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At least 685 records · Page 38

The Halite-Bearing Zag and Monahans (1998) Meteorite Breccias: Shock Metamorphism, Thermal Metamorphism and Aqueous Alteration on the H-Chondrite Parent Body

Zag and Monahans (1998) are H-chondrite regolith breccias comprised mainly of lightcolored metamorphosed clasts, dark clasts that exhibit extensive silicate darkening, and a halite-bearing clastic matrix. These meteorites reflect a complex set of modification processes that occurred on the H-chondrite parent body. The light-colored clasts are thermally metamorphosed H5 and H6 rocks that were fragmented and deposited in the regolith. The dark clasts formed from light-colored clasts during shock events that melted and mobilized a significant fraction of their metallic Fe-Ni and troilite grains. The clastic matrices of these meteorites are rich in solar-wind gases. Parent-body water was required to cause leaching of chondri tic minerals and chondrule glass; the fluids became enriched in Na, K, CI, Br, AI, Ca, Mg and Fe. Evaporation of the fluids caused them to become brines as halides and alkalies became supersaturated; grains of halite (and, in the case of Monahans (1998), halite with sylvite inclusions) precipitated at low temperatures (less than or equal to 100 C) in the porous regolith. In both meteorites fluid inclusions were trapped inside the halite crystals. Primary fluid inclusions were trapped in the growing crystals; secondary inclusions formed subsequently from fluid trapped within healed fractures.

Rubin, Alan E.↗

The Holbrook Meteorite - 99 Years Out in the Weather

At 7:15pm on the evening of 19th July 1912, a bright fireball appeared in the sky above Navajo County, Arizona [1]. After several loud detonations, approximately 16,000 mostly pea-sized stones fell near the Arntz siding of the Santa Fe Railroad, 7 miles from the town of Holbrook. A search orchestrated by W.M.Foote resulted in nearly 220 kg of material being recovered; samples were exchanged with a great many of the World's Museums [2]. In 1931 Harvey Nininger revisited the site and was able to find another 23 kg that had originally been missed [3]. One of us (EKG) returned again in 1968 and found a further ca 1.5 kg specimen [4]. Meteorite hunters have been going back to Holbrook ever since in the hope of more finds. For example in 2001 a group of 45 searchers accumulated 440 g of previously overlooked L6 group meteorite fragments. In 2011, the 99th anniversary of the event, Rubin Garcia located 11 mini-meteorites [5].

Pillinger, C. T.↗

Mid-Infrared Study of Samples from Several Stones from the Sutter's Mill Meteorite

On April 22, 2012, a fireball was observed over California and Nevada, and the falling fragments of the meteorite were detected by weather radar near small townships in the El Dorado County, California. Some of these stones were collected at Sutter s Mill, in the historic site where the California gold rush was initiated, giving the name to this meteorite. Thus far, 77 pieces of the meteorite have been collected, for a total mass of 943 g, with the biggest stone weighing 205 g [1].

Sandford, Scott↗

Bench Crater Meteorite: Hydrated Asteroidal Material Delivered to the Moon

D/H measurements from the lunar regolith agglutinates [8] indicate mixing between a low D/H solar implanted component and additional higher D/H sources (e.g., meteoritic/ cometary/volcanic gases). We have determined the range and average D/H ratio of Bench Crater meteorite, which is the first direct D/H analysis of meteoritic material delivered to the lunar surface. This result provides an important ground truth for future investigations of lunar water resources by missions to the Moon.

Joy, K. H.↗

Constraints on the Composition and Evolution of the Lunar Crust from Meteorite NWA 3163

The lunar meteorite NWA 3163 (paired with NWA 4881, 4483) is a ferroan, feldspathic granulitic breccia characterized by pigeonite, augite, olivine, maskelynite and accessory Tichromite, ilmenite and troilite. Bulk rock geochemical signatures indicate the lack of a KREEP- derived component (Eu/Eu* = 3.47), consistent with previously studied lunar granulites and anorthosites. Bulk rock chondrite-normalized signatures are however distinct from the anorthosites and granulites sampled by Apollo missions and are relatively REE-depleted. In-situ analyses of maskelynite reveal little variation in anorthite content (average An% is 96.9 +/- 1.6, 2 sigma). Olivine is relatively ferroan and exhibits very little variation in forsterite content with mean Fo% of 57.7 +/- 2.0 (2 sigma). The majority of pyroxene is low-Ca pigeonite (En57Fs33Wo10). Augite (En46Fs21Wo33) is less common, comprising approximately 10% of analyzed pyroxene. Two pyroxene thermometry on co-existing orthopyroxene and augite yield an equilibrium temperature of 1070C which is in reasonable agreement with temperatures of 1096C estimated from pigeonite compositions. Rb-Sr isotopic systematics of separated fractions yield an average measured Sr-87/Sr-87 of 0.699282+/-0.000007 (2 sigma). Sr model ages are calculated using a modern day Sr-87/Sr-86 Basaltic Achondrite Best Initial (BABI) value of 0.70475, from an initial BABI value Sr-87/Sr-86 of 0.69891 and a corresponding Rb-87/Sr-97 of 0.08716. The Sr model Thermomechanical analysis (TMA) age, which represents the time of separation of a melt from a source reservoir having chondritic evolution, is 4.56+/-0.1 Ga. A Sr model T(sub RD) age, which is a Rb depletion age and assumes no contribution from Rb in the sample in the calculation, yields 4.34+/-0.1 Ga (i.e. a minimum age). The Ar-Ar dating of paired meteorite NWA 4881 reveals an age of c. 2 Ga, likely representing the last thermal event this meteorite experienced. An older Ar-40/Ar-39 age of c. 3.5 Ga may record the thermal event which produced the granulitic texture. Additional chronological constraints will be provided by Sm-Nd systematics. Ferroan Anorthosites like NWA 3163 have been interpreted to represent direct lunar magma ocean (LMO) crystallization products. If this is the case, trace element concentrations in NWA 3163 primary mineral phases should be in equilibrium with residual LMO liquids present during crystallization of those phases. Results from petrogenetic modeling suggest that the NWA 3163 protolith did not form from crystallization of an initially LREE depleted LMO but rather require an initially chondritic LMO with early garnet crystallization. Furthermore, a two-stage crystallization model where plagioclase crystalized prior to pyroxene (93% vs. 99.5% of LMO crystallization) is implied.

McLeod, C. L.↗

Organic Analysis of Catalytic Fischer-Tropsch Type Synthesis Products: Are they Similar to Organics in Chondritic Meteorites?

Fischer-Tropsch Type (FTT) synthesis of organic compounds has been hypothesized to occur in the early solar nebula that formed our Solar System. FTT is a collection of abiotic chemical reactions that convert a mixture of carbon monoxide and hydrogen over nano-catalysts into hydrocarbons and other more complex aromatic compounds. We hypothesized that FTT can generate similar organic compounds as those seen in chondritic meteorites; fragments of asteroids that are characteristic of the early solar system. Specific goals for this project included: 1) determining the effects of different FTT catalyst, reaction temperature, and cycles on organic compounds produced, 2) imaging of organic coatings found on the catalyst, and 3) comparison of organic compounds produced experimentally by FTT synthesis and those found in the ordinary chondrite LL5 Chelyabinsk meteorite. We used Pyrolysis Gas Chromatography Mass Spectrometry (PY-GCMS) to release organic compounds present in experimental FTT and meteorite samples, and Scanning Electron Microscopy (SEM) to take images of organic films on catalyst grains.

Yazzie, Cyriah A.↗

Noble Gases in Two Fragments of Different Lithologies from the Almahata Sitta Meteorite

The Almahata Sitta meteorite, whose preat-mospheric body was the asteroid 2008 TC3, fell on October 7, 2008 in the Nubian Desert in northern Sudan [e.g., 1, 2]. Numer-ous fragments have been recovered during several expeditions organized from December 2008 [2]. The meteorite was classified as an anomalous polymict ureilite with several different kinds of chondritic fragments [e.g., 3-5]. Noble gas studies performed on several fragments from the meteorite showed cosmic-ray expo-sure ages of about 20 My [e.g., 6-8], although slightly shorter ages were also reported in [9, 10]. Concentrations of trapped heavy noble gases are variable among the fragments of different lithologies [9, 10]. We report noble gas data on two samples from the #1 and #47 fragments [2], which were the same as those re-ported by Ott et al. [9]. Experimental Procedure: Weights of bulk samples #1 and #47 used in this work were 16.1 mg and 17.6 mg, respectively. Noble gases were extracted by stepwise heating at the tempera-tures of 800, 1200 and 1800˚C for #1 and 600, 800, 1000, 1200, 1400, 1600 and 1800˚C for #47. Concentrations and isotopic ra-tios of noble gases were measured with a modified-VG5400/MS-III at the Geochemical Research Center, University of Tokyo. Results and Discussion: Cosmogenic He and Ne are domi-nant in both #1 and #47, but trapped Ar, Kr and Xe concentra-tions are much higher in #47 than in #1, showing that noble gas compositions in #47 are similar to those of ureilites. 3He/21Ne and 22Ne/21Ne of cosmogenic He and Ne are 4.8 and 1.12 for #1 and 3.6 and 1.06 for #47, respectively, both of which plot on a Bern line [11]. This indicates negligible loss of cosmogenic 3He from #1 in our sample, unlike the low 3He/21Ne of 3.1 for #1 by Ott et al. [9]. Concentrations of cosmogenic 3He and 21Ne (10-8 cc/g) are 30 and 6.3 for #1 and 32 and 9.0 for #47, respectively, which are higher than those in [9] and give cosmic-ray exposure ages of ca. 20 My depending on assumed production rates. Rela-tive abundances of trapped 36Ar, 84Kr and 132Xe for #1 resemble those of Q-component, which is a dominant trapped noble gas component in chondrites. In contrast to #1, #47 plots below a trend for ureilites [12] as well as Q, which implies a partial loss of trapped 36Ar from the lithology of #47.

Nagao, K.↗

Coordinated Chemical and Isotopic Imaging of Bells (CM2) Meteorite Matrix

Meteoritic organic matter is a complex conglomeration of species formed in distinct environments and processes in circumstellar space, the interstellar medium, the Solar Nebula and asteroids. Consequently meteorites constitute a unique record of primordial organic chemical evolution. While bulk chemical analysis has provided a detailed description of the range and diversity of organic species present in carbonaceous chondrites, there is little information as to how these species are spatially distributed and their relationship to the host mineral matrix. The distribution of organic phases is nevertheless critical to understanding parent body processes. The CM and CI chondrites all display evidence of low temperature (< 350K) aqueous alteration that may have led to aqueous geochromatographic separation of organics and synthesis of new organics coupled to aqueous mineral alteration. Here we present the results of the first coordinated in situ isotopic and chemical mapping study of the Bells meteorite using a newly developed two-step laser mass spectrometer (mu-L(sup 2)MS) capable of measuring a broad range of organic compounds.

Clemett, S. J.↗

Evidence from Hydrogen Isotopes in Meteorites for a Subsurface Hydrogen Reservoir on Mars

The surface geology and geomorphology of Mars indicates that it was once warm enough to maintain a large body of liquid water on its surface, though such a warm environment might have been transient. The transition to the present cold and dry Mars is closely linked to the history of surface water, yet the evolution of surficial water is poorly constrained. We have conducted in situ hydrogen isotope (D/H) analyses of quenched and impact glasses in three Martian meteorites (Yamato 980459, EETA79001, LAR 06319) by Cameca ims-6f at Digital Terrain Models (DTM) following the methods of [1]. The hydrogen isotope analyses provide evidence for the existence of a distinct but ubiquitous water/ice reservoir (D/H = 2-3 times Earth's ocean water: Standard Mean Ocean Water (SMOW)) that lasted from at least the time when the meteorites crystallized (173-472 Ma) to the time they were ejected by impacts (0.7-3.3 Ma), but possibly much longer [2]. The origin of this reservoir appears to predate the current Martian atmospheric water (D/H equals approximately 5-6 times SMOW) and is unlikely to be a simple mixture of atmospheric and primordial water retained in the Martian mantle (D/H is approximately equal to SMOW [1]). Given the fact that this intermediate-D/H reservoir (2-3 times SMOW) is observed in a diverse range of Martian materials with different ages (e.g., SNC (Shergottites, Nakhlites, Chassignites) meteorites, including shergottites such as ALH 84001; and Curiosity surface data [3]), we conclude that this intermediate-D/H reservoir is likely a global surficial feature that has remained relatively intact over geologic time. We propose that this reservoir represents either hydrated crust and/or ground ice interbedded within sediments. Our results corroborate the hypothesis that a buried cryosphere accounts for a large part of the initial water budget of Mars.

Usui, Tomohiro↗

Petrography and Geochemistry of Lunar Meteorite Miller Range 13317

Miller Range (MIL) 13317 is a 32-g lunar meteorite collected during the 2013-2014 ANSMET (Antarctic Search for Meteorites) field season. It was initially described as having 25% black fusion crust covering a light- to dark-grey matrix, with numerous clasts ranging in size up to 1 cm; it was tenta-tively classified as a lunar anorthositic breccia. Here we present the petrography and geochemistry of MIL 13317, and examine possible pairing relationships with previously described lunar meteorites.

Zeigler, R. A.↗

STXM-XANES Analysis of Organic Matter in Dark Clasts and Halite Crystals in Zag and Monahans Meteorites

Zag and Monahans meteorites (H5) contains xenolithic dark clasts and halite (NaCl) crystals [e.g., 1]. The proposed source of the H chondrites is asteroid 6 Hebe [2]. The modern orbits of 1 Ceres and 6 Hebe essentially cross, with aphelion/perihelion of Ceres and Hebe of 2.99/2.55 and 2.91/1.94 AU (Astronomical Units), respectively. Therefore, Ceres might be the source of the clasts and halite in Zag and Monahans meteorites. Recent results from NASA's Dawn mission shows that bright spots in Ceres's crater may be hydrated magnesium sulfate with some water ice, and an average global surface contains ammoniated phyllosilicates that is likely of outer Solar System origin. One dark clast and all halite crystals in Zag and Monahans meteorites contain carbon-rich particles. We report organic analyses of these carbon-rich particles using carbon, nitrogen, and oxygen X-ray absorption near edge structure (C-, N-, and O-XANES), in order to constrain the origin of the clast and halite crystals.

Kebukawa, Y.↗

Indigenous Carbonaceous Matter in the Nakhla Mars Meteorite

Detailed microanalysis of the Martian meteorite Nakhla has shown there are morphologically distinct carbonaceous features spatially associated with low-T aqueous alteration phases including salts and id-dingsite. A comprehensive suite of analytical instrumentation including optical microscopy, field emission scanning electron microscopy (FESEM), energy dispersive X-ray (EDX) spectroscopy, focused ion beam (FIB) microscopy, transmission electron microscopy (TEM), two-step laser mass spectrometry (mu-L(sup 2)MS), laser mu-Raman spectroscopy, Fourier transform infrared spectroscopy (FTIR), and nanoscale secondary ion mass spectrometry (NanoSIMS) are being used to characterize the carbonaceous matter and host mineralogy. The search for carbonaceous matter on Mars has proved challenging. Viking Landers failed to unambiguously detect simple organics at either of the two landing sites although the Martian surface is estimated to have acquired at least 10(exp15) kg of C as a consequence of meteoritic accretion over the last several Ga. The dearth of organics at the Martian surface has been attributed to various oxidative processes including UV photolysis and peroxide activity. Consequently, investigations of Martian organics need to be focused on the sub-surface regolith where such surface processes are either severely attenuated or absent. Fortuitously since Martian meteorites are derived from buried regolith materials they provide a unique opportunity to study Martian organic geochemistry.

Clemett, S. J.↗

Utilizing Weather RADAR for Rapid Location of Meteorite Falls and Space Debris Re-Entry

This activity utilizes existing NOAA weather RADAR imagery to locate meteorite falls and space debris falls. The near-real-time availability and spatial accuracy of these data allow rapid recovery of material from both meteorite falls and space debris re-entry events. To date, at least 22 meteorite fall recoveries have benefitted from RADAR detection and fall modeling, and multiple debris re-entry events over the United States have been observed in unprecedented detail.

Fries, Marc D.↗

Brachinite-Like Clast in the Kaidun Meteorite: First Report of Primitive Achondrite Material

Kaidun is a brecciated meteorite containing many different types of meteorites. It is composed of carbonaceous, enstatite, ordinary and R chondrites with smaller amounts of basaltic achondrites, impact melt products and unknown [1, 2]. Because of the multiple components and high abundance of carbonaceous chondrites, the Kaidun parent body was probably a large C-type asteroid in order to have accumulated clasts of many unrelated asteroids, and thus Kaidun contains previously unknown materials[1]. It has been suggested that the Kaidun parent body trawled through different regions of the solar system [3], but the formation of Kaidun meteorite is still uncertain. In this abstract, we report the first discovery of a brachinite-like clast in Kaidun.

Higashi, K.↗

Investigation of Effective Material Properties of Stony Meteorites

To assess the threat posed by an asteroid entering Earth's atmosphere, one must predict if, when, and how it fragments during entry. A comprehensive understanding of the Asteroid material properties is needed to achieve this objective. At present, the meteorite material found on Earth are the only objects from an entering asteroid that can be used as representative material and be tested inside a laboratory setting. Therefore, unit cell models are developed to determine the effective material properties of stony meteorites and in turn deduce the properties of asteroids. The unit cell is representative volume that accounts for diverse minerals, porosity, and matrix composition inside a meteorite. The various classes under investigation includes H-class, L-class, and LL-class chondrites. The effective mechanical properties such as Young's Modulus and Poisson's Ratio of the unit cell are calculated by performing several hundreds of Monte-Carlo simulations. Terrestrial analogs such as Basalt and Gabbro are being used to validate the unit cell methodology.

Asteroids↗

Hydrogen in Martian Meteorites

Most volatile studies of Mars have targeted its surface via spacecraft and rover data, and have evidenced surficial water in polar caps and the atmosphere, in the presence of river channels, and in the detection of water bearing minerals. The other focus of Martian volatile studies has been on Martian meteorites which are all from its crust. Most of these studies are on hydrous phases like apatite, a late-stage phase, i.e. crystallizing near the end of the differentiation sequence of Martian basalts and cumulates. Moreover, calculating the water content of the magma a phosphate crystallized from is not always possible, and yet is an essential step to estimate how much water was present in a parent magma and its source. Water, however, is primarily dissolved in the interiors of differentiated planets as hydrogen in lattice defects of nominally anhydrous minerals (olivine, pyroxene, feldspar) of the crust and mantle. This hydrogen has tremendous influence, even in trace quantities, on a planet's formation, geodynamics, cooling history and the origin of its volcanism and atmosphere as well as its potential for life. Studies of hydrogen in nominally anhydrous phases of Martian meteorites are rare. Measuring water contents and hydrogen isotopes in well-characterized nominally anhydrous minerals of Martian meteorites is the goal of our study. Our work aims at deciphering what influences the distribution and origin of hydrogen in Martian minerals, such as source, differentiation, degassing and shock.

Peslier, A. H.↗

Kinetic Damage from Meteorites

Comparing the natural meteorite flux at the Earth's surface to that of space debris, reentering debris is approx. 2 orders of magnitude less of a kinetic hazard at all but the very largest (and therefore rarest) sizes compared to natural impactors. Debris re-entries over several metric tonnes are roughly as frequent as natural impactors, but the survival fraction is expected to be much higher. Kinetic hazards from meteorites are very small, with only one recorded (indirect) injury reported. We expect fatalities to be even more rare, on the order of one person killed per several millennia. That several reports exist of small fragments/sand hitting people during meteorite falls is consistent with our prediction that this should occur every decade or so.

Cooke, W.↗

Historical Trends in U.S. Antarctic Meteorite Allocations, With a Close Look at Cr Chondrites

ANSMET samples have been housed at and allocated from NASA-JSC since 1978. This nearly 40 year history of allocations from the collection has been contemporaneous with many major milestones such as the discovery that we have meteorites from Moon and Mars, missions to S-type asteroids (NEAR, Hayabusa, Dawn), and C-type asteroids (Dawn, Hayabusa 2, and OSIRIS-REx). We look for the possible influence of these major milestones on historical trends in the meteorite allocations, identify other factors that might contribute to allocation trends, and focus on the allocation history of a few select meteorites.

Righter, K.↗