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At least 811 records · Page 45
All sourcesNASA NTRSDOE OSTI
NASA NTRSDate not supplied

The Side Plume of Magnetically Shielded Hall Thrusters

A combination of near-thruster laser-induced fluorescence and far-field plasma probe measurements collected from two magnetically shielded Hall thrusters have shown that there exist an independent ion population of medium-energy (on average, 60-190 eV) exiting out the side (60° to 100° from firing axis) of the thrusters. Studying the trends with background pressure and known discrepancies between the laser-induced fluorescence and far-field plasma probe data suggest that at zero pressure the side plume is likely to exhibit higher energy and lower density than at facility background pressures. The possibility that these ions were produced by the modified two-stream instability is explored and while the agreement is good, there are areas of notable disagreement. Based on the idea that production of the side plume and channel exit striations are due to the same plasma wave actions, a theory was explored that explains why striations form under certain circumstances but not others. Another theory, based on the idea that side plume production only occurs over certain portion of the global discharge oscillation cycle, was also explored and areas of disagreement were identified. While the exact mechanism for side plume acceleration remains unclear, if the theory behind side plume production is correct, then side plume can be expected to be present in a wide range of magnetically-shielded as well as non-shielded Hall thrusters.

Electric propulsion↗
DOE OSTI2020

Nanostructure Accelerators: Novel concept and path to its realization

TeV/m acceleration gradients using crystals as originally envisioned by R. Hofstadter, an early pioneer of HEP, have remained unrealizable. Fundamental obstacles that have hampered efforts on particle acceleration using bulk-crystals arise from collisional energy loss and emittance degradation in addition to severe beam disruption despite the favorable effect of particle channeling along interatomic planes in bulk. We aspire for the union of nanoscience with accelerator science to not only overcome these problems using nanostructured tubes to avoid direct impact of the beam on bulk ion-lattice but also to utilize the highly tunable characteristics of nanomaterials. We pioneer a novel surface wave mechanism in nanostructured materials with a strong electrostatic component which not only attains tens of TeV/m gradients but also has focusing fields. Under our initiative, the proof-of-principle demonstration of tens of TeV/m gradients and beam nanomodulation is underway. Realizable nanostructure accelerators naturally promise new horizons in HEP as well as in a wide range of areas of research that utilize beams of high-energy particles or photons.

43 PARTICLE ACCELERATORS↗
DOE OSTI2024

Metadynamics simulations reveal mechanisms of Na + and Ca 2+ transport in two open states of the channelrhodopsin chimera, C1C2

Cation conducting channelrhodopsins (ChRs) are a popular tool used in optogenetics to control the activity of excitable cells and tissues using light. ChRs with altered ion selectivity are in high demand for use in different cell types and for other specialized applications. However, a detailed mechanism of ion permeation in ChRs is not fully resolved. Here, we use complementary experimental and computational methods to uncover the mechanisms of cation transport and valence selectivity through the channelrhodopsin chimera, C1C2, in the high- and low-conducting open states. Electrophysiology measurements identified a single-residue substitution within the central gate, N297D, that increased Ca 2+ permeability vs. Na + by nearly two-fold at peak current, but less so at stationary current. We then developed molecular models of dimeric wild-type C1C2 and N297D mutant channels in both open states and calculated the PMF profiles for Na + and Ca 2+ permeation through each protein using well-tempered/multiple-walker metadynamics. Results of these studies agree well with experimental measurements and demonstrate that the pore entrance on the extracellular side differs from original predictions and is actually located in a gap between helices I and II. Cation transport occurs via a relay mechanism where cations are passed between flexible carboxylate sidechains lining the full length of the pore by sidechain swinging, like a monkey swinging on vines. In the mutant channel, residue D297 enhances Ca 2+ permeability by mediating the handoff between the central and cytosolic binding sites via direct coordination and sidechain swinging. We also found that altered cation binding affinities at both the extracellular entrance and central binding sites underly the distinct transport properties of the low-conducting open state. This work significantly advances our understanding of ion selectivity and permeation in cation channelrhodopsins and provides the insights needed for successful development of new ion-selective optogenetic tools.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2023

Measurement of φ-meson production in Cu + Au collisions at $\sqrt{s_{NN}}$ = 200 GeV and U + U collisions at $\sqrt{s_{NN}}$ = 193 GeV

The PHENIX experiment reports systematic measurements at the Relativistic Heavy Ion Collider of φ-meson production in asymmetric Cu + Au collisions at $\sqrt{s_{NN}}$ = 200 GeV and in U + U collisions at $\sqrt{s_{NN}}$ = 193 GeV. Measurements were performed via the φ → K + K – decay channel at midrapidity |η| < 0.35. Features of φ- meson production measured in Cu + Cu, Cu + Au, Au + Au, and U + U collisions were found to not depend on the collision geometry, which was expected because the yields are averaged over the azimuthal angle and follow the expected scaling with nuclear-overlap size. The elliptic flow of the φ meson in Cu + Au, Au + Au, and U + U collisions scales with second-order-participant eccentricity and the length scale of the nuclear-overlap region (estimated with the number of participating nucleons). At moderate $p_T$ , φ-meson production measured in Cu + Au and U + U collisions is consistent with coalescence-model predictions, whereas at high $p_T$ the production is in agreement with expectations for in-medium energy loss of parent partons prior to their fragmentation. Finally, the elliptic flow for φ mesons measured in Cu + Au and U + U collisions is well described by a (2+1)-dimensional viscous-hydrodynamic model with specific-shear viscosity η/s = 1/4π.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗
DOE OSTI2023

Direct Mapping of Fluorine in Cation Disordered Rocksalt Cathodes

Cation-disordered rocksalt (DRX) oxides are promising candidates as next-generation cathodes for lithium-ion batteries. Partial fluorination of the DRX oxides enhances their cyclability. However, the lattice position, concentration, and spatial distribution of fluorine within DRX lattices remain elusive. Here, in this work, we use atom location by channeling-enhanced microanalysis, energy-dispersive X-ray spectroscopy, electron energy loss spectroscopy, and integrated differential phase contrast imaging in a scanning transmission electron microscope to gain atomic-level insights into DRX with nominal composition of Li 1.2 Mn 0.7 Ti 0.1 O 1.7 F 0.3 and Li 1.15 Ni 0.45 Ti 0.3 Mo 0.1 O 1.85 F 0.15 . We reveal that fluorine substitutes oxygen in the DRX lattices. The O/F ratio in terms of O+F = 2 is in the range from 1.92:0.08 to 1.82:0.18. Spatially, fluorine is distributed in the proximity of the Li-rich regions but distinct from lithium fluoride. Additionally, we observe that incorporation of fluorine in the DRX lattice induces a larger variation in cation–anion separation. These observations provide insight into the guided design of oxyfluoride DRX cathodes for high-performance batteries.

(S)TEM↗
DOE OSTI2025

Nuclear Astrophysics in the Storage Ring: Background Suppressed Simultaneous Measurement of (p,γ) and (p,n) Reactions

We report the application of the new elimination of Rutherford elastic scattering technique for the measurement of proton-induced reaction cross sections utilizing stored ions decelerated to astrophysical energies. This approach results in a background reduction factor of about 1 order of magnitude, enabling the first measurement of a (p, n) cross section in a storage ring. Here, the reaction channels 124 Xe⁢(p,n) and 124 Xe⁢(p,γ) have been studied just above the neutron threshold energy. The new data provide valuable constraints for Hauser-Feshbach theory and extrapolation of the (p,γ) cross section to lower energies. Most importantly, for nuclei of limited availability, the method represents a powerful improvement to efficiently study proton-induced reactions at energies within or close to the astrophysical Gamow window, bringing many reaction measurements within reach that were previously inaccessible in the laboratory.

73 NUCLEAR PHYSICS AND RADIATION PHYSICS↗
DOE OSTI2024

Structural bases for stoichiometry‐selective calcium potentiation of a neuronal nicotinic receptor

Background and Purpose α4β2 nicotinic acetylcholine (nACh) receptors assemble in two stoichiometric forms, one of which is potentiated by calcium. The sites of calcium binding that underpin potentiation are not known. Experimental Approach To identify calcium binding sites, we applied cryo‐electron microscopy (cryo‐EM) and molecular dynamics (MD) simulations to each stoichiometric form of the α4β2 nACh receptor in the presence of calcium ions. To test whether the identified calcium sites are linked to potentiation, we generated mutants of anionic residues at the sites, expressed wild type and mutant receptors in clonal mammalian fibroblasts, and recorded ACh‐elicited single‐channel currents with or without calcium. Key Results Both cryo‐EM and MD simulations show calcium bound to a site between the extracellular and transmembrane domains of each α4 subunit (ECD‐TMD site). Substituting alanine for anionic residues at the ECD‐TMD site abolishes stoichiometry‐selective calcium potentiation, as monitored by single‐channel patch clamp electrophysiology. Additionally, MD simulation reveals calcium association at subunit interfaces within the extracellular domain. Substituting alanine for anionic residues at the ECD sites reduces or abolishes stoichiometry‐selective calcium potentiation. Conclusions and Implications Stoichiometry‐selective calcium potentiation of the α4β2 nACh receptor is achieved by calcium association with topographically distinct sites framed by anionic residues within the α4 subunit and between the α4 and β2 subunits. Stoichiometry‐selective calcium potentiation could result from the greater number of calcium sites in the stoichiometric form with three rather than two α4 subunits. The results are relevant to modulation of signalling via α4β2 nACh receptors in physiological and pathophysiological conditions.

Pharmacology & Pharmacy↗
NASA NTRS1976

A.t.m. observations on the X u.v. emission from solar flares

The paper summarizes observations of selected solar flares made with a far-UV spectroheliograph (190-465 A) and a UV spectrograph (900-1900 A) aboard Skylab. The emission lines used in the present analysis are identified, and three events are described in detail: the flare of June 15, 1973, a small subflare observed on August 9, 1973, and the flare of January 21, 1974. Ultraviolet images of two other events are also presented in an attempt to sketch a general picture of a flare as seen in this spectral region. It is found that a small kernel seems to be the source of the primary energy release of a flare. The size, electron density, and ion temperature of a typical kernel are estimated, and it is noted that hot clouds of coronal gas at 20 million K surrounded the observed kernels. It is speculated that flare kernels might be very thin channels through which high-energy particles, originating in deep layers, are ejected into the corona.

Brueckner, G. E.↗
NASA NTRS1991

Dissociative attachment of electrons with Si2H6

Cross-sections for the production of negative ion fragments by electron attachment to Si2H6 and ion pair formation from it have been measured by utilizing the crossed electron beam-molecular beam collision technique. The negative ions are mass-analyzed by employing a quadrupole mass spectrometer. There are serious disagreements between the present and two previously published results. In the present paper cross-section values, appearance potentials, and the various channels of dissociation for the formation of negative monosilane fragments are presented.

Krishnakumar, E.↗
NASA NTRS2011

MESSENGER Searches for Less Abundant or Weakly Emitting Species in Mercury's Exosphere

Mercury's exosphere is composed of material that originates at the planet's surface, whether that material is native or delivered by the solar wind and micrometeoroids. Many exospheric species have been detected by remote sensing, including H and He by Mariner 10, Na, K, and Ca by ground-based observations, and H, Na, Ca, Mg, and Ca+ by the MErcury Surface, Space ENvironment, GEochemistry, and Ranging (MESSENGER) spacecraft. Other exospheric species, including Fe, AI, Si, 0, S, Mn, CI, Ti, OH, and their ions, are expected to be present on the basis of MESSENGER surface measurements and models of Mercury's surface chemistry. Here we report on searches for these species made with the Ultraviolet and Visible Spectrometer (UVVS) channel of the Mercury Atmospheric and Surface Composition Spectrometer (MASCS). No obvious signatures of the listed species have yet been observed in Mercury's exosphere by the UVVS as of this writing. It is possible that detections are elusive because the optimum regions of the exosphere have not been sampled. The Sun-avoidance constraints on MESSENGER place tight limits on instrument boresight directions, and some regions are probed infrequently. If there are strong spatial gradients in the distribution of weakly emitting species, a high-resolution sampling of specific regions may be required to detect them. Summing spectra over time will also aid in the ability to detect weaker emission. Observations to date nonetheless permit strong upper limits to be placed on the abundances of many undetected species, in some cases as functions of time and space. As those limits are lowered with time, the absence of detections can provide insight into surface composition and the potential source mechanisms of exospheric material.

Vervack, Ronald J., Jr.↗
DOE OSTI2020

Enabling fast charging of lithium-ion batteries through secondary- /dual- pore network: Part I - Analytical diffusion model

Battery performance is strongly correlated with electrode microstructural properties. Enabling fast charging of lithium-ion batteries requires improved through-plane ionic diffusion that can be achieved through, among other strategies, structured electrodes with a secondary- or dual-pore network (SPN). In this work, an analytical model investigates the impact of such an SPN on ionic diffusion with a composite electrode, considering various pore-channel geometries and comparing to standard electrodes with identical gravimetric- and volumetric-specific theoretical capacities. Relevant SPN design parameters and tortuosity coefficients are identified according to three optimization objectives that aim to balance the improved overall through-plane diffusion, thanks to the coarse aligned channels, and degraded in-plane diffusion because of the porous matrix densification required to maintain gravimetric- and volumetric-specific theoretical capacities. The model indicates that a relatively low amount of SPN is required and that electrodes with high through-plane tortuosity and low in-plane tortuosity benefit most from such architecture.

25 ENERGY STORAGE↗
DOE OSTI2023

Selective area doping of GaN toward high-power applications

Abstract Selective area doping in GaN, especially p-type, is a critical and inevitable building block for the realization of advanced device structures for high-power applications, including, but not limited to, current-aperture vertical electron transistors, junction termination extensions, junction barrier Schottky diodes, junction field-effect transistors (JFETs), vertical-channel JFETs, U-shaped metal–oxide–semiconductor field-effect transistors (U-MOSFETs), and Fin MOSFETs. This paper reviews and summarizes some of the recent advances in the fields of selective area etching and regrowth, ion implantation, and polarity-dependent doping that may lead to the practical realization of GaN-based power devices.

Physics↗
DOE OSTI2020

Open Source Visualization and Analysis Platform for 3D Reconstructions of Materials by Transmission Electron Microscopy

Three-dimensional characterization of materials at the nano- and meso-scale has become possible with transmission and scanning transmission electron microscopes (S/TEM). Its importance has extended to a wide class of nanomaterials such as hydrogen fuel cells, solar cells, industrial catalysts, new battery materials and semiconductor devices, as well as spanning high-tech industry, universities, and national labs. While capable instrumentation is abundant, this rapidly expanding demand for high-resolution tomography is bottlenecked by software that is instead tailored for lower-dose, biological applications and not optimized for higher-resolution materials applications. Existing tomography fails to utilize the chemical information provided by S/TEM spectrometers. To address this problem, this project delivered a scalable, fully functional, freely-distributable, open Source materials tomography package with a modern user interface that enables automated acquisition, alignment, and real-time reconstruction of raw tomography data, and provides advanced segmentation, three-dimensional chemical visualization and analysis optimized for materials applications. It has established an extendable framework capable of automation for high-throughput for the tomography of materials from data acquisition to visualization. Phase I and II delivered a full-featured, cross-platform, clean and integrated application for S/TEM materials tomography. It can read projection data from the microscope, with graphical tools for alignment of data, tomographic reconstruction, segmentation, and visualization of the reconstructed 3D volume. The entire pipeline can be saved to an XML state file, enabling fully reproducible data processing and analysis with a full Python environment for the development of custom algorithms, processing, and analysis requirements. Phase IIB extended the application to provide real-time tomographic reconstruction, "live updates" as data is processed, analysis of big data, and multi-channel tomography. Here, quantitative assessment of nanomaterials can occur as data is being recorded on a 3D visualization platform that accommodates additional information from multiple channels. We provide unmatched high-throughput tomography, where the complete tomographic pipeline from measurement to 3D visualization can occur rapidly. The project was extended to offer capabilities for micro-CT, X-ray, neutron, focused ion beam, atomic electron tomography and atom probe tomography. With over 600 transmission electron microscopes worldwide and approximately 50 coming online each year, the demand and impact of an open-source tomography tool is large. Significant opportunities exist in high-tech industry, universities, and national labs to enable or enhance three-dimensional imaging at the nanoscale and bring automated high-throughput approaches that will accelerate progress in materials characterization and metrology. The project supports a service based business model by enabling lab-specific acquisition and processing customization and integration-support and development that will be provided into Phase III and beyond.

36 MATERIALS SCIENCE↗
NASA NTRS1978

Reactions of OH/+/ and H2O/+/ ions with some diatomic and simple polyatomic molecules

The rate constants and product distributions of the reactions of OH(+) and H2O(+) with some diatomic and simple polyatomic molecules were studied by ion cyclotron resonance (ICR) mass spectrometric techniques. Reaction rates with CO, NO, O2, N2, CO2, H2S, N2O, H2CO, CH4 and CD4 were measured. Charge transfer and proton transfer were generally observed in cases for which the reaction channel is exothermic, but processes involving rearrangement were not found.

Karpas, Z.↗
NASA NTRS1983

Corotation anisotropies in Saturn's magnetosphere

Ion data from the Voyager 1 and 2 low-energy charged particle (LECP) experiment are fit to a second-order harmonic expansion to determine anisotropies within the Saturnian magnetosphere. Anisotropies from the low-energy channels (28-130 keV) are often consistent with those expected from corotation (generally with a small radial component on the dayside) but are at times distinctly different from corotation. On the dayside, near the noon meridian, first-order anisotropies often depart significantly from the corotation direction. On the nightside, amplitudes are consistent with full corotation but begin to drop below corotation values at a dipole L of approximately 27 Saturn radii (corresponding to a velocity of approximately 265 km/s). Second-order anisotropies are significant, even dominant at times, on the dayside where a relatively broad range of pitch angles is sampled by the instrument. In all cases there is a departure of approximately 180 deg from the first-order anisotropies expected due to corotation beginning outside the Rhea L shell and continuing through at least the orbit of Dione. This is the region where the cold and hot plasma tori have been observed. The anisotropies expected from rigid corotation of the observed flux distributions are computed, and it is concluded that parts of the Saturnian magnetosphere are not rigidly corotating. Calculations based on the combined effects of corotation plus solar wind generated convective electric fields appear to provide insights into the anisotropies along the dawn meridian. However, on the dayside near noon, turbulence and/or time variations seem necessary to explain the departure from simple convection models.

Carbary, J. F.↗
DOE OSTI2021

Interconnected cathode-electrolyte double-layer enabling continuous Li-ion conduction throughout solid-state Li-S battery

All-solid-state lithium (Li) batteries with high energy density are a promising solution for the next-generation energy storage systems in large-scale devices. To simultaneously overcome the challenges of poor ionic conduction of solid electrolytes and shuttling of active materials, here we introduce a functional electrolyte-cathode bilayer framework with interconnected LLAZO channels from the electrolyte into the cathode for advanced solid-state Li-S batteries. Differing from the traditional solid-state batteries with separated layer compositions, the introduced bilayer framework provides ultrafast and continuous ion/electron conduction. Instead of transferring Li+ across the polymer and garnet phases which involve huge interfacial resistance, Li+ is directly conducted through the LLAZO channels created continuously from the cathode layer to the solid electrolyte layer, significantly shortening the diffusion distance and facilitating the redox reaction of sulfur and sulfides. A stable cycle life is demonstrated in the prototype Li-S solid-state batteries assembled with the introduced LLAZO-LLAZO@CNF interconnected bilayer framework. High capacity is obtained at room temperature, indicating the superior electrochemical properties of the bilayer framework that result from the unique design of the interconnected LLAZO garnet phase.

25 ENERGY STORAGE↗
NASA NTRS1999

Water transport by the bacterial channel alpha-hemolysin

This study is an investigation of the ability of the bacterial channel alpha-hemolysin to facilitate water permeation across biological membranes. alpha-Hemolysin channels were incorporated into rabbit erythrocyte ghosts at varying concentrations, and water permeation was induced by mixing the ghosts with hypertonic sucrose solutions. The resulting volume decrease of the ghosts was followed by time-resolved optical absorption at pH 5, 6, and 7. The average single-channel permeability coefficient of alpha-hemolysin for water ranged between 1.3x10-12 cm/s and 1.5x10-12 cm/s, depending on pH. The slightly increased single-channel permeability coefficient at lower pH-values was attributed to an increase in the effective pore size. The activation energy of water transport through the channel was low (Ea=5.4 kcal/mol), suggesting that the properties of water inside the alpha-hemolysin channel resemble those of bulk water. This conclusion was supported by calculations based on macroscopic hydrodynamic laws of laminar water flow. Using the known three-dimensional structure of the channel, the calculations accurately predicted the rate of water flow through the channel. The latter finding also indicated that water permeation data can provide a good estimate of the pore size for large channels.

Non-NASA Center↗
DOE OSTI2020

PETN spark-gap detonators

The well-developed theory of Lorentz plasma that is dominated by electron–ion interactions is used to calculate the PETN arc characteristics. The spark-gap discharge current is a ramp with 10 to 25 ns rise time to peak and remaining constant subsequently. The approximate formulas for the arc channel conductivity, arc temperature, arc radius, and shock pressure from the arc are obtained from a system of nonlinear ordinary differential equations, which is the similarity solution of hydrodynamic equations similar to the Braginskii approximation. These arc parameters are given for the peak current ranging from 100 A to 1000 A and with different rise times. Representative cases are compared to the nonlinear ordinary differential equation code results. The shock pressures at the peak current are comparable to those from a typical commercial EBW bridgewire burst reported in the literature; the arc radius at the peak current is comparable to a typical bridgewire diameter of 0.0375 mm (e.g., RISI detonators, RP-1, and RP-80). The relevant Pop-Plot for low-density PETN is converted into an empirical detonation criterion, which is applicable to explosives subject to shocks of variable pressure. Finally, this criterion is then used to determine the detonation thresholds, which are comparable with test data obtained by Tucker, et al.

42 ENGINEERING↗