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At least 685 records · Page 38

Near-Zero Power MOF-Based Sensors for NO 2 Detection

Detection and capture of toxic nitrogen oxides (NO x ) is important for emissions control of exhaust gases and general public health. The ability to directly electrically detect trace (0.5–5 ppm) NO 2 by a metal–organic framework (MOF)-74-based sensor at relatively low temperatures (50 °C) is demonstrated via changes in electrical properties of M-MOF-74, M = Co, Mg, Ni. The magnitude of the change is ordered Ni > Co > Mg and explained by each variant's NO 2 adsorption capacity and specific chemical interaction. Ni-MOF-74 provides the highest sensitivity to NO 2 ; a 725× decrease in resistance at 5 ppm NO2 and detection limit <0.5 ppm, levels relevant for industry and public health. Furthermore, the Ni-MOF-74-based sensor is selective to NO 2 over N 2 , SO 2 , and air. Linking this fundamental research with future technologies, the high impedance of MOF-74 enables applications requiring a near-zero power sensor or dosimeter, with the active material drawing <15 pW for a macroscale device 35 mm 2 with 0.8 mg MOF-74. Finally, this represents a 10 4 –10 6 × decrease in power consumption compared to other MOF sensors and demonstrates the potential for MOFs as active components for long-lived, near-zero power chemical sensors in smart industrial systems and the internet of things.

47 OTHER INSTRUMENTATION↗

Implementation of AI/DEEP learning disruption predictor into a plasma control system

Abstract This paper reports on advances in the state‐of‐the‐art deep learning disruption prediction models based on the Fusion Recurrent Neural Network (FRNN) originally introduced in a 2019 NATURE publication [ https://doi.org/10.1038/s41586‐019‐1116‐4 ]. In particular, the predictor now features not only the “disruption score,” as an indicator of the probability of an imminent disruption, but also a “sensitivity score” in real time to indicate the underlying reasons for the imminent disruption. This adds valuable physics interpretability for the deep learning model and can provide helpful guidance for control actuators now implemented into a modern plasma control system (PCS). The advance is a significant step forward in moving from modern deep learning disruption prediction to real‐time control and brings novel AI‐enabled capabilities relevant for application to the future burning plasma ITER system. Our analyses use large amounts of data from JET and DIII‐D vetted in the earlier NATURE publication. In addition to “when” a shot is predicted to disrupt, this paper addresses reasons “why” by carrying out sensitivity studies. FRNN is accordingly extended to use more channels of information, including measured DIII‐D signals such as (i) the “n1rms” signal that is correlated with the n = 1 modes with finite frequency, including neoclassical tearing mode and sawtooth dynamics; (ii) the bolometer data indicative of plasma impurity control; and (iii) “q‐min”—the minimum value of the safety factor relevant to the key physics of kink modes. The additional channels and interpretability features expand the ability of the deep learning FRNN software to provide information about disruption subcategories as well as more precise and direct guidance for the actuators in a PCS.

70 PLASMA PHYSICS AND FUSION TECHNOLOGY↗

Integrating Mercury Concentrations in American Alligators ( Alligator mississippiensis ) with Hunter Consumption Surveys to Estimate Exposure Risk

Mercury is a naturally occurring element but is also considered a widespread contaminant due to global anthropogenic activity. Even in moderate amounts, mercury (Hg) is an established neurotoxin and is associated with a range of adverse outcomes both in humans and wildlife. Humans in the United States are most commonly exposed to Hg through contaminated food or drinking water, and the consumption of game species, particularly those occupying higher trophic levels, has the potential to expose hunters to high concentrations of Hg. In the present study, we determined Hg concentrations in tail muscle and blood from American alligators (Alligator mississippiensis) inhabiting a region (Savannah River Site, SC, USA) with known Hg contamination. We then integrated these data with alligator harvest records and previously published surveys of alligator meat consumption patterns to estimate potential exposure risk. We found that the average Hg concentrations in tail muscle (1.34 mg/kg, wet wt) from sampled alligators exceeded the recommended threshold for Hg exposure based on the World Health Organization's guidelines (0.5mg/kg, wet wt). In addition, based on regional consumption patterns reported for both adults and children, we estimated Hg exposures (x¯ Adult = 0.419 μg/kg/day, x¯ Child = 2.24 μg/kg/day) occurring well above the US Environmental Protection Agency methylmercury reference dose of 0.1 μg/kg/day. Although the two reservoirs sampled in the present study are not currently open to alligator hunting, they are connected to waters that are publicly accessible, and the extent of alligator mobility across these sites is not known. Together, the findings reported in the present study further demonstrate the need for active monitoring of Hg concentrations in game species, which can convey substantial exposure risks to the public.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Progress Towards a Comprehensive Approach for Habitat Restoration in the Columbia Basin: Case Study in the Grande Ronde River

Abstract Despite immense resources directed towards habitat restoration, recovering fish populations remains a daunting and perplexing issue. In 2015, recommendations for a comprehensive approach to habitat restoration in the Columbia River basin were published in Fisheries, which included elements of landscape ecology and resilience, broad public support, governance for collaboration and integration, and capacity for learning and adaptation. Using the Grande Ronde River basin as a case study, we convened a working group consisting of local restoration practitioners, managers, and researchers involved in habitat restoration research, monitoring, and evaluation to assess progress towards meeting these recommendations. We concluded that partnerships and collaborations in governance have been formed and research using a landscape perspective has been integrated into decision making, but efforts would benefit from gaining broader public support, formalizing an adaptive management strategy, and defining objectives and indicators for biological and ecological diversity. Continued progress will require consistent policy and funding support from the broader region. We envision this self-assessment at the 5-year milestone would be helpful to other groups facing similar challenges.

White, Seth M. (ORCID:0000000349186865)↗

Estimating dermal contact soil exposure for amphibians

Abstract Chemical exposure estimation through the dermal route is an underemphasized area of ecological risk assessment for terrestrial animals. Currently, there are efforts to create exposure models to estimate doses from this pathway for use in ecological risk assessment. One significant limitation has been insufficient published data to characterize exposure and to support the selection and parameterization of appropriate models, particularly for amphibians in terrestrial habitats. Recent publications measuring pesticide doses to terrestrial‐phase amphibians have begun to rectify this situation. We collated and summarized available measurements of terrestrial amphibian dermal exposure to pesticides from 11 studies in which researchers measured tissue concentrations associated with known pesticide experimental application rates. This data set included tissue concentrations in 11 amphibian species and 14 different pesticides. We then compared the results of two screening exposure models that differed based on surface area scaling approaches as a function of body weight (one based on birds as surrogates for amphibians and another amphibian‐specific) to the measured tissue residue concentrations. We define a false‐negative rate for each screening model as the proportion of amphibians for which the predicted concentration is less than the observed concentration (i.e., underestimate), contrary to the intent of screening models, which are intended to have a bias for higher exposure concentrations. The screening model that uses birds as surrogates did not have any instances where estimated expected avian doses were less than measured amphibian body burdens. When using the amphibian‐specific exposure model that corrected for differences between avian and amphibian surface area, measured concentrations were greater than model estimates for 11.3% of the 1158 comparisons. The database of measured pesticide concentrations in terrestrial amphibians is provided for use in calculating bioconcentration factors and for future amphibian dermal exposure model development. Integr Environ Assess Manag 2023;19:9–16. © 2022 SETAC. This article has been contributed to by U.S. Government employees and their work is in the public domain in the USA.

Environmental Sciences & Ecology↗

Sanitary Waste Landfill Effects on an Invasive Wild Pig Population

Being opportunistic omnivores, wild pigs (Sus scrofa) readily feed on edible garbage. Given the presence of substantial volumes of edible food waste, large multi-county and regional municipal sanitary waste landfills constitute attractive forage resources for pigs, providing a year-round anthropogenic source of potentially high-quality forage. Our objective was to assess the effects that a large regional landfill has on the local pigs foraging in that facility's waste disposal cells. The landfill, located on the United States Department of Energy's Savannah River Site (SRS) in South Carolina, USA, became operational in 1998 and pigs began foraging there in 2001. By 2009 >100 pigs/night were observed foraging in the landfill, suggesting landfill establishment may have important consequences for population dynamics, public safety, and disease transmission. We evaluated changes in body mass, fetal litter size, numbers of pigs removed, and wild pig-vehicle collisions (WPVCs) before (1980–2000) and after (2001–2019) pigs began foraging in the landfill on SRS. Body mass during the after period increased to a greater extent for pigs in the vicinity of the landfill compared to pigs on the rest of SRS. Fetal litter size increased for pigs in the vicinity of the landfill, whereas it remained unchanged on the rest of SRS. Our density surrogate (number of pigs harvested) increased around the landfill during the after period by 2.9 times, whereas on the rest of the site it only increased by 53%. No WPVCs occurred adjacent to the landfill before 2001, but WPVCs increased along the 2 major roads bordering the landfill after 2001. Effects of sanitary waste landfills on wild pig populations scavenging there can present unique challenges to population management, control, public safety, and disease transmission. Potential approaches to address these challenges could be exclusion fencing to prevent access to the landfill's waste disposal cells or enhanced placement of waste cell covers to reduce access.

60 APPLIED LIFE SCIENCES↗

A successful start for mLife

mLife made its debut with the publication of the inaugurating issue on March 30, 2022. We are pleased to have published 42 high-quality articles, including reviews, research articles, and application notes, which cover microbial genetics, biochemistry and physiology, ecology and evolution, pathogenic and public health microbiology, and so forth. Nine of the articles concern technical innovations and applications in areas including genome editing, single-cell analysis, and database. To pay tribute to the great microbiologist Carl Woese on the 10th anniversary of his death, the Journal published a special section containing three thought-provoking articles in the last issue of the year. mLife and its collaborating publisher Wiley have made great efforts to increase the Journal's national and continental representation. As a result, the Journal received submissions from over 20 countries in five continents last year. The authors of the published articles are from China, United States, Great Britain, France, Canada, Ger many, Japan, Switzerland, and Austria.

59 BASIC BIOLOGICAL SCIENCES↗

HopBox: An image analysis pipeline to characterize hop cone morphology

Abstract Hop cone morphology can influence picking and drying ability, and color can impact consumer preference and may be indicative of quality. However, these characteristics are not generally evaluated in hop breeding programs due to the tedious nature of trait quantification and the extensive variation among cones within a genotype. We developed the HopBox, which is a simply constructed light box with a camera mount, and a publicly available image processing pipeline that identifies hop cones within color‐corrected images, reads a QR code within the image, and outputs data on hop cone length, width, area, perimeter, openness, weight, color, and density. The trained model was applied to images of 500 cones each from 15 replicated advanced hop genotypes from the USDA‐ARS breeding program in Prosser, Washington. Analysis of variance revealed significant ( p < 0.001) differences between genotypes for all traits measured, enabling breeders to discriminate between genotypes for selection purposes. Broad sense heritability for all traits ranged from 0.23 to 0.59. A random sampling of hop cones from the complete dataset revealed that imaging only 5–10 cones adequately captured genotypic variation and provided acceptable rank correlations ( r s > 0.75); however, increasing the sample size to 30 provided optimal precision. Instructions for constructing a HopBox and the code for the analysis pipeline are publicly available online and have wide applicability for hop breeding and research.

Altendorf, Kayla R.↗

Evolving efforts to maintain and improve XPS analysis quality in an era of increasingly diverse uses and users

Based on literature analysis, X-ray photoelectron spectroscopy (XPS) use continues to increase exponentially. This increased use is accompanied by anecdotal reports and systematic analyses indicating a growing presence of significantly flawed data analyses. Recognition of this problem within the surface analysis community has increased with an understanding that both inexperienced users and increased use of XPS outside the surface analysis community contribute to the problem. The XPS community has initiated several efforts to help address the problem, which is not unique to XPS. This paper describes some of the specific problems identified and some of the community efforts intended to address them. Here, we describe activities focused on three specific issues: (i) requests for detailed guides and protocols and bite-sized versions of information for non-experts, (ii) incomplete data and analysis reporting, and (iii) the high rate of peak fitting problems. A 2019 survey identified the need for guides, protocols, and standards to assist XPS users. One set of such guides has been published, and another is being assembled. Providing incremental bites of useful information is the goal of a series of papers on specific challenges to surface analysis with example solutions has been initiated as Notes and Insights papers in Surface and Interface Analysis. Examination of XPS-containing papers finds that information to establish the credibility and reproducibility of XPS results is often very incomplete. Unfortunately, ISO and ASTM standards require an amount of parameter reporting that seems excessive and unrealistic for many research publications. Initial approaches to develop and distribute a graded approach to parameter reporting are briefly described. Multiple efforts are underway to address the high rate of problems associated with photoelectron peak fitting. These include guides to peak fitting, guides to peak identification and fitting for specific elements, and the development of a peak fitting social network. The fitting social network is designed to facilitate interactions between new and experienced XPS users; analysts trying to fit XPS data (for publication or other reasons) can ask questions and establish dynamic conversations. Encouraging and enabling high-quality XPS analysis and reporting requires several different types of effort from all members of the surface and interface analysis community.

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗

What can surface wind observations tell us about interannual variation in wind energy output?

The past decade of wind power growth was supported by capacity factor improvements and associated cost reductions. But are higher capacity factors a technology success story or, as suggested by recent research, has the influence of technology been overstated by ignoring positive surface wind speed trends? The answer could influence estimates of wind energy's cost and even future deployment rates. We find that US surface wind speed observations imply a 2.6% improvement in capacity factors from 2010 to 2019. Yet newer vintages of wind plants have recorded capacity factors that are ~25% larger than plants built close to 2010. It follows that technological factors and improved site quality, not higher wind speeds, drove most of the improvement in capacity factors. Additionally, we match hundreds of meteorological stations to nearby (< 25 km) wind plants and compare annual estimated generation, based on a function of surface wind speed observations, to annual recorded generation. Researchers rely on this publicly available surface data because measurements co-located with wind plants are generally considered proprietary. Our analysis addresses a research gap: interannual variation in observed surface wind speeds is rarely compared to observed data at wind plant locations and turbine heights. We find that despite its common use for this purpose, generation estimates based on publicly available surface observational data provide a poor proxy for interannual variability in recorded wind generation. These findings suggest that caution is generally needed when researchers use surface wind speed measurements to investigate long-term wind energy trends.

17 WIND ENERGY↗

NuGraph2 with context-aware inputs: physics-inspired improvements in semantic segmentation

Graph neural networks have recently shown strong promise for event reconstruction tasks in Liquid Argon Time Projection Chambers, yet their performance remains limited for underrepresented classes of particles, such as Michel electrons. In this work, we investigate physics-informed strategies to improve semantic segmentation within the NuGraph2 architecture. We explore three complementary approaches: (i) enriching the input representation with context-aware features derived from detector geometry and track continuity, (ii) introducing auxiliary decoders to capture class-level correlations, and (iii) incorporating energy-based regularization terms motivated by Michel electron energy distributions. Experiments on MicroBooNE public datasets show that physics-inspired feature augmentation yields the largest gains, particularly boosting Michel electron precision and recall by disentangling overlapping latent space regions. In contrast, auxiliary decoders and energy-regularization terms provided limited improvements, partly due to the hit-level nature of NuGraph2, which lacks explicit particle- or event-level representations. Our findings highlight that embedding physics context directly into node-level inputs is more effective than imposing task-specific auxiliary losses, and suggest that future hierarchical architectures such as NuGraph3, with explicit particle- and event-level reasoning, will provide a more natural setting for advanced decoders and physics-based regularization. The code for this work is publicly available on Github at https://github.com/vitorgrizzi/nugraph_phys/tree/main_phys.

Other Experiments↗

Jet-veto resummation at N 3 LL p + NNLO in boson production processes

Vetoing energetic jet activity is a crucial tool for suppressing backgrounds and enabling new physics searches at the LHC, but the introduction of a veto scale can introduce large logarithms that may need to be resummed. We present an implementation of jet-veto resummation for color-singlet processes at the level of N 3 LL p matched to fixed-order NNLO predictions. Our public code MCFM allows for predictions of a single boson, such as Z/γ*, W ± or H, or with a pair of vector bosons, such as W + W – , W ± Z or ZZ. The implementation relies on recent calculations of the soft and beam functions in the presence of a jet veto over all rapidities, with jets defined using a sequential recombination algorithm with jet radius R. However one of the ingredients that is required to reach full N 3 LL accuracy is only known approximately, hence N 3 LL p . We describe in detail our formalism and compare with previous public codes that operate at the level of NNLL. Our higher-order predictions improve significantly upon NNLL calculations by reducing theoretical uncertainties. We demonstrate this by comparing our predictions with ATLAS and CMS results.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗

Comparison and multi-model inference of excess risks models for radiation-related solid cancer

In assessments of detrimental health risks from exposures to ionising radiation, many forms of risk to dose–response models are available in the literature. The usual practice is to base risk assessment on one specific model and ignore model uncertainty. The analysis illustrated here considers model uncertainty for the outcome all solid cancer incidence, when modelled as a function of colon organ dose, using the most recent publicly available data from the Life Span Study on atomic bomb survivors of Japan. Seven recent publications reporting all solid cancer risk models currently deemed plausible by the scientific community have been included in a model averaging procedure so that the main conclusions do not depend on just one type of model. The models have been estimated with different baselines and presented for males and females at various attained ages and ages at exposure, to obtain specially computed model-averaged Excess Relative Risks (ERR) and Excess Absolute Risks (EAR). Monte Carlo simulated estimation of uncertainty on excess risks was accounted for by applying realisations including correlations in the risk model parameters. Three models were found to weight the model-averaged risks most strongly depending on the baseline and information criteria used for the weighting. Fitting all excess risk models with the same baseline, one model dominates for both information criteria considered in this study. Based on the analysis presented here, it is generally recommended to take model uncertainty into account in future risk analyses.

63 RADIATION, THERMAL, AND OTHER ENVIRON. POLLUTAN↗

Fusion Innovation and the Valley of Death—Lessons from Fission

Over the past several decades, the United States (U.S.) and other countries have done important research and development in advanced nuclear energy technologies, both fission and fusion. The urgency of our current climate, energy, and security needs have prompted a concerted effort by innovators, investors, and the public sector to transition from research and development (R&D) to demonstration and commercialization—to cross the proverbial “valley of death.” The stakes are high: humanity needs clean energy options, and the failure of any promising alternative will lower our odds of success. The process of moving an innovation into use has often been described in phases that begin with early research and end with deployment at scale. Between those two phases lies an area often referred to as the “valley of death” because it can require a long period of time, large investments, and often includes significant challenges related to regulation, standardization, and entering markets already structured around incumbent technologies. What can we learn from recent experience with fission to inform our path forward with fusion? At least five key lessons rise to the top: 1) Set bold targets; 2) Empower the private sector; 3) Engage with regulators and the public; 4) Address costs and markets; and 5) Deliver results. Here, this editorial will consider each of these in turn.

22 GENERAL STUDIES OF NUCLEAR REACTORS↗

Leveraging artificial intelligence and advanced food processing techniques for enhanced food safety, quality, and security: a comprehensive review

Artificial intelligence is emerging as a transformative force in addressing the multifaceted challenges of food safety, food quality, and food security. This review synthesizes advancements in AI-driven technologies, such as machine learning, deep learning, natural language processing, and computer vision, and their applications across the food supply chain, based on a comprehensive analysis of literature published from 1990 to 2024. AI enhances food safety through real-time contamination detection, predictive risk modeling, and compliance monitoring, reducing public health risks. It improves food quality by automating defect detection, optimizing shelf-life predictions, and ensuring consistency in taste, texture, and appearance. Furthermore, AI addresses food security by enabling resource-efficient agriculture, yield forecasting, and supply chain optimization to ensure the availability and accessibility of nutritious food resources. This review also highlights the integration of AI with advanced food processing techniques such as high-pressure processing, ultraviolet treatment, pulsed electric fields, cold plasma, and irradiation, which ensure microbial safety, extend shelf life, and enhance product quality. Additionally, the integration of AI with emerging technologies such as the Internet of Things, blockchain, and AI-powered sensors enables proactive risk management, predictive analytics, and automated quality control. By examining these innovations' potential to enhance transparency, efficiency, and decision-making within food systems, this review identifies current research gaps and proposes strategies to address barriers such as data limitations, model generalizability, and ethical concerns. These insights underscore the critical role of AI in advancing safer, higher-quality, and more secure food systems, guiding future research and fostering sustainable food systems that benefit public health and consumer trust.

AI↗

Correlating real-world incidents with vessel traffic off the coast of Hawaii, 2017–2020

Abstract Objectives Because of the high-risk nature of emergencies and illegal activities at sea, it is critical that algorithms designed to detect anomalies from maritime traffic data be robust. However, there exist no publicly available maritime traffic data sets with real-world expert-labeled anomalies. As a result, most anomaly detection algorithms for maritime traffic are validated without ground truth. Data description We introduce the HawaiiCoast_GT data set, the first ever publicly available automatic identification system (AIS) data set with a large corresponding set of true anomalous incidents. This data set—cleaned and curated from raw Bureau of Ocean Energy Management (BOEM) and National Oceanic and Atmospheric Administration (NOAA) automatic identification system (AIS) data—covers Hawaii’s coastal waters for four years (2017–2020) and contains 88,749,176 AIS points for a total of 2622 unique vessels. This includes 208 labeled tracks corresponding to 154 rigorously documented real-world incidents.

99 GENERAL AND MISCELLANEOUS↗

Nuclear Criticality Safety [Book Chapter]

Nuclear Criticality Safety is a field of nuclear engineering that involves worker and public safety during the handling, processing, transportation, and storage activities of fissile isotopes ( 233 U, 235 U, and 239 Pu) outside of nuclear reactors. Criticality accidents release energy as a result of accidentally producing a self-sustaining fission chain reaction. If these occur during hands-on operations the results can be lethal to worker within about 4.6 m (15 ft.) of the accident. There have been 22 process criticality accidents in the world between 1953 and 1999 resulting in physical injury, on and off-site dose, or death. Nuclear Criticality Safety involves work by qualified persons to preclude criticality accidents and their consequences by ensuring activities with fissionable materials remain subcritical, i.e., safe, during all normal and credible abnormal conditions. This article presents information about those nuclear fuel cycle steps presenting Nuclear Criticality Safety concerns that must be considered to ensure worker and public safety is assured.

11 NUCLEAR FUEL CYCLE AND FUEL MATERIALS↗

Bayesian modeling of traffic-related air pollutants: A case study of urban transportation and air quality dynamics in Columbia, South Carolina

Traffic emissions significantly impact near-road air quality and public health. This research applies a Bayesian modeling framework to investigate these impacts using high-resolution traffic and air pollutant data from an urban corridor in Columbia, South Carolina. Despite a data collection period truncated by the COVID-19 lockdown, the Bayesian approach successfully identified significant predictors and quantified model uncertainty. Employing Bayesian Model Selection and Averaging enhanced prediction accuracy and evaluated model uncertainty. Findings indicate that higher temperatures and increased moisture levels elevate particulate matter (PM 1.0 , PM 2.5 , PM 10 ) concentrations, while traffic speed significantly affects nitrogen dioxide (NO 2 ) levels. Specifically, higher average traffic speeds (indicative of smoother flow) correspond to lower NO 2 concentrations, suggesting that less congested conditions reduce NO 2 emissions. This study highlights the robustness of Bayesian methods for generating reliable air quality insights even under data-constrained conditions. The findings underscore the importance of traffic flow management (e.g., reducing congestion) for mitigating near-road NO 2 exposure and provide a basis for developing targeted public health strategies.

54 ENVIRONMENTAL SCIENCES↗