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At least 685 records · Page 38

Technology Development Plan and Preliminary Results for a Low Temperature Hybrid Mars Ascent Vehicle Concept

A hybrid propulsion system is being considered for a potential Mars Ascent Vehicle (MAV) based on its low temperature capability, ability to restart and high performance. The hybrid’s ability to survive in low and variable temperatures reduces power requirements and therefore system mass. Its ability to restart enables a Single Stage to Orbit (SSTO) design, minimizing system complexity. The hybrid’s high-performance (approximately 314 s Isp (I (sub sp)) (specific impulse in seconds) leads to a low total Gross Lift Off Mass (GLOM). These advantages set the hybrid design above the alternatives in the system studies completed at JPL (Jet Propulsion Laboratory). However, this solution has the lowest Technology Readiness Level (TRL) of the propulsion options. Therefore, a technology development effort has been undertaken to raise the TRL of the hybrid option and potentially enable its infusion into a future MAV or other in-space application. The culmination of this technology development is a flight demonstration, which is currently in the planning phases for launch in the early 2020’s.

Karp, Ashley↗

The Impact of Transition-Edge Sensor Design on Internal Thermal Fluctuation Noise and Thermal Conductance

The measured noise in transition-edge sensor (TES) microcalorimeters with a Mo/Au bilayer has been shown to have a significant contribution from internal thermal fluctuation noise (ITFN) between the absorber and the TES. Previous measurements showed the relevant thermal link leading to the noise was the thermal conductance of the TES bilayer, and ITFN has been shown to correlate with the sheet resistance of the TES. As a result, ITFN is particularly significant in devices with a large bilayer sheet resistance. However, because of more favorable transition shapes, such high resistance devices have recently been shown to be preferable under alternating current bias, which is required for the frequency division multiplexed readout baselined for the X-ray Integral Field Unit (X-IFU) instrument on the ATHENA satellite. Therefore, it is important to investigate how else to minimize the ITFN beyond changes to the sheet resistance. In this presentation, we will discuss our investigation of how changes to the TES design can affect ITFN for a fixed sheet resistance. We will present how ITFN is altered by changes to the aspect ratio of the TES, the addition of normal metal banks parallel to the TES current direction, and the size and position of the connections between the absorber and the TES. We will also discuss how these design changes impact the superconducting transition shape, and the thermal conductance from the TES to the thermal bath. These results may provide routes for further improvements of TES performance, and a deeper understanding of the physics of the thermal network in a TES microcalorimeter.

Nicholas A Wakeham↗

Universal Design Principles for Cascade Heterojunction Solar Cells with High Fill Factors and Internal Quantum Efficiencies Approaching 100%

Cascade heterojunction (CHJ) organic solar cells have recently emerged as an alternative to conventional bulk heterojunctions and series-connected tandems due to their significant promise for high internal quantum efficiency (IQE) and broad spectral coverage. However, CHJ devices thus far have also exhibited poor fill factor (FF), resulting in minimal enhancements (or even decreases) in power conversion efficiency (PCE) when compared with single heterojunction (SHJ) cells. In this study, the major variables controlling the CHJ maximum power point and FF are determined using a combinatorial approach. By matching the maximum power point voltage (VMPP) of the constituent parallel-connected heterojunctions (subjunctions) and minimizing the injection barriers intrinsic to CHJs, high FF and PCE can be achieved. Optimized CHJ devices are demonstrated with >99% IQE in the interlayer and a 46% increase in PCE compared to a SHJ reference (4.1% versus 2.8%). Devices with a transparent exciton dissociation layer (EDL)/interlayer/acceptor structure are employed, such that each CHJ has absorption efficiency identical to its interlayer/acceptor SHJ counterpart. Using these results, a clear map of performance as a function of material parameters is developed, providing straightforward, universal design rules to guide future engineering of molecules and layer architectures for CHJ organic photovoltaic devices.

36 MATERIALS SCIENCE↗

An overview of switchgrass phenotypes variability across diverse populations and their implications for conversion to fuels

There have been substantial changes to the human lifestyle over the past two centuries, which are reflected in the amount of fuel we consume to power our day-to-day needs. The way we use these resources has indeed manifested in an overdependence on non-renewable energy sources, such as coal and petroleum, for generating electricity and powering our transportation needs. There is a pressing need to explore alternative ways of fueling our current lifestyle without impacting the environment. Biofuels have long been touted as a sustainable solution for use as drop-in fuels in aviation and maritime applications. Still, they have yet to establish themselves as a competitive commercial alternative, necessitating further research and development. Lignocellulosic biomass is an underutilized resource that is widely accessible for the commercial processing of renewable biofuels. Bioenergy crops, such as switchgrass (Panicum virgatum L.), which can be cultivated on marginal lands with minimal competition for agricultural land, are an ideal and promising candidate for bulk-scale biofuel synthesis. Over the past 30 years, significant progress has been made in breeding and genetically modifying these grasses to enhance their drought resilience and subsequent yields. However, discrepancies in biomass composition can lead to irregular feedstocks for downstream operations, which in turn affect overall production targets for biofuels. Here, this review examines the variability in switchgrass (P. virgatum L.) biomass phenotypes across diverse populations and plant components, and their implications for biofuel conversion. The study highlights significant variations in biomass yield, composition, and cell wall chemistry both between switchgrass genotypes and within individual cultivars. Key findings include differences in cellulose, hemicellulose, and lignin content between leaves and stems, which affect biomass digestibility and ethanol yield. The review also discusses the impact of lignin chemistry, particularly the syringyl/guaicyl (S/G) ratio, on the efficiency of biomass saccharification. Furthermore, it explores how these variations respond differently to various pretreatment techniques, affecting overall biofuel production. We conclude that understanding and quantifying this variability is crucial for optimizing switchgrass as a feedstock for commercial biofuel production, thereby potentially addressing the pressing need for sustainable energy sources in sectors such as aviation.

Kousika, Rohit [Univ. of Tennessee, Knoxville, TN ↗

Prostatic Artery Embolization After Failed Urological Interventions for Benign Prostatic Obstruction: A Case Series of Three Patients

Benign prostate obstruction with associated lower urinary tract symptoms is a common diagnosis with multiple minimally invasive treatment options available. Herein, the authors describe three patients who failed prior different urological interventions who underwent prostate artery embolization with a subsequent improvement in symptoms. The positive response suggests that embolization may be an effective treatment alternative in this subset of patients.

62 RADIOLOGY AND NUCLEAR MEDICINE↗

Upgraded biogas from municipal solid waste for natural gas substitution and CO{sub 2} reduction – A case study of Austria, Italy, and Spain

Highlights: • Biogas can be upgraded to create biomethane, a substitute to natural gas. • Biogas upgrading was applied to landfills and anaerobic digestors in 3 countries. • Up to 0.6% of a country’s consumption of natural gas could be replaced by biomethane. • Italy could save 46% of the national CO{sub 2} emissions attributed to the waste sector. • Scenarios were created to increase biomethane production. - Abstract: Biogas is rich in methane and can be further purified through biogas upgrading technologies, presenting a viable alternative to natural gas. Landfills and anaerobic digestors treating municipal solid waste are a large source of such biogas. They therefore offer an attractive opportunity to tap into this potential source of natural gas while at the same time minimizing the global warming impact resulting from methane emissions in waste management schemes (WMS) and fossil fuel consumption reduction. This study looks at the current municipal solid waste flows of Spain, Italy, and Austria over one year (2009), in order to determine how much biogas is generated. Then it examines how much natural gas could be substituted by using four different biogas upgrading technologies. Based on current waste generation rates, exploratory but realistic WMS were created for each country in order to maximize biogas production and potential for natural gas substitution. It was found that the potential substitution of natural gas by biogas resulting from the current WMS seems rather insignificant: 0.2% for Austria, 0.6% for Italy and 0.3% for Spain. However, if the WMS is redesigned to maximize biogas production, these figures can increase to 0.7% for Austria, 1% for Italy and 2% for Spain. Furthermore, the potential CO{sub 2} reduction as a consequence of capturing the biogas and replacing fossil fuel can result in up to a 93% reduction of the annual national waste greenhouse gas emissions of Spain and Italy.

54 ENVIRONMENTAL SCIENCES↗

Examining and Modeling Oxygen Uncoupling Kinetics of Cu-Based Oxygen Carriers for Chemical Looping with Oxygen Uncoupling (CLOU) in a Drop Tube Fluidized Bed Reactor

Chemical looping combustion with oxygen uncoupling (CLOU) is a promising carbon capture and storage (CCS) technology for conversion of gaseous and solid hydrocarbon fuels where the release of gaseous O 2 from an oxygen carrier is favored at high temperature and low O 2 partial pressure. One promising CLOU material is the copper oxide redox system (CuO–Cu 2 O). The primary objective of this study was to examine the use of a drop tube fluidized bed reactor (DT-FBR) for evaluating the kinetics of oxygen uncoupling with Cu-based oxygen carriers. Appropriate rate expressions from redox experiments are needed to model and scale up CLOU systems. Additionally, the determined oxygen uncoupling kinetic parameters were validated using a computational fluid dynamic model. Two oxygen carriers consisting of 20 wt % CuO/Al 2 O 3 and 9 wt % CuO/Al 2 O 3 were prepared by physical mixing. A third oxygen carrier sample was prepared at 9 wt % CuO/Al 2 O 3 by incipient wetness impregnation. The reaction rates of the copper oxide redox system are strongly dependent on thermodynamic effects of the oxygen partial pressure relative to the equilibrium oxygen partial pressure. The results presented in this paper offer an alternative and simplified kinetic analysis compared to that traditionally presented in the literature for the thermal reduction of copper oxide or other CLOU oxygen carriers. The reactor system used in this study allows for operating parameters to be adjusted, minimizing thermodynamic and mass transfer limitations, which eliminates the need for more complex kinetic/thermodynamic reaction models. The reaction kinetics measured in this study is compared based on the preparation method and the CuO weight percent loading. These results may aid in the development of CLOU technologies during reactor design and process modeling.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Improved Surface Functionalization and Characterization of Membrane-Targeted Semiconductor Voltage Nanosensors

In this work, type-II ZnSe/CdS voltage sensing seeded nanorods (vsNRs) were functionalized with alpha helical peptides and zwitterionic decorated lipoic acids (zw LA). Specific membrane targeting with high loading efficiency and minimal non specific binding was achieved . These vsNRs display quantum yield (QY) modulation as function of membrane potential (MP) changes, as demonstrated at the ensemble level for (i) vesicles treated with valinomycin and (ii) wild type HEK cells under alternating buffers with different [K + ]. ΔF/F of ~ 1% was achieved.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

CO 2 Capture with Capsules of Ionic Liquid/Amines

Carbon capture remains an urgent issue that has gained a great deal of attention over the past few decades. Aqueous amines have excellent selectivity, but present corrosion and volatility issues, whereas ionic liquids (ILs) have negligible volatility and tunable physical properties, but high viscosities. One approach to improve the practical performance of these liquids is encapsulating them in a CO 2 permeable polymer shell to enhance the accessibility of the liquid and the CO 2 absorption rate. In this work, we report the encapsulation of a mixture of amine and IL (i.e., monoethanolamine (MEA) and 1-butyl-3-methylimidazolium tetrafluoroborate ([BMIM][BF 4 ])) and demonstrate enhanced carbon capture performance. A soft-template approach and interfacial polymerization are used to give capsules with liquid core (64 wt %) and polyurea shell. Compared to the bulk liquid, the encapsulated liquid shows improved thermal stability over cycles of absorption at 25 °C, and desorption at 75 °C. The capsules with core of [BMIM][BF 4 ]-MEA show 0.2 mol CO 2 /kg of capsules at 1 bar CO 2 , compared to the bulk liquid, which has 0.05 mol CO 2 /kg of sorbent. This is attributed to the limited evaporation of the amines. Alternatively, the same capsules but with 5 wt % of piperazine (Pz) in the core have doubled gravimetric CO 2 capacity of the capsules (0.4 mol CO 2 /kg of capsules); performance is evaluated over 10 capture–release cycles showing minimal mass loss. Characterization of the CO 2 uptake of the polymer shell itself reveals that the shell contributes only ~10% of the observed capacity, likely attributed to amine functionalities of the polymer. Here, this facile approach to encapsulating such “active” liquids can be applied to other CO 2 selective solvents that are volatile, viscous, and corrosive.

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CH↗

Tomographic Sparse View Selection Using the View Covariance Loss

Standard computed tomography (CT) reconstruction algorithms such as filtered back projection (FBP) and Feldkamp-Davis-Kress (FDK) require many views for producing high-quality reconstructions, which can slow image acquisition and increase cost in non-destructive evaluation (NDE) applications. Over the past 20 years, a variety of methods have been developed for computing high-quality CT reconstructions from sparse views. However, the problem of how to select the best views for CT reconstruction remains open. In this paper, we present a novel view covariance loss (VCL) function that measures the joint information of a set of views by approximating the normalized mean squared error (NMSE) of the reconstruction. We present fast algorithms for computing the VCL along with an algorithm for selecting a subset of views that approximately minimizes its value. Our experiments on simulated and measured data indicate that for a fixed number of views our proposed view covariance loss selection (VCLS) algorithm results in reconstructions with lower NRMSE, fewer artifacts, and greater accuracy than current alternative approaches.

Lin, Jingsong [Purdue University]↗

Microbead Encapsulation for Protection of Electronic Components

Here, this study investigates the application of microbeads as an innovative encapsulation technique to protect electronic components from harsh mechanical strain. Traditional encapsulation methods using hard epoxy provide substantial mechanical support but create thermal expansion mismatch issues, potentially leading to electronic component failure. We explore the use of finely powdered microbeads to achieve protective structures combining stiffness and energy absorption. The research focuses on key variables, including microbead size, microbead roughness, compaction of microbeads, and circuit board mounting in the encapsulation, all of which influence the encapsulation’s effectiveness. Experimental setups and testing protocols were developed to assess the performance of various microbead materials under different impact conditions. Results demonstrate that microbead encapsulation significantly reduces strain on circuit boards, minimizing the risk of damage during mechanical shocks. However, challenges remain, such as optimizing microbead characteristics and modeling their behavior within large-scale circuit board assemblies. Despite these challenges, the findings suggest that microbead encapsulation offers a promising alternative to conventional methods, enhancing the durability and reliability of electronic components in high-stress environments.

42 ENGINEERING↗

Manufacturing of low-background copper electrical components for rare-event detection. Final report

This SBIR Phase I project developed the manufacturing capability for the production of ultra-low-background copper and lead for use in electronic interconnects and support architecture. Copper is an attractive electronic and support material because of its favorable conductivity and mechanical properties. Fortuitously, the material can also be electroplated with high radiopurity, particularly if the electroforming is performed in shielded, buried facilities within which the cosmogenic background is minimized. The machining of the electroformed copper into wires, feedthroughs, and support hardware can potentially introduce impurities through the shop environment or through the dies used in wire-drawing and part formation. During Phase I, we demonstrated an alternative low-cost solution-based approach in which copper nanoparticles are colloidally-grown and self-assembled into solids that can serve as thermal structures- such as cold-fingers, mechanical structures- such as the inner shielding lining, and electronic devices. We demonstrated ultrastrong, high-conductivity free-standing copper conductors during Phase I suitable for battery electrodes, interconnects, and cabling, all components that enable next-generation flexible electronics. In nanoparticle form, copper forms in a crystalline lattice with very low impurity content, but its self-assembly is facilitated by organic capping ligands that can serve as impurity sources. Upon the formation of a colloidal solid, the copper particles can be fused and the organic components evaporated through vacuum annealing. The study of ultra-pure copper was expanded during Phase I to include nanostructured lead, which is an important radiation-shielding material. By growing lead particles in a water-based solution the resulting solution can be poured into the desired form-factor mold, within which it will self-assemble and harden upon evaporation of the water and any organics. The effort during Phase II is designed to complete the development of the manufacturing process and to use that process to deliver high radio-purity copper and lead components to the rare-event detection community so that the noise-floor contribution from the surrounding materials is substantially eliminated.

36 MATERIALS SCIENCE↗

Gyro and accelerometer failure detection and identification in redundant sensor systems.

An algorithm for failure detection and identification for redundant non-orthogonal arrays of single degree of freedom gyros and accelerometers is described which is optimum in the sense that detection occurs as soon as it is no longer possible to account for the instrument outputs as the outputs of good instruments operating within their noise tolerances, and identification occurs as soon as it is true that only a particular instrument failure could account for the actual instrument outputs within the noise tolerance of good instruments. An estimation algorithm is described which minimizes the maximum possible error magnitude for the given set of instrument outputs. Monte Carlo simulation results are presented for the application of the algorithms to an inertial reference unit consisting of six gyros and six accelerometers in two alternate configurations.

Potter, J. E.↗

Cosmological structure formation from soft topological defects

Some models have extremely low-mass pseudo-Goldstone bosons that can lead to vacuum phase transitions at late times, after the decoupling of the microwave background.. This can generate structure formation at redshifts z greater than or approx 10 on mass scales as large as M approx 10 to the 18th solar masses. Such low energy transitions can lead to large but phenomenologically acceptable density inhomogeneities in soft topological defects (e.g., domain walls) with minimal variations in the microwave anisotropy, as small as delta Y/T less than or approx 10 to the minus 6 power. This mechanism is independent of the existence of hot, cold, or baryonic dark matter. It is a novel alternative to both cosmic string and to inflationary quantum fluctuations as the origin of structure in the Universe.

Hill, Christopher T.↗

A widely adaptable habitat construction system utilizing space resources

This study suggests that the cost of providing accommodations for various manned activities in space may be reduced by the extensive use of resources that are commonly found throughout the solar system. Several concepts are proposed for converting these resources into simple products with many uses. Concrete is already being considered as a possible moonbase material. Manufacturing equipment should be as small and simple as possible, which leads to the idea of molding it into miniature modules that can be produced and assembled in large numbers to create any conceivable shape. Automated equipment could build up complex structures by laying down layer after layer in a process resembling stereolithography. These tiny concrete blocks handle compression loads and provide a barrier to harmful radiation. They are joined by a web of tension members that could be made of wire or fiber-reinforced plastic. The finished structure becomes air-tight with the addition of a flexible liner. Wire can be made from the iron modules found in lunar soil. In addition to its structural role, a relatively simple apparatus can bend and weld it into countless products like chairs and shelving that would otherwise need to be supplied from Earth. Wire woven into a loose blanket could be an effective micrometeoroid shield, tiny wire compression beams could be assembled into larger beams which in turn form larger beams to create very large space-frame structures. A technology developed with lunar materials could be applied to the moons of Mars or the asteroids. To illustrate its usefulness several designs for free-flying habitats are presented. They begin with a minimal self-contained living unit called the Cubicle. It may be multiplied into clusters called Condos. These are shown in a rotating tether configuration that provides a substitute for gravity. The miniature block proposal is compared with an alternate design based on larger triangular components and a tetrahedral geometry. The overall concept may be expanded to envision city-sized self-sufficient environments where humans could confortably live their entire lives. One such proposal is the Hive. It is configured around a unique sunlight collection system that could provide all its energy needs and that could be scaled up to compensate for the reduced solar intensity at greater distances from the sun. Its outer perimeter consists of a cylindrical section mated to two conical end walls that taper inwards toward a small aperture at the center of rotation. Light collected by two huge mirrors of unusual design enters the aperture and is redirected to the inside of the cylinder. The conical end walls are shielded from direct sunlight and are designed to radiate heat into space. They are lined with air ducts that passively recirculate the atmosphere while extracting moisture by condensation. Although there is no immediate demand for spacecraft on this scale, their consideration can influence even the earliest stages of the development process.

Wykes, Harry B.↗

Multi-partitioning for ADI-schemes on message passing architectures

A kind of discrete-operator splitting called Alternating Direction Implicit (ADI) has been found to be useful in simulating fluid flow problems. In particular, it is being used to study the effects of hot exhaust jets from high performance aircraft on landing surfaces. Decomposition techniques that minimize load imbalance and message-passing frequency are described. Three strategies that are investigated for implementing the NAS Scalar Penta-diagonal Parallel Benchmark (SP) are transposition, pipelined Gaussian elimination, and multipartitioning. The multipartitioning strategy, which was used on Ethernet, was found to be the most efficient, although it was considered only a moderate success because of Ethernet's limited communication properties. The efficiency derived largely from the coarse granularity of the strategy, which reduced latencies and allowed overlap of communication and computation.

Vanderwijngaart, Rob F.↗

Peak Prediction Using Multi Layer Perceptron (MLP) for Edge Computing ASICs Targeting Scientific Applications

High data rate detectors play an integral part in scientific research and their development is actively pursued at High Energy Physics (HEP) facilities around the world. Edge Machine Learning (ML) offers the ability to reduce data rates by integrating ML algorithms into Application Specific Integrated Circuits (ASICs) on the front end electronics. In this work, we explore a set of neural network architectures for predicting the peak amplitudes in the detector's sensor response. We have designed and synthesized several MLP based neural networks comparing their inference accuracy, power consumption, and area targeting for minimal latency. The neural networks are synthesized in a commercial 65nm process. The effect of quantizing the network's weights and biases on hardware performance and area is reported. We also conduct design space exploration to compare between design alternatives

47 OTHER INSTRUMENTATION↗

ERL with non-scaling fixed field alternating gradient lattice for eRHIC

The proposed eRHIC electron-hadron collider uses a "non-scaling FFAG" (NS-FFAG) lattice to recirculate 16 turns of different energy through just two beam lines located in the RHIC tunnel. This paper presents lattices for these two FFAGs that are optimized for low magnet field and to minimize total synchrotron radiation across the energy range. The higher number of recirculations in the FFAG allows a shorter linac (1.322GeV) to be used, drastically reducing cost, while still achieving a 21.2 GeV maximum energy to collide with one of the existing RHIC hadron rings at up to 250GeV. eRHIC uses many cost-saving measures in addition to the FFAG: the linac operates in energy recovery mode, so the beams also decelerate via the same FFAG loops and energy is recovered from the interacted beam. All magnets will be constructed from NdFeB permanent magnet material, meaning chillers and large magnet power supplies are not needed. This paper also describes a small prototype ERL-FFAG accelerator that will test all of these technologies in combination to reduce technical risk for eRHIC.

43 PARTICLE ACCELERATORS↗