Advanced Inorganic Membranes for Fuel Separation and Recycle in the Fusion Fuel Cycle
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11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗
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Results for “PALLADIUM ALLOY”
Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.
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Strain-Modulated Platinum–Palladium Nanowires for Oxygen Reduction Reaction
Electrocatalytic activity of alloy nanocatalytsts can be manipulated effectively by tuning their physical properties (ensemble, geometric, and ligand effects) to afford optimal surface structure and compositions for proton exchange membrane fuel cell (PEMFC) application. Herein, highly catalytic platinum-palladium nanowires (Pt n Pd 100-n NWs) with a subtle lattice strain and Boerdijk-Coxeter helix type morphology are synthesized through a surfactant-free, thermal single phase solvent method. X-ray diffraction results show that Pt n Pd 100-n NWs are exposed through the (111) facets and their shrinking or expanding lattice parameters can be modulated by the alloy compositions. Electrochemical results reveal that their high catalytic activity correlates with the lattice shrinking, facets, and bimetallic compositions, showing higher activity when the ratio of Pt and Pd is similar to ~78:22, which is further supported by DFT results. Compared to the nanoparticle type platinum-palladium alloyed catalysts with similar metal compositions (Pt n Pd 100-n NPs), the Pt n Pd 100-n NWs exhibit significantly improved electrocatalytic activity and stability for the oxygen reduction reaction. Our findings open new strategies to design the highly active and stable alloy nanocatalysts with controllable compositions.
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
Co‐Electrolysis of CO 2 and H 2 O to Syngas on Bimetallic Pd x Cu 1‐ x Catalysts for Tandem Thermochemical Conversion to Carbon Nanofibers
Electrification of chemical production using renewable energy and abundant feedstocks offers a promising pathway for decarbonizing the chemical industry. Current efforts on CO 2 valorization largely focus on making chemicals and fuels. Here, to help achieve net-negative emissions through long-term carbon storage, this study aims to develop efficient electrocatalysts for a tandem electrochemical-thermochemical process to convert CO 2 into carbon nanofibers (CNFs). CO 2 and water are first electrochemically reduced in a membrane electrode assembly (MEA) electrolyzer to produce syngas (CO + H 2 ), which is subsequently fed into a thermochemical packed bed reactor to facilitate CNF growth. This work systematically evaluated Pd x Cu 1-x bimetallic electrocatalysts to assess the effect of Pd–Cu alloying on enhancing syngas production while reducing Pd loading. Transmission electron microscopy and Raman spectroscopy confirmed the formation of high-purity, crystalline CNFs, regardless of the syngas composition from the MEA. In situ X-ray absorption spectroscopy and X-ray diffraction measurements revealed that increasing Cu content in the Pd x Cu 1-x alloy progressively inhibited palladium hydride formation, consistent with DFT calculations on the stability of Pd x Cu 1-x under reducing electrochemical potentials.
58 GEOSCIENCES↗
Progress on a PdCr wire strain gage
The principal activity under the HOST effort to improve the state of the art in high temperature static strain measurement has been a contract under which a palladium-chromium (PdCr) alloy was developed. The contract effort is continuing with the goal of developing a thin film high temperature static strain gage system. In addition to this effort, researchers contracted with Battelle-Columbus Laboratories to draw the PdCr allow into wire while researchers at Lewis worked to gain experience with this alloy as a wire strain gage.
Englund, David R.↗
Hydrogen migration at restructuring palladium–silver oxide boundaries dramatically enhances reduction rate of silver oxide
Heterogeneous catalysts are complex materials with multiple interfaces. A critical proposition in exploiting bifunctionality in alloy catalysts is to achieve surface migration across interfaces separating functionally dissimilar regions. Herein, we demonstrate the enhancement of more than 10 4 in the rate of molecular hydrogen reduction of a silver surface oxide in the presence of palladium oxide compared to pure silver oxide resulting from the transfer of atomic hydrogen from palladium oxide islands onto the surrounding surface formed from oxidation of a palladium-silver alloy. The palladium-silver interface also dynamically restructures during reduction, resulting in silver-palladium intermixing. This study clearly demonstrates the migration of reaction intermediates and catalyst material across surface interfacial boundaries in alloys with a significant effect on surface reactivity, having broad implications for the catalytic function of bimetallic materials.
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
Preparation and evaluation of advanced catalysts for phosphoric acid fuel cells
The platinum electrocatalysts were characterized for their crystallite sizes and the degree of dispersion on the carbon supports. One application of these electrocatalysts was for anodic oxidation of hydrogen in hot phosphoric acid fuel cells, coupled with the influence of low concentrations of carbon monoxide in the fuel gas stream. In a similar way, these platinum on carbon electrocatalysts were evaluated for oxygen reduction in hot phosphoric acid. Binary noble metal alloys were prepared for anodic oxidation of hydrogen and noble metal-refractory metal mixtures were prepared for oxygen reduction. An exemplar alloy of platinum and palladium (50/50 atom %) was discovered for anodic oxidation of hydrogen in the presence of carbon monoxide, and patent disclosures were submitted. For the cathode, platinum-vanadium alloys were prepared showing improved performance over pure platinum. Preliminary experiments on electrocatalyst utilization in electrode structures showed low utilization of the noble metal when the electrocatalyst loading exceeded one weight percent on the carbon.
Stonehart, P.↗
Technology for pressure-instrumented thin airfoil models, phase 1
A network of channels was chemically milled into one surface of a pair of matched plates having bond planes which were neither planar or profiled to match the contour of the trailing edge of a supercritical airfoil for testing in cryogenic wind tunnels. Vacuum brazing bonded the plates together to create a network of pressure passages without blockages or cross leaks. The greatest success was achieved with the smaller samples and planar bonding surfaces. In larger samples, problems were encountered due to warpage created by the relief of residual stresses. Successful bonds were formed by brazing A286, Nitronic 40 and 300 series stainless steels at 1065 C using AMS 4777B brazing alloy, but excessive grain growth occurred in samples of 200 grade 18 nickel maraging steels. Good bonds were obtained with maraging steel using a 47 percent Nickel-47 percent Palladium-6 percent Silicon alloy and brazing at 927 C. Electro-Discharge-Machining was an effective method of cutting profiled bond planes and airfoil contours. Orifices of good definition were obtained when the EDM wire cut passed through predrilled holes. Possible configurations for joints between small segments and the larger main wing were also studied.
Wigley, D. A.↗
Reducing Stress-Corrosion Cracking in Bearing Alloys
Resistance to stress-corrosion cracking in some stainless-steel alloys increased by addition of small amounts of noble metals. 0.75 to 1.00 percent by weight of palladium or platinum added to alloy melt sufficient to improve properties of certain stainless steels so they could be used in manufacture of high-speed bearings.
Paton, N. E.↗
Electronic Structure of Single-Atom Alloys and Its Impact on The Catalytic Activities
Single-atom alloys (SAAs) are promising materials for heterogeneous catalysis due to their unique structure and electronic properties. SAAs have active sites narrowed down to the single-atom level, which combines the advantages of alloy materials and single-site catalysts. Given the unique structural feature of SAAs, their electronic properties can be more flexibly tailored than for their monometallic counterparts, which can be used to effectively control their catalytic activities. One interesting feature commonly observed for SAAs is the lower density of state (DOS) near the Fermi level than their bulk references. Comparing with results for their monometallic bulk reference, the most noticeable electronic property change in SAAs is the narrowing of the valence band, which gives them free-atom-like character. Moreover, the d-band position of both single atoms and their host metals can show a pronounced shift. These changes of electronic structure in SAAs could largely affect the adsorption behavior of adsorbates during the catalytic processes. Close examination of the relationship between electronic structure and catalytic activity can provide useful guidance for rational design of new catalysts with improved performance.
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
PdCr Based High Temperature Static Strain Gage
The program at NASA Lewis Research Center to develop a high temperature static strain gage system for the hypersonic vehicle and turbine engine research has emphasized a palladium- 13wt%chromium (PdCr) alloy. Gages made from this alloy are being developed in both fine wire and thin film form. The wire gage system had platinum wire as a temperature compensator and was coated with a special alumina and zirconia mixture overcoat. This PdCr compensated wire gage responded linearly to the imposed strain to at least i000 microstrain. The strain sensitivity of the gage did not vary much with temperature. The apparent strain of this compensated gage was significantly lower than that of the other gages. It varied within 300 microstrain from room temperature to 800 deg. C with a reproducibility within 50 microstrain between thermal cycles to 800 deg. C. This is a significant advance over the 400 deg. C barrier of previous techniques for resistance static strain gages. The sputtered thin film PdCr strain gage, whose size was 8x8 mm and 10 micron thick, has demonstrated the possibility of extending the use of the PdCr strain gage to a temperature of approximately 1000 deg. C.
Lei, Jih-Fen↗
The structure of nickel-palladium solid solutions
Ni-Pd alloys atomic arrangements and displacements by single crystal X ray diffuse scattering, using computer simulated model
Lin, W.↗
Electrochemical corrosion of multiphase stainless steel-based alloy nuclear waste forms
Abstract The electrochemical corrosion behaviors of two multiphase alloys representing waste forms made with 316 L stainless steel and different amounts of surrogate metallic fuel wastes were measured and related to the microstructures. Potentiodynamic (PD) scans were performed in an acid brine solution and the corroded surfaces were characterized with scanning electron microscopy (SEM) to compare the electrochemical responses to the corrosion of specific phases. PD scans for the two multiphase alloys, 316 L stainless steel, and pure palladium were compared to understand the complex corrosion behavior of these multiphase alloys also recently classified as multi principle element alloys (MPEAs) and to determine the effects of alloying elements and noble metals present in constituent phases on the corrosion behavior.
Gattu, Vineeth Kumar (ORCID:0000000307265813)↗
On the Application of Diffuse X-ray Scattering to the Study of the Structure of Binary Alloys Semiannual Progress Report, Mar. 1 - Aug. 31, 1966
X-ray diffuse scattering measurements of nickel- palladium, iron-aluminum, and nickel-tungsten alloy systems
ALLOY↗
A resistance strain gage with repeatable and cancellable apparent strain for use to 800 C
A temperature compensated static strain gage, which is fabricated from palladium-13w/o chromium (Pd13Cr) alloy and a platinum (Pt) compensator, is being developed and was tested over a temperature range to 800 C at NASA-Lewis. The PdCr compensated strain gage has significantly lower apparent strain to 800 C than other high temperature strain gages. The PdCr compensated gage is protected from oxidation by a flame-sprayed alumina-4w/o zirconia overcoating. Test results to 800 C indicate apparent strain variations of less than 300 micro-epsilon and reproducibility between thermal cycles within 50 micro-epsilon. Apparent strain of the coated PdCr compensated gage can be predicted and cancelled due to its reproducibility and low value.
Lei, Jih-Fen↗
Diffuser Braze Development
At the request of SRTE, through the PDRD project, SRNL is developing a vacuum brazing process to facilitate the fabrication of hydrogen purification systems. In particular, this effort is directed at tube-style hydrogen diffusers. The diffusers are comprised of numerous palladium-silver tubes that are brazed to a nickel fitting, which is subsequently welded to a stainless steel tube, fitting, or tube sheet. Historically, torch brazing has been used as a heat source; for this work vacuum furnace brazing was suggested to improve the uniformity of the process. This report describes the braze process development for braze selection and simple nickel fitting to tube brazing. Five braze alloys were selected and sessile drop testing was conducted over a range of temperatures from 25 to 75° C over the liquidus temperature. Samples were characterized for wetting angle, erosion, and brazability. The cup-to-tube braze joints were inspected using digital radiography, ultrasonic testing, and metallographic examination. Two of the five alloys exhibited excellent fabrication properties and are considered for further development.
36 MATERIALS SCIENCE↗
Regeneration of Active Surface Alloys during Cyclic Oxidation and Reduction: Oxidation of H 2 on Pd/Ag(111)
The surface morphology and composition of a catalyst during excursions between oxidizing and reducing conditions can change substantially, especially in bimetallic alloys. Both thermodynamic and kinetic factors play a role in determining the properties of alloy surfaces where the active phase may be a metastable state. Previously, Ag oxide reduction was shown to be dramatically enhanced when Pd is on the surface; however, Pd is more stable when dissolved in Ag, raising the question as to whether a highly active Pd surface state will persist over multiple reaction cycles—a requirement for catalytic function. Experiments herein demonstrate that the enhanced chemical functionality due to the presence of Pd on the surface is retained, based on the enhanced rate of silver oxide reduction over multiple oxidation/reduction cycles for a Pd/Ag(111) model. Repeated oxidation and reduction promote PdAg alloying and reversible structural and compositional changes are detected using X-ray photoelectron spectroscopy. Furthermore, this study establishes that metastable phases can persist in reactive processes on surfaces, indicating their potential in heterogeneous catalysis.
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
Enhancing ORR Performance of Bimetallic PdAg Electrocatalysts by Designing Interactions between Pd and Ag
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99 GENERAL AND MISCELLANEOUS↗
New electrocatalysts for hydrogen-oxygen fuel cells
Platinum-silver, palladium-gold, and platinum-gold alloys serve as oxygen reduction catalysts in high-current-density cells. Catalysts were tested on polytetrafluoroethylene-bonded cathodes and a hydrogen anode at an operating cell temperature of 80 degrees C.
Cattabriga, R. A.↗