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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 739 records · Page 41
All sourcesNASA NTRSDOE OSTI
NASA NTRS2004

Digital Averaging Phasemeter for Heterodyne Interferometry

A digital averaging phasemeter has been built for measuring the difference between the phases of the unknown and reference heterodyne signals in a heterodyne laser interferometer. This phasemeter performs well enough to enable interferometric measurements of distance with accuracy of the order of 100 pm and with the ability to track distance as it changes at a speed of as much as 50 cm/s. This phasemeter is unique in that it is a single, integral system capable of performing three major functions that, heretofore, have been performed by separate systems: (1) measurement of the fractional-cycle phase difference, (2) counting of multiple cycles of phase change, and (3) averaging of phase measurements over multiple cycles for improved resolution. This phasemeter also offers the advantage of making repeated measurements at a high rate: the phase is measured on every heterodyne cycle. Thus, for example, in measuring the relative phase of two signals having a heterodyne frequency of 10 kHz, the phasemeter would accumulate 10,000 measurements per second. At this high measurement rate, an accurate average phase determination can be made more quickly than is possible at a lower rate.

Johnson, Donald↗
NASA NTRS1983

Aerodynamic coefficient identification package dynamic data accuracy determinations: Lessons learned

The errors in the dynamic data output from the Aerodynamic Coefficient Identification Packages (ACIP) flown on Shuttle flights 1, 3, 4, and 5 were determined using the output from the Inertial Measurement Units (IMU). A weighted least-squares batch algorithm was empolyed. Using an averaging technique, signal detection was enhanced; this allowed improved calibration solutions. Global errors as large as 0.04 deg/sec for the ACIP gyros, 30 mg for linear accelerometers, and 0.5 deg/sec squared in the angular accelerometer channels were detected and removed with a combination is bias, scale factor, misalignment, and g-sensitive calibration constants. No attempt was made to minimize local ACIP dynamic data deviations representing sensed high-frequency vibration or instrument noise. Resulting 1sigma calibrated ACIP global accuracies were within 0.003 eg/sec, 1.0 mg, and 0.05 deg/sec squared for the gyros, linear accelerometers, and angular accelerometers, respectively.

Heck, M. L.↗
DOE OSTI2023

Numerical modeling of chemical looping oxidative dehydrogenation of ethane in parallel packed beds

Chemical looping oxidative dehydrogenation (CL-ODH) of ethane has the potential to be a highly efficient alternative to steam cracking for ethylene production. Accurate reactor modeling is of critical importance to efficiently scale up and optimize this new technology. This study reports a one-dimensional, heterogeneous packed bed model to simulate the CL-ODH of ethane to ethylene with a Na 2 MoO 4 -promoted CaTi 0.1 Mn 0.9 O 3 redox catalyst. Here, the overall reaction kinetics was well-described by coupling the gas-phase steam cracking of ethane with the reduction kinetics of the redox catalyst by H 2 and C 2 H 4 . The impact of H 2 on the formation rate of CO 2 byproduct from C 2 H 4 conversion was also thoroughly investigated to validate the applicability of the kinetic model under operational environments. The temperature variation within the different CL-ODH steps and the temperature distribution along the bed were also carefully considered. The accuracy of the model was validated by experiments conducted in a large lab-scale packed bed reactor (200 g catalyst loading), with an average deviation of 2.8% in terms of ethane conversion and ethylene yield. The model was subsequently used to optimize the operating parameters of the CL-ODH reactor, indicating that up to 63.7% single-pass C 2 +olefin yield can be achieved with the current redox catalyst bed whereas further optimization of the redox catalyst to inhibit C 2 H 4 activation can result in 69.4% single-pass C 2 +yield while maintaining low CO 2 selectivity.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2026

Single-Particle Isotopic Analysis Using the Liquid Sampling-Atmospheric Pressure Glow Discharge Microplasma Coupled to an Orbitrap Mass Spectrometer

Isotope ratio (IR) determinations on individual particles can provide valuable information relative to the sample, including processing and dating, which could be valuable to geological and nuclear material analysis communities. In comparison to “bulk” measurements, in which all particle information is lost and homogenized within a sample, “particle” measurements allow for fingerprinting and can provide unique insights related to the sample’s nano- and micro- compositions. Furthermore, the complex nature of particles, with potential isobaric interferences from either the matrix or other elements within the same particle, poses a significant analytical challenge for conventional mass spectrometry platforms employed for elemental analysis due to their limited mass resolution. Presented here is the first demonstration of an ultrahigh resolution method for single particle (SP) isotopic analysis using the liquid sampling-atmospheric pressure glow discharge (LS-APGD) microplasma ionization source coupled to an Orbitrap mass spectrometer and FTMS Booster X2T acquisition/processing system. For proof of concept, well-characterized CeO 2 microparticles with a nominal diameter of 1.0 μm were analyzed at a mass resolution of ∼330,000. Important instrumental parameters were optimized to enable the detection of single particles. The 142 Ce/ 140 Ce ratio of individual particles and the population average were determined and compared to an SP inductively coupled plasma time-of-flight mass spectrometry (ICP-TOF-MS) analysis. The isotopic accuracy and precision were determined by two methods and found to be in good agreement with the SP-ICP-TOF-MS method, with the linear regression slope method providing a more accurate ratio, showing a ∼1.4% relative difference from the ratio determined from a particle digest. The encouraging performance of the method was further supported by a determined detection limit of 2.9 fg ( 142 Ce). The developed method is anticipated to overcome many of the challenges posed by isobaric interferences encountered in conventional mass spectrometry techniques when analyzing real-world samples for particle isotopic composition.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2025

Real-time elemental analysis of liquids for process monitoring using laser-induced breakdown spectroscopy with a liquid wheel sampling approach

This article presents an engineered sampling system that used a rotating wheel to form a thin liquid layer, permitting the use of laser-induced breakdown spectroscopy (LIBS) for in situ, real-time elemental impurity quantification during liquid processing. The sampling approach was demonstrated on eight elements from across the periodic table (Na, Al, K, Ca, Ti, Sr, Mo, and Yb). Univariate and multivariate calibrations were presented for each element. The average value for percent root mean square errors of cross-validation for the multivariate models was 3.64%, highlighting the method's strong prediction accuracy. Additionally, the limits of detection for each analyte were estimated from their univariate models: Na = 0.0532, Al = 18.5, K = 0.105, Ca = 0.273, Ti = 67.7, Sr = 0.640, Mo = 22.4, and Yb = 22.9 μg mL –1 . Finally, a test in which multivariate models were used to monitor a liquid system for 80 min was performed to investigate the real-time monitoring capabilities of this liquid LIBS sampling approach. Rigorous measurements were performed to effectively predict the absence and concentrations of multiple analytes as they were spiked and diluted. This demonstration showed the feasibility of using LIBS for real-time liquid quantification models with estimated precision ≤ 8.1%. Finally, the limitations of this approach and potential future improvements are discussed.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2021

OrbNet Denali: A machine learning potential for biological and organic chemistry with semi-empirical cost and DFT accuracy

We present OrbNet Denali, a machine learning model for an electronic structure that is designed as a drop-in replacement for groundstate density functional theory (DFT) energy calculations. The model is a message-passing graph neural network that uses symmetryadapted atomic orbital features from a low-cost quantum calculation to predict the energy of a molecule. OrbNet Denali is trained on a vast dataset of 2.3 × 10 6 DFT calculations on molecules and geometries. This dataset covers the most common elements in biochemistry and organic chemistry (H, Li, B, C, N, O, F, Na, Mg, Si, P, S, Cl, K, Ca, Br, and I) and charged molecules. OrbNet Denali is demonstrated on several well-established benchmark datasets, and we find that it provides accuracy that is on par with modern DFT methods while offering a speedup of up to three orders of magnitude. For the GMTKN55 benchmark set, OrbNet Denali achieves WTMAD-1 and WTMAD-2 scores of 7.19 and 9.84, on par with modern DFT functionals. For several GMTKN55 subsets, which contain chemical problems that are not present in the training set, OrbNet Denali produces a mean absolute error comparable to those of DFT methods. For the Hutchison conformer benchmark set, OrbNet Denali has a median correlation coefficient of R 2 = 0.90 compared to the reference DLPNO-CCSD(T) calculation and R 2 = 0.97 compared to the method used to generate the training data (ωB97X-D3/def2- TZVP), exceeding the performance of any other method with a similar cost. Similarly, the model reaches chemical accuracy for noncovalent interactions in the S66x10 dataset. For torsional profiles, OrbNet Denali reproduces the torsion profiles of ωB97X-D3/def2-TZVP with an average mean absolute error of 0.12 kcal/mol for the potential energy surfaces of the diverse fragments in the TorsionNet500 dataset.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2020

A low-complexity non-intrusive approach to predict the energy demand of buildings over short-term horizons

Reliable, non-intrusive, short-term (of up to 12 hours ahead) prediction of a building's energy demand is a critical component of intelligent energy management applications. A number of such approaches have been proposed over time, utilizing various statistical and, more recently, machine learning techniques, such as decision trees, neural networks and support vector machines. Importantly, all of these works barely outperform simple seasonal auto-regressive integrated moving average models, while their complexity is significantly higher. Here, we propose a novel low-complexity non-intrusive approach that improves the predictive accuracy of the state-of-the-art by up to ~10%. The backbone of our approach is a K-nearest neighbours search method, that exploits the demand pattern of the most similar historical days, and incorporates appropriate time-series pre-processing and easing. In the context of this work, we evaluate our approach against state-of-the-art methods and provide insights on their performance.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗
DOE OSTI2024

AI-Driven Crack Detection for Remanufacturing Cylinder Heads Using Deep Learning and Engineering-Informed Data Augmentation

Detecting cracks in cylinder heads traditionally relies on manual inspection, which is time-consuming and susceptible to human error. As an alternative, automated object detection utilizing computer vision and machine learning models has been explored. However, these methods often face challenges due to a lack of sufficiently annotated training data, limited image diversity, and the inherently small size of cracks. Addressing these constraints, this paper introduces a novel automated crack-detection method that enhances data availability through a synthetic data generation technique. Unlike general data augmentation practices, our method involves copying cracks from one location to another, guided by both random and informed engineering decisions about likely crack formations due to cyclic thermomechanical loads. The innovative aspect of our approach lies in the integration of domain-specific engineering knowledge into the synthetic generation process, which substantially improves detection accuracy. We evaluate our method’s effectiveness using two metrics: the F2 score, which emphasizes recall to prioritize detecting all potential cracks, and mean average precision (MAP), a standard measure in object detection. Experimental results demonstrate that, without engineering insights, our method increases the F2 score from 0.40 to 0.65, while maintaining a stable MAP. Incorporating detailed engineering knowledge further enhances the F2 score to 0.70 and improves MAP to 0.57, representing increases of 63% and 43%, respectively. These results confirm that our approach not only mitigates the limitations of traditional data augmentation but also significantly advances the reliability and precision of crack detection in industrial settings.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗
DOE OSTI2023

Designing an Optimal LSST Deep Drilling Program for Cosmology with Type Ia Supernovae

The Vera C. Rubin Observatory's Legacy Survey of Space and Time (LSST) is forecast to collect a large sample of Type Ia supernovae (SNe Ia) expected to be instrumental in unveiling the nature of dark energy. The feat, however, requires accurately measuring the two components of the Hubble diagram, distance modulus and redshift. Distance is estimated from SN Ia parameters extracted from light-curve fits, where the average quality of light curves is primarily driven by survey parameters. An optimal observing strategy is thus critical for measuring cosmological parameters with high accuracy. We present in this paper a three-stage analysis to assess the impact of the deep drilling (DD) strategy parameters on three critical aspects of the survey: redshift completeness, the number of well-measured SNe Ia, and cosmological measurements. We demonstrate that the current DD survey plans (internal LSST simulations) are characterized by a low completeness (z ~ 0.55–0.65), and irregular and low cadences (several days), which dramatically decrease the size of the well-measured SN Ia sample. We propose a method providing the number of visits required to reach higher redshifts. We use the results to design a set of optimized DD surveys for SN Ia cosmology taking full advantage of spectroscopic resources for host galaxy redshift measurements. The most accurate cosmological measurements are achieved with deep rolling surveys characterized by a high cadence (1 day), a rolling strategy (at least two seasons of observation per field), and ultradeep (z ≳ 0.8) and deep (z ≳ 0.6) fields. A deterministic scheduler including a gap recovery mechanism is critical to achieving a high-quality DD survey.

79 ASTRONOMY AND ASTROPHYSICS↗
NASA NTRS1976

ESCA studies of the surface chemistry of lunar fines

The paper presents an ESCA analysis based on the use of a synthetic lunar-glass standard that allows determination of the surface composition of lunar samples with an accuracy that appears to be better than 10% of the amount present for all major elements except Ti. It is found that, on the average, grain surfaces in the lunar fines samples 10084 and 15301 are strongly enriched in Si, moderately enriched in Fe, moderately depleted in Al and Ca, and strongly depleted in Mg. This pattern could not be produced by the deposition of any expected meteoritic vapor. Neither could it be produced by simple inverse-mass-dependent element loss during sputtering. It is suggested that at least part of the pattern may be a simple consequence of agglutinate glass formation in the fines since there is some evidence that Si can become enriched on the surface of silicate melts. These results do not support the strong enrichments in Fe on grain surfaces reported from Auger studies.

Housley, R. M.↗
NASA NTRS1982

Precipitable water: Its linear retrieval using leaps and bounds procedure and its global distribution from SEASAT SMMR data

Eight subsets using two to five frequencies of the SEASAT scanning multichannel microwave radiometer are examined to determine their potential in the retrieval of atmospheric water vapor content. Analysis indicates that the information concerning the 18 and 21 GHz channels are optimum for water vapor retrieval. A comparison with radiosonde observations gave an rms accuracy of approximately 0.40 g sq cm. The rms accuracy of precipitable water using different subsets was within 10 percent. Global maps of precipitable water over oceans using two and five channel retrieval (average of two and five channel retrieval) are given. Study of these maps reveals the possibility of global moisture distribution associated with oceanic currents and large scale general circulation in the atmosphere. A stable feature of the large scale circulation is noticed. The precipitable water is maximum over the Bay of Bengal and in the North Pacific over the Kuroshio current and shows a general latitudinal pattern.

Pandey, P. C.↗
NASA NTRS1983

A theoretical investigation of the sound radiation fields associated with a Bellmouth inlet

Analytical results are obtained by numerical integration of a cylindrically symmetric integral representation of the external solutions of the Helmholtz equation. The accuracy of this method is checked by comparisons of computed results with 'exact' solutions generated by the point source method. In all cases, the average error for the amplitude and phase of the points calculated in the field is found to be less than ten percent. Theoretical studies which model experiments run for the NASA Langely Bellmouth inlet configuration are presented and comparisons are made with the experimental results. In all cases very good agreement is obtained between the experimental and theoretically calculated values.

Meyer, W. L.↗
NASA NTRS1984

Automated mesoscale winds derived from GOES multispectral imagery

An automated technique for extracting mesoscale winds from sequences of GOES VISSR image pairs was developed, tested and configured for quasi-real time/research applications on a computing system which gives mesoscale wind estimates at the highest spatial/temporal resolution possible from the VISSR imagery down to a wind vector separation of 10 km. Preprocessing of imagery using IR resampling, VIS edge preserving filtering, and reduced VIS resolution averaging improved height assignments and vector extraction for 10, 15, and 30 min imagery. An objective quality control system provides much greater than 99% accuracy in eliminating questionable wind estimates. Automated winds generally have better spatial coverage and density, and have random error estimates half as large as the manual winds. Dynamical analysis of cloud wind divergence revealed temporally consistent convergence centers on the meso beta scale that are highly correlated with on going and future developing convective storms. The entire system of computer codes was successfully vectorized for execution on an array processor resulting in job turnaround in less than one hour.

Wilson, G. S.↗
NASA NTRS1984

Symmetry-dependent broadening parameters for methane

Experimental results for the pressure-broadened linewidths gamma of methane are presented and compared with theoretical results. A solar Fourier transform spectrometer with spectral resolving power of about one million was used together with a 6-m base length multitraversal absorption cell. Pressures were determined to an accuracy of + or - 0.2 Torr by means of a capacitance manometer. The pressuring gases were N2, H2, and He. Results are presented for numerical averages of all linewidths corresponding to a given tetrahedral symmetry for J = 0-6. For all cases studied, gamma(E) is found to be substantially less than gamma(A), and gamma(A) is found to be near to, but significantly smaller than, gamma(F). Relative inelastic cross sections calculated for argon scattering from methane are compared with relative pressure-broadened linewidths measured in several experiments involving methane and other gases.

Fox, K.↗
NASA NTRS1991

A measurement of planetary relativistic deflection

The technique of differential VLBI, over two DSN California-Australia baselines, is used to measure the angular deflection of the ray path of P0201 + 113 when it passed within 200 arcsec of Jupiter on March 21, 1988. Its angular position was measured 10 times over 4 hr on that date, with a similar measurement set on April 2, 1988, to detect the differential angular deflection of the ray path. According to general relativity, the expected gravitational bend of the ray path averaged over the March experiment duration was approximately 300 microarcsec, projected onto the two California-Australia baselines over which it was measured. Measurement accuracies of the order of 160 microarcsec were obtained for each of the ten differential measurements. The chi(2) per degree of freedom of the data for the noise and tropospheric fluctuations fully accounted for the scatter in the measured angular deflections. The chi(2) per degree of freedom for the hypothesis of no gravitational deflection by Jupiter was 4.1, which rejects the no-deflection hypothesis with greater than 99.999-percent confidence.

Treuhaft, R. N.↗
NASA NTRS1994

Arctic sea ice concentrations from special sensor microwave imager and advanced very high resolution radiometer satellite data

Nearly coincident data from the special sensor microwave imager (SSM/I) and the advanced very high resolution radiometer (AVHRR) are used to compute and compare Arctic sea ice concentrations for different regions and times of the year. To help determine overall accuracies and to highlight sources of differences between passive microwave, optical wavelength, and thermal wavelength data, ice concentrations are estimated using two operational SSM/I ice concentration algorithms and with visible- and thermal-infrared wavelength AVHRR data. All algorithms capture the seasonal patterns of ice growth and melt. The ranges of differences fall within the general levels of uncertainty expected for each method and are similar to previous accuracy estimates. The estimated ice concentrations are all highly correlated, with uniform biases, although differences between individual pairs of observations can be large. On average, the NASA Team algorithm yielded 5% higher ice concentrations than the Bootstrap algorithm, while during nonmelt periods the two SSM/I algorithms agree to within 0.5%. These seasonal differences are consistent with the ways that the 19-GHz and 37-GHz microwave channels are used in the algorithms. When compared to the AVHRR-derived ice concentrations, the Team-algorithm results are more similar on average in terms of correlation and mean differences. However, the Team algorithm underestimates concentrations relative to the AVHRR output by 6% during cold months and overestimates by 3% during summer. Little seasonal difference exists between the Bootstrap and AVHRR results, with a mean difference of about 5%. Although the mean differences are less between the SSM/I-derived concentrations and concentrations estimated using AVHRR channel 1, the correlations appear substantially better between the SSM/I data and concentrations derived from AVHRR channel 4, particularly for the Team algorithm output.

Emery, W. J.↗
NASA NTRS2010

Laser-Induced Fluorescence Velocity Measurements in Supersonic Underexpanded Impinging Jets

We report on an application of nitric oxide (NO) flow-tagging velocimetry to impinging underexpanded jet flows issuing from a Mach 2.6 nozzle. The technique reported herein utilizes a single laser, single camera system to obtain planar maps of the streamwise component of velocity. Whereas typical applications of this technique involve comparing two images acquired at different time delays, this application uses a single image and time delay. The technique extracts velocity by assuming that particular regions outside the jet flowfield have negligible velocity and may therefore serve as a stationary reference against which to measure motion of the jet flowfield. By taking the average of measurements made in 100 single-shot images for each flow condition, streamwise velocities of between -200 and +1,000 m/s with accuracies of between 15 and 50 m/s are reported within the jets. Velocity measurements are shown to explain otherwise seemingly anomalous impingement surface pressure measurements.

Inman, Jennifer A.↗
NASA NTRS2016

Lighting Condition Analysis for Mars Moon Phobos

A manned mission to Phobos may be an important precursor and catalyst for the human exploration of Mars, as it will fully demonstrate the technologies for a successful Mars mission. A comprehensive understanding of Phobos' environment such as lighting condition and gravitational acceleration are essential to the mission success. The lighting condition is one of many critical factors for landing zone selection, vehicle power subsystem design, and surface mobility vehicle path planning. Due to the orbital characteristic of Phobos, the lighting condition will change dramatically from one Martian season to another. This study uses high fidelity computer simulation to investigate the lighting conditions, specifically the solar radiation flux over the surface, on Phobos. Ephemeris data from the Jet Propulsion Laboratory (JPL) DE405 model was used to model the state of the Sun, the Earth, and Mars. An occultation model was developed to simulate Phobos' self-shadowing and its solar eclipses by Mars. The propagated Phobos' state was compared with data from JPL's Horizon system to ensure the accuracy of the result. Results for Phobos lighting condition over one Martian year are presented in this paper, which include length of solar eclipse, average solar radiation intensity, surface exposure time, total maximum solar energy, and total surface solar energy (constrained by incident angle). The results show that Phobos' solar eclipse time changes throughout the Martian year with the maximum eclipse time occurring during the Martian spring and fall equinox and no solar eclipse during the Martian summer and winter solstice. Solar radiation intensity is close to minimum at the summer solstice and close to maximum at the winter solstice. Total surface exposure time is longer near the north pole and around the anti- Mars point. Total maximum solar energy is larger around the anti-Mars point. Total surface solar energy is higher around the anti-Mars point near the equator. The results from this study and others like it will be important in determining landing site selection, vehicle system design and mission operations for the human exploration of Phobos and subsequently Mars.

Li, Zu Qun↗