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At least 667 records · Page 37

Phase transition induced strain in ZnO under high pressure

Under high pressure, the phase transition mechanism and mechanical property of material are supposed to be largely associated with the transformation induced elastic strain. However, the experimental evidences for such strain are scanty. The elastic and plastic properties of ZnO, a leading material for applications in chemical sensor, catalyst, and optical thin coatings, were determined using in situ high pressure synchrotron axial and radial x-ray diffraction. The abnormal elastic behaviors of selected lattice planes of ZnO during phase transition revealed the existence of internal elastic strain, which arise from the lattice misfit between wurtzite and rocksalt phase. Furthermore, the strength decrease of ZnO during phase transition under non-hydrostatic pressure was observed and could be attributed to such internal elastic strain, unveiling the relationship between pressure induced internal strain and mechanical property of material. Ultimately, these findings are of fundamental importance to understanding the mechanism of phase transition and the properties of materials under pressure.

36 MATERIALS SCIENCE↗

High power actively Q-switched downhole LIBS analysis systems

An actively Q-switched laser induced breakdown spectroscopy (LIBS) probe, utilizing an optical fiber, a pump beam transmitted through the optical fiber, a coupler, and a lens for collimating the pump beam. The actively Q-switched laser, coupled to a sensor which provides information to a computer that controls a high voltage pulser providing a pulse to a Pockels cell located within the laser which can selectively cause the laser to pulse, resulting in high energy pulses and a second lens for focusing the output pulse such that it creates a plasma or spark. The light from the spark is captured and directed back through an optical system to remote equipment for elemental and/or molecular analysis.

McIntyre, Dustin Langdon↗

Sensor Incipient Fault Impacts on Building Energy Performance: A Case Study on a Multi-Zone Commercial Building

Existing studies show sensor faults/error could double building energy consumption and carbon emissions compared with the baseline. Those studies assume that the sensor error is fixed or constant. However, sensor faults are incipient in real conditions and there were extremely limited studies investigating the incipient sensor fault impacts systematically. This study filled in this research gap by studying time-developing sensor fault impacts to rule-based controls on a 10-zone office building. The control sequences for variable air volume boxes (VAV) with an air handling unit (AHU) system were selected based on ASHRAE Guideline 36-2018: High-Performance Sequences of Operation for HVAC Systems. Large-scale simulations on cloud were conducted (3600 cases) through stochastic approach. Results show (1) The site energy differences could go –3.3% lower or 18.1% higher, compared with baseline. (2) The heating energy differences could go –66.5% lower or 314.4% higher, compared with baseline. (3) The cooling energy differences could go –11.5% lower or 65.0% higher, compared with baseline. (4) The fan energy differences could go 0.15% lower or 6.9% higher, compared with baseline.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

Design Considerations for High-Q Bandpass Microwave Oscillator Sensors Based Upon Resonant Amplification

A series of microwave resonant oscillator sensors were designed and characterized using bandpass planar and volumetric electrical resonators having loaded quality factor (Q) values in the range of 2 to 20. The use of these resonators in positive feedback circuits yielded sensor Q-factors of up to 2 x 107, demonstrating Q-factor amplifications on the order of 106. It is shown that the Q-factor amplification can be increased in a positive feedback system through the selection of feedback loop group delay, allowing use of resonators with lower Qstat values. A low-frequency electromagnetic interference sensing application is demonstrated for two resonant oscillator configurations, showing considerable frequency sensitivity to 45 kHz emitters.

split ring resonator, regenerative feedback, senso↗

The modeling of risk perception in the use of structural health monitoring information for optimal maintenance decisions

This paper proposes an approach to select a maintenance strategy from a predefined set of choices considering the decision maker’s behavioral risk profile. It is assumed that the damage state is characterized by a continuous state parameter probabilistically inferred from observable sensor data. This work applies an engineering application of consequence-based decision-making incorporating the acceptable risk intensity of the decision-maker, i.e., the decision-maker’s (individual or an organization) valuation of the outcome of a decision, using a risk profile model. The utility of a decision-maker is subjective, and this paper considers the fact that different decision-makers mentally assign a different importance factor (the utility) to the seriousness or urgency to take necessary actions with the increasing intensity of structural damage. The approach herein incorporates a layer of human psychology on selecting appropriate maintenance strategies that not only depend on the posterior distribution of unmeasurable damage state but also consider the behavioral risk profile of the decision-maker. Further, the collective decision-making of an organization consisting of many individuals is also investigated. The approach is exemplified in a case study involving life cycle monitoring of a miter gate, part of a lock system enabling navigation of inland waterways.

42 ENGINEERING↗

Impact of the Number of Applied Current Meter Sensors on the Accuracy of Flow Rate Measurements across a Range of Hydroelectric Facilities Indicative of the Domestic Hydroelectric Fleet

The following paper represents the results of an investigation into the impact of the number and placement of Current Meter (CM) flow sensors on the accuracy to which they are capable of predicting the overall flow rate. Flow measurement accuracy is of particular importance in multiunit plants because it plays a pivotal role in determining the operational efficiency characteristics of each unit, allowing the operator to select the unit (or combination of units) which most efficiently meet demand. Several case studies have demonstrated that optimization of unit dispatch has the potential to increase plant efficiencies from between 1 to 4.4 percent [2] [3]. Unfortunately current industry standards do not have an established methodology to measure the flow rate through hydropower units with short converging intakes (SCI); the only direction provided is that CM sensors should be used. The most common application of CM is horizontally, along a trolley which is incrementally lowered across a measurement cross section. As such, the measurement resolution is defined horizontally and vertically by the number of CM and the number of measurement increments respectively. There has not been any published research on the role of resolution in either direction on the accuracy of flow measurement. The work below investigates the effectiveness of flow measurement in a SCI by performing a case study in which point velocity measurements were extracted from a physical plant and then used to calculate a series of reference flow distributions. These distributions were then used to perform sensitivity studies on the relation between the number of CM and the accuracy to which the flow rate was predicted. The following research uncovered that a minimum of 795 plants contain SCI, a quantity which represents roughly 12% of total domestic hydropower capacity. In regards to measurement accuracy, it was determined that accuracy ceases to increase considerably due to strict increases in vertical resolution beyond the application of 49 transects. Moreover the research uncovered that the application of 5 CM (when applied at 49 vertical transects) resulted in an average accuracy of 95.6% and the application of additional sensors resulted in a linear increase in accuracy up to 17 CM which had an average accuracy of 98.5%. Beyond 17 CM incremental increases in accuracy due to the addition of CM was found decrease exponentially. Future work that will be performed in this area will investigate the use of computational fluid dynamics to acquire a broader range of flow fields within SCI.

Flow Measurement↗

High-yield synthesis of SnO{sub 2} nanobelts by water-assisted chemical vapor deposition for sensor applications

Highlights: ► The well crystalline and structurally uniform SnO{sub 2} nanobelts were prepared. ► Au-modified small Sn particle was used as source material to ensure the high yield. ► The SnO{sub 2} nanobelt exhibited better gas sensing property to NO{sub 2} than nanoparticle. ► The SnO{sub 2} nanobelt showed obvious sensing selectivity towards NO{sub 2} over CO and CH{sub 4}. -- Abstract: Well-crystallized one-dimensional (1D) SnO{sub 2} nanobelts were in situ prepared using a simple water-assisted chemical vapor deposition (CVD) method. The small Sn particles with Au-modifications were used as source materials instead of big size Sn grains to ensure the high yield of SnO{sub 2} belts. The Au layer was modified on the small Sn particles by treating Sn powders in HAuCl{sub 4} solution combined with the UV irradiation. The as-prepared SnO{sub 2} nanobelts were characterized by SEM, HRTEM, XRD, EDS and XPS. These results indicate that the growth temperature plays an important role in controlling the length-to-width ratio of nanobelts. The length-to-width ratio decreases with the growth temperature from 850 °C to 1000 °C. The nanobelts prepared at 850 °C shows a single-crystalline tetragonal rutile phase with a high length-to-width ratio (approximately tens of microns in length and 40–70 nm in width). However, below 850 °C, nanobelts cannot be formed. The as-prepared nanobelts exhibited excellent sensing properties compared with SnO{sub 2} nanoparticles and high sensing selectivity towards NO{sub 2}. The high sensing selectivity to NO{sub 2} is attributed to the oxygen vacancies presenting in the as-prepared nanobelts.

36 MATERIALS SCIENCE↗

Addressing a systematic bias in carbon dioxide flux measurements with the EC150 and the IRGASON open-path gas analyzers

Across a global network of eddy covariance flux towers, two relatively new open-path infrared gas analyzers (IRGAs), the IRGASON and the EC150, are increasingly used to measure net carbon dioxide (CO 2 ) fluxes (F c_OP ). Differences in net CO 2 fluxes derived from open- and closed-path IRGAs in general remain poorly constrained. In particular, the performance of the IRGASON and the EC150 for measuring F c_OP has not been characterized yet. These IRGAs measure CO 2 absorption, which is scaled with air temperature and pressure before converting it to instantaneous CO 2 density. This sensor-internal conversion is based on a slow-response thermistor air temperature measurement. In this paper, we test if the high-frequency temperature attenuation causes selectively systematic F c_OP errors that scale with kinematic temperature fluxes. First, we examine the relationship between wintertime F c_OP and kinematic temperature fluxes for eight northern ecosystems. Second, we investigate how residuals between F c_OP and CO 2 fluxes from co-located closed-path IRGAs (F C_CP ) are related to kinematic temperature fluxes for three different ecosystem types (i.e., boreal forest, grassland, and irrigated cropland). We find that kinematic temperature fluxes, but not mean ambient air temperatures or CO 2 flux regime, consistently determine the absolute magnitude of F c_OP errors. This selectively systematic bias causes the most pronounced relative F c_OP errors to occur when “true” CO 2 fluxes are low and kinematic temperature fluxes are high (e.g., northern ecosystems during the winter). The smallest relative errors occur during periods with large “true” CO 2 fluxes and low kinematic temperature fluxes. To address this bias, we replace the slow-response air temperature in the absorption-to-CO 2 density conversion with a fast-response air temperature derived from sonic anemometer measurements. The use of the fast-response air temperature improves the agreement between half-hourly F c_OP and F C_CP for all open- versus closed-path IRGA comparisons. Additionally, cumulative F c_OP and F c_CP sums are more comparable as differences drop from 63 %–13 % to 20 %–8 %. Finally, the improved IRGASON and EC150 performance enhances the ability and confidence to synthesize flux measurements across multiple sites including these two relatively new IRGAs.

47 OTHER INSTRUMENTATION↗

Environmental contaminants activate human and polar bear (Ursus maritimus) pregnane X receptors (PXR, NR1I2) differently

Background: Many persistent organic pollutants (POPs) accumulate readily in polar bears because of their position as apex predators in Arctic food webs. The pregnane X receptor (PXR, formally NR1I2, here proposed to be named promiscuous xenobiotic receptor) is a xenobiotic sensor that is directly involved in metabolizing pathways of a wide range of environmental contaminants. Objectives: In the present study, we comparably assess the ability of 51 selected pharmaceuticals, pesticides and emerging contaminants to activate PXRs from polar bears and humans using an in vitro luciferase reporter gene assay. Results: We found that polar bear PXR is activated by a wide range of our test compounds (68%) but has a slightly more narrow ligand specificity than human PXR that was activated by 86% of the 51 test compounds. The majority of the agonists identified (70%) produces a stronger induction of the reporter gene via human PXR than via polar bear PXR, however with some notable and environmentally relevant exceptions. Conclusions: Due to the observed differences in activation of polar bear and human PXRs, exposure of each species to environmental agents is likely to induce biotransformation differently in the two species. Bioinformatics analyses and structural modeling studies suggest that amino acids that are not part of the ligand-binding domain and do not interact with the ligand can modulate receptor activation. - Highlights: • Comparative study of ligand activation of human and polar bear PXRs. • Polar bear PXR is a promiscuous ligand-activated nuclear receptor but less so than human PXR. • Environmental contaminants activate human and polar bear PXRs differently. • Expression and ligand promiscuity indicate that PXR is a xenosensor in polar bears.

60 APPLIED LIFE SCIENCES↗

Optically detected magnetic resonance imaging

Optically detected magnetic resonance provides ultrasensitive means to detect and image a small number of electron and nuclear spins, down to the single spin level with nanoscale resolution. Despite the significant recent progress in this field, it has never been combined with the power of pulsed magnetic resonance imaging techniques. Here, we demonstrate how these two methodologies can be integrated using short pulsed magnetic field gradients to spatially encode the sample. This result in what we denote as an 'optically detected magnetic resonance imaging' technique. It offers the advantage that the image is acquired in parallel from all parts of the sample, with well-defined three-dimensional point-spread function, and without any loss of spectroscopic information. In addition, this approach may be used in the future for parallel but yet spatially selective efficient addressing and manipulation of the spins in the sample. Such capabilities are of fundamental importance in the field of quantum spin-based devices and sensors.

71 CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSIC↗

Evaluation of radiation hardness of High-Voltage silicon vertical JFETs

In the future ATLAS Inner Tracker, each silicon strip module will be equipped with a switch able to separate the high voltage supply from the sensor in case the latter becomes faulty. The switch, placed in between the HV supply and the sensor, needs to sustain a high voltage in its OFF state, to offer a low resistance path for the sensor leakage current in the ON state, and be radiation hard up to 1.2 * 10 15 neq/cm 2 along with other requirements. While GaN JFETs have been selected as suitable rad-hard switch, a silicon vertical HV-JFET was developed by Brookhaven National Laboratory as an alternative option. Pre-irradiation results showed the functionality of the device and proved that the silicon HV-JFET satisfied the pre-irradiation requirements for the switch. To assess its suitability after irradiation, a few p-type HV-JFETs have been neutron irradiated at Jozef Stefan Institute (JSI, Ljubljana, Slovenia). Overall, this paper reports the static characterization of these irradiated devices and the TCAD numerical simulations used to get an insight of the physics governing the post-irradiation behaviour.

47 OTHER INSTRUMENTATION↗

Preliminary engineering assessment of the HCLL and HCPB Neutron Activation System

The Neutron Activation System (NAS) is one of the four types of neutronics sensors considered for the testing of the HCLL and HCPB Test Blanket Module (TBM) in ITER. It measures the absolute neutron flux intensity with information on the neutron spectrum in selected positions of the TBM. The working principle of the NAS is as follows: the system moves small activation probes (capsules) into selected positions in the TBM (irradiation ends) by means of pneumatic transport with pressurized helium gas; the capsules are irradiated for a selected period, depending on their materials composition (several tens of seconds up to the full plasma pulse length); immediately after the irradiation they are extracted and transported to a gamma spectrometer by means of the same pneumatic transport system; the gamma spectrometer determines the induced gamma activity; the neutron flux and neutron fluence is calculated from the measured gamma activity and the known activation cross section of the materials in the activation probe; after the measurement the capsule is sent either to a disposal or storage (for later measurement). This paper summarizes the results of the feasibility assessment of the TBM NAS in the conceptual design phase, including design justification, identification of requirements based on the expected operating conditions in ITER and preliminary engineering assessment of the activation materials, irradiation ends integration in the modules design and the counting station. (authors)

46 INSTRUMENTATION RELATED TO NUCLEAR SCIENCE AND ↗

Post-fire time series of sensor and geochemistry sample data from surface water, groundwater, precipitation, soil, and vegetation across Oak Creek watershed, Washington

This dataset supports a broader study examining wildfire impacts on hydrologic connectivity across 5 sites within the Oak Creek watershed and the resulting biogeochemical impacts. Stream sites were selected using the Advanced Terrestrial Simulator (ATS) hydrologic model to identify locations with varying groundwater contributions and hydrologic responses across different burn severity scenarios. The Retreat Fire burned from July 23 to August 2 in 2024, affecting the five study sites at varying burn severities. Each site is equipped with YSI EXO2 sondes logging sub-hourly throughout the year, and grab samples are collected approximately every six weeks. YSI sondes are used to measure temporally resolved proxies for groundwater inputs (specific conductivity) and organic matter (fluorescent dissolved organic matter; fDOM) along with basic water quality and depth. Grab samples of surface water, groundwater, and precipitation are analyzed for water stable isotopes and conductivity to understand endmembers for hydrologic mixing Grab samples of surface water, groundwater, soil water, and litter/vegetation/soil leachates are analyzed for organic matter composition measured by Fourier-Transform Ion Cyclotron Resonance Mass Spectrometry (FTICR-MS) to understand organic matter dynamics. Game camera photos are provided in a separate data package available at https://data.ess-dive.lbl.gov/datasets/doi:10.15485/3018598. Future versions of this dataset will include time series data from YSI EXO2 sondes (fDOM, dissolved oxygen, temperature, depth, specific conductance, turbidity, pH), BaroTROLL sensors (air temperature and barometric pressure), rain gauges (precipitation), and data from the soil and vegetation samples. Because this study is ongoing, this data package will be updated regularly to include newly collected data and the additional data types. For details on how to navigate data packages generated by this project, see https://data.ess-dive.lbl.gov/portals/PNNLRiverCorridorSFA/About. In addition to a readme, this data package also includes a file-level metadata (FLMD) file that describes each file and a data dictionary (DD) that describes all column/row headers and variable definitions. This dataset is comprised of (1) a folder of field photos; (2) a folder of surface water sample data; (3) a folder of raw Fourier transform ion cyclotron resonance mass spectrometry (FTICR-MS) data; (4) a data checks report; (5) file-level metadata; (6) data dictionary; (7) field metadata; (8) readme; (9) international generic sample number (IGSN) mapping file; and (10) field protocols. The sample data subfolder contains (1) dissolved organic carbon (DOC, measured as non-purgeable organic carbon, NPOC) data and averages; (2) total dissolved nitrogen data and averages; (3) stable water isotopes and averages; (4) methods codes; (5) FTICR-MS methods; and (15) a subfolder of 9.4 Tesla (9.4T) FTICR-MS data. This folder contains the processed data and three subfolders, one containing the .xml files, one containing the water CoreMS output files, and the other containing instructions and scripts for processing the files in CoreMS (https://github.com/EMSL-Computing/CoreMS). All files are .csv, .pdf, .R, .xml, .d, .html, .Rmd, .py, .cal, .json, .jpg, .jpeg, .png, .mov, or .mp4.

Biogeochemistry↗

Barium ion sensing with IPG K + molecular probes

Fluorophores covalently bound to azacrown ether ionophores can be assembled into sensitive turn-on chemosensors. The size specificity and electron-rich nature of the ionophore's binding domain contribute to both selectivity and strong turn-on fluorescence sensing by various mechanisms when properly constructed. Aza-18-crown-6 ethers are quite selective for binding to K + and Ba 2+ , yet the more electron-withdrawing dicationic nature of barium imposes a larger electronic effect on turn-on fluorescent sensors. Barium chemosensors can be important for measuring soluble Ba 2+ in drinking water and have gained recent attention for their potential to enhance the detection of rare events in xenon decay. Here we quantify the capability of three chemosensors, marketed for biologically useful K + sensing, as effective probes for Ba 2+ ions. Here, we present measurements from bulk spectrofluorometry to characterize the system in aqueous solutions and demonstrate the usefulness of these species for low-background single-ion fluorescence microscopy, revealing new candidates for Ba 2+ sensing.

Miller, R. L. [Department of Chemistry and Biochem↗

Compiler-Directed Soft Error Detection and Recovery to Avoid DUE and SDC via Tail-DMR

This article presents Clover, a compiler-directed soft error detection and recovery scheme for lightweight soft error resilience. The compiler carefully generates soft-error-tolerant code based on idempotent processing without explicit checkpoints. During program execution, Clover relies on a small number of acoustic wave detectors deployed in the processor to identify soft errors by sensing the wave made by a particle strike. To cope with DUEs (detected unrecoverable errors) caused by the sensing latency of error detection, Clover leverages a novel selective instruction duplication technique called tail-DMR (dual modular redundancy) that provides a region-level error containment. Once a soft error is detected by either the sensors or the tail-DMR, Clover takes care of the error as in the case of exception handling. To recover from the error, Clover simply redirects program control to the beginning of the code region where the error is detected. The experimental results demonstrate that the average runtime overhead is only 26%, which is a 75% reduction compared to that of the state-of-the-art soft error resilience technique. In addition, this article evaluates an alternative technique called tail-wait, comparing it to Clover. According to the evaluation with the different processor configurations and the various error detection latencies, Clover turns out to be a superior technique, achieving 1.06 to 3.49× speedup over the tail-wait.

Computer Science↗

TRANSENSOR: Transformer Real-time Assessment INtelligent System with Embedded Network of Sensors and Optical Readout. Final Report

Utilities across the world are wrestling with evolving market dynamics, population growth and climate change. Distributed Energy Resources (DERs) such as solar photovoltaics, distributed generators and energy storage systems are becoming important parts of the U.S. energy mix. These factors are driving an increasing need for low-cost grid asset monitoring. Aside from being costly, traditional utility monitoring systems are not sufficiently robust and do not provide real-time visibility into the condition of grid assets such as transformers. Lack of accurate real-time measurements on performance has resulted in the use of lagging indicators, such as oil sample analysis. To address this need, an innovative embedded optical sensing technology, Transformer Real-time Assessment Intelligent System (TRANSENSOR) was developed, validated and demonstrated in this project. To date, TRANSENSOR has focused on transformers but is extendable to other grid assets. In addition to the technology being embedded into new transformers during manufacturing, a retrofit configuration that can be installed on existing transformers in the field was also developed. It is anticipated that the ability to retrofit existing transformers will help accelerate adoption of the underlying TRANSENSOR technology. Phase 1 of the project focused on laboratory development and qualification of the technology. Following iterations and exploration of relevant optical sensing modalities and multiplexed configurations of interest for the transformer environment, an effective candidate configuration was agreed upon, down-selected and custom-designed for embedding into General Electric (GE) network transformers. Two new GE 500 kilovolt ampere (kVA), 27 kilovolt (kV) distribution network transformers were built with embedded fiber-optic (FO) sensors and successfully qualified per industry standards at GE’s Shreveport, Louisiana facility during Phase 1 of the project. Following the successful completion of Phase 1, the team proceeded to Phase 2, which focused on a field demonstration of the technology. Over Phase 2, the first new GE transformer built with embedded fiber-optic sensors was installed in an above-ground cage and connected to the grid at Con Edison’s Astoria facility. A second transformer equipped with TRANSENSOR was installed in an underground vault. Additionally, an older (1982 year model) GE transformer in an above-ground cage was retrofitted with fiber- optic sensors and reconnected to the grid at ConEd’s facility. Analysis of data acquired from the sensors showed interesting correlations with transformer loading. Additionally, key events such as transformer low-voltage network connection, primary-side energizing, and a pressure loss event from an oil sampling were detected by the TRANSENSOR system. Online data processing/feature extraction algorithms for the second transformer in the underground vault detected key features and event alerts that were transmitted through a wireless 4G connection. The remote deployment concept showed promising results with data collection running for a total of 8 months across the three (3) GE transformers instrumented for the Phase 2 field demonstration. This sets the stage well for further development and commercialization.

24 POWER TRANSMISSION AND DISTRIBUTION↗

Adopting occupancy-based HVAC controls in commercial building energy codes: Analysis of cost-effectiveness and decarbonization potential

Recent research has shown the energy-saving potential of occupancy-based HVAC controls (OBCs) in commercial buildings. However, building energy codes have not fully adopted this technology. This study aims to evaluate the cost-effectiveness and decarbonization benefits of OBCs and provide guidance for integrating occupancy sensors into building energy code development. To this end, a parametric simulation using EnergyPlus and a nationwide cost-effectiveness analysis are carried out considering three building types and 40 representative cities in the U.S. Here, the findings reveal that the current cost-effectiveness performance of OBCs is limited due to the high cost of occupancy sensors. However, incorporating the societal cost of carbon factor in future energy and environmental policy could greatly enhance the actual cost-effectiveness performance. Besides, a reduction in the cost of occupancy sensors to approximately 60% of the current price level could also greatly shorten the discounted payback period of OBCs. Additionally, OBCs demonstrate significant potential in building decarbonization, with potential CO 2 emissions savings of more than 5.56 million metric tons across the three building types and 40 selected cities. Finally, policy implications are provided to guide the incorporation of occupancy-based HVAC controls in future energy codes.

32 ENERGY CONSERVATION, CONSUMPTION, AND UTILIZATI↗

AN EXPERIMENTAL STUDY OF FUEL SELECTION FOR A GASOLINE MULTI-MODE

In this study of fuels of different reactivities and their performance in a low-temperature combustion (LTC) engine. The engine was a 2.2L CRDI engine code D4HB provided by industry partner Hyundai America Technical Center inc. (HATCI). The engine was instrumented with in-cylinder pressure sensors allowing for monitoring of the combustion process. First, the engine was operated with standard US pump grade gasoline, Research Octane number (RON) 91 E10, to find initial operation conditions as well as control points of stable operation for daily checks on system conditions. Tested were 8 different fuel blends, the four base blends were provided by Phillips 66 (P66) with a RON value ranging from 60 to 91, and three other variations of these fuels were formulated by splash blending alcohols, iso-butanol, and ethanol, with the RON60 fuel and the final blend, was US RON91 E10 pump gasoline. Using these 8 fuels, the low load performance was analyzed allowing a selection of one of the fuels to be made to proceed with experimentation. To study the low load performance of each fuel, the load was decreased until combustion became too unstable to continue. This was done at 1500 rpm with all of the fuels. At 1200 rpm, the same methodology was applied, though all of the fuels were not tested, only the fuels which showed promise at 1500 rpm. Meaning that the lowest targeted load was achieved without any aid to the combustion process other than advancing combustion, increasing intake air temperature (IAT) for example was not done to maintain consistency across all fuels. The same methodology was applied at 800 rpm based upon the 1200 rpm results to see the ability of the engine to idle with the given fuel. It was found that fuel with a RON of 80 showed good low load performance while allowing for high load performance to be maintained. A blend of 25% Iso-Butanol and 75% RON 60 equated to a RON of 80 and showed good low load performance and showed peak indicated thermal efficiency (ITE) numbers of 46% at 17 bar indicated mean effective pressure (IMEP) and 2200 rpm.

02 PETROLEUM↗