnominal reentry. During the recovery of the collector materials from the capsule, many of the collector fragments were placed on the adhesive protion of post-it notes to prevent the fragments from moving during transport back to Johnson Space Center. This unknowingly provided an additional contaminate that would prove difficult to remove with the limited chemistries allowed in the Genesis Curation Laboratory. Generally when collector material samples are prepared for allocation to PIs, the samples are cleaned front side only with Ultra-Pure Water (UPW) via megasonic dispersion to the collector surface to remove crash debris and contamination. While this cleaning method works well on samples that were not placed on post-its during recovery, it has caused movement of the residue on the back of the sample to be deposited on the front in at least two examples. Therefore, samples placed on the adhesive portion on post-it note, require enhanced cleaning methods since post-it residue has proved resistant to UPW cleaning.

Allums, K. K.↗
NASA NTRS1980

NASCAP modelling computations on large optics spacecraft in geosynchronous substorm environments

The NASA Charging Analyzer Program (NASCAP) is used to evaluate qualitatively the possibility of such enhanced spacecraft contamination on a conceptual version of a large satellite. The evaluation is made by computing surface voltages on the satellite due to encounters with substorm environments and then computing charged particle trajectories in the electric fields around the satellite. Particular attention is paid to the possibility of contaminants reaching a mirror surface inside a dielectric tube because this mirror represents a shielded optical surface in the satellite model used. Deposition of low energy charged particles from other parts of the spacecraft onto the mirror was found to be possible in the assumed moderate substorm environment condition. In the assumed severe substorm environment condition, however, voltage build up on the inside and edges of the dielectric tube in which the mirror is located prevents contaminants from reaching the mirror surface.

Stevens, N. J.↗
NASA NTRS2012

Evidence from Olivine-Hosted Melt Inclusions that the Martian Mantle has a Chondritic D/H Ratio and that Some Young Basalts have Assimilated Old Crust

Magmatic degassing of volatile elements affects the climate and near-surface environment of Mars. Telescopic and meteorite studies have revealed that the Martian atmosphere and near-surface materials have D/H ratios ~5-6 times terrestrial values [e.g., 1, 2]. Such high D/H ratios are interpreted to result from the preferential loss of H relative to heavier D from the Martian atmosphere, assuming that the original Martian water inventory had a D/H ratio similar to terrestrial values and to H in primitive meteorites [e.g., 1, 3]. However, the primordial Martian D/H ratio has, until now, not been well constrained. The uncertainty over the Martian primordial D/H ratio has arisen both from the scarcity of primitive Martian meteorites and as a result of contamination by terrestrial and, perhaps, Martian surface waters that obscure the signature of the Martian mantle. This study reports a comprehensive dataset of magmatic volatiles and D/H ratios in Martian primary magmas based on low-contamination, in situ ion microprobe analyses of olivine-hosted melt inclusions from both depleted [Yamato 980459 (Y98)] and enriched [Larkman Nunatak 06319 (LAR06)] Martian basaltic meteorites. Analyses of these primitive melts provide definitive evidence that the Martian mantle has retained a primordial D/H ratio and that young Martian basalts have assimilated old Martian crust.

Usui, Tomohiro↗
NASA NTRS1980

Residual Silicone Detection

Both photoelectron emission and ellipsometry proved successful in detecting silicone contamination on unpainted and epoxy painted metal surfaces such as those of the external tank and the solid rocket booster. Great success was achieved using photoelectron emission (PEE). Panels were deliberately contaminated to controlled levels and then mapped with PEE to reveal the areas and levels that were contaminated. The panels were then tested with regard to adhesive properties. Tapes were bonded over the contaminated and uncontaminated regions and the peel force was measured, or the contaminated panels were bonded (with CPR 483 foam) to uncontaminated panels and made into lap shear specimens. Other panels were bonded and made into wedge specimens for hydrothermal stress endurance tests. Strong adhesion resulted if the PEE signal fell within an acceptance window, but was poor outside the acceptance window. A prototype instrument is being prepared which can automatically be scanned over the external liquid hydrogen tank and identify those regions that are contaminated and will cause bond degradation.

Smith, T.↗
NASA NTRS2015

A Bispectral Composite Threshold Approach for Automatic Cloud Detection in VIIRS Imagery

The detection of clouds in satellite imagery has a number of important applications in weather and climate studies. The presence of clouds can alter the energy budget of the Earth‐atmosphere system through scattering and absorption of shortwave radiation and the absorption and re‐emission of infrared radiation at longer wavelengths. The scattering and absorption characteristics of clouds vary with the microphysical properties of clouds, hence the cloud type. Thus, detecting the presence of clouds over a region in satellite imagery is important in order to derive atmospheric or surface parameters that give insight into weather and climate processes. For many applications however, clouds are a contaminant whose presence interferes with retrieving atmosphere or surface information. In these cases, is important to isolate cloud‐free pixels, used to retrieve atmospheric thermodynamic information or surface geophysical parameters, from cloudy ones. This abstract describes an application of a two‐channel bispectral composite threshold (BCT) approach applied to VIIRS imagery. The simplified BCT approach uses only the 10.76 and 3.75 micrometer spectral channels from VIIRS in two spectral tests; a straight‐forward infrared threshold test with the longwave channel and a shortwave - longwave channel difference test. The key to the success of this approach as demonstrated in past applications to GOES and MODIS data is the generation of temporally and spatially dependent thresholds used in the tests from a previous number of days at similar observations to the current data. The paper and subsequent presentation will present an overview of the approach and intercomparison results with other satellites, methods, and against verification data.

LaFontaine Frank J.↗
NASA NTRS1975

Chemical reactions of metal powders with organic and inorganic liquids during ball milling

Chromium and/or nickel powders were milled in metal chlorides and in organic liquids representative of various functional groups. The powders always reacted with the liquid and became contaminated with elements from them. The milled powders had specific surface areas ranging from 0.14 to 37 sq m/g, and the total contamination with elements from the milling liquid ranged from 0.01 to 56 weight percent. Compounds resulting from substitution, addition, or elimination reactions formed in or from the milling liquid.

Arias, A.↗
NASA NTRS1976

Metal powder reactions in ball milling

On milling chromium powder in three metal chlorides and either chromium or nickel powders in ten organic liquids representative of nine different functional groups, the powders always reacted with the liquids and became contaminated with elements from them. The milled powders had specific surface areas ranging from 0.14 to 37 sq m/g, and the total contamination with elements from the milling liquid ranged from 0.01 to 56 wt%. In most milling runs, compounds resulting from substitution, addition, or elimination reactions formed in or from the milling liquid, and in most runs with organic liquids H2, CH4, and CO2 were generated.

Arias, A.↗
NASA NTRS2013

Microbiological Sampling Methods and Sanitation of Edible Plants Grown on ISS

Pathogenic microbes on the surfaces of salad crops and growth chambers pose a threat to the health of crew on International Space Station. For astronauts to safely consume spacegrown vegetables produced in NASA's new vegetable production unit, VEGGIE, three technical challenges must be overcome: real-time sampling, microbiological analysis, and sanitation. Raphanus sativus cultivar Cherry Bomb II and Latuca sativa cultivar Outredgeous, two saled crops to be grown in VEGGIE, were inoculated with Salmonella enterica serovar Typhimurium (S. Typhimurium), a bacterium known to cause food-borne illness~ Tape- and swab-based sampling techniques were optimized for use in microgravity and assessed for effectiveness in recovery of bacteria from crop surfaces: Rapid pathogen detection and molecular analyses were performed via quantitative real-time polymerase chain reactiop using LightCycler® 480 and RAZOR® EX, a scaled-down instrument that is undergoing evaluation and testing for future flight hardware. These methods were compared with conventional, culture-based methods for the recovery of S. Typhimurium colonies. A sterile wipe saturated with a citric acid-based, food-grade sanitizer was applied to two different surface materials used in VEGGIE flight hardware that had been contaminated with the bacterium Pseudomonas aeruginosa,. another known human pathogen. To sanitize surfaces, wipes were saturated with either the sanitizer or sterile deionized water and applied to each surface. Colony forming units of P. aeruginosa grown on tryptic soy agar plates were enumerated from surface samples after sanitization treatments. Depending on the VEGGIE hardware material, 2- to 4.5-log10 reductions in colony-forming units were observed after sanitization. The difference in recovery of S. Typhimurium between tape- and swab- based sampling techniques was insignificant. RAZOR® EX rapidly detected S. Typhimurium present in both raw culture and extracted DNA samples.

Parrish, Charles H. II↗
NASA NTRS2026

Gateway Element and Payload Materials Outgassing Analyses: HALO, HERMES, and ERSA

Gateway was intended to be humanity’s first space station around the Moon, but its development has been paused as the National Aeronautics and Space Administration (NASA) shifts focus to achieving the United States’ National Space Policy goals. Instead of an orbiting lunar outpost, NASA will now pursue the development of a lunar surface base to support a sustained human presence on the Moon. Before the program’s pause, Gateway’s Induced Environments team worked to ensure payloads and elements (i.e., modules) complied with induced environment requirements. Methods developed and insights gained from this work will have applicability to NASA’s Moon Base and the potential repurposing of Gateway elements and payloads, as well as to induced environments modeling for future space stations. The Gateway program’s induced environment included molecular contamination, electric thruster plume sputter and redeposition, and lunar dust transfer from the Human Landing System (HLS). Primary sources of external molecular contamination included materials outgassing, chemical thruster plume contamination, and vacuum venting. The focus of this paper will be on element- and payload-level materials outgassing analyses performed for Gateway Configuration 1, extending the previously-developed framework for Gateway system-level external molecular contamination modeling. Gateway Configuration 1 consisted of the Power and Propulsion Element (PPE) and the Habitation and Logistics Outpost (HALO). It also included payloads like the European Radiation Sensor Array (ERSA) attached to PPE and the Heliophysics Environmental and Radiation Measurement Experiment Suite (HERMES) attached to HALO. The element- and payload-level analyses to be introduced in this paper for HALO, HERMES, and ERSA enabled high-fidelity descriptions of Gateway’s external molecular contamination environment. Approaches to geometric modeling, meshing, outgassing rate assignment, molecular transport modeling, and analysis methodology will be presented. Element and payload contaminant deposition onto sensitive Gateway receiver surfaces will be summarized and results compared to induced environment requirements. While these results incorporate refinements made over the course of the program, they were not intended to be final. Therefore, modeling assumptions and inputs, potential improvements, and lessons-learned will be documented to inform future work on Moon Base, repurposed elements and payloads, and other space stations.

Gateway↗
NASA NTRS2018

Preliminary Testing of NASA's Molecular Adsorber Coating Technology for Future Missions to Mars

The Molecular Adsorber Coating (MAC) is a sprayable coatings technology that was developed at NASA Goddard Space Flight Center (GSFC). The coating is comprised of highly porous, zeolite materials that help capture outgassed molecular contaminants on spaceflight applications. The adsorptive capabilities of the coating can alleviate molecular contamination concerns on or near sensitive surfaces and instruments within a spacecraft. This paper will discuss the preliminary testing of NASA’s MAC technology for use on future missions to Mars. The study involves evaluating the coating’s molecular adsorption properties in simulated test conditions, which include the vacuum environment of space and the Martian atmosphere. MAC adsorption testing was performed using a commonly used plasticizer called dioctyl phthalate (DOP) as the test contaminant.

CO2↗
NASA NTRS2018

Preliminary Testing of NASA's Molecular Adsorber Coating Technology for Future Missions to Mars

The Molecular Adsorber Coating (MAC) is a sprayable coatings technology that was developed at NASA Goddard Space Flight Center (GSFC). The coating is comprised of highly porous, zeolite materials that help capture outgassed molecular contaminants on spaceflight applications. The adsorptive capabilities of the coating can alleviate molecular contamination concerns on or near sensitive surfaces and instruments within a spacecraft. This paper will discuss the preliminary testing of NASA's MAC technology for use on future missions to Mars. The study involves evaluating the coating's molecular adsorption properties in simulated test conditions, which include the vacuum environment of space and the Martian atmosphere. MAC adsorption testing was performed using a commonly used plasticizer called dioctyl phthalate (DOP) as the test contaminant.

outgassing↗
NASA NTRS1978

Theoretical contamination of cryogenic satellite telescopes

The state of contaminant molecules, the deposition rate on key surfaces, and the heat transfer rate were estimated by the use of a zeroth-order approximation. Optical surfaces of infrared telescopes cooled to about 20 K should be considered to be covered with at least several deposition layers of condensible molecules without any contamination controls. The effectiveness of the purge gas method of contamination controls was discussed. This method attempts to drive condensible molecules from the telescope tube by impacts with a purge gas in the telescope tube. For this technique to be sufficiently effective, the pressure of the purge gas must be more than 2 x .000001 torr. The influence caused by interactions of the purged gas with the particulate contaminants was found to slightly increase the resident times of the particulate contaminants within the telescope field of view.

Murakami, M.↗