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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 73 records · Page 4

Liquid fragility maximum in lithium borate glass‐forming melts related to the local structure

Abstract The structure of liquid lithium pyroborate, Li 4 B 2 O 5 ( J = Li/B = 2), has been measured over a wide temperature range by high‐energy X‐ray diffraction, and compared to that of its glass and borate liquids of other compositions. The results indicate a gradual increase in tetrahedral boron fraction from 3(1)% to 6(1)% during cooling from T = 1271(15) to 721(8) K, consistent with the larger N 4 = 10(1)% found for the glass, and literature 11 B nuclear magnetic resonance measurements. van't Hoff analysis based on a simple boron isomerization reaction BØ 3 O 2 – ⇌ BØO 2 2– yields Δ H = 13(1) kJ mol –1 and Δ S = 40(1) J mol –1 K –1 for the boron coordination change from 4 to 3, which are, respectively, smaller and larger than found for singly charged isomers for J ≤ 1. With these, we extend our model for N 4 ( J , T ), nonbridging oxygen fraction f nbr ( J , T ), configurational heat capacity , and entropy S conf ( J , T ) contributions up to J = 3. A maximum is revealed in at J = 1, and shown semi‐quantitatively to lead to a corresponding maximum in fragility contribution, akin to that observed in the total fragilities by temperature‐modulated differential scanning calorimetry. Lithium is bound to 4.6(2) oxygen in the pyroborate liquid, with 2.7(1) bonds centered around 1.946(8) Å and 1.9(1) around 2.42(1) Å. In the glass, n LiO = 5.4(4), the increase being due to an increase in the number of short Li–O bonds.

36 MATERIALS SCIENCE↗

PV Performance Modeling and Stakeholder Engagement (Final Technical Report)

This core capability project’s objective is to increase the value of photovoltaic (PV) performance models by improving their functionality, demonstrating, and quantifying their validity, and offering a wide range of stakeholder engagement opportunities. In FY22-24, we developed new and improved modeling algorithms and functions to represent PV performance more accurately in a variety of environments and conditions. The “Model parameter toolkit” was developed and includes functions to translate between different module temperature models, incidence angle modifier models, and single-diode models. A new modeling capability named “PV Atlas” was also developed leveraging Sandia’s High Performance Computing resources. This capability allows us to investigate several questions and provide climate-specific best practices and geographic data files; all these are hosted on an interactive website on Sandia’s GitHub and can be used for training, system optimization, or to provide best practices for uncertainty reduction. For model validation, we published high-quality PV performance, and weather data; these data are well documented, filtered, and processed for quality and include examples on how to run PV simulations. We also developed well documented, standardized methods for validating PV models and ran independent model validation and 2 blind modeling intercomparisons engaging with 49 organizations from 17 countries. We co-led and contributed to a growing, well documented and maintained suite of open-source functions for PV modeling (i.e., the pvlib-python) and we outreached to the PV modeling stakeholders via the PVPMC workshops and web resources. In addition, this project supported US representation and leadership for the International Energy Agency (IEA) PVPS Task 13; specifically, members of our team led and supported 3 subtasks on: 1) Best practices for the optimization of bifacial photovoltaic tracking, 2) Extreme weather events and their multiple impact on PV power plants: Risks, failure mechanisms and mitigation strategies, and 3) Best practice guidelines for the use of economic and technical Key Performance Indicators (KPIs). This project resulted in the publications of 14 peer reviewed journal papers, 37 conference presentations, 6 SAND reports, 5 public datasets and 6 new webpages on the PVPMC website. It supported the release of 13 pvlib-python versions where 28 enhancements were from this PV Performance Modeling project. We co-organized 5 PVPMC workshops in FY22-24 with the participation of 214 unique institutions and around 700 participants. The PVPMC website was redesigned, and its reliability was improved; it receives over 50,000 visitors/year from 202 unique countries.

14 SOLAR ENERGY↗

PV Performance Modeling - Data and Resources

The Photovoltaic (PV) Performance Modeling Collaborative (PVPMC) organized a blind PV performance modeling intercomparison to allow PV modelers to blindly test their models and modeling ability against real system data. Measured weather and irradiance data were provided along with detailed descriptions of PV systems from two locations (Albuquerque, New Mexico, USA and Roskilde, Denmark). Participants were asked to simulate the plane-of-array irradiance, module temperature, and DC power output from six systems and submit their results to Sandia for processing. This dataset includes seven MS-Excel sheets with instructions, notes and all necessary data (weather, irradiance, temperature, power) used for the data analysis of the blind modeling comparison. The hourly data represent six different systems from Albuquerque, NM and Roskilde, Denmark over a period of one year. These data are useful for PV performance model validation studies.

14 SOLAR ENERGY↗

Portable He-3 detector cryostat for the far infrared

The design of a portable He-3 cryostat for far infrared detection applications is described, with a cutaway drawing of the cryostat, including bolometer and cooled optics, provided. Consideration is given to the selection and testing of various bolometer materials, including Ge:Ga and Ge:InSb; the resistance-temperature coefficients of the materials examined are presented. The absolute flux calibration of the detector system using a new temperature-modulated cold source method is described.

Radostitz, J. V.↗

Testing flat plate photovoltaic modules for terrestrial environment

New qualification tests have been developed for flat plate photovoltaic modules. Temperature cycling, cyclic pressure load, and humidity exposure are especially useful for detecting design and fabrication deficiencies. There is positive correlation between many of the observed field effects, such as power loss, and qualification test induced degradation. The status of research efforts for the development of test methodology for field-related problems is reviewed.

Hoffman, A. R.↗

Temperature Controller for a Solar Furnace

Relatively-simple movable sheild has been suggested for controlling temperature of solar furnace. Temperature modulator can be set to have collected solar energy fully "on", fully "off" or any intermediate level. Parabolic mirror concentrates Sunlight into receiver. Shade plate that blocks insolation at back of receiver produces shade zone in center of collector. No radiation is returned to receiver from shade zone; only rays falling on other areas of reflecting surface are directed back toward receiver.

Hale, R. R.↗

Oxygen generation subsystem for spacecraft

Recovery of oxygen from water will be needed on future long-duration manned space missions. An oxygen generation subsystem (OGS) for NASA based on the alkaline electrolyte, static feed water electrolysis concept. Recent advances in hardware development have resulted in the design, fabrication and testing of a self-contained, one-person capacity OGS (WS-1). This subsystem consists of three major parts: a six-cell electrochemical module to generate the product O2, a coolant control assembly to maintain module temperature and a pressure controller which maintains product gas pressures. The subsystem provides 0. 82 kg/d O2 while operating at a current density of 206 mA/ sq cm, a temperature of 339 K and a pressure of 1240 kPa.

Schubert, F. H.↗

Throughput of the Composite Infrared Spectrometer (CIRS) Mid Infrared (MIR) Channel for the Cassini Mission to Saturn

The Composite Infrared Spectrometer (CIRS) of the Cassini mission to Saturn has two interferometers covering the far infrared and mid infrared wavelength region. The instrument was aligned at ambient temperature, but operates at 170 Kelvin and has challenging interferometric alignment tolerances. Cryogenic alignment tests of the instrument indicate that it should suffer minimal degradation due to the cooldown from ambient to operational temperature. System level tests performed by the calibration team indicated a lower than expected signal level on the MIR channel, while providing ambiguous optical throughput data. Therefore it became imperative to develop a metric that could be used to determine the instrument performance at both the instrument and system levels, at ambient and cryogenic temperature. Modulation efficiency and throughput measurements were performed and new analytical models developed to evaluate the status of the instrument. Empirical and analytical data were eventually reconciled and deviations from the design values explained.

Hagopian, John G.↗

Remote Sensing of Global Wetland Dynamics

Although natural wetlands only cover about 4% of the earth's ice-free land surface, they are the world's largest methane (CH4) source and the only one dominated by climate. In addition, wetlands affect climate by modulating temperatures and heat fluxes, storing water, increasing evaporation, and altering the seasonality of runoff and river discharge to the oceans. Current CH4 emissions from wetlands are relatively well understood but the sensitivity of wetlands and their emissions to climate variations remains the largest uncertainty in the global CH4 cycle and could strongly influence predictions of future climate. Therefore, characterizing climate-sensitive processes prevailing in the world's wetlands is crucial to understanding and predicting physical and biogeochemical responses of wetlands to interannual and longer-term climate variations. Recent research has resulted in the first generation of models to predict methane emissions from wetlands but the models must still be applied to static data on wetland distributions. Moreover, no models currently exist to realistically predict the distribution and dynamics of wetlands themselves for the current, or any other, climate. The dominant obstacle to modeling wetland dynamics has been lack of remote sensing techniques and data useful for characterizing quantitatively the seasonal and interannual variations of wetlands. We report on initial remote sensing studies undertaken to validate a global hydrological model linking rivers, takes and wetlands. Using a combination of SSM/I microwave and TOPEX Poseidon altimetry data sets, we developed and applied techniques to quantify inundation extent and duration for several large wetlands in tropical Africa and South America. Our initial results indicate that seasonally-inundated wetlands can be well characterized over large spatial scales and at monthly time scales using these remote sensing data. The results also confirm that currently available remote sensing products can be applied to provide crucial data to the research community modeling global hydrological and biogeochemical cycles.

Matthews, Elaine↗

Ground Based Remote Sensing of Upper Atmosphere Dynamics, Thermodynamics and Composition in Support of TIMED Satellites Scientific Mission

The following research work was accomplished: 1. We operated high throughput spectrophotometers and interferometers at eight observatories in the Arctic, Antarctic and mid-latitude regions to record relatively high-resolution spectra of very low light level airglow and auroral line as well as band emissions. 2. Our Polar observations of auroral emissions from N2 and O emissions have been analyzed to derive the O/N2 ratios around 110 km height in the Polar thermosphere during different auroral events triggered by the precipitation of auroral electrons with average energy of about 10 keV. These results have been compared with similar ratios derived from TIMED satellite s GUVI measurements of N2 LBH and 01 1356A emissions. 3. Our airglow measurements show MLT density and temperature modulations by Planetary, Tidal and Gravity Waves. They also indicate Mesopause cooling preceding a Stratospheric Warming Event (SWE).

Source record↗

Preliminary 3D Simulations of Anomalous Thermocouple Coupling to Surface Electric Fields

Anomalous measurements from subsurface thermocouples have been observed during re-entry of the Orion capsule (EFT-1 plugs). These measurements are considered anomalous because the amplitude and frequency of the inferred temperature modulations are too large to be due to plausible heating processes. Consequently, it is believed the anomalies are caused by electrical interference generated by the re-entry plasma. Quantifying these effects requires several steps: modeling the external plasma flows, modeling the plasma-surface interaction, and finally modeling the surface-thermocouple coupling. This paper addresses this last step using 3D finite element simulations of a wire embedded in a weakly conductive medium.

thermocouple anomaly↗

RadLab and the Environmental Data Application Dashboard: Graphical and Programming Interfaces for Interrogation of Space Telemetry Data

Sensors on the International Space Station (ISS) and multiple spacecraft elsewhere in Earth orbit and in deep space continuously monitor and collect environmental data, transmitting this information back to Earth. These data include ionizing radiation and, on the ISS, CO2, relative humidity levels, and temperature, and are of great importance to space biology research. Ionizing radiation in particular has been established in ground-based experiments as being correlated with increased risk of carcinogenesis and cardiovascular and neurological effects. Looking ahead to future long duration crewed missions beyond low Earth orbit, the ability to study how factors including CO2 levels, light cycle, temperature modulate the response to ionizing radiation and microgravity is essential. To date, access to these data has been fragmented across space agencies, spacecraft, and databases. To address this issue, NASA’s Open Science Data Repository (osdr.nasa.gov) has developed two Web applications: the Environmental Data Application (EDA) and a radiation-specific RadLab. Each consists of an API (application programming interface) and an associated GUI (graphical user interface) that provide single points of access to the data. To date, OSDR has focused on the sensors from payloads and radiation detectors located on the ISS. The Web applications process telemetry information and associated data, such as spacecraft location and orientation, from multiple international databases. The applications’ request syntax enables users to interrogate these data by craft, sensor type, time range, radiation type (galactic cosmic rays, solar particle events, the contribution of the South Atlantic Anomaly), facilitating arbitrary comparisons of original source data at varying time resolutions. The applications provide programmatic access for use in computational pipelines and GUIs for data visualization and exploration, making these data FAIR (Findable, Accessible, Interoperable, and Reusable), complementing the biological data contained in OSDR, and providing the space science community with a valuable resource for scientific analyses.

radiation↗

Scanning tunneling thermometer

Various examples are provided related to scanning tunneling thermometers and scanning tunneling microscopy (STM) techniques. In one example, a method includes simultaneously measuring conductance and thermopower of a nanostructure by toggling between: applying a time modulated voltage to a nanostructure disposed on an interconnect structure, the time modulated voltage applied at a probe tip positioned over the nanostructure, while measuring a resulting current at a contact of the interconnect structure; and applying a time modulated temperature signal to the nanostructure at the probe tip, while measuring current through a calibrated thermoresistor in series with the probe tip. In another example, a device includes an interconnect structure with connections to a first reservoir and a second reservoir; and a scanning tunneling probe in contact with a probe reservoir. Electrical measurements are simultaneously obtained for temperature and voltage applied to a nanostructure between the reservoirs.

Chinivaranahalli Shastry, Abhay Shankar↗

Scanning tunneling thermometer

Various examples are provided related to scanning tunneling thermometers and scanning tunneling microscopy (STM) techniques. In one example, a method includes simultaneously measuring conductance and thermopower of a nanostructure by toggling between: applying a time modulated voltage to a nanostructure disposed on an interconnect structure, the time modulated voltage applied at a probe tip positioned over the nanostructure, while measuring a resulting current at a contact of the interconnect structure; and applying a time modulated temperature signal to the nanostructure at the probe tip, while measuring current through a calibrated thermoresistor in series with the probe tip. In another example, a device includes an interconnect structure with connections to a first reservoir and a second reservoir; and a scanning tunneling probe in contact with a probe reservoir. Electrical measurements are simultaneously obtained for temperature and voltage applied to a nanostructure between the reservoirs.

Chinivaranahalli Shastry, Abhay Shankar↗

Efficiency and Regulation of Commercial Low Power DC/DC Converter Modules at Low Temperatures

DC/DC converters that are capable of operating at cryogenic temperatures are anticipated to play an important role in the power systems of future NASA deep space missions. Design of these converters to survive cryogenic temperatures will improve the power system performance, and reduce development and launch costs. At the NASA Glenn Research Center Low Temperature Electronics Laboratory, several commercial off-the-shelf dc/dc converter modules were evaluated for their low temperature performance. Various parameters were investigated as a function of temperature, in the range of 20 C to -190 C. Data pertaining to the efficiency and voltage regulation of the tested converters is presented and discussed.

Elbuluk, Malik E.↗

Potential Vorticity Dynamics Explain How Extratropical Oceans and the Arctic Modulate Wintertime Land–Temperature Variations

Temperature variations across the continental northern hemisphere at the interdecadal scale are thought to be remotely modulated by oceanic internal climate variability and the Arctic. Nevertheless, further elucidating the dynamics is essential for clarifying ongoing debates. We show that potential vorticity (PV) dynamics provide a concise explanation for these teleconnections. Our findings demonstrate that extratropical oceans and the Arctic can remotely modulate the wintertime continental temperature variations by stimulating PV anomalies, which are constrained by climatological PV gradients and jet streams. A causal explanation includes anomalous temperature and precipitation over oceans and the Arctic inducing local PV anomalies via diabatic heating. Subsequently, meridional and downstream advection distributes the anomalous PV to remote land regions where the climatological PV gradients are strong, that is, involving PV fronts, as well as jet streams; therefore, PV fronts and jet streams jointly indicate land regions that are largely and frequently impacted. However, land can also modulate other regions through the same mechanism when variations over land occur in advance. Clear causality depends on which factor is independent, while interactions among those regions may convolute the causality, thereby causing further debates.

54 ENVIRONMENTAL SCIENCES↗

Cryogenic Pressure Calibrator for Wide Temperature Electronically Scanned (ESP) Pressure Modules

Electronically scanned pressure (ESP) modules have been developed that can operate in ambient and in cryogenic environments, particularly Langley's National Transonic Facility (NTF). Because they can operate directly in a cryogenic environment, their use eliminates many of the operational problems associated with using conventional modules at low temperatures. To ensure the accuracy of these new instruments, calibration was conducted in a laboratory simulating the environmental conditions of NTF. This paper discusses the calibration process by means of the simulation laboratory, the system inputs and outputs and the analysis of the calibration data. Calibration results of module M4, a wide temperature ESP module with 16 ports and a pressure range of +/- 4 psid are given.

Faulcon, Nettie D.↗

Cold-Starting All-Solid-State Batteries from Room Temperature by Thermally Modulated Current Collector in Sub-Minute

All-solid-state batteries (ASSBs) show great potential as high-energy and high-power energy storage devices but their attainable energy/power density at room temperature is severely reduced because of the sluggish kinetics of lithium-ion transport. Here we first reported a thermally modulated current collector (TMCC), which can rapidly cold-start ASSBs from room temperature to operating temperatures (70–90 °C) in less than one minute, and simultaneously enhance the transient peak power density by 15-fold compared to one without heating. This TMCC is prepared by integrating a uniform, ultrathin (~200 nm) nickel layer as a thermal modulator within an ultralight polymer-based current collector. By isolating the thermal modulator from the ion/electron pathway of ASSBs, it can provide fast, stable heat control yet does not interfere with regular battery operation. Moreover, this ultrathin (13.2 μm) TMCC effectively shortens the heat transfer pathway, minimizes heat losses, and mitigates the formation of local hot spots. The simulated heating energy consumption can be as low as ~3.94% of total battery energy. This TMCC design with good tunability opens new frontiers towards smart energy storage devices in the future from the current collector perspective.

25 ENERGY STORAGE↗