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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 757 records · Page 42

Wide-Bandgap Semiconductor Amplifiers for Fusion Plasma Heating and Control

This paper discusses power electronics developed under the ARPA-E GAMOW program to support nuclear fusion power production. The goal of this project was to develop and assess the potential for wide-bandgap (WBG) semiconductor devices in power electronics to enable high-efficiency and high-voltage solid-state systems for fusion plasma generation, heating, and control. The power electronics use an architecture in which multiple high-power boards can be combined to produce megawatt-level power, where using multiple boards provides high reliability. Two main areas of power electronics boards are developed in this project for fusion plasma heating and control applications: (1) pulse generation and control and (2) radiofrequency generation. The first area is for boards capable of driving high-voltage millisecond pulses at high duty cycles. The envisioned application of these pulses is in plasma control of magnetohydrodynamic instabilities, plasma position, and edge-localized modes. Pulse-width modulation allows for the implementation of a wide variety of linear and nonlinear control systems. The boards developed for this project could actuate control coils based on digital input signals and can be parallelized to provide megawatts of output power. The design of the pulse generator is a low-side load switch. A load switch was designed and constructed that utilized 2-kV-rated field-effect transistor (FET)-based cascodes developed by Qorvo under this project to perform initial testing of these cascodes. The second area is being implemented using class E amplifiers with WBG devices and a reactance steering network to handle inductive or capacitive plasma loads. Applications include ion cyclotron resonance heating (ICRH) and high-harmonic fast-wave (HHFW) heating. A class E reactance steering network is demonstrated in modeling and experiment with a resistive-inductive load that models an inductively-coupled plasma. Power combining of boards with class E reactance steering networks is also simulated and demonstrated experimentally, to enable scaling up to high power. Modeling of high-power-density cooling and remaining useful life is conducted to enable reliable, effectively cooled high-power electronics for fusion applications.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Application of functional genomics for domestication of novel non-model microbes

Abstract With the expansion of domesticated microbes producing biomaterials and chemicals to support a growing circular bioeconomy, the variety of waste and sustainable substrates that can support microbial growth and production will also continue to expand. The diversity of these microbes also requires a range of compatible genetic tools to engineer improved robustness and economic viability. As we still do not fully understand the function of many genes in even highly studied model microbes, engineering improved microbial performance requires introducing genome-scale genetic modifications followed by screening or selecting mutants that enhance growth under prohibitive conditions encountered during production. These approaches include adaptive laboratory evolution, random or directed mutagenesis, transposon-mediated gene disruption, or CRISPR interference (CRISPRi). Although any of these approaches may be applicable for identifying engineering targets, here we focus on using CRISPRi to reduce the time required to engineer more robust microbes for industrial applications. One-Sentence Summary The development of genome scale CRISPR-based libraries in new microbes enables discovery of genetic factors linked to desired traits for engineering more robust microbial systems.

59 BASIC BIOLOGICAL SCIENCES↗

Structural insights into the assembly and the function of the plant oxidative phosphorylation system

One of the key functions of mitochondria is the production of ATP to support cellular metabolism and growth. The last step of mitochondrial ATP synthesis is performed by the oxidative phosphorylation (OXPHOS) system, an ensemble of protein complexes embedded in the inner mitochondrial membrane. In the last 25 yr, many structures of OXPHOS complexes and supercomplexes have been resolved in yeast, mammals, and bacteria. However, structures of plant OXPHOS enzymes only became available very recently. In this review, we highlight the plant-specific features revealed by the recent structures and discuss how they advance our understanding of the function and assembly of plant OXPHOS complexes. Here we also propose new hypotheses to be tested and discuss older findings to be re-evaluated. Further biochemical and structural work on the plant OXPHOS system will lead to a deeper understanding of plant respiration and its regulation, with significant agricultural, environmental, and societal implications.

59 BASIC BIOLOGICAL SCIENCES↗

The oscillating Fischer-Tropsch reaction

The mechanistic steps that underlie the formation of higher hydrocarbons in catalytic carbon monoxide (CO) hydrogenation at atmospheric pressure over cobalt-based catalysts (Fischer-Tropsch synthesis) have remained poorly understood. Here, we reveal nonisothermal rate-and-selectivity oscillations that are self-sustained over extended periods of time (>24 hours) for a cobalt/cerium oxide catalyst with an atomic ratio of cobalt to cerium of 2:1 (Co 2 Ce 1 ) at 220°C and equal partial pressures of the reactants. A microkinetic mechanism was used to generate rate-and-selectivity oscillations through forced temperature oscillations. Experimental and theoretical oscillations were in good agreement over an extended range of reactant pressure ratios. Additionally, phase portraits for hydrocarbon production were constructed that support the thermokinetic origin of our rate-and-selectivity oscillations.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Deletion of Re -citrate synthase allows for analysis of contributions of tricarboxylic acid cycle directionality to the growth of Heliomicrobium modesticaldum

ABSTRACT Heliomicrobium modesticaldum,a phototrophic member of the phylum Firmicutes and family Clostridiales, possesses most of the enzymes specific to the reductive tricarboxylic acid (rTCA) cycle, except for the key enzyme, ATP-citrate lyase. It is thought to utilize a split TCA cycle when growing on pyruvate as a carbon source, in which the oxidative TCA (oTCA) direction generates most of the 2-ketoglutarate, but some can be produced in the reductive direction. Although a typicalSi-citrate synthase gene is not found in the genome, it was suggested that gene HM1_2993, annotated as homocitrate synthase, actually encodesRe-citrate synthase, which would function as the initial enzyme of the oTCA cycle. We deleted this gene to test this hypothesis and, if true, see what effect severing access to the oTCA cycle would have on this organism. The endogenous CRISPR-Cas system was used to replace the open reading frame with a selectable marker. The deletion mutants could grow on pyruvate but were unable to grow phototrophically on acetate + CO 2 as carbon source. Growth on acetate could be rescued by the addition of different electron sources (formate or ascorbate), suggesting that the oTCA cycle is used to oxidize acetate to generate electrons required to drive the carboxylation of acetyl-CoA. The deletion mutants were capable of growing in acetate minimal media without additional organic supplements beyond formate, demonstrating that the rTCA cycle can be employed to support sufficient 2-ketoglutarate production in this organism, unlike citrate synthase mutants in several chemoheterotrophic organisms utilizing the oTCA cycle. IMPORTANCE Heliobacteria are a unique group of phototrophic bacteria that are obligate anaerobes and possess a rudimentary system to use light as a source of energy. They do not make oxygen or fix carbon dioxide. Here, we explore their fundamental carbon metabolism to understand the role and operation of the central TCA cycle. This work shows both the role and operation of this cycle under different growth modes and explains how these organisms can obtain electrons to drive their biosynthetic metabolism. This foundational knowledge will be crucial in the future when attempts are made to use this organism as a platform for oxygen-sensitive synthesis of compounds in an anaerobe that can use light as its energy source.

Biotechnology & Applied Microbiology↗

Behavioral Health/Employee Assistance. Interim Program Report FY 2020

The Sandia National Laboratories' (SNL) Corporate Behavioral Health Program is a workplace- based program that: 1) provides Employee Assistance Program (EAP) services including early identification and resolution of personal concerns which may impact job performance, 2) assists managers and the organization in addressing productivity issues, and 3) supports the SNL commitment to provide a safe and healthful work environment. The program is offered to approximately 13,500 employees in New Mexico. The Behavioral Health Program is a corporate program combining services in NM and CA. It is integrated with other occupational health and clinical services including disability, disease management and preventive health programs. In addition, Sandia's Behavioral Health Program provides critical management consultation and psychological assessment services for external organizations including Human Resources, the Department of Energy and Security through the Clinical Evaluation (CE) process, Human Reliability Program (HRP), Protective Force Program, Workplace Violence/Threat Assessment Team (TAT), and Insider Threat Working Group programs. The program supports Sandia National Laboratories' mission to safeguard national security, the environment, and the public; it is a proactive approach to early identification, intervention and assessment. Importantly, it reduces barriers to accessing mental health services and assists with reducing health care costs attributed to illness or injuries related to unhealthy lifestyles and behaviors. The team is comprised of a professional staff including a licensed Clinical Psychologist, a licensed professional clinical counselor (LPCC) and a licensed Marriage and Family counselor (MFT) who is also a Certified Employee Assistance Professional and who holds a doctorate in counseling psychology.

99 GENERAL AND MISCELLANEOUS↗

Milestone 2.8: Preliminary Radiolytic Gas Generation Measurements from Helium-Backfilled Samples

The Department of Energy (DOE) is currently managing nearly 13 metric tons of aluminum-clad spent nuclear fuel (ASNF) with the intention of extended (> 50 years) dry storage in helium-backfilled canisters. Due to in-reactor and cooling pond conditions, oxyhydroxide corrosion layers have formed on the surface of the ASNF elements. These corrosion layers are susceptible to radiolysis and the formation of molecular hydrogen gas (H 2 ) due to the fuel’s inherent radiation field. Consequently, a rigorous evaluation of the effect of helium gas on radiolytic H 2 production is necessary to support the Technical Considerations and Challenges for Extended (> 50 yrs) Dry Storage of ASNF program, especially as previous Task 2 - Oxyhydroxide Layer Radiolytic Gas Generation Resolution work demonstrated a significant effect of gas composition on the radiolytic yield (G-value) of H 2 . Here we report preliminary G-values for the radiolytic formation of H 2 from the gamma irradiation of pre-corroded aluminum alloy 1100 coupons flame sealed in helium environments. Irradiations yielded G(H 2 ) values of (5.1 ± 0.5) x 10 –4 and (9.4 ± 0.9) x 10 –4 µmol J –1 for pristine coupons, and (10.1 ± 0.4) x 10 –4 and (15.1 ± 1.2) x 10 –4 µmol J –1 for pre-corroded coupons for 0% and 50% relative humidity, respectively. These helium environment G(H 2 ) values are between 28% and 58% higher than previously reported values for argon environments. This enhancement is attributed to the significant difference in first ionization energy between helium (24.59 eV) and argon (15.76) facilitating additional processes, e.g., Penning ionization. These new preliminary helium environment G(H 2 ) values will be employed by Task 3 - Sealed and Vented System Episodic Breathing and Gas Generation Prediction to model the effect of radiolytic H 2 accumulation in helium environments to evaluate the practicality of the extended storage standard canister design.

38 RADIATION CHEMISTRY, RADIOCHEMISTRY, AND NUCLEA↗

Abstract for CRADA between National Energy Technology Laboratory and Malachite Technologies, Inc.

The National Energy Technology Laboratory (NETL) and Malachite Technologies, Inc (MTI) will collaborate in the demonstration of early-stage feasibility of a process which will produce JP-10 fuel compliant with Mil Spec MIL-DTL-87107E. Our process will convert, by means of a plasma reactor, carbon dioxide (CO 2 ) feedstock which, along with hydrogen, will serve as a feedstock for an integrated Fischer-Tropsch (FT) reactor. A customized zeolite catalyst will support a highly selective production of JP-10 in the FT reactor.

10 SYNTHETIC FUELS↗

Extremely Durable Concrete using Methane Decarbonization Nanofiber Co-products with Hydrogen

This project successfully developed a scalable, low-cost co-production process for hydrogen (H₂) and carbon nanofibers (CNFs) using methane through catalytic chemical vapor deposition (CVD). CNFs are high-value materials with exceptional mechanical, electrical, and chemical properties, while hydrogen is a critical clean energy resource. By leveraging vapor deposition to create highly dispersed metal catalysts, this work addressed the dual challenge of producing low-cost hydrogen and enhancing the durability of concrete using co-produced CNFs. Unlike prior approaches, which required separating the carbon product from the catalyst, this innovative method integrated the carbon product, catalyst, and silica support as a crack-bridging additive for Portland cement. This novel application aimed to advance the performance of high-performance concrete (HPC) by improving its flexural toughness, durability, and resistance to environmental degradation.

08 HYDROGEN↗

Technology and Innovation Roadmap

This Technology and Innovation Roadmap outlines the Hanford Tank Waste Operations & Closure, LLC (H2C) strategic approach for advancing the Hanford Tank Waste Treatment Mission (HTWTM) through technology development. Our focus is on addressing technology needs that address risks, enhance efficiency, ensure worker safety, and uphold environmental standards. This Roadmap identifies key technology initiatives essential for the successful completion of the Hanford Site tank waste cleanup. Updated annually, it incorporates insights from the U.S. Department of Energy (DOE), the Integrated Tank Disposition Contractor (ITDC) H2C, recognized national lab experts, and fieldwork specialists. The Roadmap includes approximately 100 technology elements, each detailed in Technology Element Description Summaries (TEDS) and summarized in catalog sheets. These elements are crucial for aligning technology development activities with mission objectives across the HTWTM. With the initiation of the Direct-Feed Low-Activity Waste (DFLAW) program and the operation of the Tank Side Cesium Removal (TSCR) system, our focus now shifts to the support of scaled up production in East Area; applying similar and exploring new treatment alternatives to West Area Tank Waste; and advancing retrieval, delivery and treatment technologies for waste managed as high-level waste (HLW) across the Hanford tank farms. This transition is reflected in the technology and maturation (TM&E) charts, which highlight the evolving technology priorities. This document serves as a guide for navigating the challenges and opportunities in technology development at the Hanford Site.

12 MANAGEMENT OF RADIOACTIVE AND NON-RADIOACTIVE W↗

Environmental life-cycle analysis of hydrogen technology pathways in the United States

Hydrogen is a zero-carbon energy carrier with potential to decarbonize industrial and transportation sectors, but its life-cycle greenhouse gas (GHG) emissions depend on its energy supply chain and carbon management measures (e.g., carbon capture and storage). Global support for clean hydrogen production and use has recently intensified. In the United States, Congress passed several laws that incentivize the production and use of renewable and low-carbon hydrogen, such as the Bipartisan Infrastructure Law (BIL) in 2021 and the Inflation Reduction Act (IRA) in 2022, which provides tax credits of up to $3/kg depending on the carbon intensity of the produced hydrogen. A comprehensive life-cycle accounting of GHG emissions associated with hydrogen production is needed to determine the carbon intensity of hydrogen throughout its value chain. In the United States, Argonne’s R&D GREET ® (Greenhouse Gases, Regulated emissions, and Energy use in Technologies) model has been widely used for hydrogen carbon intensity calculations. This paper describes the major hydrogen technology pathways considered in the United States and provides data sources and carbon intensity results for each of the hydrogen production and delivery pathways using consistent system boundaries and most recent technology performance and supply chain data.

Elgowainy, Amgad↗

Satellite Data Applications for Sustainable Energy Transitions

Transitioning to a sustainable energy system poses a massive challenge to communities, nations, and the global economy in the next decade and beyond. A growing portfolio of satellite data products is available to support this transition. Satellite data complement other information sources to provide a more complete picture of the global energy system, often with continuous spatial coverage over targeted areas or even the entire Earth. We find that satellite data are already being applied to a wide range of energy issues with varying information needs, from planning and operation of renewable energy projects, to tracking changing patterns in energy access and use, to monitoring environmental impacts and verifying the effectiveness of emissions reduction efforts. While satellite data could play a larger role throughout the policy and planning lifecycle, there are technical, social, and structural barriers to their increased use. We conclude with a discussion of opportunities for satellite data applications to energy and recommendations for research to maximize the value of satellite data for sustainable energy transitions.

29 ENERGY PLANNING, POLICY, AND ECONOMY↗

The Roman View of Strong Gravitational Lenses

Galaxy–galaxy strong gravitational lenses can constrain dark matter models and the Lambda cold dark matter cosmological paradigm at subgalactic scales. Currently, there is a dearth of images of these rare systems with high signal-to-noise ratio (SNR) and angular resolution. The Nancy Grace Roman Space Telescope (hereafter Roman), scheduled for launch in late 2026, will play a transformative role in strong-lensing science with its planned wide-field surveys. With its remarkable 0.281 square degree field of view and diffraction-limited angular resolution of ~0$^{''}_.$1, Roman is uniquely suited to characterizing dark matter substructure from a robust population of strong lenses. We present a yield simulation of detectable strong lenses in Roman’s planned High Latitude Wide Area Survey (HLWAS). We simulate a population of galaxy–galaxy strong lenses across cosmic time with cold dark matter subhalo populations, select those detectable in the HLWAS, and generate simulated images accounting for realistic Wide Field Instrument detector effects. For a fiducial case of single 146 s exposures, we predict around 160,000 detectable strong lenses in the HLWAS, of which about 500 will have sufficient SNR to be amenable to detailed substructure characterization. We investigate the effect of variation of the point-spread function across Roman’s field of view on detecting individual subhalos and the suppression of the subhalo mass function at low masses. Our simulation products are available to support strong-lens science with Roman, such as training neural networks and validating dark matter substructure analysis pipelines.

79 ASTRONOMY AND ASTROPHYSICS↗

Advanced space engine preliminary design

A preliminary design was completed for an O2/H2, 89 kN (20,000 lb) thrust staged combustion rocket engine that has a single-bell nozzle with an overall expansion ratio of 400:1. The engine has a best estimate vacuum specific impulse of 4623.8 N-s/kg (471.5 sec) at full thrust and mixture ratio = 6.0. The engine employs gear-driven, low pressure pumps to provide low NPSH capability while individual turbine-driven, high-speed main pumps provide the system pressures required for high-chamber pressure operation. The engine design dry weight for the fixed-nozzle configuration is 206.9 kg (456.3 lb). Engine overall length is 234 cm (92.1 in.). The extendible nozzle version has a stowed length of 141.5 cm (55.7 in.). Critical technology items in the development of the engine were defined. Development program plans and their costs for development, production, operation, and flight support of the ASE were established for minimum cost and minimum time programs.

Cuffe, J. P. B.↗

Geodetic corrections and related information from oceanographic measurements made by Seasat-A

Oceanographic measurements taken by SEASAT-A are not only applicable to correct altimetry data for the desired geoid but also, as a result, they themselves are useful by-products for basic and applied research in the fields of sciences and engineering, exploratory development in sensor design and measurement techniques, and prediction products for operational fleet support. Among these measurements the important ones are current, sea state, and tides. Identified are parameters of the measurements which will be used to eliminate temporal environmental biases from geodetic measurements, and also to describe the physical processes involved.

Chen, D.↗

Exploitation of Seasat-A oceanographic measurements for Navy R and D applications

Basic research, exploratory development and operational demonstration potentials for exploitation of SEASAT-A data are discussed. Some of the interactions and tradeoffs in sensor design and measurement technology, and advanced development of environmental analysis and prediction products for operational fleet support are outlined.

Noble, V.↗