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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 73 records · Page 4
All sourcesNASA NTRSDOE OSTI
NASA NTRS1978

Design concepts of solar thermoelectric generators in space applications

Several thermoelectric technologies have been examined as to their suitability for use in a solar thermoelectric generator (STG) as a nonpropulsive power source for space applications. The results show that of all the presently available thermoelectric technologies, i.e., lead telluride, bismuth telluride, selenide, and silicon-germanium alloys, the latter type provides the optimum STG. Detailed results are presented on the performance and configurational characteristics of various silicon-germanium alloy STGs, including the performance of such STGs as a function of time in a Mercury orbit and the orbit of Mercury around the sun. It is shown that an STG design based on the use of silicon germanium alloy thermoelectric material, using multiple high voltage thermopiles with individual solar concentrators, presents the optimum combination of technology and configuration for minimizing power source mass. Additional concepts studied and discussed are the flat plate individual thermopile type and single concentrator compact thermopile type. The STG possesses an attractive potential for this application and represents a useful addition to the family of power sources for consideration in various space applications.

Raag, V.↗
NASA NTRS1979

Solar thermoelectric power generation for Mercury orbiter missions

Mercury orbiter mission study results have shown that conventional silicon solar cell array technology is not adequate to produce power because of expected temperatures which range from -90 C to +285 C in about 50 minutes for 16 sun eclipses/day. The solar thermoelectric generator (STG), which requires relatively high temperatures, is being developed as a replacement power source. Several thermoelectric technologies (i.e., lead telluride alloys, bismuth telluride, selenide, and silicon-germanium alloys have been examined for their suitability. Solar concentrator configurations (i.e., flat plate, Fresnel lens, mini-cone, and Cassegrain types) were also studied as candidates for increasing incident radiation during Mercury orbital operations. Detailed results are presented, and show that an STG design based on the use of silicon-germanium alloy thermoelectric material and using high-voltage thermopiles with individual miniconical concentrators presents the optimum combination of technology and configuration for minimizing power source mass.

Swerdling, M.↗
NASA NTRS1984

Lead salt diode lasers and development of tunable solid state lasers for remote sensing

Extensive studies of the output characteristics of single quantum well lead-telluride lasers developed at the General Motors Research Laboratories were carried out. Threshold currents, output powers and line structures were measured as a function of temperature. Very low-current lasing thresholds, record high operating temperatures and over 30% tuning ranges were achieved. Excellent reproducibilities, good far-field patterns and reasonable linewidths (approx. 500 kHz) were found.

Freed, C.↗
NASA NTRS1987

Refractory semiconductors for high temperature thermoelectric energy conversion

Thermoelectric energy conversion utilizing nuclear heat sources has been employed for several decades to generate power for deep space probes. In the past, lead telluride and, more recently, silicon-germanium alloys have been the prime choices as thermoelectric materials for this application. Currently, a number of refractory semiconductors are under investigation at the Jet Propulsion Laboratory in order to produce power sources of higher conversion efficiency and, thus, lower mass per unit of power output. Included among these materials are improved Si-Ge alloys, rare earth compounds and boron-rich borides. The criteria used to select thermoelectric materials, in general, and the above materials, in particular, will be discussed. The current state of the art and the accomplishments to date in thermoelectric materials research will be reviewed.

Wood, Charles↗
NASA NTRS1990

Thermoelectric power conversion in space

A radiatively-heated multicouple for use in the next generation of radioisotope thermoelectric generator (RTG) will employ 20 individual couples within a single cell, so that 40 n- and p-semiconductor legs will be interconnected in series. At the hot end of the RTG, the legs will be electrically interconnected using silicon molybdenum; on the cold side, the legs are interconnected by tungsten. The entire cell is then mechanically attached to a radiator, which conducts heat away and radiates it into space. Deep-space applications will use RTGs developed for vacuum operation; thermoelectric converter power systems using a unicouple configuration have flown on such missions as Pioneers 10 and 11, which used lead telluride thermoelectric converters, and Voyagers I and II, which used silicon germanium-based thermoelectrics.

Awaya, Henry I.↗
NASA NTRS1991

Exposure to space radiation of high-performance infrared multilayer filters

The University of Reading experiment exposed IR interference filters and crystal substrates on identical earth facing and leading-edge sites of the Long Duration Exposure Facility (LDEF). Filters mostly comprised multilayer coatings of lead telluride (PbTe)/II-IV on germanium (Ge) and other substrates: crystals comprised CdTe, MgF2, sapphire, quartz, silicon, and some softer materials. Identical control samples were maintained in the laboratory throughout the experiment. The filters were novel in their design, construction and manufacture, and categorized high-performance because of their ability to resolve emission spectra of the important atmospheric gases for various purposes in remote sensing. No significant changes were found in the spectra of the hard-coated filters or in the harder crystals (the softer materials were degraded to an extent). By virtue of this well-documented and long exposure in LDEF, the qualification of the filter type is significantly improved for its future requirements.

Seeley, J. S.↗
NASA NTRS1980

New PbSnTe heterojunction laser diode structures with improved performance

Several recent advances in the state-of-the-art of lead tin telluride double heterojunction laser diodes are summarized. Continuous Wave operation to 120 K and pulsed operation to 166 K with single, lowest order transverse mode emission to in excess of four times threshold at 80 K were achieved in buried stripe lasers fabricated by liquid phase epitaxy in the lattice-matched system, lead-tin telluride-lead telluride selenide. At the same time, liquid phase epitaxy was used to produce PbSnTe distributed feedback lasers with much broader continuous single mode tuning ranges than are available from Fabry-Perot lasers. The physics and philosophy behind these advances is as important as the structures and performance of the specific devices embodying the advances, particularly since structures are continually being evolved and the performance continues to be improved.

Fonstad, C. G.↗
NASA NTRS1983

Solutal diffusion coefficient for liquid PbTe-SnTe

The solutal diffusion coefficient has been determined for liquid lead telluride-tin telluride using a modified shear cell technique. Postdiffusion concentration profiles are presented for several diffusion couples. The best analytical curve fit to the data gives a composition-dependent diffusion coefficient of (/3/7/ to the C power) x 0.00014 sq cm/sec, where C is the PbTe concentration. In addition, data are presented to show the importance of solutal convection in the lead-tin-telluride system.

Clark, I. O.↗
NASA NTRS1999

Growth of Compound Semiconductors in a Low Gravity Environment: Microgravity Growth of PbSnTe

The growth of the alloy compound semiconductor lead tin telluride (PbSnTe) was chosen for a microgravity flight experiment in the Advanced Automated Directional Solidification Furnace (AADSF), on the United States Microgravity Payload-3 (USMP-3) and on USMP-4 Space Shuttle flights in February, 1996, and November, 1997. The objective of these experiments was to determine the effect of the reduction in convection, during the growth process, brought about by the microgravity environment. The properties of devices made from PbSnTe are dependent on the ratio of the elemental components in the starting crystal. Compositional uniformity in the crystal is only obtained if there is no significant mixing in the liquid during growth. Lead tin telluride is an alloy of PbTe and SnTe. The technological importance of PbSnTe lies in its band gap versus composition diagram which has a zero energy crossing at approximately 40% SnTe. This facilitates the construction of long wavelength (>6 micron) infrared detectors and lasers. Observations and experimental methods of crystal growth of PbSnTe on both Space Shuttle Flights are presented.

Fripp, Archibald L.↗
NASA NTRS1972

Photodiodes for ten micrometer laser communication systems

The performance is discussed of 10-micron mercury-cadmiumtelluride and lead-tin-telluride photodiodes in laser heterodyne communication systems. The dependence of detector quantum efficiency, resistance, frequency response, and signal-to-noise ratio on temperature, bias, and local oscillator power are examined. Included in the discussion is an analysis of the feasibility of high temperature operation, and ability of the detector to dissipate power to a heat sink is explored. Some aspects of direct detection response are considered and figures showing flux levels from a blackbody presented.

Cohen, S. C.↗
NASA NTRS1980

Long wavelength PbSnTe lasers with CW operation above 77 K

Lead tin telluride diode lasers with emission wavelengths of 6 to 9 micrometers easily operate continuously at temperatures above 77K. These lasers have the Pb(1-y) Sn(y) TE/Pb(1-y) Te/Pb(1-y) Sn(y) Te/PbTe (substrate), (x y) double heterostructure. To prepare this structure by LPE, the growth temperature must be below 600 C to suppress diffusion of the tin during the epitaxial growth. When the heterojunctions are formed by the usual LPE method, the junction boundaries become irregular in the case for the lasers with wavelengths of over 10 micrometers at 77K. The mechanism by which the heterojunction boundaries become irregular is cleared and a new LPE method which prevents the irregularity is explained. The lasers prepared from the wafers grown by the new method have demonstrated CW operation at wavelengths longer than 10 micrometers above liquid nitrogen temperature.

Shinohara, K.↗
NASA NTRS1984

Experimental investigation of the effects of gravity on thermosolutal convection and compositional homogeneity in Bridgman grown, compound semiconductors

Lead-tin-telluride has been grown in a thermally stable mode (solutally unstable) and in a solutally stable (thermally unstable) mode in a Bridgman configuration. Significant differences in the crystal morphology and the compositional homogeneity have been found between the two configurations. In addition, for the solutally stable configuration, evidence has been found that the flow characteristics in the melt change drastically during the course of the run.

Crouch, R. K.↗
NASA NTRS1985

Crystal Growth Research in Space

The objectives of this work are to develop growth techniques and theory leading to improved bulk growth of semiconductor single crystals. Ground based experiments will be complemented by experiments carried out in the low-g environment provided by the space shuttle. Analytical studies and laboratory investigations are being conducted to better define the causes of crystalline defects and inhomogeneities. The compound semiconductor lead-tin-telluride is being used as the modeling material. Theoretical techniques are being developed to predict the thermal and solutal fields which are present during bulk growth from a melt. Techniques for measuring the thermophysical properties of semiconductors at high temperatures have been developed. During the past year electrochemical etching techniques have been developed for delineation of inhomogeneous regions in crystals. Thermal diffusivity measurements have been completed for the solid and liquid phases of PbTe and PbSnTe. Preliminary results have been obtained on the effects on crystal morphology of gravity, interface shape and interaction between the melt and the container.

Crouch, R. K.↗
NASA NTRS1988

Imaging Of Directional-Solidification Interfaces

X-ray and gamma-ray technique developed at NASA Langley Research Center enables melt/solid interface to be observed visually during crystal growth by directional solidification in Bridgman furnace. Technique used to observe movement and shape of interface in germanium and in lead tin telluride. Valuable tool in efforts to grow seeded semiconductor materials in Bridgman furnaces.

Fripp, Archibald L., Jr.↗
NASA NTRS1988

Electrochemical Growth Of Crystals In Gels

Nucleation and growth rates readily controlled. Technique developed to grow crystals by controlling rate of transfer of one component into crystallization volume. Method involves electrochemically controlled generation of one of precipitation species, coupled with diffusion barrier. New procedure, developed in connection with formation of lead tin telluride by reaction in gels of metal ions with telluride ions.

Barber, Patrick G.↗
NASA NTRS1987

Results from a compound semiconductor crystal growth experiment in a low gravity environment

A directional solidification experiment in the compound semiconductor lead tin telluride has been carried out in a low-gravity environment on board the Space Shuttle during a flight in October, 1985. Optical etching techniques and concentration profiles from wavelength dispersive electron microscopy indicate that there was a significant amount of convection during the solidifcation of the sample. A preliminary hypothesis of this result, that even at gravity levels on the order of 0.0001 g, the convective forces can be significant compared to mass transport due to diffusion, is being tested.

Crouch, Roger K.↗
NASA NTRS1989

Modelling melt-solid interfaces in Bridgman growth

Doped epoxy models with abrupt interfaces were prepared to test radiographic and computer enhancement procedures used to study the images of melt-solid interfaces during crystal growth in Bridgman furnaces. A column averaging procedure resulted in improved images that faithfully reproduced the positions and shapes of interfaces even at very low density differences. These techniques were applied to lead tin telluride growing in Bridgman furnaces.

Barber, Patrick G.↗