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Search indexed NASA NTRS and DOE OSTI research on propulsion, heat transfer, battery materials and energy systems. Follow report and document links to the original sources.

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At least 685 records · Page 38
All sourcesNASA NTRSDOE OSTI
DOE OSTI2021

Exploring the Interface of Skin-Layered Titanium Fibers for Electrochemical Water Splitting

Water electrolysis is the key to a decarbonized energy system, as it enables the conversion and storage of renewably generated intermittent electricity in the form of hydrogen. However, reliability challenges arising from titanium-based porous transport layers (PTLs) have hitherto restricted the deployment of next-generation water-splitting devices. Here, it is shown for the first time how PTLs can be adapted so that their interface remains well protected and resistant to corrosion across ˜4000 h under real electrolysis conditions. It is also demonstrated that the malfunctioning of unprotected PTLs is a result triggered by additional fatal degradation mechanisms over the anodic catalyst layer beyond the impacts expected from iridium oxide stability. Now, superior durability and efficiency in water electrolyzers can be achieved over extended periods of operation with less-expensive PTLs with proper protection, which can be explained by the detailed reconstruction of the interface between the different elements, materials, layers, and components presented in this work.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2020

Local and global approaches to treat the torsional barriers of 4-methylacetophenone using microwave spectroscopy

The Fourier transform microwave spectrum of 4-methylacetophenone recorded from 8 GHz to 18 GHz under jet-cooled conditions has revealed large tunneling splittings arising from a low barrier to internal rotation of the ring methyl group and small splittings from a high torsional barrier of the acetyl methyl group. The large splittings are especially challenging to model, while the small splittings are difficult to analyze due to the resolution limit of 120 kHz. The combination of two methyl groups undergoing internal rotations caused each rotational transition to split into five torsional species, which were resolved and fitted using a modified version of the XIAM code and the newly devel- oped ntop code to a root-mean-square deviation close to measurement accuracy, providing an estimate of the V 3 potential barriers of about 22 cm -1 and 584–588 cm -1 for the ring and the acetyl methyl groups, respectively. The assignment was aided by separately fitting the five torsional species using odd-power order operators. Only one conformer in which all heavy atoms are located on a symmetry plane could be identified in the spectrum, in agreement with results from conformation analysis using quantum chemical calculations.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2026

Superlattice reflection signatures of the insulator–metal transition in V 3 O 5 thin films

Nanoelectronic systems that are inspired by the brain are increasingly looking to insulator–metal transition (IMT) materials as they can mimic the response characteristics of neurons to temperature changes so that these can be used in robotic and computational applications. V 3 O 5 has an insulator–metal transition at ∼430 or ∼80 K higher than VO 2 and provides a unique high-temperature opportunity for these types of applications. Here, in this work, we track the structural evolution of V 3 O 5 thin films across the IMT through conventional selected-area electron diffraction (SAED) and four-dimensional scanning TEM (4D-STEM), correlated with temperature-dependent resistance measurements. SAED patterns show reversible evidence of superlattice reflections associated with the IMT—present below T IMT and absent above it—consistent with the accompanying drop in resistance. At room temperature, nanobeam electron diffraction patterns further reveal three local configurations: (i) type I regions with clean patterns lacking superlattice reflections and spot splitting; (ii) type II regions exhibiting rows of superlattice reflections and split spots indicative of crystallographic variants; and (iii) type III regions with negligible superlattice reflections but larger spot splitting suggestive of overlapping domains of insulating and conducting phases likely driven by local lattice distortions. Upon heating, the superlattice reflections disappear between 413 and 453 K, concurrent with the resistance drop at T IMT , consistent with the emergence of a conducting phase. The overall diffraction geometry remains essentially unchanged up to 573 K, implying that relative domain orientations persist through the transition. These observations reveal nanoscale structural heterogeneity in V 3 O 5 thin films across the IMT and inform operation in regimes where mixed-phase textures are expected. A plausible indexing framework rationalizing the observed geometries is presented in the Discussion section, alongside its limitations and alternative interpretations.

25 ENERGY STORAGE↗
DOE OSTI2021

Color halo scenario of charmonium-like hybrids

The internal structures of J PC =1 -- ,(o,1,2) -+ charmonium-like hybrids are investigated under lattice QCD in the quenched approximation. We define the Bethe-Salpeter wave function (Φn(r)) in the Coulomb gauge as the matrix element of a spatially extended hybrid-like operator ($\bar{c}cg$) between the vacuum and n-th state for J PC , with r being the spatial separation between a localized $\bar{c}c$ component and the chromomagnetic strength tensor. These wave functions exhibit some similarities for states with the aforementioned different quantum numbers, and their r-behaviors (no node for the ground states and one node for the first excited states) imply that r can be a meaningful dynamical variable for these states. Additionally, the mass splittings of the ground states and first excited states of charmonium-like hybrids in these channels are obtained for the first time to be approximately 1.2-1.4 GeV. These results do not support the flux-tube description of heavy-quarkonium-like hybrids in the Born-Oppenheimer approximation. In contrast, a charmonium-like hybrid can be viewed as a "color halo" charmonium for which a relatively localized color octet $\bar{c}c$ is surrounded by gluonic degrees of freedom, which can readily decay into a charmonium state along with one or more light hadrons. The color halo picture is compatible with the decay properties of Y (42600) and suggests LHCb and BelleII to search for (0,1,2) -+ charmonium-like hybrids in Xc0,1,2N and J/ψω(φ) final states.

72 PHYSICS OF ELEMENTARY PARTICLES AND FIELDS↗
NASA NTRS1971

Dynamics of heat-pipe reactors.

A split-core heat-pipe reactor fueled with either 233-UC or 235-UC in a tungsten cermet and cooled by 7-Li-W heat pipes is examined for the effects of the heat pipes on this reactor in trying to safely absorb large reactivity inputs through inherent shutdown mechanisms. Limits on ramp reactivity inputs due to fuel-melting temperature and heat-pipe wall heat flux are mapped for the reactor in both startup and at-power operating modes.

Niederauer, G. F.↗
NASA NTRS2007

MCM Polarimetric Radiometers for Planar Arrays

A polarimetric radiometer that operates at a frequency of 40 GHz has been designed and built as a prototype of multiple identical units that could be arranged in a planar array for scientific measurements. Such an array is planned for use in studying the cosmic microwave background (CMB). All of the subsystems and components of this polarimetric radiometer are integrated into a single multi-chip module (MCM) of substantially planar geometry. In comparison with traditional designs of polarimetric radiometers, the MCM design is expected to greatly reduce the cost per unit in an array of many such units. The design of the unit is dictated partly by a requirement, in the planned CMB application, to measure the Stokes parameters I, Q, and U of the CMB radiation with high sensitivity. (A complete definition of the Stokes parameters would exceed the scope of this article. In necessarily oversimplified terms, I is a measure of total intensity of radiation, while Q and U are measures of the relationships between the horizontally and vertically polarized components of radiation.) Because the sensitivity of a single polarimeter cannot be increased significantly, the only way to satisfy the high-sensitivity requirement is to make a large array of polarimeters that operate in parallel. The MCM includes contact pins that can be plugged into receptacles on a standard printed-circuit board (PCB). All of the required microwave functionality is implemented within the MCM; any required supporting non-microwave ("back-end") electronic functionality, including the provision of DC bias and control signals, can be implemented by standard PCB techniques. On the way from a microwave antenna to the MCM, the incoming microwave signal passes through an orthomode transducer (OMT), which splits the radiation into an h + i(nu) beam and an h - i(nu) beam (where, using complex-number notation, h denotes the horizontal component, nu denotes the vertical component, and +/-i denotes a +/-90deg phase shift). Each of these beams enters the MCM through one of two WR-22 waveguide input terminals in the lid of the MCM. The h + i(nu0 and h - i(nu) signals are amplified, then fed to a phase-discriminator hybrid designed specifically to fit the predominantly planar character of the MCM geometry and to enable determination of Q and U. The phase-discriminator hybrid generates four outputs, which are detected and used to calculate I, Q, and U.

Kangaslahti, Pekka↗
NASA NTRS1989

Atmospheric methane measurement instrument using a Zeeman-split He-Ne laser

The construction of an atmospheric methane measurement instrument based on a Zeeman-split IR He-Ne laser is reported. The laser has a tranverse magnetic field over about 2/3 of its gain length and can oscillate at an (unsplit) frequency (2947.91/cm) centered on a methane absorption line, or on either of two frequencies split by + or - 0.055/cm from the center, with low CH4 absorption. The laser is tuned to dwell sequentially at each frequency, giving two differential absorption measurements in each 46-ms tuning cycle. Atmospheric measurements are made using two multiple pass absorption cells, one with fast (0.75-s) and one with slow (5-s) flow response times. Fluctuations in ambient CH4 of about 20-ppb (rms, 1-s averaging) are detected, with interference fringe effects the dominant noise source. The instrument has operated in a field experiment (NASA GTE/ABLE-3A) in Alaska.

Mcmanus, J. Barry↗
NASA NTRS1991

5-year lifetime hybrid superfluid helium dewar for the AXAF X-Ray Spectrometer (XRS)

The focal plane of the AXAF X-Ray Spectrometer requires an operating temperature of 0.1 K with a mission lifetime of 5 yrs. This demanding task is accomplished with a hybrid cryogenic subsystem consisting of mechanical coolers, a superfluid helium dewar and an adiabatic demagnetization refrigerator. By using mechanical coolers to remove heat from the dewar outer vapor-cooled shield, a 5-yr lifetime is achievable with only a 483-liter tank. This approach takes advantage of flight-proven, high-performance dewar technology and recent success in the development of split, Stirling-cycle mechanical coolers. Although the dewar design principles are similar to those used previously, parasitic heat flow is reduced to a new level by an optimized tension strap support system and careful attention to insulation system details. The benefit of the mechanical coolers is maximized by dewar interface design features that minimize parasitic heating and thermal impedance of the coupling. The dewar design and thermal performance analysis are discussed. Helium lifetime sensitivities and the effects of mechanical cooler failures are predicted.

Nieczkoski, Stephen J.↗
NASA NTRS2007

Lunar Lander Structural Design Studies at NASA Langley

The National Aeronautics and Space Administration is currently developing mission architectures, vehicle concepts and flight hardware to support the planned human return to the Moon. During Phase II of the 2006 Lunar Lander Preparatory Study, a team from the Langley Research Center was tasked with developing and refining two proposed Lander concepts. The Descent-Assisted, Split Habitat Lander concept uses a disposable braking stage to perform the lunar orbit insertion maneuver and most of the descent from lunar orbit to the surface. The second concept, the Cargo Star Horizontal Lander, carries ascent loads along its longitudinal axis, and is then rotated in flight so that its main engines (mounted perpendicular to the vehicle longitudinal axis) are correctly oriented for lunar orbit insertion and a horizontal landing. Both Landers have separate crew transport volumes and habitats for surface operations, and allow placement of large cargo elements very close to the lunar surface. As part of this study, lightweight, efficient structural configurations for these spacecraft were proposed and evaluated. Vehicle structural configurations were first developed, and preliminary structural sizing was then performed using finite element-based methods. Results of selected structural design and trade studies performed during this activity are presented and discussed.

Wu, K. Chauncey↗
DOE OSTI2023

Significance of slight ambient temperature variation on the electrocatalyst performance toward oxygen evolution reaction

Hundreds of oxygen evolution reaction (OER) electrocatalysts have been developed over the past few decades, and their performances are evaluated and compared at ambient temperature. However, the effect of ambient temperature variation on OER electrocatalyst performance has received less attention, which may play a remarkable role in the electrocatalytic activity. In this work, we systematically investigated the influence of ambient temperature variation on electrocatalyst performance toward OER. The results show that the slight ambient temperature variation has a significant effect on OER catalyst performance based on the changes of overpotential (10mAcm -2 ) and Tafel slope. Both remarkable chances are observed on transition metal (Ni) and noble metal (IrO 2 ) electrocatalysts, and the overpotentials decrease around 81 mV with a temperature increase by 20°C (from 10° to 30°C) for both Ni and IrO 2 electrocatalysts with the Tafel slope drops of 36.9 and 29.5 mV dec -1 , respectively. Further, a similar trend is also found in the electrochemically active surface (ECSA) normalized performance and the charge transfer resistance. This study demonstrates that reporting the actual operating temperature for OER is not only recommended but also necessary to evaluate and compare electrocatalyst activities from different materials systems properly, and neglecting the ambient temperature variation effect can highly mislead conclusions.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗
DOE OSTI2026

A two-stage optical fusion framework for wildfire severity mapping across the conterminous United States

Accurate wildfire severity mapping (WSM) is essential for post-fire recovery planning, erosion risk assessment, ecosystem monitoring, and disaster risk reduction. Although Landsat and Sentinel optical imagery have been widely used for burn severity assessment, the added value of fusing multiple optical sensors has not been sufficiently quantified across diverse fire events, particularly since the launch of Landsat-9. This study evaluates whether multisensor optical fusion improves wildfire severity mapping relative to single-sensor baselines using Sentinel-2, Landsat-8, and Landsat-9 imagery across 40 wildfire events in the conterminous United States. We tested a two-stage fusion framework that combines feature-level fusion with pixel-level dimensionality reduction. First, feature-level fused datasets were created through early fusion by combining standardized post-fire bands from each sensor into a single predictor stack. Both raw reflectance bands and pairwise spectral transforms were retained to capture within- and cross-sensor spectral interactions. Second, Linear Discriminant Analysis was applied to both single-sensor and fused datasets to produce comparable low-dimensional feature spaces. Six machine-learning classifiers were then used to benchmark model performance with repeated spatially buffered train–test splits. Results show that Landsat-9 was the strongest single-sensor baseline. Among the fusion strategies, Sentinel-2 + Landsat-9 produced the most consistent improvement and reduced performance variability. Landscape-condition analysis further showed that this fusion was most beneficial in shrubland-dominated and high-terrain fires, where it achieved the highest overall mean accuracy and the fewest failures. In contrast, its benefits were less reliable in evergreen forests, mixed vegetation, and low- to moderate-elevation terrain. In operational settings, the Sentinel-2 + Landsat-9 configuration offers a practical solution for post-fire recovery planning, erosion-risk assessment, watershed management, and ecological monitoring when field observations are available and timely satellite-based information is needed.

Landsat↗
DOE OSTI2020

High temperature water electrolysis testing of gold-based electrodes for H 2 production

The Hybrid Sulfur (HyS) process is a promising thermochemical water-splitting cycle with global scale hydrogen production potential. The SO 2 -depolarized electrolyzer (SDE) is a critical component of the cycle. At the core of the SDE is the membrane-electrode assembly (MEA), which consists of a polymer electrolyte membrane (PEM) sandwiched between two electrocatalyst layers. New electrocatalyst and membrane materials are being developed with the goals of improving the electrolyzer performance and extending the lifetime of the MEA. In this work, we evaluated the performance of three different membranes and optimized operating conditions, resulting is one of the highest performances in the literature.

08 HYDROGEN↗
NASA NTRS1990

Precipitable water estimation from high-resolution split window radiance measurements

A technique that uses the spatial variance of image brightness temperature to derive total column precipitable water is applied to high-resolution multispectral aircraft scanner data for the June 19, 1986 COHMEX day. The technique has several advantages over other approaches in that it requires only relative calibration accuracy, is less susceptible to instrument error, and does not directly use a priori information. Results indicate significant horizontal variability of precipitable water at the mesoscale. Precipitable water gradients of 6 mm per 10 km are not uncommon. The results verify well against special rawinsonde measurements and the ensuing cloud field development. While only applied to this specialized aircraft data, the applicability of the technique to operational AVHRR and VAS data is discussed.

Jedlovec, Gary J.↗
NASA NTRS1977

Linear aerospike engine

A description is presented of a dual-fuel modular split-combustor linear aerospike engine concept. The considered engine represents an approach to an integrated engine for a reusable single-stage-to-orbit (SSTO) vehicle. The engine burns two fuels (hydrogen and a hydrocarbon) with oxygen in separate combustors. Combustion gases expand on a linear aerospike nozzle. An engine preliminary design is discussed. Attention is given to the evaluation process for selecting the optimum number of modules or divisions of the engine, aspects of cooling and power cycle balance, and details of engine operation.

Kirby, F. M.↗
NASA NTRS1978

Executive summary: Benefit-cost evaluation of an intra-regional air service in the Bay Area and a technology assessment of transportation system investments

The benefits and costs that would result from an intra-regional air service operation in the San Francisco Bay area were determined by utilizing an iterative statistical decision model to evaluate combinations of commuter airport sites and surface transportation facilities in conjunction with service by a given commuter aircraft type in light of area regional growth alternatives and peak and off-peak regional travel patterns. The model evaluates such transportation option with respect to criteria of airline profitability, public acceptance, and public and private non-user costs. In so doing, it incorporates information on modal split, peak and off-peak use of the air commuter fleet, terminal and airport costs, development costs and uses of land in proximity to the airport sites, regional population shifts, and induced zonal shifts in travel demand. The model is multimodal in its analytic capability, and performs exhaustive sensitivity analysis.

Haefner, L. E.↗
NASA NTRS1993

Advanced Rotorcraft Transmission (ART) program

Work performed by the McDonnell Douglas Helicopter Company and Lucas Western, Inc. within the U.S. Army/NASA Advanced Rotorcraft Transmission (ART) Program is summarized. The design of a 5000 horsepower transmission for a next generation advanced attack helicopter is described. Government goals for the program were to define technology and detail design the ART to meet, as a minimum, a weight reduction of 25 percent, an internal noise reduction of 10 dB plus a mean-time-between-removal (MTBR) of 5000 hours compared to a state-of-the-art baseline transmission. The split-torque transmission developed using face gears achieved a 40 percent weight reduction, a 9.6 dB noise reduction and a 5270 hour MTBR in meeting or exceeding the above goals. Aircraft mission performance and cost improvements resulting from installation of the ART would include a 17 to 22 percent improvement in loss-exchange ratio during combat, a 22 percent improvement in mean-time-between-failure, a transmission acquisition cost savings of 23 percent of $165K, per unit, and an average transmission direct operating cost savings of 33 percent, or $24K per flight hour. Face gear tests performed successfully at NASA Lewis are summarized. Also, program results of advanced material tooth scoring tests, single tooth bending tests, Charpy impact energy tests, compact tension fracture toughness tests and tensile strength tests are summarized.

Heath, Gregory F.↗
DOE OSTI2020

Failure modes of protection layers produced by atomic layer deposition of amorphous TiO 2 on GaAs anodes

Amorphous titanium dioxide (a-TiO 2 ) films formed by atomic layer deposition can serve as protective coatings for semiconducting photoanodes in water-splitting cells using strongly alkaline aqueous electrolytes. Herein, we experimentally examine the mechanisms of failure for p + -GaAs anodes coated with a-TiO 2 films (GaAs/a-TiO 2 ). Galvanic displacement of exposed GaAs by Au allowed imaging of pinholes in the a-TiO 2 coatings, and enabled collection of quantitative and statistical data associated with pinhole defects. A combination of imaging, electrochemical measurements, and quantitative analyses of corrosion products indicated that extrinsic pinholes were present in the a-TiO 2 films before electrochemical operation. During electrochemical operation these pinholes led to pitting corrosion of the underlying GaAs substrate. The dominant source of pinholes was the presence of atmospheric particulate matter on the GaAs surface during deposition of the a-TiO 2 layer. The pinhole density decreased substantially when the thickness of the a-TiO 2 coating increased beyond 45 nm, and approached zero when the thickness of the film exceeded 112 nm. The density of pinholes in films thinner than 45 nm decreased when the a-TiO 2 coating was deposited in an environmentally controlled cleanroom. Pinhole-free GaAs/a-TiO 2 devices were also tested via chronoamperometry to quantify the rate of pinhole formation during electrochemistry. The time-to-failure increased with thickness, suggesting that the failure mechanism may involve diffusion or migration through the film. However, other mechanisms may also contribute to the degradation of thicker films (>112 nm). Nevertheless, as previously hypothesized, extrinsic pinhole defects formed during deposition and testing control the short-term protective performance of the a-TiO 2 film for GaAs anodes evolving O 2 from water.

25 ENERGY STORAGE↗
NASA NTRS2012

Modular Growth NTR Space Transportation System for Future NASA Human Lunar, NEA and Mars Exploration Missions

The nuclear thermal rocket (NTR) is a proven, high thrust propulsion technology that has twice the specific impulse (I(sub sp) approx.900 s) of today's best chemical rockets. During the Rover and NERVA (Nuclear Engine for Rocket Vehicle Applications) programs, twenty rocket reactors were designed, built and ground tested. These tests demonstrated: (1) a wide range of thrust; (2) high temperature carbide-based nuclear fuel; (3) sustained engine operation; (4) accumulated lifetime; and (5) restart capability - everything required for affordable human missions beyond LEO. In NASA's recent Mars Design Reference Architecture (DRA) 5.0 study, the NTR was selected as the preferred propulsion option because of its proven technology, higher performance, lower IMLEO, versatile vehicle design, and growth potential. Furthermore, the NTR requires no large technology scale-ups since the smallest engine tested during the Rover program - the 25 klb(sub f) "Pewee" engine is sufficient for human Mars missions when used in a clustered engine configuration. The "Copernicus" crewed Mars transfer vehicle developed for DRA 5.0 was an expendable design sized for fast-conjunction, long surface stay Mars missions. It therefore has significant propellant capacity allowing a reusable "1-year" round trip human mission to a large, high energy near Earth asteroid (NEA) like Apophis in 2028. Using a "split mission" approach, Copernicus and its two key elements - a common propulsion stage and integrated "saddle truss" and LH2 drop tank assembly - configured as an Earth Return Vehicle / propellant tanker, can also support a short round trip (approx.18 month) / short orbital stay (60 days) Mars reconnaissance mission in the early 2030's before a landing is attempted. The same short stay orbital mission can be performed with an "all-up" vehicle by adding an "in-line" LH2 tank to Copernicus to supply the extra propellant needed for this higher energy, opposition-class mission. To transition to a reusable Mars architecture, Copernicus' saddle truss / drop tank assembly is replaced by an in-line tank and "star truss" assembly with paired modular drop tanks to further increase the vehicle's propellant capacity. Shorter "1-way" transit time fast-conjunction Mars missions are another possibility using this vehicle configuration but, as with reusability, increased launch mass is required. "Scaled down" versions of Copernicus (sized to a SLS lift capability of approx.70 t - 100 t) can be developed initially allowing reusable lunar cargo delivery and crewed landing missions, easy NEA missions (e.g., 2000 SG344 also in 2028) or an expendable mission to Apophis. Mission scenario descriptions, key vehicle features and operational characteristics are provided along with a brief discussion of NASA's current activities and its "pre-decisional" plans for future NTR development.

Borowski, Stanley K.↗