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At least 829 records · Page 46
All sourcesNASA NTRSDOE OSTI
DOE OSTI2021

Near total reflection x-ray photoelectron spectroscopy: quantifying chemistry at solid/liquid and solid/solid interfaces

Near total reflection regime has been widely used in x-ray science, specifically in grazing incidence small angle x-ray scattering and in hard x-ray photoelectron spectroscopy (XPS). In this work, we introduce some practical aspects of using near total reflection (NTR) in ambient pressure XPS and apply this technique to study chemical concentration gradients in a substrate/photoresist system. Experimental data are accompanied by x-ray optical and photoemission simulations to quantitatively probe the photoresist and the interface with the depth accuracy of ~1 nm. Together, our calculations and experiments confirm that NTR XPS is a suitable method to extract information from buried interfaces with highest depth-resolution, which can help address open research questions regarding our understanding of concentration profiles, electrical gradients, and charge transfer phenomena at such interfaces. Furthermore, the presented methodology is especially attractive for solid/liquid interface studies, since it provides all the strengths of a Bragg-reflection standing-wave spectroscopy without the need of an artificial multilayer mirror serving as a standing wave generator, thus dramatically simplifying the sample synthesis.

solid/solid interface↗
DOE OSTI2013

DETERMINING REFLECTANCE SPECTRA OF SURFACES AND CLOUDS ON EXOPLANETS

Planned missions will spatially resolve temperate terrestrial planets from their host star. Although reflected light from such a planet encodes information about its surface, it has not been shown how to establish surface characteristics of a planet without assuming known surfaces to begin with. We present a reanalysis of disk-integrated, time-resolved, multiband photometry of Earth obtained by the Deep Impact spacecraft as part of the EPOXI Mission of Opportunity. We extract reflectance spectra of clouds, ocean, and land without a priori knowledge of the numbers or colors of these surfaces. We show that the inverse problem of extracting surface spectra from such data is a novel and extreme instance of spectral unmixing, a well-studied problem in remote sensing. Principal component analysis is used to determine an appropriate number of model surfaces with which to interpret the data. Shrink-wrapping a simplex to the color excursions of the planet yields a conservative estimate of the planet's endmember spectra. The resulting surface maps are unphysical, however, requiring negative or larger-than-unity surface coverage at certain locations. Our ''rotational unmixing'' supersedes the endmember analysis by simultaneously solving for the surface spectra and their geographical distributions on the planet, under the assumption of diffuse reflection and known viewing geometry. We use a Markov Chain Monte Carlo to determine best-fit parameters and their uncertainties. The resulting albedo spectra are similar to clouds, ocean, and land seen through a Rayleigh-scattering atmosphere. This study suggests that future direct-imaging efforts could identify and map unknown surfaces and clouds on exoplanets.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2013

DIFFRACTION, REFRACTION, AND REFLECTION OF AN EXTREME-ULTRAVIOLET WAVE OBSERVED DURING ITS INTERACTIONS WITH REMOTE ACTIVE REGIONS

We present observations of the diffraction, refraction, and reflection of a global extreme-ultraviolet (EUV) wave propagating in the solar corona. These intriguing phenomena are observed when the wave interacts with two remote active regions, and together they exhibit properties of an EUV wave. When the wave approached AR11465, it became weaker and finally disappeared in the active region, but a few minutes later a new wavefront appeared behind the active region, and it was not concentric with the incoming wave. In addition, a reflected wave was also simultaneously observed on the wave incoming side. When the wave approached AR11459, it transmitted through the active region directly and without reflection. The formation of the new wavefront and the transmission could be explained with diffraction and refraction effects, respectively. We propose that the different behaviors observed during the interactions may be caused by different speed gradients at the boundaries of the two active regions. We find that the EUV wave formed ahead of a group of expanding loops a few minutes after the start of the loops' expansion, which represents the initiation of the associated coronal mass ejection (CME). Based on these results, we conclude that the EUV wave should be a nonlinear magnetosonic wave or shock driven by the associated CME, which propagated faster than the ambient fast mode speed and gradually slowed down to an ordinary linear wave. Our observations support the hybrid model that includes both fast wave and slow non-wave components.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗
DOE OSTI2013

NuSTAR SPECTROSCOPY OF GRS 1915+105: DISK REFLECTION, SPIN, AND CONNECTIONS TO JETS

We report on the results of spectral fits made to a NuSTAR observation of the black hole GRS 1915+105 in a 'plateau' state. This state is of special interest because it is similar to the 'low/hard' state seen in other black holes, especially in that compact, steady jets are launched in this phase. The 3-79 keV bandpass of NuSTAR, and its ability to obtain moderate-resolution spectra free from distortions such as photon pile-up, are extremely well suited to studies of disk reflection in X-ray binaries. In only 15 ks of net exposure, an extraordinarily sensitive spectrum of GRS 1915+105 was measured across the full bandpass. Ionized reflection from a disk around a rapidly spinning black hole is clearly required to fit the spectra; even hybrid Comptonization models including ionized reflection from a disk around a Schwarzschild black hole proved inadequate. A spin parameter of a = 0.98 ± 0.01 (1σ statistical error) is measured via the best-fit model; low spins are ruled out at a high level of confidence. This result suggests that jets can be launched from a disk extending to the innermost stable circular orbit. A very steep inner disk emissivity profile is also measured, consistent with models of compact coronae above Kerr black holes. These results support an emerging association between the hard X-ray corona and the base of the relativistic jet.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2015

UNAMBIGUOUS DETECTION OF REFLECTION IN MAGNETIC CATACLYSMIC VARIABLES: JOINT NuSTAR–XMM-NEWTON OBSERVATIONS OF THREE INTERMEDIATE POLARS

In magnetic cataclysmic variables (CVs), X-ray emission regions are located close to the white dwarf surface, which is expected to reflect a significant fraction of intrinsic X-rays above 10 keV, producing a Compton reflection hump. However, up to now, a secure detection of this effect in magnetic CVs has largely proved elusive because of the limited sensitivity of non-imaging X-ray detectors. Here we report our analysis of joint NuSTAR–XMM-Newton observations of three magnetic CVs, V709 Cas, NY Lup, and V1223 Sgr. The improved hard X-ray sensitivity of the imaging NuSTAR data has resulted in the first robust detection of Compton hump in all three objects, with amplitudes of ∼1 or greater in NY Lup, and likely <1.0 in the other two. We also confirm earlier reports of a strong spin modulation above 10 keV in V709 Cas, and we report the first detection of small spin amplitudes in the others. We interpret this as due to different height of the X-ray emitting region among these objects. A height of ∼0.2 white dwarf radii provides a plausible explanation for the low reflection amplitude of V709 Cas. Since emission regions above both poles are visible at certain spin phases, this can also explain the strong hard X-ray spin modulation. A shock height of ∼0.05 white dwarf radii can explain our results on V1223 Sgr, while the shock height in NY Lup appears negligible.

79 ASTRONOMY AND ASTROPHYSICS↗
DOE OSTI2020

In situ laser reflectivity to monitor and control the nucleation and growth of atomically thin 2D materials*

The growth of atomically thin two-dimensional (2D) layered and other quantum materials is typically performed without in situ monitoring or control. Here, a simple laser reflectivity approach is demonstrated to provide in situ control over sub-monolayer thickness and growth kinetics during pulsed laser deposition (PLD) of MoSe 2 layers. First, the general technique is presented with emphasis on designing the maximum sensitivity of the optical contrast through consideration of Fresnel's equations with proper choice of layer thickness, substrate, and laser monitoring wavelength, incidence angle, and laser polarization. Then the 632.8 nm optical reflectivity of MoSe 2 layers on SiO 2 /Si substrates was predicted and compared with in situ monitoring of MoSe 2 growth by PLD under actual growth conditions using a probe HeNe laser beam. The measurements showed high sensitivity and excellent agreement with MoSe 2 surface coverages calculated from atomic resolution STEM analysis of 2D layers deposited in arrested growth experiments. Finally, growth kinetics revealed by these measurements showed sigmoidal nucleation and growth stages in the formation of the 2D MoSe 2 layers that are described by a simple model, indicating the promise of the laser reflectivity technique for in situ monitoring and control of 2D materials deposition.

2D materials↗
DOE OSTI2022

Deep-learning-guided high-resolution subsurface reflectivity imaging with application to ground-penetrating radar data

Subsurface reflectivity imaging is one of the most important geophysical characterization methods for revealing subsurface structures. In many cases, accurate subsurface reflectivity imaging is challenging because of, for example, random or coherent noise in the data and sparse source-receiver observation geometry. Here, we develop a deep-learning-guided iterative imaging method to improve subsurface structure imaging. Specifically, we train a supervised neural network to infer a noise-free, high-resolution image from a noisy, low-resolution image and use this estimated image as guidance to regularize least-squares imaging. We develop a systematic method to generate high-quality synthetic training data (data-label pairs) to train the guidance neural network. The trained neural network can provide high-fidelity predictions even for field-data images that are not in the training data. We validate our new imaging method using one synthetic and two field ground-penetrating radar data examples, and find that our method can produce clean, high-resolution subsurface reflectivity images where existing single-pass and least-squares imaging methods fail due to noise and insufficient data coverage.

58 GEOSCIENCES↗
DOE OSTI2018

Femtosecond tracking of carrier relaxation in germanium with extreme ultraviolet transient reflectivity

Extreme ultraviolet (XUV) transient reflectivity around the germanium M 4,5 edge (3d core-level to valence transition) at 30 eV is advanced to obtain the transient dielectric function of crystalline germanium [100] on femtosecond to picosecond time scales following photoexcitation by broadband visible-to-infrared (VIS/NIR) pulses. By fitting the transient dielectric function, carrier-phonon induced relaxations are extracted for the excited carrier distribution. The measurements reveal a hot electron relaxation rate of 3.2±0.2ps attributed to the X-L intervalley scattering and a hot hole relaxation rate of 600±300fs ascribed to intravalley scattering within the heavy hole (HH) band, both in good agreement with previous work. An overall energy shift of the XUV dielectric function is assigned to a thermally induced band gap shrinkage by formation of acoustic phonons, which is observed to be on a timescale of 4-5 ps, in agreement with previously measured optical phonon lifetimes. The results reveal that the transient reflectivity signal at an angle of 66° with respect to the surface normal is dominated by changes to the real part of the dielectric function, due to the near critical angle of incidence of the experiment (66°-70° for the range of XUV energies used. Finally, this work provides a methodology for interpreting XUV transient reflectivity near core-level transitions, and it demonstrates the power of the XUV spectral region for measuring ultrafast excitation dynamics in solids.

74 ATOMIC AND MOLECULAR PHYSICS↗
DOE OSTI2025

Extending the capillary wave model to include the effect of bending rigidity: X-ray reflectivity and diffuse scattering

The surface roughness of a thin film at a liquid interface exhibits contributions of thermally excited fluctuations. This thermal roughness depends on temperature (𝑇), surface tension (𝛾), and elastic material properties, specifically the bending modulus (𝜅) of the film. A nonzero 𝜅 suppresses the thermal roughness at small length scales compared to an interface with zero 𝜅, as expressed by the power spectral density of the thermal roughness. The description of the x-ray scattering of the standard capillary wave model (CWM), which is valid for zero 𝜅, is extended to include the effect of 𝜅. The extended CWM (eCWM) provides a single analytical form for both the specular x-ray reflectivity (XRR) and the diffuse scattering around the specular reflection, and recovers the expression of the CWM at its zero 𝜅 limit. This theoretical approach enables the use of single-shot grazing incidence x-ray off-specular scattering (GIXOS) measurements for characterizing the structure of thin films on a liquid surface. The eCWM analysis approach decouples the thermal roughness factor from the surface scattering signal, providing direct access to the intrinsic surface-normal structure of the film and its bending modulus. Moreover, the eCWM facilitates the calculation of reflectivity at any desired resolution (pseudo-XRR approach). The transformation into pseudo-XRR provides the benefit of using widely available XRR software to perform GIXOS analysis. The extended range of the vertical scattering vector (𝑄 𝑧 ) available with the GIXOS pseudo-XRR approach allows for a higher spatial resolution than with conventional XRR. Experimental results are presented for various lipid systems, showing strong agreement between conventional specular XRR and pseudo-XRR methods. This agreement validates the proposed approach and highlights its utility for analyzing soft, thin films.

36 MATERIALS SCIENCE↗
DOE OSTI2022

Study of interface reaction in a B 4 C/Cr mirror at elevated temperature using soft X-ray reflectivity

Boron carbide is a prominent material for high-brilliance synchrotron optics as it remains stable up to very high temperatures. The present study shows a significant change taking place at 550°C in the buried interface region formed between the Cr adhesive layer and the native oxide layer present on the silicon substrate. An in situ annealing study is carried out at the Indus-1 Reflectivity beamline from room temperature to 550°C (100°C steps). The studied sample is a mirror-like boron carbide thin film of 400 Å thickness deposited with an adhesive layer of 20 Å Cr on a silicon substrate. The corresponding changes in the film structure are recorded using angle-dependent soft X-ray reflectivity measurements carried out in the region of the boron K-edge after each annealing temperature. Analyses performed using the Parratt recursive formalism reveal that the top boron carbide layer remains intact but interface reactions take place in the buried Cr–SiO2 region. After 300°C the Cr layer diffuses towards the substrate. At higher temperatures of 500°C and 550°C the Cr reacts with the native oxide layer and tends to form a low-density compound of chromium oxysilicide (CrSiOx). Depth profiling of Si and Cr distributions obtained from secondary ion mass spectroscopy measurements corroborate the layer model obtained from the soft X-ray reflectivity analyses. Details of the interface reaction taking place near the substrate region of boron carbide/Cr sample are discussed.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗
DOE OSTI2019

A Total Internal Reflection Photoconductive Switch

We demonstrate a novel illumination technique for extrinsic photoconductive switches based on the creation of a total internal reflection trap to increase the optical path length. The optimal geometry is a square substrate illuminated from one of the corners along the diagonal, ensuring that the total internal reflection condition is maintained after any reflection off the device lateral sides. The optical absorption uniformity throughout the device bulk was improved by designing the entry window to have a cylindrical shape and by using a square core optical fiber as an illumination source. In conclusion, the concept is experimentally validated on a vanadium-doped silicon carbide device that shows approximately four-fold improvement in responsivity compared to normal illumination.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗
DOE OSTI2020

The Numerical Computation of Clear-Sky Transmittance and Reflectance of Solar Radiation for the Modeling of PV System Performance

Modeling of photovoltaics (PV) system performance requires numerical computation of plane-of-array (POA) irradiances that are influenced by atmospheric absorption and scattering. Clear-sky transmittance and reflectance of diffuse irradiance are essential for the understanding of solar radiation related to multiple reflection between land surface and clouds. This study analytically solves the radiative transfer equation for clear-sky conditions and numerically computes the transmittance and reflectance of diffuse irradiance as functions of the optical thickness of the atmosphere. The computation will be implemented in all-sky radiative transfer models to improve their computational efficiency.

14 SOLAR ENERGY↗
DOE OSTI2014

Characterization of zinc oxide thin film using atomic force microscopy and optimized X-ray reflectivity by genetic algorithm

For the nanostructured thin films, the study of surface physical parameters is often of crucial importance. For example, the transport properties of ZnO thin film are strongly affected by the geometry of this film. In this study sol—gel ZnO thin film was spin coated on glass substrate. The inverse problem of thin film characterization is formulated as a parameter identification problem in which a set of parameters corresponding to the thin film property can be found by minimizing fitness functions formulated using theoretical and experimental X-ray reflectivity. Atomic force microscopy (AFM) measurements used as an independent procedure for extracting structural parameters of the film and accurate interpretation of X-ray reflectivity data. After applying Fractal calculations on the AFM measured data the Genetic algorithm (GA) method was applied for extracting other important structural parameters. Optimization of specular X-ray reflectivity by GA method gives information along the depth such as thickness, roughness, and electron density profile of layers in the film.

36 MATERIALS SCIENCE↗
DOE OSTI2018

The Effect of Specular Reflectances on the Interaction of an Electromagnetic E Wave with a Thin Metal Film Placed between Two Dielectric Media

The interaction of an electromagnetic E wave with a thin metal film placed between two dielectric media is calculated in the case of different specular reflectances q{sub 1} and q{sub 2} for the reflection of electrons from the surface of the thin metal layer, in the case of variations in the values of dielectric permittivities ε{sub 1} and ε{sub 2} of the media, and in the case of different values of angle of incidence θ of the electromagnetic wave. The behavior of reflection coefficient R, transmission coefficient T, and absorption coefficient A in relation to the frequency of the external field is analyzed.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗
DOE OSTI2014

Andreev reflection in rotating superfluid {sup 3}He-B

Andreev reflection of quasiparticle excitations from quantized line vortices is reviewed in the isotropic B phase of superfluid {sup 3}He in the temperature regime of ballistic quasiparticle transport at T ≤ 0.20T{sub c}. The reflection from an array of rectilinear vortices in solid-body rotation is measured with a quasiparticle beam illuminating the array mainly in the orientation along the rotation axis. The result is in agreement with the calculated Andreev reflection. The Andreev signal is also used to analyze the spin-down of the superfluid component after a sudden impulsive stop of rotation from an equilibrium vortex state. In a measuring setup where the rotating cylinder has a rough bottom surface, annihilation of the vortices proceeds via a leading rapid turbulent burst followed by a trailing slow laminar decay, from which the mutual friction dissipation can be determined. In contrast to the currently accepted theory, it is found to have a finite value in the zero-temperature limit: α(T→0) = (5 ± 0.5) × 10{sup −4}.

75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND↗
DOE OSTI2016

Reflection and backscattering of microwaves under doubling of the plasma density and displacement of the gyroresonance region during electron cyclotron resonance heating of plasma in the l-2M stellarator

Reflection and backscattering of high-power (400 kW) gyrotron radiation creating and heating plasma at the second harmonic of the electronic cyclotron frequency in the L-2M stellarator have been investigated experimentally. The effect of the displacement of the gyroresonance region from the axis of the plasma column under doubling of the plasma density on the processes of reflection and backscattering of microwave radiation has been examined. A near doubling of short-wavelength (k{sub ⊥} ≈ 30 cm{sup –1}) turbulent density fluctuations squared is observed. The change in the energy confinement time under variations of plasma parameters and characteristics of short-wavelength turbulence is discussed. A discrepancy between the measured values of the reflection coefficient from the electron cyclotron resonance heating region and predictions of the one-dimensional model is revealed.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗
DOE OSTI2013

Optical reflection from the Bragg lattice of AsSb metal nanoinclusions in an AlGaAs matrix

The optical properties of metal-semiconductor metamaterials based on an AlGaAs matrix are studied. The specific feature of these materials is that there are As and AsSb nanoinclusion arrays which modify the dielectric properties of the material. These nanoinclusions are randomly arranged in the medium or form a Bragg structure with a reflectance peak at a wavelength close to 750 nm, corresponding to the transparency region of the matrix. The reflectance spectra are studied for s- and p-polarized light at different angles of incidence. It is shown that (i) As nanoinclusion arrays only slightly influence the optical properties of the medium in the wavelength range 700-900 nm, (ii) chaotic AsSb nanoinclusion arrays cause strong scattering of light, and (iii) the spatial periodicity in the arrangement of AsSb nanoinclusions is responsible for Bragg resonance in the optical reflection.

36 MATERIALS SCIENCE↗
DOE OSTI2016

Plasmon–phonon coupling in the infrared reflectance spectra of Bi{sub 2}Se{sub 3} films

The results of studies of optical reflection in the far- and mid-infrared spectral regions are reported. The reflectance of five Bi{sub 2}Se{sub 3} topological insulator films grown by molecular-beam epitaxy on Si(111) substrates is measured. The characteristic parameters of phonons and plasmons are determined by means of dispersion analysis for multilayer structures. It is found that the plasma frequency in a layer close to the Si–film interface is noticeably higher than that in the film bulk. Calculations of the loss function show that plasmon–phonon coupling plays an important role in Bi{sub 2}Se{sub 3} films. The attenuated total internal reflection method is used to determine the frequency of the surface plasmon–phonon mode.

36 MATERIALS SCIENCE↗